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1.发明申请Transition Metal-Containing Catalysts and Processes for Their Preparation and Use As Oxidation and Dehydrogenation Catalysts 有权过渡金属的催化剂及其制备和使用作为氧化和脱氢催化剂的方法公开(公告)号：US20110301381A1
公开(公告)日：2011-12-08
申请号：US13049496
申请日：2011-03-16
申请人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan Arhancet
发明人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan Arhancet
CPC分类号： B01J27/24 , B01J21/18 , B01J23/40 , B01J23/72 , B01J27/22 , B01J35/023 , B01J35/1023 , B01J35/1028 , B01J37/084 , B82Y30/00 , C07C209/68 , C07C249/02 , C07F9/3813 , Y02P20/582 , C07C251/06
摘要： This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation and dehydrogenation reactions, including the preparation of secondary amines by the catalytic oxidation of tertiary amines and the preparation of carboxylic acids by the catalytic dehydrogenation of alcohols.
摘要翻译： 本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。 本发明还涉及催化氧化和脱氢反应的领域，包括通过叔胺的催化氧化制备仲胺和通过醇的催化脱氢制备羧酸。
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2.发明授权Transition metal-containing catalysts and processes for their preparation and use as oxidation and dehydrogenation catalysts 有权过渡金属的催化剂及其制备和使用的方法作为氧化和脱氢催化剂公开(公告)号：US07932419B2
公开(公告)日：2011-04-26
申请号：US10919028
申请日：2004-08-16
申请人： Fuchen Liu , Juan Arhancet , James P. Coleman , Martin P. McGrath
发明人： Fuchen Liu , Juan Arhancet , James P. Coleman , Martin P. McGrath
IPC分类号： C07F9/22
CPC分类号： B01J27/24 , B01J21/18 , B01J23/40 , B01J23/72 , B01J27/22 , B01J35/023 , B01J35/1023 , B01J35/1028 , B01J37/084 , B82Y30/00 , C07C209/68 , C07C249/02 , C07F9/3813 , Y02P20/582 , C07C251/06
摘要： This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation and dehydrogenation reactions, including the preparation of secondary amines by the catalytic oxidation of tertiary amines and the preparation of carboxylic acids by the catalytic dehydrogenation of alcohols.
摘要翻译： 本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。 本发明还涉及催化氧化和脱氢反应的领域，包括通过叔胺的催化氧化制备仲胺和通过醇的催化脱氢制备羧酸。
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3.发明授权Transition metal-containing catalysts and processes for their preparation and use as oxidation and dehydrogenation catalysts 有权过渡金属的催化剂及其制备和使用的方法作为氧化和脱氢催化剂公开(公告)号：US08697904B2
公开(公告)日：2014-04-15
申请号：US13049496
申请日：2011-03-16
申请人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan Arhancet
发明人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan Arhancet
CPC分类号： B01J27/24 , B01J21/18 , B01J23/40 , B01J23/72 , B01J27/22 , B01J35/023 , B01J35/1023 , B01J35/1028 , B01J37/084 , B82Y30/00 , C07C209/68 , C07C249/02 , C07F9/3813 , Y02P20/582 , C07C251/06
摘要： This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation and dehydrogenation reactions, including the preparation of secondary amines by the catalytic oxidation of tertiary amines and the preparation of carboxylic acids by the catalytic dehydrogenation of alcohols.
摘要翻译： 本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。 本发明还涉及催化氧化和脱氢反应的领域，包括通过叔胺的催化氧化制备仲胺和通过醇的催化脱氢制备羧酸。
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公开(公告)号：US07390920B2
公开(公告)日：2008-06-24
申请号：US10923416
申请日：2004-08-20
申请人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan Arhancet
发明人： James P. Coleman , Martin P. McGrath , Fuchen Liu , Juan Arhancet
CPC分类号： B01J21/18 , B01J23/40 , B01J23/626 , B01J23/72 , B01J23/74 , B01J23/89 , B01J23/8906 , B01J23/8913 , B01J27/22 , B01J27/24 , B01J31/1616 , B01J31/1805 , B01J31/183 , B01J35/0033 , B01J35/023 , B01J35/10 , B01J35/1033 , B01J37/0203 , B01J37/0205 , B01J37/082 , B01J37/084 , B01J2231/70 , B01J2231/763 , B01J2531/64 , B01J2531/66 , B01J2531/842 , B01J2531/845 , C07C209/68 , C07C249/02 , C07F9/3813 , Y02P20/588 , C07C251/06
摘要： This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation, including the preparation of secondary amines by the catalytic oxidation of tertiary amines.
摘要翻译： 本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。 本发明还涉及催化氧化领域，包括通过叔胺的催化氧化制备仲胺。
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公开(公告)号：US20080318768A1
公开(公告)日：2008-12-25
申请号：US12124497
申请日：2008-05-21
IPC分类号： B01J21/18
CPC分类号： B01J21/18 , B01J23/40 , B01J23/626 , B01J23/72 , B01J23/74 , B01J23/89 , B01J23/8906 , B01J23/8913 , B01J27/22 , B01J27/24 , B01J31/1616 , B01J31/1805 , B01J31/183 , B01J35/0033 , B01J35/023 , B01J35/10 , B01J35/1033 , B01J37/0203 , B01J37/0205 , B01J37/082 , B01J37/084 , B01J2231/70 , B01J2231/763 , B01J2531/64 , B01J2531/66 , B01J2531/842 , B01J2531/845 , C07C209/68 , C07C249/02 , C07F9/3813 , Y02P20/588 , C07C251/06
摘要： This invention relates to the field of heterogeneous catalysis, and more particularly to catalysts including carbon supports having formed thereon compositions which comprise a transition metal in combination with nitrogen and/or carbon. The invention further relates to the fields of catalytic oxidation, including the preparation of secondary amines by the catalytic oxidation of tertiary amines.
摘要翻译： 本发明涉及非均相催化领域，更具体地说涉及包括其上形成的碳载体的催化剂，其包含与氮和/或碳组合的过渡金属。 本发明还涉及催化氧化领域，包括通过叔胺的催化氧化制备仲胺。
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公开(公告)号：US07129373B2
公开(公告)日：2006-10-31
申请号：US10366947
申请日：2003-02-14
CPC分类号： B01J31/1616 , B01J21/18 , B01J23/626 , B01J23/74 , B01J23/89 , B01J23/8906 , B01J23/8913 , B01J31/1805 , B01J31/183 , B01J35/0033 , B01J35/023 , B01J35/10 , B01J35/1033 , B01J37/0203 , B01J37/0205 , B01J37/082 , B01J2531/842 , B01J2531/845 , C07C209/68 , C07F9/3813 , Y02P20/588
摘要： An oxidation catalyst is prepared by pyrolyzing a source of iron and a source of nitrogen on a carbon support. Preferably, a noble metal is deposited over the modified support which comprises iron and nitrogen bound to the carbon support. The catalyst is effective for oxidation reactions such as the oxidative cleavage of tertiary amines to produce secondary amines, especially the oxidation of N-(phosphonomethyl)iminodiacetic acid to N-(phosphonomethyl)glycine.
摘要翻译： 通过在碳载体上热解铁源和氮源来制备氧化催化剂。 优选地，贵金属沉积在改性载体上，其包含结合到碳载体上的铁和氮。 该催化剂对氧化反应有效，例如叔胺的氧化裂解产生仲胺，特别是N-（膦酰基甲基）亚氨基二乙酸氧化为N-（膦酰基甲基）甘氨酸。
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公开(公告)号：US20100041546A1
公开(公告)日：2010-02-18
申请号：US12604629
申请日：2009-10-23
CPC分类号： B01J31/1616 , B01J21/18 , B01J23/626 , B01J23/74 , B01J23/89 , B01J23/8906 , B01J23/8913 , B01J31/1805 , B01J31/183 , B01J35/0033 , B01J35/023 , B01J35/10 , B01J35/1033 , B01J37/0203 , B01J37/0205 , B01J37/082 , B01J2531/842 , B01J2531/845 , C07C209/68 , C07F9/3813 , Y02P20/588
摘要： An oxidation catalyst is prepared by pyrolyzing a source of iron and a source of nitrogen on a carbon support. Preferably, a noble metal is deposited over the modified support which comprises iron and nitrogen bound to the carbon support. The catalyst is effective for oxidation reactions such as the oxidative cleavage of tertiary amines to produce secondary amines, especially the oxidation of N-(phosphonomethyl)iminodiacetic acid to N-(phosphonomethyl)-glycine.
摘要翻译： 通过在碳载体上热解铁源和氮源来制备氧化催化剂。 优选地，贵金属沉积在改性载体上，其包含结合到碳载体上的铁和氮。 催化剂对氧化反应有效，如叔胺的氧化裂解产生仲胺，特别是N-（膦酰基甲基）亚氨基二乙酸氧化为N-（膦酰基甲基） - 甘氨酸。
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8.发明授权
公开(公告)号：US5457147A
公开(公告)日：1995-10-10
申请号：US383046
申请日：1995-02-03
摘要： A process for preparing a controlled functional density poly(secondary amine) comprising: (a) contacting a polymer containing olefinic unsaturation with carbon monoxide in hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst to produce a controlled functional density polyaldehyde containing reactive carbon-carbon double bonds, and (b) contacting the polyaldehyde with hydrogen and a primary amine under reductive amination conditions in the presence of a ruthenium-containing imine hydrogenation catalyst or (b.sup.1) contacting the polyaldehyde with a sterically hindered aliphatic or cycloaliphatic primary amine or an aromatic primary amine under reductive amination conditions in the presence of an alkali metal borohydride to produce poly(secondary amine) having a substantially equivalent ratio of secondary amine groups to reactive carbon-carbon double bonds as the ratio of aldehyde groups to reactive carbon-carbon double bonds in the polyaldehyde.
摘要翻译： 一种制备受控功能密度聚（仲胺）的方法，包括：（a）在加氢甲酰化条件下，在加氢甲酰化催化剂存在下，使含有烯属不饱和的聚合物与一氧化碳在氢气中接触，以产生受控的功能密度聚醛， 碳双键，和（b）在还原胺化条件下，在含钌亚胺氢化催化剂存在下使聚醛与伯胺接触，或（b1）使多醛与空间位阻的脂族或脂环族伯胺或 芳族伯胺在还原胺化条件下在碱金属硼氢化物存在下反应生成具有基本上当量的仲胺基与反应性碳 - 碳双键的比例的聚（仲胺）作为醛基与反应性碳 - 碳双重比例 多醛中的键。
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公开(公告)号：US5382629A
公开(公告)日：1995-01-17
申请号：US181937
申请日：1994-01-18
申请人： Aubert Y. Coran , Samuel J. Tremont , Leonard H. Davis , Frederick Ignatz-Hoover , Martin P. McGrath
发明人： Aubert Y. Coran , Samuel J. Tremont , Leonard H. Davis , Frederick Ignatz-Hoover , Martin P. McGrath
IPC分类号： C08K5/17 , C08C19/34 , C08F8/32 , C08K3/06 , C08K13/02 , C08L9/00 , C08L21/00 , C08L23/16 , C08L15/00 , C08L23/26
摘要： Vulcanizable rubber compositions are disclosed which contain co-activator of vulcanization which is a polymeric amine, that is, a hydrocarbon polymer with pendent alkyl amine groups. The co-activators impart increased rates of vulcanization with little decrease in scorch delay and very little increase in the modulus of the cured compositions. No increase in heat build-up or decrease in flex-fatigue life is shown. Typical polymers forming the backbone of the co-activators include EPDM rubber and polymers from butadiene or isoprene, with optional co-monomers.
摘要翻译： 公开了可硫化的橡胶组合物，其含有作为聚合胺的硫化共活化剂，即具有侧链烷基胺基团的烃聚合物。 共活化剂赋予硫化速度提高，焦烧延迟几乎不降低，固化组合物的模量几乎没有增加。 显示不增加热积聚或减少疲劳寿命。 形成共活化剂主链的典型聚合物包括EPDM橡胶和来自丁二烯或异戊二烯的聚合物，以及任选的共聚单体。
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公开(公告)号：US5457155A
公开(公告)日：1995-10-10
申请号：US383045
申请日：1995-02-03
摘要： A process for preparing a controlled functional density poly(secondary amine) comprising: (a) contacting a polymer containing olefinic unsaturation with carbon monoxide in hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst to produce a controlled functional density polyaldehyde containing reactive carbon-carbon double bonds, and (b) contacting the polyaldehyde with hydrogen and a primary amine under reductive amination conditions in the presence of a ruthenium-containing imine hydrogenation catalyst or (b.sup.1) contacting the polyaldehyde with a sterically hindered aliphatic or cycloaliphatic primary amine or an aromatic primary amine under reductive amination conditions in the presence of an alkali metal borohydride to produce poly(secondary amine) having a substantially equivalent ratio of secondary amine groups to reactive carbon-carbon double bonds as the ratio of aldehyde groups to reactive carbon-carbon double bonds in the polyaldehyde.
摘要翻译： 一种制备受控功能密度聚（仲胺）的方法，包括：（a）在加氢甲酰化条件下，在加氢甲酰化催化剂存在下，使含有烯属不饱和的聚合物与一氧化碳在氢气中接触，以产生受控的功能密度聚醛， 碳双键，和（b）在还原胺化条件下，在含钌亚胺氢化催化剂存在下使聚醛与伯胺接触，或（b1）使多醛与空间位阻的脂族或脂环族伯胺或 芳族伯胺在还原胺化条件下在碱金属硼氢化物存在下反应生成具有基本上当量的仲胺基与反应性碳 - 碳双键的比例的聚（仲胺）作为醛基与反应性碳 - 碳双重比例 多醛中的键。
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