公开(公告)号：US3652716A

公开(公告)日：1972-03-28

申请号：US3652716D

申请日：1969-07-01

Applicant: GEN ELECTRIC

Inventor： HOLUB FRED F ,  EVANS MILTON L

IPC: C08G63/685 ,  C08G63/91 ,  C08L67/06 ,  C08F27/08

CPC classification number: C08G63/91 ,  C08G63/6858 ,  C08L67/06 ,  Y10S525/905 ,  Y10S525/906 ,  C08L71/00

Abstract: POLYESTERS HAVING AT LEAST ONE CHEMICALLY COMBINED ALIPHATICALLY UNSATURATED IMIDO RADICAL, SUCH AS A MALEIMIDO RADICAL ARE PROVIDED AND A METHOD FOR MAKING SUCH MATERIALS. REACTION CAN BE EFFECTED BETWEEN A POLYESTER AND AN IMIDO-SUBSTITUTED ACYLHALIDE, SUCH AS A MALEIMIDOBENZOYLCHLORIDE IN THE PRESENCE OF AN ACID ACCEPTOR. BLENDS OF THE IMIDO-SUBSTITUTED POLYESTER AND A VARIETY OF ALIPHATICALLY UNSATURATED ORGANIC MONOMERS, SUCH AS STYRENE, CHLOROSTYRENE, DIALLYLPHTHALATE, N-PHENYLMALEIMIDE, BISMALEMIDES OR ORGANIC POLYMERS SUCH AS POLYSTYRENES, STYRENE-BUTADIENE BLOCK COPOLYMERS, POLYVINYLFLUORIDE, POLYVINYLCHLORIDE, POLYESTERS, POLYSULFONE, POLYSULFONE ETHERS, POLYCARBONATE, POLYPHENYLENE OXIDES, EPOXY RESINS, PHENOL-FORMALDEHYDE RESINS, ACRYLONITRILE BUTADIENE STYRENE TERPOLYMERS, ETC., ALSO ARE PROVIDED. THE IMIDO-SUBSTITUTED POLYESTER COMPOSITIONS OF THE PRESENT INVENTION CAN BE EMPLOYED AS COATINGS, VARNISHES, INJECTION MOLDING COMPOUNDS, LAMINATING COMPOUNDS, ETC.

公开(公告)号：US3622529A

公开(公告)日：1971-11-23

申请号：US3622529D

申请日：1969-03-14

Applicant: GEN ELECTRIC

Inventor： EVANS MILTON L

IPC: C08L83/04 ,  C08F21/04

CPC classification number: C08L83/04 ,  C08G77/16 ,  C08G77/24 ,  C08G77/26 ,  C08L2666/44

Abstract: Composition stable under substantially anhydrous conditions and curable to the solid, elastic state in the presence of moisture which comprises a silanol chain-stopped polydiorganosiloxane in which the organo groups are selected from the group consisting of hydrocarbyl, halohydrocarbyl and cyanoalkyl and an imidatosilane of the formula

WHEREIN R5 and R6 are each aliphatic hydrocarbyl, a is an integer of 2 to 4, inclusive, b is an integer of 0 to 2, inclusive, d is an integer of 0 to 1, and the sum of a, b and d is 4.

WHEREIN R4 is an organic radical selected from the group consisting of aliphatic hydrocarbyl, aliphatic halohydrocarbyl, aliphatic nitrohydrocarbyl, and

WHEREIN R1 is an organic radical of not more than 18 carbon atoms selected from the group consisting of hydrogen, hydrocarbyl, halohydrocarbyl and cyanoalkyl, R. and R2 are each organic radicals of not more than 18 carbon atoms selected from the group consisting of hydrocarbyl, halohydrocarbyl, nitrohydrocarbyl and alkoxyhydrocarbyl, R3 is an organic radical of not more than 18 carbon atoms selected from the group consisting of hydrogen, hydrocarbyl, halohydrocarbyl, nitrohydrocarbyl, alkoxyhydrocarbyl, dialkylamino and

公开(公告)号：US3665026A

公开(公告)日：1972-05-23

申请号：US3665026D

申请日：1969-03-14

Applicant: GEN ELECTRIC

Inventor： EVANS MILTON L

IPC: C07F7/02 ,  C07F7/10 ,  C07F7/18 ,  C08L83/04 ,  C07F7/04

CPC classification number: C07F7/1868 ,  C07F7/025 ,  C07F7/10 ,  C08L83/04 ,  C08L2666/44

Abstract: Compound of the formula: WHEREIN R1 and R7 are each organic radicals of not more than 18 carbon atoms selected from the group consisting of hydrogen, hydrocarbyl, halohydrocarbyl and cyanoalkyl, R and R2 are each organic radicals of not more than 18 carbon atoms selected from the group consisting of hydrocarbyl, halohydrocarbyl, nitrohydrocarbyl and alkoxyhydrocarbyl, R3 is an organic radical of not more than 18 carbon atoms selected from the group consisting of hydrogen, hydrocarbyl, halohydrocarbyl, nitrohydrocarbyl, alkoxyhydrocarbyl, dialkylamino and WHEREIN R4 is an organic radical selected from the group consisting of aliphatic hydrocarbyl, aliphatic halohydrocarbyl, aliphatic nitrohydrocarbyl, and WHEREIN R5 and R6 are each aliphatic hydrocarbyl, a is an integer of 1 to 4, inclusive, b is an integer of 0 to 3, inclusive, d and e are each integers of 0 to 1, and the sum of a, b, d and e is 4. The imidatosilanes are useful as chain extenders and as curing agents in one-package RTV compositions.

公开(公告)号：US3652715A

公开(公告)日：1972-03-28

申请号：US3652715D

申请日：1969-07-01

Applicant: GEN ELECTRIC

Inventor： HOLUB FRED F ,  EVANS MILTON L

IPC: C08G64/04 ,  C08G64/12 ,  C08G73/16 ,  C08L69/00 ,  H01B3/42 ,  C08F27/08

CPC classification number: H01B3/426 ,  C08G64/045 ,  C08G64/12 ,  C08G73/16 ,  C08L69/00 ,  Y10S525/906 ,  C08L2666/02

Abstract: POLYCARBONATE COMPOSITIONS ARE PROVIDED COMPRISING POLYCARBONATES SUBSTITUTED WITH AT LEAST ONE CHEMICALLYCOMBINED ALIPHATICALLY UNSATURATED IMIDO RADICAL, SUCH AS A MALEIMIDO RADICAL. THE IMIDO-SUBSTITUTED POLYCARBONATES CAN BE BLENDED WITH VARIOUS ALIPHATICALLY UNSATURATED MONOMERS, SUCH AS STYRENE, CHLOROSTYRENE, N-PHENYL MALEIMIDE, DIALLYLPHTHALATE, TRIALLYLCYANURATE, ETC. AND VARIOUS ORGANIC POLYMERS, SUCH AS POLYSTYRENE, POLYCARBONATE, POLYSULFONE, POLYPHENYLENEOXIDE, POLYURETHANE, ETC. THE POLYCARBONATE, COMPOSITIONS OF THE PRESENT INVENTIONS CAN BE EMPLOYED AS MOLDING COMPOUNDS, FOR MAKING FILMS, LAMINATES, ETC.

公开(公告)号：US3576031A

公开(公告)日：1971-04-20

申请号：US3576031D

申请日：1969-05-05

Applicant: GEN ELECTRIC

Inventor： HOLUB FRED F ,  EVANS MILTON L

IPC: C07F7/10 ,  C07F7/12 ,  C07F7/18 ,  C08G77/26 ,  C08J5/08 ,  C08L83/04

CPC classification number: C08J5/08 ,  C07F7/10 ,  C07F7/12 ,  C07F7/182 ,  C07F7/1836 ,  C08G77/16 ,  C08G77/26 ,  C08G77/60 ,  C08L83/04 ,  C08L2666/44

Abstract: ORGANOSILANES ARE PROVIDED HAVING AT LEAST ONE CHEMICALLY-COMBINES ALIPHATICALLY UNSATURATED IMIDO ORGANIC RADICAL, SUCH AS A MATEIMIDO-SUBSTITUTED ORGANOSILANE AND A METHOD FOR MAKING THESE MATERIALS. FOR EXAMPLE, REACTION CAN BE EFFECTED BETWEEN AN ALIPHATICALLY UNSATURATED DISCARBOXYLIC ACID ANHYDRIDE AND AN AMINOORGANOALKOXYSILANE. IN CERTAIN INSTANCES, AMIDO ACID PRECURSORS OF SUCH UNSATURATED IMIDO-SUBSTITUTED ORGANOSILANES ALSO CAN BE MADE. THE ALIPHATICALLY UNSATURATED IMIDO-SUBSTITUTED ORGANOSILANES OF THE PRESENT INVENTION CAN BE EMPLOYED TO IMPART IMPROVED SURFACE CHARACTERISTICS TO CELLULOSIC SUBSTRATES AND TO MAKE ALIPHATICALLY UNSATURATED IMIDO-SUBSTITUTED ORGANOPOLYSILOXANES.

公开(公告)号：US3689464A

公开(公告)日：1972-09-05

申请号：US3689464D

申请日：1970-12-18

Applicant: GEN ELECTRIC

Inventor： HOLUB FRED F ,  EVANS MILTON L

IPC: C08G69/48 ,  C08G73/12 ,  C08G20/20

CPC classification number: C08G69/48 ,  C08G73/12 ,  Y10S525/925 ,  Y10S525/929

Abstract: POLYAMIDES HAVING TERMINAL ALIPHATICALLY UNSATURATED IMIDO RADICALS ARE PROVIDED AND A METHOD FOR MAKING SUCH MATERIALS. BLENDS OF THE IMIDOSUBSTITUTED POLYAMIDES AND A VARIETY OF ALIPHATICALLY UNSATURATED ORGANIC MONOMERS, SUCH AS STYRENE, N-PHENYLMALEIMIDE, BISMALEIMIDES OR ORGANIC POLYMERS, SUCH AS POLYPHENYLENE OXIDES, POLYVINYL CHLORIDE, POLYSTYRENE, POLYSULFONE, POLYCARBONATE, ETC., ALSO ARE PROVIDED. THE IMIDO-SUBSTITUTED COMPOSITIONS OF THE PRESENT INVENTION CAN BE EMPLOYED AS MOLDING COMPOUNDS, LAMINATES, VARNISHES AND ADHESIVES.

公开(公告)号：US3567685A

公开(公告)日：1971-03-02

申请号：US3567685D

申请日：1969-08-26

Applicant: GEN ELECTRIC

Inventor： BIALOUS CHARLES A ,  EVANS MILTON L

IPC: C08G63/685 ,  C08G64/12 ,  C08G73/16 ,  C08G17/13

CPC classification number: C08G64/12 ,  C08G63/685 ,  C08G73/16

Abstract: A COMPOSITION CONSISTING OF THE REACTION PRODUCT OF A DIHYDRIC PHENOL, A PARTICULAR IMIDE AND A CARBONYL HALIDE WHEREIN THE PARTICULAR IMIDE IS EITHER

2-(X-R-),5-(HOOC-)ISOINDOLINE-1,3-DIONE OR

(5-(HOOC-)ISOINDOLINE-1,3-DION-2-YL)2-R

OR MIXTURES THEREOF. IN THE FORMULAS, R IS DIVALENT HYDROCARBON RADICAL CONTAINING 1 TO 25 CARBON ATOMS AND X IS EITHER A CARBOXYL, A MERCAPTO, A HYDROXYL OR A SECONDARY AMINO GROUP.

公开(公告)号：US3535403A

公开(公告)日：1970-10-20

申请号：US3535403D

申请日：1968-01-19

Applicant: GEN ELECTRIC

Inventor： HOLUB FRED F ,  EVANS MILTON L

IPC: C08F299/02 ,  C09D4/06 ,  C09D123/02 ,  C08G45/04

CPC classification number: C09D4/06 ,  C08F299/026 ,  C09D123/02 ,  Y10S525/922 ,  C08F291/00 ,  C08L2666/22

公开(公告)号：US3646084A

公开(公告)日：1972-02-29

申请号：US3646084D

申请日：1970-09-16

Applicant: GEN ELECTRIC

Inventor： EVANS MILTON L ,  MITCHELL TYRONE D ,  SELIN TERRY G

IPC: C07F7/02 ,  C07F7/10 ,  C08L83/04 ,  C07F7/18

CPC classification number: C07F7/10 ,  C07F7/025 ,  C08L83/04 ,  C08L2666/44

Abstract: IMIDATOSILANES ARE PREPARED BY REACTING AN IMIDATE WITH A CHLOROSILANE IN AN INERT ORGANIC SOLVENT AND IN THE PRESENCE OF AN AMINE ACID ACEPTOR. THE AMINE SALT WHICH IS FORMED AS A BY-PRODUCT OF THE REACTION IS REMOVED FROM THE IMIDATOSILANE WHICH IS FORMED BY EXTRACTING IT WITH WATER.

公开(公告)号：US3558741A

公开(公告)日：1971-01-26

申请号：US3558741D

申请日：1969-05-05

Applicant: GEN ELECTRIC

Inventor： HOLUB FRED F ,  EVANS MILTON L

IPC: C07F7/08 ,  C08G77/26 ,  C08G77/388 ,  C08F35/02 ,  C08G31/24 ,  C08G47/10

CPC classification number: C07F7/0854 ,  C08G77/26 ,  C08G77/388 ,  Y10S525/905 ,  Y10S525/906 ,  Y10S525/91 ,  Y10S525/912 ,  Y10S525/925

Abstract: CURABLE ORGANOPOLYSILOXANE COMPOSITIONS ARE PROVIDED AND A METHOD FOR MAKING THEM, COMPRISING ORGANOPOLYSILOXANE HAVING ONE OR MORE ALIPHATICALLY UNSATURATED IMIDO ORGANO RADICALS ATTACHED TO SILICON THROUGH A CARBON-SILICON BOND. THE CURABLE ORGANOPOLYSILOXANE COMPOSITIONS CAN BE IN THE FORM OF BLENDS OF SUCH IMIDO-SUBSTITUTED ORGANOPOLYSILOXANE IN COMBINATION WITH AT LEAST ONE OLEFINICALLY UNSATURATED MONOMER, SUCH AS N-PHENYLMALEIMIDE, BISMALEMIDE, STYRENE, ETC., OR AT LEAST ONE POLYMER, SUCH AS POLYCARBONATE, POLYVINYLCHLORIDE, ETC., OR MIXTURES THEREOF.