公开(公告)号：US20100261937A1

公开(公告)日：2010-10-14

申请号：US12755975

申请日：2010-04-07

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C41/01 ,  C07C31/04

CPC classification number: C10L1/02 ,  C07C29/1518 ,  C07C41/09 ,  C07C31/04 ,  C07C43/043

Abstract: The invention provides a method for rendering petroleum oil as an essentially environmentally carbon dioxide-neutral fuel and source material. Carbon dioxide produced from petroleum oil combustion is captured, purified, combined with steam and light hydrocarbon fractions, or with hydrogen, and reacted under reaction conditions sufficient to form methanol and/or dimethyl ether, which can be used as fuel or feedstock for derived synthetic hydrocarbons and products.

Abstract translation: 本发明提供一种使石油作为基本环境的二氧化碳中性燃料和源材料的方法。 从石油燃烧产生的二氧化碳被捕获，纯化，与蒸汽和轻烃馏分或氢气结合，并在足以形成甲醇和/或二甲醚的反应条件下反应，其可用作衍生合成的燃料或原料 碳氢化合物和产品。

公开(公告)号：US20110054045A1

公开(公告)日：2011-03-03

申请号：US12941773

申请日：2010-11-08

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C27/06

CPC classification number: C07C29/1518 ,  C01B3/38 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1211 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/148 ,  C07C29/154 ,  C07C41/01 ,  C07C41/09 ,  Y02P20/52 ,  C07C43/043 ,  C07C31/04

Abstract: The invention provides for \ a method of forming methanol by combining a mixture of methane, water and carbon dioxide under reaction conditions sufficient to form a mixture of hydrogen and carbon monoxide. Hydrogen and carbon monoxide are reacted under conditions sufficient to form methanol. The molar ratio of hydrogen to carbon monoxide is at least two moles of hydrogen to one mole of carbon monoxide and the overall molar ratio between methane, water and carbon dioxide is about 3:2:1. Methane, carbon dioxide and water are bi-reformed over a catalyst. The catalyst includes a single metal, a metal oxide, a mixed catalyst of a metal and a metal oxide or a mixed catalyst of at least two metal oxides.

Abstract translation: 本发明提供了在足以形成氢气和一氧化碳的混合物的反应条件下，通过组合甲烷，水和二氧化碳的混合物来形成甲醇的方法。 氢气和一氧化碳在足以形成甲醇的条件下反应。 氢与一氧化碳的摩尔比为1摩尔一氧化碳至少2摩尔的氢，而甲烷，水和二氧化碳之间的总摩尔比约为3：2：1。 甲烷，二氧化碳和水在催化剂上进行双重改性。 催化剂包括单一金属，金属氧化物，金属和金属氧化物的混合催化剂或至少两种金属氧化物的混合催化剂。

公开(公告)号：US20100274060A1

公开(公告)日：2010-10-28

申请号：US12755997

申请日：2010-04-07

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C31/04

CPC classification number: C10L1/02 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/061 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/141 ,  C01B2203/148 ,  C07C29/1518 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/302 ,  C10G2300/308 ,  C10G2300/805 ,  Y02P20/52 ,  C07C31/04

Abstract: The invention provides for a method for processing heavy oil from any sources including tar sands, oil shales, varied residues in a bi-reforming process utilizing reaction conditions with steam and carbon dioxide sufficient to form a mixture of hydrogen and carbon monoxide to form methanol. Methanol produced can be dehydrated to form dimethyl ether, with water produced being recycled back to the bi-reforming process.

Abstract translation: 本发明提供了一种从任何来源处理重油的方法，包括焦油砂，油页岩，双重重整过程中不同残留物，利用反应条件与足以形成氢气和一氧化碳的混合物形成甲醇的蒸汽和二氧化碳。 生产的甲醇可以脱水形成二甲醚，产生的水循环回到双重重整过程。

公开(公告)号：US20120115965A1

公开(公告)日：2012-05-10

申请号：US13354042

申请日：2012-01-19

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C29/151 ,  C07C29/157 ,  B82Y30/00

CPC classification number: C07C29/1518 ,  C01B3/38 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1211 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/148 ,  C07C29/154 ,  C07C41/01 ,  C07C41/09 ,  Y02P20/52 ,  C07C43/043 ,  C07C31/04

Abstract: The invention provides for a method of forming methanol by combining a mixture of methane, water and carbon dioxide under specific reaction conditions sufficient to form a mixture of hydrogen and carbon monoxide which are then reacted under conditions sufficient to form methanol. The molar ratio of hydrogen to carbon monoxide is at least two moles of hydrogen to one mole of carbon monoxide and the overall molar ratio between methane, water and carbon dioxide is about 3:2:1. Methane, carbon dioxide and water are bi-reformed over a catalyst. The catalyst includes a single metal, a metal oxide, a mixed catalyst of a metal and a metal oxide or a mixed catalyst of at least two metal oxides.

Abstract translation: 本发明提供了通过在足以形成氢气和一氧化碳的混合物的特定反应条件下混合甲烷，水和二氧化碳的混合物来形成甲醇的方法，然后在足以形成甲醇的条件下反应。 氢与一氧化碳的摩尔比为1摩尔一氧化碳至少2摩尔的氢，而甲烷，水和二氧化碳之间的总摩尔比约为3：2：1。 甲烷，二氧化碳和水在催化剂上进行双重改性。 催化剂包括单一金属，金属氧化物，金属和金属氧化物的混合催化剂或至少两种金属氧化物的混合催化剂。

公开(公告)号：US20100261938A1

公开(公告)日：2010-10-14

申请号：US12755957

申请日：2010-04-07

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C31/04 ,  C01B3/32

CPC classification number: C10L1/02 ,  C07C29/151 ,  C07C41/09 ,  Y02P20/582 ,  Y02P30/42 ,  C07C31/04 ,  C07C43/043

Abstract: The invention provides a method for rendering natural gas as an environmentally essentially carbon dioxide-neutral fuel. Carbon dioxide produced from natural gas combustion or from natural gas wells is captured, purified, combined with natural gas or methane or with hydrogen, and reacted under reaction conditions sufficient to form methanol and/or dimethyl ether, which can be used as fuel or feedstock for derived synthetic hydrocarbons and products.

Abstract translation: 本发明提供了一种使天然气作为环境基本上是二氧化碳中性燃料的方法。 从天然气燃烧或天然气井产生的二氧化碳被捕获，纯化，与天然气或甲烷或氢气结合，并在足以形成甲醇和/或二甲醚的反应条件下反应，可用作燃料或原料 用于衍生合成碳氢化合物和产物。

公开(公告)号：US20090014336A1

公开(公告)日：2009-01-15

申请号：US12171904

申请日：2008-07-11

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C25B3/04

CPC classification number: C25B1/04 ,  C07C29/1518 ,  C25B1/00 ,  C25B15/08 ,  Y02E60/366 ,  Y02P20/133 ,  Y02P20/134 ,  C07C31/04

Abstract: An environmentally beneficial method of producing methanol from varied sources of carbon dioxide including flue gases of fossil fuel burning power plants, industrial exhaust gases or the atmosphere itself. Converting carbon dioxide by an electrochemical reduction of carbon dioxide in a divided electrochemical cell that includes an anode in one cell compartment and a metal cathode electrode in another cell compartment that also contains an aqueous solution comprising methanol and an electrolyte of one or more alkyl ammonium halides, alkali carbonates or combinations thereof to produce therein a reaction mixture containing carbon monoxide and hydrogen which can be subsequently used to produce methanol while also producing oxygen in the cell at the anode.

Abstract translation: 一种从不同来源的二氧化碳生产甲醇的环境有益的方法，包括燃烧发电厂的废气，工业废气或大气本身。 在包括一个电池室中的阳极和另一个电池隔室中的金属阴极电极的分隔电化学电池中通过电化学还原二氧化碳来转化二氧化碳，其还含有包含甲醇和一种或多种烷基卤化铵的电解质的水溶液 ，碱金属碳酸盐或其组合以在其中产生含有一氧化碳和氢的反应混合物，其随后可用于产生甲醇，同时在阳极中的电池中产生氧。

公开(公告)号：US20080319093A1

公开(公告)日：2008-12-25

申请号：US11850501

申请日：2007-09-05

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C27/00

CPC classification number: C07C29/1518 ,  C01B3/38 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1052 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1211 ,  C01B2203/1235 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/148 ,  C07C29/154 ,  C07C41/01 ,  C07C41/09 ,  Y02P20/52 ,  C07C43/043 ,  C07C31/04

Abstract: The invention discloses a method of converting carbon dioxide to methanol and/or dimethyl ether using any methane source or natural gas consisting of a combination of steam and dry reforming, in a specific ratio to produce a 2:1 molar ratio of hydrogen and carbon monoxide with subsequent conversion of the CO and H2 mixture exclusively to methanol and/or dimethyl ether. This method is termed the BI-REFORMING™ process. Dehydrating formed methanol allows producing dimethyl ether (DME) using any suitable catalytic method, including use of solid acid catalysts. When recycling formed water into the bi-reforming step the conversion of carbon dioxide with methane produces exclusively dimethyl ether without any by-product formation and complete utilization of hydrogen

Abstract translation: 本发明公开了一种将二氧化碳转化为甲醇和/或二甲醚的方法，使用任何甲烷源或由蒸汽和干重整组合组成的天然气，以特定比例将氢气和一氧化碳摩尔比为2:1 随后将CO和H 2混合物随后转化成甲醇和/或二甲醚。 这种方法被称为双重重整过程。 脱水形成的甲醇允许使用任何合适的催化方法生产二甲醚（DME），包括使用固体酸催化剂。 当将形成的水再循环到双重重整步骤中时，二氧化碳与甲烷的转化仅产生二甲醚，而没有任何副产物形成和氢气的完全利用

公开(公告)号：US20160340278A1

公开(公告)日：2016-11-24

申请号：US15036506

申请日：2014-11-14

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C29/00 ,  E21B43/26 ,  C10L1/04 ,  C07C41/09 ,  C07C1/24 ,  E21B43/16 ,  E21B43/34

CPC classification number: C07C29/00 ,  C07C1/24 ,  C07C41/09 ,  C10L1/04 ,  C10L2290/42 ,  E21B43/164 ,  E21B43/26 ,  E21B43/267 ,  E21B43/34 ,  E21B43/40

Abstract: A method of producing methanol from shale gas and CO2 by the exclusive dry CO2 fracking of shale rock by injection of gaseous CO2 at a pressure between 10 and 100 atm to extract shale gas and recover it together with used CO2; combining and admixing produced shale gas containing CO2 and steam to produce a mixture of methane:carbon dioxide:water having a molar ratio of 3:1:2 for conducting the bi-reforming reaction to form a mixture of hydrogen and carbon monoxide having a molar ratio of 2:1 to 2.1:1; and converting the hydrogen and carbon monoxide under conditions sufficient to exclusively form methanol.

Abstract translation: 通过在10〜100atm的压力下注入气态二氧化碳，通过专用的干式二氧化碳压裂页岩气生产甲醇的方法，以提取页岩气，并与二氧化碳一起回收; 组合和混合生成的含有CO 2和蒸汽的页岩气，以产生甲烷：二氧化碳：摩尔比为3:1:2的水的混合物，以进行双重整反应以形成具有摩尔比的氢和一氧化碳的混合物 比例为2：1至2.1：1; 并在足以独特形成甲醇的条件下转化氢气和一氧化碳。

公开(公告)号：US08816137B2

公开(公告)日：2014-08-26

申请号：US12755997

申请日：2010-04-07

Applicant: George A. Olah ,  G.K. Surya Prakash

Inventor： George A. Olah ,  G.K. Surya Prakash

IPC: C07C29/88 ,  C07C29/90 ,  C07C31/04

CPC classification number: C10L1/02 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/061 ,  C01B2203/1041 ,  C01B2203/1047 ,  C01B2203/1058 ,  C01B2203/1076 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/141 ,  C01B2203/148 ,  C07C29/1518 ,  C10G2300/202 ,  C10G2300/205 ,  C10G2300/302 ,  C10G2300/308 ,  C10G2300/805 ,  Y02P20/52 ,  C07C31/04

Abstract: The invention provides for a method for processing heavy oil from any sources including tar sands, oil shales, varied residues in a bi-reforming process utilizing reaction conditions with steam and carbon dioxide sufficient to form a mixture of hydrogen and carbon monoxide to form methanol. Methanol produced can be dehydrated to form dimethyl ether, with water produced being recycled back to the bi-reforming process.

Abstract translation: 本发明提供了一种从任何来源处理重油的方法，包括焦油砂，油页岩，双重重整过程中不同残留物，利用反应条件与足以形成氢气和一氧化碳的混合物形成甲醇的蒸汽和二氧化碳。 生产的甲醇可以脱水形成二甲醚，产生的水循环回到双重重整过程。

公开(公告)号：US20140066640A1

公开(公告)日：2014-03-06

申请号：US14113482

申请日：2012-04-19

Applicant: G.K. Surya Prakash ,  Parag V. Jog ,  Patrice T.D. Batamack ,  George A. Olah

Inventor： G.K. Surya Prakash ,  Parag V. Jog ,  Patrice T.D. Batamack ,  George A. Olah

IPC: C07D307/44 ,  C07C29/62 ,  C07C41/01 ,  C07F7/08

CPC classification number: C07D307/44 ,  C07B39/00 ,  C07C17/269 ,  C07C17/32 ,  C07C29/40 ,  C07C29/62 ,  C07C41/01 ,  C07C41/30 ,  C07C41/50 ,  C07C45/455 ,  C07C201/12 ,  C07C303/16 ,  C07C2603/24 ,  C07D213/26 ,  C07D307/42 ,  C07F7/081 ,  C07F7/0896 ,  C07C22/08 ,  C07C205/26 ,  C07C205/11 ,  C07C205/37 ,  C07C309/06 ,  C07C33/46 ,  C07C43/23 ,  C07C33/486 ,  C07C49/80 ,  C07C43/317 ,  C07C43/225

Abstract: A direct trifluoromethylation method preferably using a trifluoromethane as a fluoro-methylating species. In particular, the present method is used for preparing a trifluoromethylated substrate by reacting a fluoromethylatable substrate with a trifiuoromethylating agent in the presence of an alkoxide or metal salt of silazane under conditions sufficient to trifluoromethylate the substrate; wherein the fluoromethylatable substrate includes chlorosilanes, carbonyl compounds such as esters, aryl halides, aldehydes, ketones, chalcones, alkyl formates, alkyl halides, aryl halides, alkyl borates, carbon dioxide or sulfur.

Abstract translation: 直接三氟甲基化方法优选使用三氟甲烷作为氟代甲基化物质。 特别地，本发明的方法用于通过使氟可甲基底物与三氟甲基化试剂在硅烷的醇盐或金属盐的存在下在足以使底物三氟甲基化的条件下反应制备三氟甲基化底物; 其中所述氟甲基基材包括氯硅烷，羰基化合物如酯，芳基卤化物，醛，酮，查尔酮，甲酸烷基酯，烷基卤，芳基卤，烷基硼酸盐，二氧化碳或硫。