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公开(公告)号：US10208069B2
公开(公告)日：2019-02-19
申请号：US15013220
申请日：2016-02-02
IPC分类号： C07F3/06 , C07D213/22
摘要： A process is provided for precise self-assembly and re-arrangement of a three-dimensional terpyridine-based coordination complex. A plurality of terpyridine-containing ligands are reacted with at least one metal ion, in a pre-selected molar ratio, to form a self-assembled three-dimensional terpyridine-based coordination complex having a first configuration. A triggering event, such as exposure to light or dilution, causes the coordination complex to re-arrange to form at least two smaller, substantially identical, three-dimensional terpyridine-based coordination complexes, each having a second configuration that is different from the first configuration. Upon application of a second triggering event, such as concentration, the re-arrangement is reversed.
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2.发明授权公开(公告)号：US08841451B2
公开(公告)日：2014-09-23
申请号：US13548664
申请日：2012-07-13
IPC分类号： C07D401/14 , C07F15/02 , C07F15/00
CPC分类号： C07F15/0053 , C07F15/025
摘要： The invention relates to the formation of synthesized fractal constructs and the methods of chemical self-assembly for the preparation of a non-dendritic, nano-scale, fractal constructs or molecules. More particularly, the invention relates to fractal constructs formed by molecular self-assembly, to create synthetic, nanometer-scale fractal shapes. In an embodiment, a nanoscale Sierpinski hexagonal gasket is formed. This non-dendritic, perfectly self-similar fractal macromolecule is comprised of bisterpyridine building blocks that are bound together by coordination to (36) Ru and (6) Fe ions to form a nearly planar array of increasingly larger hexagons around a hollow center.
摘要翻译： 本发明涉及合成的分形构造物的形成和用于制备非树枝状纳米级分形构造或分子的化学自组装方法。 更具体地，本发明涉及通过分子自组装形成的分形构造，以产生合成的纳米级分形。 在一个实施例中，形成纳米级的Sierpinski六角垫圈。 这种非树枝状，完全自相似的分形大分子由通过与（36）Ru和（6）Fe离子配位而结合在一起的双螺旋吡啶结构单元组成，以形成围绕中空中心的越来越大的六边形的近似平面的阵列。
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公开(公告)号：US5886127A
公开(公告)日：1999-03-23
申请号：US971872
申请日：1997-11-19
CPC分类号： C40B40/14 , C08G18/71 , C08G18/718 , C08G83/003 , C40B50/08 , C07B2200/11 , Y10S977/754
摘要： The method of forming a surface layer on a substrate is accomplished by dendrimerizing a mixture of branched monomers on the substrate surface wherein the monomers introduce heterogeneous functionalized branches and homogenous connectivity to the substrate. A cascade polymer coated substrate is formed consisting essentially of a substrate including a surface and at least one dendrimerized surface layer consisting of heterogeneous functionalities the layer being linked to the substrate by homogenous linkages, preferably isocyanate linkages.
摘要翻译： 在基材上形成表面层的方法是通过在基材表面上树枝状聚合支化单体的混合物来实现的，其中单体引入异构的官能化分支和与基材的均匀连接性。 形成级联聚合物涂覆的基底，其基本上由包含表面的底物和至少一个由异质官能团组成的树枝状聚合表面层组成，所述层通过均匀连接优选异氰酸酯键与基底连接。
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公开(公告)号：US5863919A
公开(公告)日：1999-01-26
申请号：US704813
申请日：1996-08-28
IPC分类号： A61K9/107 , A61K47/30 , A61K47/48 , B01F17/30 , C07C233/47 , C07D213/68 , C07D213/75 , C07D239/62 , C07D239/64 , C08G73/02 , C08G73/06 , C08J3/02 , C07C233/31 , C07D239/02
CPC分类号： C07D213/75 , B82Y5/00 , C07C233/47 , C07D213/68 , C07D239/62 , C07D239/64 , C08G73/028 , C08G73/0627 , Y10S424/16 , Y10S525/936 , Y10S530/816 , Y10T428/2985 , Y10T428/2987
摘要： A lock unimolecular micelle includes at least one engineered acceptor specifically binding a ligand (or specifically a "key" unimolecular micelle) thereto. A key unimolecular micelle comprises a core molecule and a plurality of branches extending therefrom, at least one of the branches including a shank portion extending therefrom having a terminal moiety at an end thereof for binding to a complimentary acceptor of a lock unimolecular micelle. Together, the lock and key micelles form a unit, either irreversibly or reversibly bound wherein the lock micelles is a soluble receptor engineered to specifically bind to the specifically engineered key micelle.
摘要翻译： 锁定单分子胶束包括至少一个工程化的受体，其特异性结合配体（或特别是“键”单分子胶束）。 关键的单分子胶束包括芯分子和从其延伸的多个分支，至少一个分支包括从其延伸的柄部分，其末端具有末端部分，用于结合锁定单分子胶束的互补受体。 锁和键胶束一起形成不可逆或可逆地结合的单元，其中锁定胶束是被工程化以特异性结合特异性工程化的键胶束的可溶性受体。
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5.发明授权Multifunctional synthons as used in the preparation of cascade polymers or unimolecular micelles 失效用于制备级联聚合物或单分子胶束的多功能合成子
公开(公告)号：US5206410A
公开(公告)日：1993-04-27
申请号：US868449
申请日：1992-04-14
IPC分类号： C07C205/15 , C07C205/30 , C07C205/51 , C07C215/10 , C07C217/28 , C07C255/13
CPC分类号： C07C217/28 , C07C205/15 , C07C205/30 , C07C205/51 , C07C215/10 , C07C255/13
摘要： The bis-homotris compounds 4-amino-4-[1-(3-hydroxypropyl)]-1,7-heptanediol and 4-[1-(3-aminopropyl)]-4-[1-(3-hydroxypropyl)]-1, 7-heptanediol, and organic synthetic methods for their preparation are described. Unique multifunctional aminotriols, as well as their percursors, quaternary nitroalkanes are disclosed as building blocks for unimolecular micelles, as well as new series of cascade polymers. The quaternary nitro compounds which are disclosed allow the synthesis of a new aminotriol containing a quaternary carbon.
摘要翻译： 双 - 同系物化合物4-氨基-4- [1-（3-羟丙基）] - 1,7-庚二醇和4- [1-（3-氨基丙基）] -4- [1-（3-羟基丙基）] -1,7-庚二醇及其制备的有机合成方法。 公开了独特的多官能氨基三醇以及它们的过氧化物，季硝基烷烃作为单分子胶束的结构单元，以及新的级联聚合物系列。 公开的季硝基化合物允许合成含有季碳的新的氨基三醇。
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6.发明授权Methods for producing materials with photo- and electroluminescence properties and systems using such materials 有权使用这种材料制造具有光敏性和电致发光性质的材料的方法和系统公开(公告)号：US08642762B2
公开(公告)日：2014-02-04
申请号：US13565923
申请日：2012-08-03
CPC分类号： C09K11/06 , C09K2211/1029 , C09K2211/188 , H01L51/0037 , H01L51/0081 , H01L51/009 , H01L51/0092 , H01L51/5012
摘要： The invention is directed to a method of preparing polymeric metallomacrocycles having measurable photo- and electroluminescence properties and devices using such materials. In an embodiment, an O-hexyl-3,5-bis(terpyridine)phenol ligand has been synthesized and transformed into a hexagonal Zn(II)-metallomacrocycle by a facile self-assembly procedure capitalizing on terpyridine-Zn(II)-terpyridine connectivity. The material is usable in an OLED device based on the photo- and electro-luminescence characteristics thereof.
摘要翻译： 本发明涉及一种制备具有可测量的光敏和电致发光性质的聚合物金属钼酸盐的方法和使用这种材料的装置。 在一个实施方案中，已经合成了O-己基-3,5-双（三联吡啶）酚配体，并通过利用三联吡啶-Zn（II） - 三联吡啶的容易的自组装方法将其转化为六方锌（II） - 金属摩尔 连接。 该材料可用于基于其光电和发光特性的OLED器件中。
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公开(公告)号：US20100286395A1
公开(公告)日：2010-11-11
申请号：US11910772
申请日：2006-04-07
IPC分类号： C07F1/08
摘要： There is provided a method and nanocomposite for the reversible assembly of nanotubes, such as oxidized single wall carbon nanotubes, based on metal coordination. The method produces a thermally stable, neutral nanocomposite possessing enhanced mechanical, electrical, physical and chemical properties for example. Disassembly can be provided by treatment with a competing ligand compound.
摘要翻译： 提供了一种用于可逆组装纳米管的方法和纳米复合材料，例如基于金属配位的氧化单壁碳纳米管。 该方法产生例如具有增强的机械，电学，物理和化学性质的热稳定的中性纳米复合材料。 可以通过用竞争配体化合物处理来提供拆卸。
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8.发明申请公开(公告)号：US20090131656A1
公开(公告)日：2009-05-21
申请号：US12299486
申请日：2007-05-10
IPC分类号： C07F15/02
CPC分类号： C07F15/0053 , C07F15/025
摘要： The invention relates to the formation of synthesized fractal constructs and the methods of chemical self-assembly for the preparation of a non-dendritic, nano-scale, fractal constructs or molecules. More particularly, the invention relates to fractal constructs formed by molecular self-assembly, to create synthetic, nanometer-scale fractal shapes. In an embodiment, a nanoscale Sierpinski hexagonal gasket is formed. This non-dendritic, perfectly self-similar fractal macromolecule is comprised of bisterpyridine building blocks that are bound together by coordination to 36 Ru and 6 Fe ions to form a nearly planar array of increasingly larger hexagons around a hollow center.
摘要翻译： 本发明涉及合成的分形构造物的形成和用于制备非树枝状纳米级分形构造或分子的化学自组装方法。 更具体地，本发明涉及通过分子自组装形成的分形构造，以产生合成的纳米级分形。 在一个实施例中，形成纳米级的Sierpinski六角垫圈。 这种非树枝状，完全自相似的分形大分子由通过与36 Ru和6 Fe离子配位而结合在一起的双螺旋吡啶结构单元组成，形成围绕中空中心的越来越大的六边形的几乎平面的阵列。
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公开(公告)号：US06566409B1
公开(公告)日：2003-05-20
申请号：US09567447
申请日：2000-05-08
IPC分类号： B01F1730
CPC分类号： C07D213/75 , B82Y5/00 , C07C233/47 , C07D213/68 , C07D239/62 , C07D239/64 , C08G73/028 , C08G73/0627 , Y10S424/16 , Y10S525/936 , Y10S530/816 , Y10T428/2985 , Y10T428/2987
摘要： A lock unimolecular micelle includes at least one engineered acceptor specifically binding a ligand (or specifically a “key” unimolecular micelle) thereto. A key unimolecular micelle comprises a core molecule and a plurality of branches extending therefrom, at least one of the branches including a shank portion extending therefrom having a terminal moiety at an end thereof for binding to a complimentary acceptor of a lock unimolecular micelle. Together, the lock and key micelles form a unit, either irreversibly or reversibly bound wherein the lock micelles is a soluble receptor engineered to specifically bind to the specifically engineered key micelle.
摘要翻译： 锁定单分子胶束包括至少一个工程化的受体，其特异性结合配体（或特别是“键”单分子胶束）。 关键的单分子胶束包括芯分子和从其延伸的多个分支，至少一个分支包括从其延伸的柄部分，其末端具有末端部分，用于结合锁定单分子胶束的互补受体。 锁和键胶束一起形成不可逆或可逆地结合的单元，其中锁定胶束是被工程化以特异性结合特异性工程化的键胶束的可溶性受体。
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公开(公告)号：US5650101A
公开(公告)日：1997-07-22
申请号：US280591
申请日：1994-07-25
IPC分类号： A61K9/107 , A61K47/30 , A61K47/48 , B01F17/30 , C07C233/47 , C07D213/68 , C07D213/75 , C07D239/62 , C07D239/64 , C08G73/02 , C08G73/06 , C08J3/02 , A61K9/50 , B01J13/20 , B01J13/22
CPC分类号： C07D213/75 , A61K47/488 , A61K47/48961 , B82Y5/00 , C07C233/47 , C07D213/68 , C07D239/62 , C07D239/64 , C08G73/028 , C08G73/0627 , Y10S424/16 , Y10S525/903 , Y10S525/936 , Y10T428/2985 , Y10T428/2987
摘要： A lock unimolecular micelle includes at least one engineered acceptor specifically binding a ligand (or specifically a "key" unimolecular micelle) thereto. A key unimolecular micelle comprises a core molecule and a plurality of branches extending therefrom, at least one of the branches including a shank portion extending therefrom having a terminal moiety at an end thereof for binding to a complimentary acceptor of a lock unimolecular micelle. Together, the lock and key micelles form a unit, either irreversibly or reversibly bound wherein the lock micelles is a soluble receptor engineered to specifically bind to the specifically engineered key micelle.
摘要翻译： 锁定单分子胶束包括至少一个工程化的受体，其特异性结合配体（或特别是“键”单分子胶束）。 关键的单分子胶束包括芯分子和从其延伸的多个分支，至少一个分支包括从其延伸的柄部分，其末端具有末端部分，用于结合锁定单分子胶束的互补受体。 锁和键胶束一起形成不可逆或可逆地结合的单元，其中锁定胶束是被工程化以特异性结合特异性工程化的键胶束的可溶性受体。
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