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19 条记录 (耗时 0.054 秒)

    Process for preparing aryl- or heteroarylhexadienoic acids
    1.
    发明授权
    Process for preparing aryl- or heteroarylhexadienoic acids 失效
    制备芳基或杂芳基己二烯酸的方法

    公开(公告)号：US4355168A

    公开(公告)日：1982-10-19

    申请号：US212238

    申请日：1980-12-02

    申请人： Gian P. Chiusoli ,  William Giroldini ,  Luciano Pallini ,  Giuseppe Salerno

    发明人： Gian P. Chiusoli ,  William Giroldini ,  Luciano Pallini ,  Giuseppe Salerno

    IPC分类号： B01J31/00 ,  C07B31/00 ,  C07B37/02 ,  C07B61/00 ,  C07C51/00 ,  C07C51/353 ,  C07C57/42 ,  C07C59/64 ,  C07C67/00 ,  C07D333/24 ,  C07D213/55 ,  C07C51/347

    CPC分类号： C07D333/24 ,  C07C51/353

    摘要： There is disclosed and claimed a process for preparing aryl- and heteroarylhexadienoic acids which is characterized in that an aryl- or heteroarylacetylene having the formula: R--C.tbd.CH, wherein R is an aryl or heteroaryl group, optionally substituted and having in the aggregate up to 20 carbon atoms, is reacted with 3-butenoic acid CH.sub.2 .dbd.CH--CH.sub.2 --COOH, in an alcoholic medium, at temperatures maintained between 50.degree. C. and 120.degree. C., approximately, in the presence of a catalyst selected from among the phosphinic complexes of rhodium having the formulas: III, Rh(PR'.sub.3).sub.n L.sub.m X associated with alkaline salts of carboxylic acids having up to 4 carbon atoms, and IV, Rh(PR'.sub.3).sub.n L.sub.p.sup.+ Y.sup.-, wherein R' is a hydrocarbyl group having up to 12 carbon atoms; "L" is a linear or cyclic olefin selected from among the olefins having from 2 to 10 carbon atoms and the chelating olefins having from 6 to 8 carbon atoms, n is an integer from 1 to 3, m is an integer from 0 to 2 and such that n+m=2 or 3, and p is an integer from 0 to 3 and such that n+p=3 or 4; X is an anion selected from among the haloid anions, preferably the hydrochloric anion, and the anions of carboxylic acids having up to 4 carbon atoms and Y is a sparingly coordinating anion, preferably selected from PF.sub.6.sup.- and BF.sub.4.sup.-.The compounds obtained are used as intermediates for organic syntheses, with particular regard to the so-called "fine chemicals" such as, for example, additives for polymers and paints, plasticizers, and the like.

    摘要翻译： 公开并要求了一种制备芳基 - 和杂芳基己二烯酸的方法，其特征在于具有下式的芳基 - 或杂芳基乙炔：其中R是芳基或杂芳基，其中R是芳基或杂芳基， 20个碳原子与3-丁烯酸CH 2 = CH-CH 2 -COOH在醇的介质中在保持在50℃和120℃之间的温度下反应，大约在存在催化剂的情况下，选自 具有以下结构式的铑的次膦酸络合物：III，Rh（PR'3）nLmX与具有至多4个碳原子的羧酸的碱金属盐，以及IV，Rh（PR'3）nLp + Y-，其中R'为 具有至多12个碳原子的烃基; “L”是选自具有2至10个碳原子的烯烃和具有6至8个碳原子的螯合烯烃，n为1至3的整数的直链或环状烯烃，m为0至2的整数 并且使得n + m = 2或3，并且p是0至3的整数，并且使得n + p = 3或4; X是选自卤素阴离子，优选盐酸阴离子的阴离子和具有至多4个碳原子的羧酸阴离子，Y是一种微量配位阴离子，优选选自PF6-和BF4-。 所得化合物用作有机合成的中间体，特别涉及所谓的“精细化学品”，例如聚合物和油漆的添加剂，增塑剂等。

    Process for preparing dienoic acids
    2.
    发明授权
    Process for preparing dienoic acids 失效
    二烯酸的制备方法

    公开(公告)号：US4465634A

    公开(公告)日：1984-08-14

    申请号：US333934

    申请日：1981-12-23

    申请人： Gian P. Chiusoli ,  Luciano Pallini ,  Giuseppe Salerno

    发明人： Gian P. Chiusoli ,  Luciano Pallini ,  Giuseppe Salerno

    IPC分类号： C07C57/03 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/353 ,  C07C67/00 ,  C11C1/00 ,  C09F5/08

    CPC分类号： C07C51/353

    摘要： This invention relates to a process for preparing dienoic acids.In particular, the present invention relates to a catalytic process for preparing octadienoic acids from 3-butenoic acids and butadiene.More particularly the present invention is directed to the preparation of octadienoic acids haing the two double bonds in position 3,6 and 2,6 in respect of the carboxylic carbon, starting from 3-butenoic acids and butadiene in the presence of complex catalysts of Rhodium or of Nickel.

    摘要翻译： 本发明涉及二烯酸的制备方法。 特别地，本发明涉及由3-丁烯酸和丁二烯制备辛二烯酸的催化方法。 更具体地说，本发明涉及在铑络合物催化剂存在下，从3-丁烯酸和丁二烯开始制备相对于羧酸在位置3,6和2,6上的两个双键的辛二烯酸 或镍。

    Granular form of a mixture of a nickel-quencher and a benzophenone and process for its preparation
    3.
    发明授权
    Granular form of a mixture of a nickel-quencher and a benzophenone and process for its preparation 失效
    颗粒形式的镍猝灭剂和二苯甲酮的混合物及其制备方法

    公开(公告)号：US06403679B1

    公开(公告)日：2002-06-11

    申请号：US09622045

    申请日：2000-08-23

    申请人： Carlo Neri ,  Luciano Pallini ,  Giovanni Sandre

    发明人： Carlo Neri ,  Luciano Pallini ,  Giovanni Sandre

    IPC分类号： C08K546

    CPC分类号： C08K5/132 ,  C08K5/005 ,  C08K5/0091 ,  C08L23/02

    摘要： Granular form of a mixture comprising: (a) a nickel-quencher corresponding to [2,2′-thio-bis(4-t-octyl-phenolate)-n-butylamine Nickel (II)]; (b) a 2-hydroxy-4-alkyloxybenzophenone corresponding to 2-hydroxy-4-n-octyloxybenzophenone; characterized in that it has two diffraction lines at angles 2&thgr;=17.593 and 2&thgr;=22.023 in the X-Ray diffraction spectrum from powders. The above granular form can be used as a light stabilizer for agricultural films based on polyolefins or olefinic copolymers.

    摘要翻译： 混合物的颗粒形式包括：（a）对应于[2,2'-硫代 - 双（4-叔辛基 - 苯酚） - 正丁胺镍（II）]的镍猝灭剂; （b）对应于2-羟基-4-正辛氧基二苯甲酮的2-羟基-4-烷氧基二苯甲酮; 其特征在于，在来自粉末的X射线衍射光谱中，它具有角度2θ= 17.593和2θ= 22.023的两条衍射线。 上述颗粒形式可用作基于聚烯烃或烯烃共聚物的农用薄膜的光稳定剂。

    Process for obtaining granular forms of additives for organic polymers
    4.
    发明授权
    Process for obtaining granular forms of additives for organic polymers 失效
    获得有机聚合物添加剂颗粒形式的方法

    公开(公告)号：US5844042A

    公开(公告)日：1998-12-01

    申请号：US937899

    申请日：1997-09-25

    申请人： Carlo Neri ,  Luciano Pallini

    发明人： Carlo Neri ,  Luciano Pallini

    IPC分类号： C08J3/22 ,  C08K3/00 ,  C08K5/00 ,  C08K5/098 ,  C08K7/16 ,  C08K5/09

    CPC分类号： C08K5/005 ,  C08J3/22 ,  C08K3/0008 ,  C08K5/098

    摘要： Process for obtaining granular forms, from mixtures of powders of two or more additives for organic polymers, including extruding the mixture at a temperature of between about the melting point of the component with the lowest melting point and 140.degree. C., with the condition that, when the mixture consists of two additives, these are not tetrakis �3-(3,5-di-t-butyl-4-hydroxyphenyl) propionyloxymethyl!methane, either in an amorphous or crystalline form, and an antiacid.

    摘要翻译： 用于从两种或更多种有机聚合物添加剂的粉末混合物中获得颗粒形式的方法，包括在最低熔点和140℃的组分的熔点之间的温度下挤出混合物，条件是 当混合物由两种添加剂组成时，它们不是无定形或结晶形式的四[3-（3,5-二叔丁基-4-羟基苯基）丙酰氧基甲基]甲烷和抗酸剂。

    Process for the preparation of (omega-carboalkoxy-nor.alkyl)-dialkylamines
    5.
    发明授权
    Process for the preparation of (omega-carboalkoxy-nor.alkyl)-dialkylamines 失效
    制备（ω-烷氧基 - 烷基） - 二烷基胺的方法

    公开(公告)号：US4468522A

    公开(公告)日：1984-08-28

    申请号：US366095

    申请日：1982-04-06

    申请人： Gian Paolo Chiusoli ,  Mirco Costa ,  Luciano Pallini ,  Giuliana Terenghi

    发明人： Gian Paolo Chiusoli ,  Mirco Costa ,  Luciano Pallini ,  Giuliana Terenghi

    IPC分类号： C07C20060101 ,  C07C101/18

    CPC分类号： C07C227/06

    摘要： Process for the preparation of (omega-carbalkoxy-nor.alkyl) dialkylamines having a linear alkyl chain, comprising the steps of amination of allyl compounds in which at least an allyl carbon atom is a part of a cyclopropane ring which contains one or two carboxyl or carbalkoxy groups on the carbon atom which is adjacent to the allyl carbon, or is a part of a lactone ring, in the presence of catalysts consisting of triarylphosphine complexes of palladium, or trialkyl phosphite complexes of nickel, and the subsequent hydrogenation of the unsaturated amine thus obtained. By so doing, interesting linear amines are obtained, which contain carboxyl units or carbalkoxy units, said amines being useful as additives for the industry of synthetic fibres (viscosity stabilizers for polycaprolactam).

    摘要翻译： 包括具有直链烷基链的（ω-烷氧基 - 烷基）二烷基胺的制备方法，包括烯丙基化合物的胺化步骤，其中至少烯丙基碳原子是含有一个或两个羧基的环丙烷环的一部分 或邻位于烯丙基碳上的碳原子上的烷氧基或作为内酯环的一部分，在由钯的三芳基膦配合物或镍的三烷基亚磷酸酯络合物组成的催化剂存在下，和随后的不饱和的氢化 胺。 通过这样做，获得了含有羧基单元或碳烷氧基单元的有趣的线性胺，所述胺可用作合成纤维工业（聚己内酰胺的粘度稳定剂）的添加剂。

    Process for the synthesis of allylated derivatives of 2,2,6,6-tetraalkylpiperidinols
    6.
    发明授权
    Process for the synthesis of allylated derivatives of 2,2,6,6-tetraalkylpiperidinols 失效
    合成2,2,6,6-四烷基哌啶醇的烯丙基化衍生物的方法

    公开(公告)号：US5270470A

    公开(公告)日：1993-12-14

    申请号：US481725

    申请日：1990-02-16

    申请人： Silvestro Costanzi ,  Luciano Pallini ,  Damiano Gussoni

    发明人： Silvestro Costanzi ,  Luciano Pallini ,  Damiano Gussoni

    IPC分类号： C07D211/46 ,  C07D211/36

    CPC分类号： C07D211/46

    摘要： A process is disclosed for the synthesis of 4-allyloxy-2,2,6,6-tetraalkylpiperidinic derivatives by starting from the corresponding 2,2,6,6-tetraaLkyLpiperidinols and from an allyl halide, characterized in that the reaction is made to take place in the absence of water, and in the presence of a finely subdivided allyl-metal hydroxide and of small amounts of a phase-transfer catalyst. The products, which are thus obtained with yields higher than 90%, are useful a stabilizers for polymers or as intermediates for such products.

    摘要翻译： 公开了用于合成4-烯丙氧基-2,2,6,6-四烷基哌啶衍生物的方法，由相应的2,2,6,6-四氢基哌啶醇和烯丙基卤开始，其特征在于使反应生成 在不存在水的情况下进行，并且在细分的烯丙基 - 金属氢氧化物和少量的相转移催化剂的存在下进行。 因此获得的产率高于90％的产品可用作聚合物的稳定剂或作为这种产品的中间体。