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    Thermoplastic olefin elastomers and process for their preparation
    1.
    发明授权
    Thermoplastic olefin elastomers and process for their preparation 失效
    热塑性烯烃弹性体及其制备方法

    公开(公告)号：US06610785B1

    公开(公告)日：2003-08-26

    申请号：US08437489

    申请日：1995-05-09

    申请人： Giuliano Cecchin ,  Enea Garagnani

    发明人： Giuliano Cecchin ,  Enea Garagnani

    IPC分类号： C08F800

    CPC分类号： C08L23/16 ,  C08L23/12 ,  C08L23/142 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2312/00 ,  C08L2666/02 ,  C08L2666/04

    摘要： Disclosed are thermoplastic elastomeric compositions include: A) from 10 to 80% by weight of one or more crystalline polymer of propylene containing from 0.05 to 15% in moles of ethylenic unsaturation, or a mixture of the above polymer with a saturated thermoplastic olefin polymer in quantities lower than or equal to 80% by weight; B) from 20 to 90% by weight of an unsaturated elastomeric olefin polymer; the compositions having been dynamically cross-linked with a cross-linking agent which includes a free radical generator.

    摘要翻译： 公开的热塑性弹性体组合物包括：A）10至80重量％的一种或多种含有0.05至15摩尔烯属不饱和度的丙烯的结晶聚合物，或上述聚合物与饱和热塑性烯烃聚合物的混合物 数量小于或等于80重量％; B）20至90重量％的不饱和弹性体烯烃聚合物;该组合物已经与包含自由基发生剂的交联剂动态交联。

    Plastic copolymers of propylene with linear dienes having conjugated double-bonds and process for preparing same
    3.
    发明授权
    Plastic copolymers of propylene with linear dienes having conjugated double-bonds and process for preparing same 失效
    丙烯与具有共轭双键的线性二烯的塑料共聚物及其制备方法

    公开(公告)号：US4602077A

    公开(公告)日：1986-07-22

    申请号：US758421

    申请日：1985-07-24

    申请人： Giuliano Cecchin ,  Floriano Guglielmi ,  Francesco Zerega

    发明人： Giuliano Cecchin ,  Floriano Guglielmi ,  Francesco Zerega

    IPC分类号： C08F210/00 ,  C08F4/60 ,  C08F4/654 ,  C08F10/06 ,  C08F210/06 ,  C08F255/02

    CPC分类号： C08F255/02 ,  C08F210/06

    摘要： Disclosed are plastic copolymers of propylene with linear dienes having conjugated double bonds, in particular with butadiene, characterized by a molar ratio between the dienic units in configuration 1,2 and those in configuration 1,4 higher than 0.2, preferably higher than 1.Such copolymers are prepared by copolymerization of propylene with linear dienes in the presence of stereospecific catalysts comprising a halogen Ti compound supported on a Mg halide.The copolymers can be reacted with radically polymerizable monomers, thus obtaining functionalized products suited to be transformed into films having good adhesion characteristics.

    摘要翻译： 公开了丙烯与具有共轭双键的线性二烯，特别是丁二烯的塑性共聚物，其特征在于构型1,2中的二烯单元与构型1,4中的二烯单元之间的摩尔比高于0.2，优选高于1。 共聚物通过在包含负载在卤化镁上的卤素Ti化合物的立体选择性催化剂存在下，使丙烯与线性二烯共聚来制备。 共聚物可与可自由基聚合的单体反应，从而获得适于转变成具有良好粘合特性的薄膜的官能化产物。

    Process for preparing components of catalysts for polymerizing alpha-olefins and mixtures thereof with ethylene
    4.
    发明授权
    Process for preparing components of catalysts for polymerizing alpha-olefins and mixtures thereof with ethylene 失效
    制备用于聚合α-烯烃的催化剂及其与乙烯的混合物的组分的方法

    公开(公告)号：US4294721A

    公开(公告)日：1981-10-13

    申请号：US134773

    申请日：1980-03-28

    申请人： Giuliano Cecchin ,  Enrico Albizzati

    发明人： Giuliano Cecchin ,  Enrico Albizzati

    IPC分类号： C08F4/00 ,  B01J31/38 ,  B01J37/02 ,  C08F4/02 ,  C08F4/60 ,  C08F4/64 ,  C08F10/00

    CPC分类号： C08F4/022 ,  C08F10/00

    摘要： A process for preparing components of catalysts for the polymerization of alpha-olefins and mixtures thereof with ethylene is disclosed. The process comprises reacting a Ti compound having at least oe Ti-halogen linkage with either (1) a mixture of a hydrocarbyl electron-donor compound ED which does not contain active H atoms and an adduct (a) of a Mg dihalide with at least one hydrocarbyl electron-donor compound AH containing active H atoms, or (2) with an adduct (b) of at least a Mg dihalide with a compound AH and ED defined in (1), adducts (a) and (b) being obtained without co-grinding of the Mg dihalide with compounds AH and ED.

    摘要翻译： 公开了一种制备用于α-烯烃聚合的催化剂组分及其与乙烯的混合物的方法。 该方法包括使具有至少一个钛卤素键的Ti化合物与（1）不含活性H原子的烃基电子给体化合物ED和二卤化镁的加合物（a）的混合物至少 一种含有活性H原子的烃基电子给体化合物AH，或者（2）与（1）中定义的化合物AH和ED的加合物（a）和（b）的至少二卤化镁的加合物（b） 没有将二卤化镁与化合物AH和ED共同研磨。

    Polyolefin compositions
    5.
    发明申请
    Polyolefin compositions 审中-公开
    聚烯烃组合物

    公开(公告)号：US20080182941A1

    公开(公告)日：2008-07-31

    申请号：US11982705

    申请日：2007-11-01

    申请人： Angelo Ferraro ,  Tiziano Dall'Occo ,  Giuliano Cecchin

    发明人： Angelo Ferraro ,  Tiziano Dall'Occo ,  Giuliano Cecchin

    IPC分类号： C08F210/00 ,  C08L23/00

    CPC分类号： C08L23/0815 ,  C08F10/00 ,  C08F210/00 ,  C08F210/16 ,  C08F255/00 ,  C08F255/02 ,  C08L23/10 ,  C08L23/16 ,  C08L51/06 ,  C08L2314/02 ,  C08F4/6555 ,  C08F4/6494 ,  C08F4/651 ,  C08L2666/06 ,  C08L2666/02 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/08 ,  C08F2500/20 ,  C08F2500/11 ,  C08F210/06 ,  C08F2500/17 ,  C08F2500/04

    摘要： A polyolefin composition, comprising: (A) from 5 to 95 parts by weight of a crystalline propylene polymer having an isotactic index greater than 80, selected from polypropylene homopolymer and propylene copolymers containing 0.5 to 15 mol % of ethylene and/or an α-olefin having 4 to 10 carbon atoms, and (B) from 5 to 95 parts by weight of an ethylene/α-olefin copolymer containing from 35 to 70% by weight of ethylene, from 30 to 65% by weight of an olefin CH2═CHR, in which R a hydrocarbyl radical with 1-12 carbon atoms, and from 0 to 10% of a polyene characterized by (i) a Molecular Weight Distribution expressed by Mw/Mn of higher than 3, (ii) a content of 2-1 regioinvertions of the α-olefin units of lower than 5% and (iii) a value of Shore A and content by weight of ethylenic units, calculated on the basis of the whole polymer, such that the point defined by such values falls below the curve defined by the following equation: Y=0.0438X2-4.1332X+A where Y is the value of the Shore A, X is the weight percentage of ethylene units in the polymer calculated by NMR and A is 145.

    摘要翻译： 一种聚烯烃组合物，其包含：（A）5至95重量份的全同立构指数大于80的结晶丙烯聚合物，其选自聚丙烯均聚物和含有0.5至15摩尔％乙烯和/或α-烯烃的丙烯共聚物， 具有4至10个碳原子的烯烃，和（B）5至95重量份的含有35至70重量％乙烯的乙烯/α-烯烃共聚物，30至65重量％的烯烃CH 2， 其中R 1具有1-12个碳原子的烃基和0至10％的多烯，其特征在于（i）由Mw / Mn表示的分子量分布高于3 ，（ii）α-烯烃单元的2-1区域转换的含量低于5％，（iii）肖氏A值和基于整个聚合物计算的烯属单元的重量含量，使得 由这些值定义的点低于由以下等式定义的曲线：<？in-line-formula description =“In-li “公式”end =“lead”？> Y = 0.0438X <2> -4.1332X + A <？in-line-formula description =“In-line Formulas”end =“tail”？> where Y是肖氏A的值，X是通过NMR计算的聚合物中乙烯单元的重量百分比，A是145。

    Crystalline polymers of propylene having improved processability in the molten state and process for their preparation
    6.
    发明授权
    Crystalline polymers of propylene having improved processability in the molten state and process for their preparation 失效
    丙烯的结晶聚合物在熔融状态下具有改进的加工性能及其制备方法

    公开(公告)号：US07332556B2

    公开(公告)日：2008-02-19

    申请号：US11385711

    申请日：2006-03-22

    申请人： Giuliano Cecchin ,  Anteo Pelliconi ,  Antonio Ciarrocchi ,  Paolo Ferrari

    发明人： Giuliano Cecchin ,  Anteo Pelliconi ,  Antonio Ciarrocchi ,  Paolo Ferrari

    IPC分类号： C08F110/06

    CPC分类号： C08F297/08 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6465 ,  C08F2/001 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/11

    摘要： Crystalline polymers and copolymers of propylene having total MIL values>2 g/10 minutes, total [η] values in tetrahydronaphthalene at 135° C.≦2.8 dl/g, mW/MN values>20, a fraction insoluble in xylene at 25° C.≧94, and including from 10 to 60% by weight of a fraction (A) having [η]≧2.6, are prepared by way of sequential polymerization in at least two stages, in the presence of a particular Ziegler-Natta catalysts supported on magnesium halides. These polymers have high melt strength, high mechanical properties, and are particularly adequate for the manufacture of articles by using various conversion technologies, such as for example extrusion in thin sheets to be subjected to thermoforming, as well as for injection molding, and blow molding.

    摘要翻译： 总共MIL值> 2g / 10分钟的丙烯结晶聚合物和共聚物，四氢化萘在135℃时的总η= 2.8dl / g，mW / MN值> 20，在25℃下不溶于二甲苯的级分 °C = 94，并且包括10至60重量％的具有η= 2.6的级分（A），通过在至少两个阶段中的顺序聚合，在特定的齐格勒（Ziegler）的存在下制备 -Natta催化剂负载在卤化镁上。 这些聚合物具有高熔体强度，高机械性能，并且特别适用于通过使用各种转化技术制造制品，例如在薄片中挤出以进行热成型，以及用于注射成型和吹塑 。

    Elastoplastic polyolefin compositions
    7.
    发明授权
    Elastoplastic polyolefin compositions 失效
    弹塑性聚烯烃组合物

    公开(公告)号：US5286564A

    公开(公告)日：1994-02-15

    申请号：US734390

    申请日：1991-07-23

    申请人： Giuliano Cecchin ,  Floriano Guglielmi ,  Anteo Pelliconi ,  Emanuele Burgin

    发明人： Giuliano Cecchin ,  Floriano Guglielmi ,  Anteo Pelliconi ,  Emanuele Burgin

    IPC分类号： C08F4/654 ,  C08F4/60 ,  C08F297/08 ,  C08J5/00 ,  C08L23/08 ,  C08L23/10 ,  C08L23/16

    CPC分类号： C08F297/08 ,  C08L2207/02 ,  Y10T428/2982

    摘要： Elastoplastic polyolefin compositions endowed with high flexibility, comprising:A) 10-50 parts by weight of a homopolymer of propylene with isotactic index greater than 80, or a copolymer of propylene with ethylene, another .alpha.-olefin, or combinations thereof, which copolymer contains over 85% by weight of propylene;B) 5-20 parts by weight of a copolymer fraction containing ethylene, insoluble in xylene at ambient temperature;C) 40-80 parts by weight of a copolymer fraction of ethylene and propylene or another .alpha.-olefin, or combinations thereof, and, optionally, minor portions of a diene, said fraction containing less than 40% by weight of ethylene, being soluble in xylene at ambient temperature, and having an intrinsic viscosity from 1.5 to 4 dl/g; the percent by weight of the sum of the (B) and (C) fractions with respect to the total polyolefin composition being of from 50% to 90% and the (B)/(C) weight ratio being lower than 0.4.

    摘要翻译： 具有高柔性的弹塑性聚烯烃组合物，包括：A）10-50重量份丙烯均等度指数大于80的均聚物，或丙烯与乙烯的共聚物，另一种（α）α-烯烃或其组合，其中 共聚物含有超过85重量％的丙烯; B）5-20重量份含乙烯的共聚物部分，在环境温度下不溶于二甲苯; C）40-80重量份的乙烯和丙烯或另一种（α） - 烯烃或其组合的共聚物部分，和任选的二烯的少部分，所述馏分含有小于40重量％的乙烯， 在环境温度下溶于二甲苯，其特性粘度为1.5-4dl / g; 相对于总聚烯烃组合物，（B）和（C）级分之和的重量百分比为50％至90％，（B）/（C）重量比低于0.4。

    Crystalline polymers of propylene having improved processability in the molten state and process for their preparation
    9.
    发明授权
    Crystalline polymers of propylene having improved processability in the molten state and process for their preparation 失效
    丙烯的结晶聚合物在熔融状态下具有改进的加工性能及其制备方法

    公开(公告)号：US07074871B2

    公开(公告)日：2006-07-11

    申请号：US10361569

    申请日：2003-02-11

    申请人： Giuliano Cecchin ,  Anteo Pelliconi ,  Antonio Ciarrocchi ,  Paolo Ferrari

    发明人： Giuliano Cecchin ,  Anteo Pelliconi ,  Antonio Ciarrocchi ,  Paolo Ferrari

    IPC分类号： C08F110/06

    CPC分类号： C08F297/08 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F4/6465 ,  C08F2/001 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/04 ,  C08F2500/11 ,  C08F2500/26

    摘要： Crystalline polymers and copolymers of propylene having total MIL values>2 g/10 minutes, total [η] values in tetrahydronaphthalene at 135° C.≦2/8 dl/g, Mw/Mn values>20, a fraction insoluble in xylene at 25° C.≧94, and including from 10 to 60% by weight of a fraction (A) having [η]≧2.6, are prepared by way of sequential polymerization in at least two stages, in the presence of particular Ziegler-Natta catalysts supported on magnesium halides. These polymers have high melt strength, high mechanical properties, and are particularly adequate for the manufacture of articles by using various conversion technologies, such as for example extrusion in thin sheets to be subjected to thermoforming, as well as for injection molding, and blow molding.

    摘要翻译： 总共MIL值> 2g / 10分钟的丙烯的结晶聚合物和共聚物，在四氢化萘中135℃时的总η= 2 / 8dl / g，Mw / Mn值> 20，不溶于二甲苯的级分 在25℃下，≥94，并且包括10至60重量％的具有η= 2.6的级分（A），通过在至少两个阶段中的顺序聚合制备，在特定的存在下 齐格勒 - 纳塔催化剂负载在卤化镁上。 这些聚合物具有高熔体强度，高机械性能，并且特别适用于通过使用各种转化技术制造制品，例如在薄片中挤出以进行热成型，以及用于注射成型和吹塑 。

    Impact resistant polyolefin compositions
    10.
    发明授权
    Impact resistant polyolefin compositions 有权
    耐冲击聚烯烃组合物

    公开(公告)号：US06441094B1

    公开(公告)日：2002-08-27

    申请号：US09831712

    申请日：2001-05-14

    申请人： Giuliano Cecchin ,  Anteo Pelliconi ,  Paola Sgarzi ,  Paolo Ferrari

    发明人： Giuliano Cecchin ,  Anteo Pelliconi ,  Paola Sgarzi ,  Paolo Ferrari

    IPC分类号： C08L2300

    CPC分类号： C08L23/10 ,  C08F297/08 ,  C08L23/0815 ,  C08L23/12 ,  C08L23/142 ,  C08L23/16 ,  C08L53/00 ,  C08L2205/02 ,  C08L2314/02 ,  C08L2666/04 ,  C08L2666/02

    摘要： Polyolefin compositions comprising (percent by weight) A) 60%-95% of a crystalline polypropylene component having a Melt Flow Rate (MFRA) value of from 2.5 to 50 g/10 min. and containing from 20% to 80% of a fraction AI) having MFRI from 0.5 to 8 g/10 min., and from 20% to 80% of a fraction AII); B) 5%-40% of a copolymer of ethylene with one or more C4-C10 &agr;-olefin(s) containing from 10 to 40% of said C4-C10 &agr;-olefin(s); the ratio MFRA/MFRI being from 2 to 25; the percentages of A) and B) being referred to the sum of A) and B), and the percentages of AI) and AII) being referred to the sun of AI) and AII).

    摘要翻译： 包含（重量％）A）60％-95％的熔体流动速率（MFRA）值为2.5至50g / 10min的结晶聚丙烯组分的聚烯烃组合物。 并含有20％至80％的MFR 1为0.5至8g / 10min的级分AI）和20％至80％的级分AII）; B）乙烯与一种或多种含有10至40％所述C 4 -C 10α-烯烃的C 4 -C 10α-烯烃的共聚物的5％-40％; MFRA / MFRI的比例为2至25; A）和B）的百分比被称为A）和B）的总和，AI）和AII的百分比被称为AI的太阳）和AII）。