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公开(公告)号：US20080119634A1
公开(公告)日：2008-05-22
申请号：US10538190
申请日：2003-12-02
申请人： Gordon Calundann , Oemer Uensal , Brian Benicewicz , Bobby G. Dawkins , J. Dean Baker , Rita H. Joiner
发明人： Gordon Calundann , Oemer Uensal , Brian Benicewicz , Bobby G. Dawkins , J. Dean Baker , Rita H. Joiner
IPC分类号： C08G73/18
CPC分类号： C08G73/08 , B01D61/025 , B01D69/141 , B01D71/62 , C08G73/06 , C08G73/0616 , C08G73/0688 , C08G73/0694 , C08G73/18 , C08G73/22 , C08J5/2256 , C08J2379/06 , H01G9/02 , H01G9/058 , H01M2/1653 , H01M8/103 , H01M8/1048 , H01M2300/0082 , Y02P70/56
摘要： The invention under consideration concerns novel high-molecular-weight polyazoles, which are suitable for the production of fibers, films, membranes, and molded articles, on the basis of their high molecular weight, expressed as intrinsic viscosity, of at least 1.3 dl/g. Moreover, the invention under consideration describes a method for the production of high-molecular-weight polyazoles.
摘要翻译： 考虑到的本发明涉及新型高分子量多唑，其适用于以其特性粘度表示的高分子量至少为1.3dl / g的纤维，膜，膜和模塑制品的生产， G。 此外，所考虑的发明描述了用于生产高分子量多偶唑的方法。
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公开(公告)号：US07696302B2
公开(公告)日：2010-04-13
申请号：US10538190
申请日：2003-12-02
申请人： Gordon Calundann , Oemer Uensal , Brian Benicewicz , Bobby G. Dawkins , J. Dean Baker , Rita H. Joiner
发明人： Gordon Calundann , Oemer Uensal , Brian Benicewicz , Bobby G. Dawkins , J. Dean Baker , Rita H. Joiner
CPC分类号： C08G73/08 , B01D61/025 , B01D69/141 , B01D71/62 , C08G73/06 , C08G73/0616 , C08G73/0688 , C08G73/0694 , C08G73/18 , C08G73/22 , C08J5/2256 , C08J2379/06 , H01G9/02 , H01G9/058 , H01M2/1653 , H01M8/103 , H01M8/1048 , H01M2300/0082 , Y02P70/56
摘要： The invention under consideration concerns novel high-molecular-weight polyazoles, which are suitable for the production of fibers, films, membranes, and molded articles, on the basis of their high molecular weight, expressed as intrinsic viscosity, of at least 1.3 dl/g. Moreover, the invention under consideration describes a method for the production of high-molecular-weight polyazoles.
摘要翻译： 考虑到的本发明涉及新型高分子量多唑，其适用于以其特性粘度表示的高分子量至少为1.3dl / g的纤维，膜，膜和模塑制品的生产， G。 此外，所考虑的发明描述了用于生产高分子量多偶唑的方法。
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公开(公告)号：US07837763B2
公开(公告)日：2010-11-23
申请号：US11684826
申请日：2007-03-12
申请人： Gordon Calundann , Oemer Uensal , Brian Benicewicz , Bobby G. Dawkins , J. Dean Baker , Rita H. Joiner
发明人： Gordon Calundann , Oemer Uensal , Brian Benicewicz , Bobby G. Dawkins , J. Dean Baker , Rita H. Joiner
IPC分类号： B01D53/22
CPC分类号： C08G73/08 , B01D61/025 , B01D69/141 , B01D71/62 , C08G73/06 , C08G73/0616 , C08G73/0688 , C08G73/0694 , C08G73/18 , C08G73/22 , C08J5/2256 , C08J2379/06 , H01G9/02 , H01G9/058 , H01M2/1653 , H01M8/103 , H01M8/1048 , H01M2300/0082 , Y02P70/56
摘要： The invention under consideration concerns novel his-molecular-weight polyazoles, which are suitable for the production of fibers, films, membranes, and molded articles, on the basis of their high molecular weight, expressed as intrinsic viscosity, of at least 1.3 dl/g. Moreover, the invention under consideration describes a method for the production of high-molecular-weight polyazoles.
摘要翻译： 考虑到的本发明涉及新型的其分子量多唑类，它们适用于生产纤维，膜，膜和模塑制品，基于其特征粘度表示的高分子量至少为1.3dl / G。 此外，所考虑的发明描述了用于生产高分子量多偶唑的方法。
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4.发明授权Proton-conducting polymer membrane comprising polyazole blends and its use in fuel cells 失效包含聚唑共混物的导电聚合物膜及其在燃料电池中的应用公开(公告)号：US08142917B2
公开(公告)日：2012-03-27
申请号：US12776489
申请日：2010-05-10
申请人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui Wong Choe
发明人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui Wong Choe
IPC分类号： H01M8/10
CPC分类号： C08J5/2275 , B01D71/62 , C08G73/18 , C08J2379/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1037 , H01M8/1039 , H01M8/1041 , H01M8/1048 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： The present invention relates to a proton-conducting polymer membrane which comprises polyazole blends and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, wherein at least one further polymer (polymer B) which is not a polyazole is added to the composition obtainable according to step A) and/or step B) and the weight ratio of polyazole to polymer B is in the range from 0.1 to 50.
摘要翻译： 本发明涉及一种质子传导性聚合物膜，其包含聚唑共混物并且可通过包括以下步骤的方法获得：A）制备包含多磷酸，至少一种聚唑（聚合物A）和/或一种或多种化合物 适用于根据步骤B）在热的作用下形成多唑类; B）将惰性气体下得到的混合物加热至高达400℃的温度; C）使用混合物 从步骤A）和/或B）到支持物，D）处理在步骤C）中形成的膜，直到其自支撑，其中至少一种不是聚唑的另外的聚合物（聚合物B）加入到 根据步骤A）和/或步骤B）可获得的组合物，并且聚唑与聚合物B的重量比在0.1至50的范围内。
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公开(公告)号：US07820314B2
公开(公告)日：2010-10-26
申请号：US10566135
申请日：2004-07-23
IPC分类号： H01M8/10
CPC分类号： H01M8/1072 , H01M8/0289 , H01M8/1004 , H01M8/103 , H01M8/1048 , Y02P70/56
摘要： The present invention relates to a novel proton-conducting polymer membrane based on polyazole block polymers which, owing to their outstanding chemical and thermal properties, can be used widely and are suitable in particular as polymer electrolyte membrane (PEM) for producing membrane electrode units or so-called PEM fuel cells.
摘要翻译： 本发明涉及一种基于聚唑嵌段聚合物的新型质子导电聚合物膜，由于其优异的化学和热性质，可广泛使用，特别适用于制备膜电极单元的聚合物电解质膜（PEM）或 所谓的PEM燃料电池。
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公开(公告)号：US20110033777A1
公开(公告)日：2011-02-10
申请号：US12907368
申请日：2010-10-19
CPC分类号： H01M8/1072 , H01M8/0289 , H01M8/1004 , H01M8/103 , H01M8/1048 , Y02P70/56
摘要： The present invention relates to a novel proton-conducting polymer membrane based on polyazole block polymers which, owing to their outstanding chemical and thermal properties, can be used widely and are suitable in particular as polymer electrolyte membrane (PEM) for producing membrane electrode units or so-called PEM fuel cells.
摘要翻译： 本发明涉及一种基于聚唑嵌段聚合物的新型质子导电聚合物膜，由于其优异的化学和热性质，可广泛使用，特别适用于制备膜电极单元的聚合物电解质膜（PEM）或 所谓的PEM燃料电池。
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7.发明申请Proton-conducting polymer membrane that contains polyazoles and is coated with a catalyst layer, and application thereof in fuel cells 有权含有聚唑并且涂有催化剂层的导电聚合物膜及其在燃料电池中的应用公开(公告)号：US20060079392A1
公开(公告)日：2006-04-13
申请号：US10530242
申请日：2003-10-02
申请人： Jochen Baurmeister , Isabel Kundler , Christoph Padberg , Oemer Uensal , Joachim Kiefer , Gordon Calundann , Brian Benicewicz , Mathias Weber
发明人： Jochen Baurmeister , Isabel Kundler , Christoph Padberg , Oemer Uensal , Joachim Kiefer , Gordon Calundann , Brian Benicewicz , Mathias Weber
CPC分类号： C08J5/2256 , B01D71/62 , C08G73/18 , C08J2379/06 , H01M4/8605 , H01M4/92 , H01M8/1004 , H01M8/1027 , H01M8/103 , H01M8/1067 , H01M8/1072 , H01M8/109 , Y02P70/56
摘要： The present invention relates to a proton-conducting polymer membrane which comprises polyazoles and is coated with a catalyst layer and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture obtained according to step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, E) application of at least one catalyst-containing coating to the membrane formed in step C) and/or in step D).
摘要翻译： 本发明涉及一种质子传导性聚合物膜，其包含多唑并涂覆有催化剂层，并且可通过包括以下步骤的方法获得：A）制备包含多磷酸，至少一种聚唑（聚合物A）和/ 或一种或多种适合于根据步骤B）在热作用下形成多唑的化合物，B）在惰性气体下将根据步骤A）获得的混合物加热至高达400℃的温度，C）应用 使用根据步骤A）和/或B）获得的混合物与载体进行反应，D）处理在步骤C）中形成的膜，直到其自支撑为止，E）施加至少一种含催化剂的涂层 到步骤C）和/或步骤D）中形成的膜。
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8.发明申请PROTON-CONDUCTING POLYMER MEMBRANE COMPRISING POLYAZOLE BLENDS AND ITS USE IN FUEL CELLS 失效包含聚唑混合物的导电聚合物膜及其在燃料电池中的使用公开(公告)号：US20100216051A1
公开(公告)日：2010-08-26
申请号：US12776489
申请日：2010-05-10
申请人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui W. Choe
发明人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui W. Choe
CPC分类号： C08J5/2275 , B01D71/62 , C08G73/18 , C08J2379/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1037 , H01M8/1039 , H01M8/1041 , H01M8/1048 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： The present invention relates to a proton-conducting polymer membrane which comprises polyazole blends and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, wherein at least one further polymer (polymer B) which is not a polyazole is added to the composition obtainable according to step A) and/or step B) and the weight ratio of polyazole to polymer B is in the range from 0.1 to 50.
摘要翻译： 本发明涉及一种质子传导性聚合物膜，其包含聚唑共混物并且可通过包括以下步骤的方法获得：A）制备包含多磷酸，至少一种聚唑（聚合物A）和/或一种或多种化合物 适用于根据步骤B）在热的作用下形成多唑类; B）将惰性气体下得到的混合物加热至高达400℃的温度; C）使用混合物 从步骤A）和/或B）到支持物，D）处理在步骤C）中形成的膜，直到其自支撑，其中至少一种不是聚唑的另外的聚合物（聚合物B）加入到 根据步骤A）和/或步骤B）可获得的组合物，并且聚唑与聚合物B的重量比在0.1至50的范围内。
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9.发明授权Proton-conducting polymer membrane containing polyazole blends, and application thereof in fuel cells 失效含有聚唑共混物的导电聚合物膜及其在燃料电池中的应用公开(公告)号：US07736779B2
公开(公告)日：2010-06-15
申请号：US10530226
申请日：2003-10-02
申请人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui W. Choe
发明人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael J. Sansone , Brian Benicewicz , Eui W. Choe
IPC分类号： H01M8/10
CPC分类号： C08J5/2275 , B01D71/62 , C08G73/18 , C08J2379/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1037 , H01M8/1039 , H01M8/1041 , H01M8/1048 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： The present invention relates to a proton-conducting polymer membrane which comprises polyazole blends and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, wherein at least one further polymer (polymer B) which is not a polyazole is added to the composition obtainable according to step A) and/or step B) and the weight ratio of polyazole to polymer B is in the range from 0.1 to 50.
摘要翻译： 本发明涉及一种质子传导性聚合物膜，其包含聚唑共混物并且可通过包括以下步骤的方法获得：A）制备包含多磷酸，至少一种聚唑（聚合物A）和/或一种或多种化合物 适用于根据步骤B）在热的作用下形成多唑类; B）将惰性气体下得到的混合物加热至高达400℃的温度; C）使用混合物 从步骤A）和/或B）到支持物，D）处理在步骤C）中形成的膜，直到其自支撑，其中至少一种不是聚唑的另外的聚合物（聚合物B）加入到 根据步骤A）和/或步骤B）可获得的组合物，并且聚唑与聚合物B的重量比在0.1至50的范围内。
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10.发明申请Proton-conducting polymer membrane containing polyazole blends and application thereof in fuel cells 失效含有聚唑共混物的导电聚合物膜及其在燃料电池中的应用公开(公告)号：US20060078774A1
公开(公告)日：2006-04-13
申请号：US10530226
申请日：2003-10-02
申请人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael Sansone , Brian Benicewicz , Eui Choe
发明人： Oemer Uensal , Joachim Kiefer , Gordon Calundann , Michael Sansone , Brian Benicewicz , Eui Choe
CPC分类号： C08J5/2275 , B01D71/62 , C08G73/18 , C08J2379/06 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1034 , H01M8/1037 , H01M8/1039 , H01M8/1041 , H01M8/1048 , H01M8/1072 , H01M8/1081 , Y02P70/56
摘要： The present invention relates to a proton-conducting polymer membrane which comprises polyazole blends and is obtainable by a process comprising the steps A) preparation of a mixture comprising polyphosphoric acid, at least one polyazole (polymer A) and/or one or more compounds which are suitable for forming polyazoles under the action of heat according to step B), B) heating of the mixture obtainable according to step A) under inert gas to temperatures of up to 400° C., C) application of a layer using the mixture from step A) and/or B) to a support, D) treatment of the membrane formed in step C) until it is self-supporting, wherein at least one further polymer (polymer B) which is not a polyazole is added to the composition obtainable according to step A) and/or step B) and the weight ratio of polyazole to polymer B is in the range from 0.1 to 50.
摘要翻译： 本发明涉及一种质子传导性聚合物膜，其包含聚唑共混物并且可通过包括以下步骤的方法获得：A）制备包含多磷酸，至少一种聚唑（聚合物A）和/或一种或多种化合物 适用于根据步骤B）在热的作用下形成多唑类; B）将惰性气体下得到的混合物加热至高达400℃的温度; C）使用混合物 从步骤A）和/或B）到支持物，D）处理在步骤C）中形成的膜，直到其自支撑，其中至少一种不是聚唑的另外的聚合物（聚合物B）加入到 根据步骤A）和/或步骤B）可获得的组合物，并且聚唑与聚合物B的重量比在0.1至50的范围内。
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