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    Hydrogenation of esters using alkali doped heterogeneous group VIII transition metal catalysts
    2.
    发明授权
    Hydrogenation of esters using alkali doped heterogeneous group VIII transition metal catalysts 失效
    使用碱掺杂的异质基团VIII过渡金属催化剂氢化酯

    公开(公告)号：US4346240A

    公开(公告)日：1982-08-24

    申请号：US307031

    申请日：1981-09-29

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: B01J23/58 ,  B01J31/28 ,  C07C29/149 ,  C07C31/38

    CPC classification number: B01J31/0204 ,  B01J23/58 ,  B01J31/0212 ,  B01J31/122 ,  B01J31/26 ,  B01J31/28 ,  B01J31/30 ,  C07C29/149 ,  B01J21/18 ,  B01J2231/641 ,  B01J31/1616 ,  Y02P20/52

    Abstract: A novel class of heterogeneous catalysts, containing Group VIII transition metals in combination with alkali organic compounds is prepared, such as potassium naphthalene on ruthenium on carbon. The catalysts are useful as heterogeneous catalysts in the hydrogenation of carboxylic acid esters. A process for producing the materials is described. The catalysts permit the process of the hydrogenation of carboxylic acid esters to primary alcohols to be conducted with the ester in the liquid phase at a temperature not exceeding about 150.degree. C. with high selectivity. Catalysts of Group VIII transition metals and alkali metal on carbon are also useful in such processes.

    Abstract translation: 制备了一类新颖的非均相催化剂，其中含有与碱性有机化合物组合的第VIII族过渡金属，例如萘上钌碳上的萘。 催化剂可用作羧酸酯氢化中的非均相催化剂。 对材料的制造方法进行说明。 催化剂允许羧酸酯与伯醇的氢化在液相中以不超过约150℃的温度以高选择性进行。 第VIII族过渡金属和碱金属碳的催化剂在这些方法中也是有用的。

    Process for hydrogenation of nitriles
    5.
    发明授权
    Process for hydrogenation of nitriles 失效
    腈水解方法

    公开(公告)号：US4254059A

    公开(公告)日：1981-03-03

    申请号：US62874

    申请日：1979-08-01

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: B01J31/18 ,  B01J31/24 ,  C07C209/48 ,  C07C85/20

    CPC classification number: C07C209/48 ,  B01J31/2404 ,  B01J2231/643 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/828 ,  B01J2531/842 ,  B01J31/1895

    Abstract: A novel process is described for the homogeneous hydrogenation of nitriles to primary amines utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the high yield hydrogenation of nitriles to primary amines to be conducted under mild conditions of temperature and pressure with high selectivity and eliminates the need for the presence of ammonia to suppress the formation of significant amounts of secondary and tertiary amines.

    Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂将腈均相氢化成伯胺的新方法。 使用这些阴离子催化剂允许腈在高温选择性条件下在温和条件下进行的腈的高产率氢化，并且不需要氨的存在来抑制显着量的仲胺和叔胺的形成。

    Process for homogeneous hydrogenation of esters
    6.
    发明授权
    Process for homogeneous hydrogenation of esters 失效
    酯类均相加氢方法

    公开(公告)号：US4232170A

    公开(公告)日：1980-11-04

    申请号：US007876

    申请日：1979-01-31

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: C07C29/149 ,  C07C69/675 ,  C07C27/04 ,  C07C31/38

    CPC classification number: C07C29/149 ,  Y02P20/52

    Abstract: A novel process is described for the homogeneous hydrogenation of carboxylic acid esters to primary alcohols utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted in solution under mild conditions of temperature and pressure with high selectivity and eliminates the disadvantages of utilizing heterogeneous catalysts. A process is also described for decarbonylating formate esters utilizing said compositions as catalysts.

    Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的羧酸酯与伯醇的均相氢化的新方法。 使用这些阴离子催化剂允许该方法在温和和高温的温和条件下在溶液中进行，并且消除了利用非均相催化剂的缺点。 还描述了使用所述组合物作为催化剂的甲酸酯脱羧酸酯的方法。

    Process for homogeneous hydrogenation of polycyclic aromatic hydrocarbons
    7.
    发明授权
    Process for homogeneous hydrogenation of polycyclic aromatic hydrocarbons 失效
    多环芳烃均相氢化方法

    公开(公告)号：US4224458A

    公开(公告)日：1980-09-23

    申请号：US7877

    申请日：1979-01-31

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: C07C5/11 ,  C07C13/28 ,  C07C15/24 ,  C07C15/28

    CPC classification number: C07C5/11 ,  C07C2102/10 ,  C07C2531/22

    Abstract: An improved process is described for the homogeneous hydrogenation of polycyclic aromatic hydrocarbons utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted under mild conditions of temperature and pressure with high selectivity for the production of partially hydrogenated derivatives of polycyclic aromatic hydrocarbons such as 1,2,3,4-tetrahydronaphthalene, and eliminates the need for the presence of base or carbon monoxide atmosphere in the process.

    Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的多环芳烃的均相氢化的改进方法。 使用这些阴离子催化剂允许该方法在温和的温度和压力条件下进行，并且高选择性地生产多环芳烃如1,2,3,4-四氢化萘的部分氢化衍生物，并且不需要 在该过程中存在碱或一氧化碳气氛。

    Direct epoxidation catalyst and process
    8.
    发明申请
    Direct epoxidation catalyst and process 失效
    直接环氧化催化剂和工艺

    公开(公告)号：US20110152550A1

    公开(公告)日：2011-06-23

    申请号：US12653678

    申请日：2009-12-17

    Applicant: Roger A. Grey ,  Robert N. Cochran ,  Bi Le-Khac

    Inventor： Roger A. Grey ,  Robert N. Cochran ,  Bi Le-Khac

    IPC: C07D301/06 ,  B01J29/068

    CPC classification number: C07D301/06 ,  B01J21/06 ,  B01J21/063 ,  B01J23/44 ,  B01J23/628 ,  B01J29/405 ,  B01J29/44 ,  B01J35/0006 ,  B01J35/0013 ,  B01J35/023 ,  B01J2229/42

    Abstract: A catalyst, useful for the direct epoxidation of olefins, is disclosed. The catalyst comprises palladium nanoparticles, support nanoparticles, and a titanium zeolite having a particle size of 2 microns or greater. The palladium nanoparticles are deposited on the support nanoparticles to form supported palladium nanoparticles, and the supported palladium nanoparticles are deposited on the titanium zeolite; or the supported palladium nanoparticles are deposited on a carrier having a particle size of 2 microns or greater. The invention also includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst. The catalysts are more active in epoxidation reactions, while demonstrating the same or better selectivity.

    Abstract translation: 公开了一种可用于烯烃直接环氧化的催化剂。 催化剂包括钯纳米颗粒，载体纳米颗粒和粒径为2微米或更大的钛沸石。 将钯纳米颗粒沉积在载体纳米颗粒上以形成负载的钯纳米颗粒，并将负载的钯纳米颗粒沉积在钛沸石上; 或者将负载的钯纳米颗粒沉积在粒径为2微米或更大的载体上。 本发明还包括一种生产环氧化物的方法，包括在催化剂存在下使烯烃，氢和氧反应。 催化剂在环氧化反应中更具活性，同时表现出相同或更好的选择性。

    Direct epoxidation process using a mixed catalyst system
    10.
    发明授权
    Direct epoxidation process using a mixed catalyst system 有权
    直接环氧化工艺采用混合催化剂体系

    公开(公告)号：US07470801B1

    公开(公告)日：2008-12-30

    申请号：US11977359

    申请日：2007-10-24

    Applicant: Roger A. Grey

    Inventor： Roger A. Grey

    IPC: C07D301/06

    CPC classification number: C07D301/06 ,  C07D301/08

    Abstract: Catalyst mixtures useful for the direct epoxidation of olefins are disclosed. The catalyst mixture comprises a titanium or vanadium zeolite and a supported catalyst comprising a noble metal, bismuth, and a carrier. The invention includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst mixture. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.

    Abstract translation: 公开了用于烯烃的直接环氧化的催化剂混合物。 催化剂混合物包含钛或钒沸石和包含贵金属，铋和载体的载体催化剂。 本发明包括一种生产环氧化物的方法，包括在催化剂混合物存在下使烯烃，氢和氧反应。 该方法可显着减少由烯烃氢化形成的烷烃副产物。

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