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    Hydrogenation of esters using alkali doped heterogeneous group VIII transition metal catalysts
    2.
    发明授权
    Hydrogenation of esters using alkali doped heterogeneous group VIII transition metal catalysts 失效
    使用碱掺杂的异质基团VIII过渡金属催化剂氢化酯

    公开(公告)号：US4346240A

    公开(公告)日：1982-08-24

    申请号：US307031

    申请日：1981-09-29

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: B01J23/58 ,  B01J31/28 ,  C07C29/149 ,  C07C31/38

    CPC classification number: B01J31/0204 ,  B01J23/58 ,  B01J31/0212 ,  B01J31/122 ,  B01J31/26 ,  B01J31/28 ,  B01J31/30 ,  C07C29/149 ,  B01J21/18 ,  B01J2231/641 ,  B01J31/1616 ,  Y02P20/52

    Abstract: A novel class of heterogeneous catalysts, containing Group VIII transition metals in combination with alkali organic compounds is prepared, such as potassium naphthalene on ruthenium on carbon. The catalysts are useful as heterogeneous catalysts in the hydrogenation of carboxylic acid esters. A process for producing the materials is described. The catalysts permit the process of the hydrogenation of carboxylic acid esters to primary alcohols to be conducted with the ester in the liquid phase at a temperature not exceeding about 150.degree. C. with high selectivity. Catalysts of Group VIII transition metals and alkali metal on carbon are also useful in such processes.

    Abstract translation: 制备了一类新颖的非均相催化剂，其中含有与碱性有机化合物组合的第VIII族过渡金属，例如萘上钌碳上的萘。 催化剂可用作羧酸酯氢化中的非均相催化剂。 对材料的制造方法进行说明。 催化剂允许羧酸酯与伯醇的氢化在液相中以不超过约150℃的温度以高选择性进行。 第VIII族过渡金属和碱金属碳的催化剂在这些方法中也是有用的。

    Process for hydrogenation of nitriles
    3.
    发明授权
    Process for hydrogenation of nitriles 失效
    腈水解方法

    公开(公告)号：US4254059A

    公开(公告)日：1981-03-03

    申请号：US62874

    申请日：1979-08-01

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: B01J31/18 ,  B01J31/24 ,  C07C209/48 ,  C07C85/20

    CPC classification number: C07C209/48 ,  B01J31/2404 ,  B01J2231/643 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/828 ,  B01J2531/842 ,  B01J31/1895

    Abstract: A novel process is described for the homogeneous hydrogenation of nitriles to primary amines utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the high yield hydrogenation of nitriles to primary amines to be conducted under mild conditions of temperature and pressure with high selectivity and eliminates the need for the presence of ammonia to suppress the formation of significant amounts of secondary and tertiary amines.

    Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂将腈均相氢化成伯胺的新方法。 使用这些阴离子催化剂允许腈在高温选择性条件下在温和条件下进行的腈的高产率氢化，并且不需要氨的存在来抑制显着量的仲胺和叔胺的形成。

    Process for homogeneous hydrogenation of esters
    4.
    发明授权
    Process for homogeneous hydrogenation of esters 失效
    酯类均相加氢方法

    公开(公告)号：US4232170A

    公开(公告)日：1980-11-04

    申请号：US007876

    申请日：1979-01-31

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: C07C29/149 ,  C07C69/675 ,  C07C27/04 ,  C07C31/38

    CPC classification number: C07C29/149 ,  Y02P20/52

    Abstract: A novel process is described for the homogeneous hydrogenation of carboxylic acid esters to primary alcohols utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted in solution under mild conditions of temperature and pressure with high selectivity and eliminates the disadvantages of utilizing heterogeneous catalysts. A process is also described for decarbonylating formate esters utilizing said compositions as catalysts.

    Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的羧酸酯与伯醇的均相氢化的新方法。 使用这些阴离子催化剂允许该方法在温和和高温的温和条件下在溶液中进行，并且消除了利用非均相催化剂的缺点。 还描述了使用所述组合物作为催化剂的甲酸酯脱羧酸酯的方法。

    Process for homogeneous hydrogenation of polycyclic aromatic hydrocarbons
    5.
    发明授权
    Process for homogeneous hydrogenation of polycyclic aromatic hydrocarbons 失效
    多环芳烃均相氢化方法

    公开(公告)号：US4224458A

    公开(公告)日：1980-09-23

    申请号：US7877

    申请日：1979-01-31

    Applicant: Roger A. Grey ,  Guido P. Pez

    Inventor： Roger A. Grey ,  Guido P. Pez

    IPC: C07C5/11 ,  C07C13/28 ,  C07C15/24 ,  C07C15/28

    CPC classification number: C07C5/11 ,  C07C2102/10 ,  C07C2531/22

    Abstract: An improved process is described for the homogeneous hydrogenation of polycyclic aromatic hydrocarbons utilizing anionic Group VIII metal hydride compositions as catalysts which contain phosphorus, arsenic or antimony organoligands. Use of these anionic catalysts allows the process to be conducted under mild conditions of temperature and pressure with high selectivity for the production of partially hydrogenated derivatives of polycyclic aromatic hydrocarbons such as 1,2,3,4-tetrahydronaphthalene, and eliminates the need for the presence of base or carbon monoxide atmosphere in the process.

    Abstract translation: 描述了使用阴离子VIII族金属氢化物组合物作为含有磷，砷或锑有机液体的催化剂的多环芳烃的均相氢化的改进方法。 使用这些阴离子催化剂允许该方法在温和的温度和压力条件下进行，并且高选择性地生产多环芳烃如1,2,3,4-四氢化萘的部分氢化衍生物，并且不需要 在该过程中存在碱或一氧化碳气氛。

    Alkali metal amide catalyst
    10.
    发明授权
    Alkali metal amide catalyst 失效
    碱金属酰胺催化剂

    公开(公告)号：US4336162A

    公开(公告)日：1982-06-22

    申请号：US288273

    申请日：1981-07-30

    Applicant: Guido P. Pez

    Inventor： Guido P. Pez

    IPC: C07C209/60 ,  B01J27/24 ,  B01J31/12

    CPC classification number: C07C209/60

    Abstract: Monolefins such as ethylene are reacted with ammonia using alkali metal amide catalysts such as cesium or rubidium amides, or low melting mixtures of amides such as cesium/potassium, cesium/sodium or sodium/potassium amides. Conversions are improved compared to reactions using sodium or potassium amide alone. Conversions of ethylene are improved also when liquid ammonia is present.

    Abstract translation: 使用碱金属酰胺催化剂如铯或铷酰胺或诸如铯/钾，铯/钠或钠/钾的酰胺的低熔点混合物，使乙烯等单烯与氨反应。 与使用单独使用钠或钾的反应相比，转化率有所改善。 当液氨存在时，乙烯的转化也得到改善。

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