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公开(公告)号：US4996353A
公开(公告)日：1991-02-26
申请号：US352575
申请日：1989-05-16
IPC分类号： C07C51/265
CPC分类号： C07C51/265
摘要： A process for the preparation of polyphenyl dicarboxylic acids is disclosed. The process comprises contacting para,para'-diisoalkyl or dialkyl-polyphenyl or an oxidation intermediate thereof with oxygen under reaction conditions sufficient to form para,para'-polyphenyldicarboxylic acid. The process is optionally carried out in the presence of cobalt, manganese, and bromine compounds.
摘要翻译： 公开了一种制备聚苯二羧酸的方法。 该方法包括在足以形成对位，对聚 - 多苯基二羧酸的反应条件下，使对位，对 - 二异烷基或二烷基 - 聚苯基或其氧化中间体与氧接触。 该方法任选在钴，锰和溴化合物的存在下进行。
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2.发明授权Process for the preparation of dihydroperoxyalkyl polyphenyls and dihydroxy polyphenyls 失效制备二氢过氧烷基聚苯基和二羟基聚苯基的方法
公开(公告)号：US5338887A
公开(公告)日：1994-08-16
申请号：US858465
申请日：1991-11-06
IPC分类号： C07C39/15 , C07C409/08 , C08G63/60
CPC分类号： C07C409/08 , C07C39/15 , C08G63/605 , Y02P20/582
摘要： A process for the preparation of dihydroxy polyphenyl compounds is disclosed which comprises the simultaneous steps of (a) contacting the corresponding diisoalkyl polyphenyl compound or an oxidation intermediate thereof with oxygen under reaction conditions sufficient to form a corresponding dihydroperoxyalkyl polyphenyl compound and (b) contacting the dihydroperoxyalkyl polyphenyl compound with an acid under reaction conditions sufficient to form the corresponding dihydroxy polyphenyl compound. In addition, the intermediate dihydroperoxyalkyl polyphenyl compound is a novel compound.
摘要翻译： 公开了制备二羟基多苯基化合物的方法，其包括（a）在足以形成相应的二氢过氧烷基聚苯基化合物的反应条件下使相应的二异烷基聚苯基化合物或其氧化中间体与氧接触的步骤，和（b）使 二氢过氧烷基聚苯基化合物与酸反应，该反应条件足以形成相应的二羟基聚苯基化合物。 此外，中间体二氢过氧烷基聚苯基化合物是新型化合物。
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公开(公告)号：US5583268A
公开(公告)日：1996-12-10
申请号：US573091
申请日：1995-12-15
CPC分类号： C07C37/14 , B01J21/04 , B01J23/58 , B01J37/0201 , B01J37/18 , C07C37/06 , C07C2101/14 , Y02P20/52
摘要： A process of catalytically reacting a 3-18 carbon mono-olefin such as cyclohexene with an arylhydroxide such as phenol in the liquid phase forming an ortho-alkylated arylhydroxide which is subsequently catalytically dehydrogentated to form an ortho-alkenylarylhydroxide or ortho-arylarylhydroxide such as ortho-phenylphenol.
摘要翻译： 在液相中使3-18碳一烯烃如环己烯与芳基氢氧化物如苯酚进行催化反应的方法，形成邻烷基化的芳基氢氧化物，随后催化脱氢，形成邻链烯基芳基氢氧化物或邻 - 芳基芳基氢氧化物， - 苯酚。
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4.发明授权Blend of copolyestercarbonate polymer derived from diaryl dicarboxylic acid 失效由二芳基二羧酸衍生的共聚酯碳酸酯聚合物的共混物
公开(公告)号：US5045610A
公开(公告)日：1991-09-03
申请号：US401213
申请日：1989-08-31
IPC分类号： C08G63/64 , C08L69/00 , C08L101/00
CPC分类号： C08L69/005 , C08G63/64 , C08L101/00
摘要： This invention relates to copolyestercarbonate polymers which are prepared with diaryl dicarboxylic acid compounds, particularly biphenyldicarboxylic acid compounds. Such copolyestercarbonate polymers show good physical properties including high glass transition temperatures and low ultraviolet radiation sensitivity. The thermoplastic copolymestercarbonates can be used to prepare films or molded articles or blended with other thermoplastic resins to give thermoplastic polymer blends for molding purposes.
摘要翻译： 本发明涉及用二芳基二羧酸化合物，特别是联苯二羧酸化合物制备的共聚酯碳酸酯聚合物。 这种共聚酯碳酸酯聚合物显示出良好的物理性质，包括高玻璃化转变温度和低紫外线辐射敏感性。 热塑性共聚酯碳酸酯可用于制备膜或模塑制品或与其它热塑性树脂共混以得到用于模制目的的热塑性聚合物共混物。
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5.发明授权Metathesis of unsaturated fatty acid esters or unsaturated fatty acids with lower olefins 有权不饱和脂肪酸酯或不饱和脂肪酸与低级烯烃的复分解公开(公告)号：US07119216B2
公开(公告)日：2006-10-10
申请号：US10469321
申请日：2002-02-27
申请人： Thomas H. Newman , Cynthia L. Rand , Kenneth A. Burdett , Bob R. Maughon , Donald L. Morrison , Eric P. Wasserman
发明人： Thomas H. Newman , Cynthia L. Rand , Kenneth A. Burdett , Bob R. Maughon , Donald L. Morrison , Eric P. Wasserman
IPC分类号： C11C3/00
CPC分类号： C07C51/353 , B01J31/1658 , B01J31/2208 , B01J31/2265 , B01J31/2273 , B01J31/24 , B01J31/2404 , B01J31/28 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07C7/04 , C07C7/12 , C07C67/333 , Y02P20/127 , C07C11/02 , C07C57/03 , C07C69/533
摘要： An olefin metathesis process involving contacting an unsaturated fatty acid ester or unsaturated fatty acid, such as methyloleate or oleic acid, with a lower olefin, preferably ethylene, in the presence of a metathesis catalyst so as to prepare a first product olefin, preferably, a reduced chain α-olefin, such as methyl-9-decenoate or 9-decenoic acid, respectively. The metathesis catalyst contains ruthenium or osmium and a chelating ligand, preferably, a chelating ligand containing a carbene moiety and a second donor moiety of a Group 15 or 16 element Optionally, the catalyst can be supported on a catalyst support, such as, a cross-linked polymeric resin.
摘要翻译： 一种烯烃复分解方法，包括使不饱和脂肪酸酯或不饱和脂肪酸如羟甲基或油酸与复分解催化剂存在下使低级烯烃（优选乙烯）接触，以制备第一产物烯烃，优选为 还原链α-烯烃，如9-癸烯酸甲酯或9-癸烯酸。 复分解催化剂含有钌或锇和螯合配体，优选含有卡宾部分和第15或16族元素的第二供体部分的螯合配体任选地，催化剂可负载在催化剂载体上，例如十字 连接的聚合物树脂。
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公开(公告)号：US06313252B1
公开(公告)日：2001-11-06
申请号：US09244921
申请日：1999-02-04
申请人： Ray E. Drumright , Robert H. Terbrueggen , Kenneth A. Burdett , Francis J. Timmers , Stephen F. Hahn
发明人： Ray E. Drumright , Robert H. Terbrueggen , Kenneth A. Burdett , Francis J. Timmers , Stephen F. Hahn
IPC分类号： C08F21208
CPC分类号： C08F8/24 , C08F8/30 , C08F2800/10 , C08F2800/20 , C08F2810/30 , C08F2810/50 , C08F210/02 , C08F8/44 , C08F8/32 , C08F8/40 , C08F8/00 , C08F8/10 , C08F8/06 , C08F8/04 , C08F8/34 , C08F8/42 , C08F8/22
摘要： Novel substantially random functionalized interpolymers and processes for making them are disclosed. The novel interpolymers include those prepared from ethylene and vinyl aromatic monomers such as ethylene-styrene interpolymers which are then functionalized with a variety of electrophilic and nucleophilic reagents.
摘要翻译： 公开了新的基本上随机的官能化互聚物及其制备方法。 新型互聚物包括由乙烯和乙烯基芳族单体如乙烯 - 苯乙烯互聚物制备的那些，然后用各种亲电子和亲核试剂进行官能化。
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7.发明授权Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups 失效具有侧链烯属不饱和氨基甲酸酯基团的加成聚合聚醚
公开(公告)号：US4287323A
公开(公告)日：1981-09-01
申请号：US1125
申请日：1979-01-05
IPC分类号： C08F299/02 , C08G18/63 , C08G18/81 , C08G65/333 , C09D171/02 , C08L75/08
CPC分类号： C08F299/024 , C08G18/635 , C08G18/81 , C08G18/8116 , C08G65/33396 , C09D171/02 , Y10S525/912 , Y10S525/925
摘要： Addition polymerizable polyethers having pendant ethylenically unsaturated urethane groups are usefully employed as flooring materials and in other applications utilizing radiation curable or chemically curable materials. Such urethane polyethers are advantageously prepared by reacting a polyether polyol such as a hydroxy terminated polypropylene glycol with an isocyanatoalkyl ester of an ethylenically unsaturated acid such as 2-isocyanatoethyl methacrylate.
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公开(公告)号：US07176336B2
公开(公告)日：2007-02-13
申请号：US10940403
申请日：2004-09-14
IPC分类号： C07C29/00 , C07C33/025 , C07C33/03
CPC分类号： C07C29/095 , C07C67/293 , C07C67/333 , C07C67/475 , C07C69/007 , C07C69/533 , C07C69/593 , C07C69/145 , C07C33/03 , C07C33/035
摘要： A process of preparing an unsaturated alcohol (olefin alcohol), such as, a homo-allylic mono-alcohol or homo-allylic polyol, involving protecting a hydroxy-substituted unsaturated fatty acid or fatty acid ester, such as methyl ricinoleate, derived from a seed oil, to form a hydroxy-protected unsaturated fatty acid or fatty acid ester; homo-metathesizing or cross-metathesizing the hydroxy-protected unsaturated fatty acid or fatty acid ester to produce a product mixture containing a hydroxy-protected unsaturated metathesis product; and deprotecting the hydroxy-protected unsaturated metathesis product under conditions sufficient to prepare the unsaturated alcohol. Preferably, methyl ricinoleate is converted by cross-metathesis or homo-metathesis into the homo-allylic mono-alcohol 1-decene-4-ol or the homo-allylic polyol 9-octadecene-7,12-diol, respectively.
摘要翻译： 一种制备不饱和醇（烯烃）的方法，例如均聚单醇或均烯基多元醇，包括保护羟基取代的不饱和脂肪酸或脂肪酸酯如蓖麻油酸甲酯，其衍生自 种子油，形成羟基保护的不饱和脂肪酸或脂肪酸酯; 羟基保护的不饱和脂肪酸或脂肪酸酯的均匀化或交叉变性以产生含有羟基保护的非饱和复分解产物的产物混合物; 并在足以制备不饱和醇的条件下脱保护羟基保护的不饱和复分解产物。 优选地，蓖麻油酸甲酯通过交叉复分解或均一复分解转化成均相烯醇1-癸烯-4-醇或均烯基多元醇9-十八碳烯-7,12-二醇。
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公开(公告)号：US5488020A
公开(公告)日：1996-01-30
申请号：US200258
申请日：1994-02-23
CPC分类号： C07C2/52 , C07C2101/16 , C07C2529/08 , C07C2529/18 , C07C2529/60 , C07C2529/70
摘要： A composition comprising a copper(I) impregnated aluminosilicate zeolite wherein the zeolite is selected from faujasites, L and .OMEGA., and wherein the zeolite has a silica to bulk alumina molar ratio between about 12 and about 50 and a silica to framework alumina molar ratio of at least about 15. The catalyst preparation involves in the following order: drying the selected zeolite, impregnating the dried zeolite with a copper(II) salt, calcining the copper(II)-impregnated zeolite, and reducing the copper(II) to copper(I). The composition is useful as a catalyst for the cyclodimerization of 1,3-butadiene to 4-vinylcyclohexene.
摘要翻译： 一种包含铜（I）浸渍的硅铝酸盐沸石的组合物，其中所述沸石选自八面沸石，L和OMEGA，并且其中所述沸石的二氧化硅与本体氧化铝摩尔比为约12至约50，二氧化硅与骨架氧化铝的摩尔比为 催化剂制备按以下顺序包括：干燥所选择的沸石，用铜（II）盐浸渍干燥的沸石，煅烧铜（II）浸渍的沸石，并将铜（II）还原成铜 （一世）。 该组合物可用作1,3-丁二烯环化为4-乙烯基环己烯的催化剂。
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10.发明授权Process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes 失效将1,3-丁二烯环化为4-乙烯基环己烯的方法
公开(公告)号：US5196621A
公开(公告)日：1993-03-23
申请号：US688808
申请日：1991-04-19
IPC分类号： C07C2/52
CPC分类号： C07C2/52 , C07C2101/16 , C07C2529/08 , C07C2529/18 , C07C2529/60 , C07C2529/70
摘要： A process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes comprising contacting a butadiene in the presence of a promoting amount of a hydroxylic solvent with a catalyst containing copper(I) ions supported on a carrier. A second process for the cyclodimerization of 1,3-butadienes to 4-vinylcyclohexenes comprising contacting a butadiene with a catalytic amount of a copper(I)-impregnated aluminosilicate zeolite characterized by a bulk SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio in the range from about 5 to about 50 and a framework SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of at least about 15. A catalyst composition comprising a copper(I)-impregnated zeolite of specified bulk and framework silica to alumina molar ratios and specified water content. The catalyst exhibits high activity and long lifetime in the aforementioned dimerization processes and is easily regenerated.
摘要翻译： 将1,3-丁二烯环化为4-乙烯基环己烯的方法包括在促进量的羟基溶剂存在下使丁二烯与负载在载体上的含有（I）的离子的催化剂接触。 1,3-丁二烯环化为4-乙烯基环己烯的第二种方法，包括将丁二烯与催化量的浸渍硅酸铜（I）的硅酸铝沸石接触，其特征在于本体SiO 2 / Al 2 O 3摩尔比在约5- 约50，骨架SiO 2 / Al 2 O 3摩尔比为至少约15.一种催化剂组合物，其包含具有规定体积和骨架二氧化硅与氧化铝摩尔比的特定水含量的铜（I）浸渍沸石。 该催化剂在上述二聚过程中表现出高的活性和长的使用寿命，并且易于再生。
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