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    Coating compositions
    1.
    发明授权
    Coating compositions 有权
    涂料组合物

    公开(公告)号：US09080059B2

    公开(公告)日：2015-07-14

    申请号：US13817015

    申请日：2011-09-13

    申请人： Xin Jin ,  Ray E. Drumright ,  Bernhard Kainz ,  Jerry E. White ,  Robert E. Hefner, Jr.

    发明人： Xin Jin ,  Ray E. Drumright ,  Bernhard Kainz ,  Jerry E. White ,  Robert E. Hefner, Jr.

    IPC分类号： B32B15/092 ,  B32B27/38 ,  C09D163/00 ,  C08G59/24 ,  B05D3/02 ,  C09D5/00 ,  C08G59/06

    CPC分类号： C09D5/00 ,  C08G59/066 ,  C08L2205/05 ,  C09D163/00 ,  C08L33/02 ,  C08L67/00

    摘要： A coating composition comprising an advanced epoxy resin polymeric composition having the following chemical structure:(formula) I where n is a number from 1 to about 3000; each m independently has a value of 0 or 1; each R0 is independently —H or —CH3; each R1 is independently —H or a C1 to C6 alkylene radical (saturated divalent aliphatic hydrocarbon radical); R′1-R′4 are independently hydrogen, an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent, for example, a nitro, an isocyanate, or an alkyloxy group; additionally, any two of R′1-R′4 may form fused ring independently; and X is cycloalkylene group, including substituted cycloalkylene group, where the substituent groups include an alkyl, cycloalkyl, an aryl or an aralkyl group or other substituent group, for example, a halide, a cyano, a nitro, a blocked isocyanate, or an alkyloxy group; the combination of cycloalkylene and alkylene groups and the combination of alkylene and cycloalkylene group with a bridging moiety in between.

    摘要翻译： 一种涂料组合物，其包含具有以下化学结构的高级环氧树脂聚合物组合物：（式）I，其中n为1至约3000的数; 每个m独立地具有0或1的值; 每个R 0独立地是-H或-CH 3; 每个R 1独立地为-H或C 1至C 6亚烷基（饱和二价脂族烃基）; R'1-R'4独立地为氢，烷基，环烷基，芳基或芳烷基或其它取代基，例如硝基，异氰酸酯基或烷氧基; 此外，R'1-R'4中的任何两个可以独立地形成稠环; 并且X是亚环烷基，包括取代的亚环烷基，其中取代基包括烷基，环烷基，芳基或芳烷基或其它取代基，例如卤素，氰基，硝基，封端异氰酸酯或 烷氧基 亚环烷基和亚烷基的组合以及亚烷基和亚环烷基之间的桥连部分的组合。

    COATING COMPOSITION, AND A PROCESS FOR PRODUCING THE SAME
    2.
    发明申请
    COATING COMPOSITION, AND A PROCESS FOR PRODUCING THE SAME 有权
    涂料组合物及其制造方法

    公开(公告)号：US20140024742A1

    公开(公告)日：2014-01-23

    申请号：US14009634

    申请日：2011-04-08

    申请人： Charles S. Kan ,  Rebecca S. Ortiz ,  John A. Roper, III ,  Jane Elizabeth Weier ,  Timothy J. Young ,  Gary E. Spilman ,  Ray E. Drumright

    发明人： Charles S. Kan ,  Rebecca S. Ortiz ,  John A. Roper, III ,  Jane Elizabeth Weier ,  Timothy J. Young ,  Gary E. Spilman ,  Ray E. Drumright

    IPC分类号： C09D167/00 ,  C09D163/00

    CPC分类号： C09D167/00 ,  C09D123/00 ,  C09D163/00 ,  C09D167/08 ,  C08L23/00 ,  C08L75/04 ,  C08L67/00 ,  C08L63/00

    摘要： The present invention provides a coating composition, a process for producing the same, one or more coating layers derived therefrom, and articles comprising one or more such coating layers. The coating composition according to the present invention comprises: (a) from 10 to 90 percent by weight of an aqueous, high-solid, solvent-free alkyd dispersion comprising: (i) from 40 to 70 percent by weight of one or more alkyds based on the total weight of the dispersion, wherein each said one or more alkyds has an acid value of less than 20 and a molecular weight (Mn) in the range of greater than 1000 Dalton; (ii) from less than 10 percent by weight of one or more surfactants, based on the total weight of the dispersion; and (iii) from 30 to 55 percent by weight of water, based on the total weight of the dispersion; wherein said aqueous, high-solid, solvent-free alkyd dispersion has an average particle size diameter in the range of from 0.05 to 5 μm; (b) from 10 to 90 one or more second dispersions, one or more second emulsions, or combinations thereof; wherein said coating composition has a solid content of in the range of from 25 to 65 percent by weight of solid content, based on the total weight of the coating composition, and the coating composition has a pH in the range of from 7 to 11, and wherein the coating composition has a volume average particle size in the range of from 0.03 to 5 μm, and wherein the coating composition has a viscosity in the range of from 100 to 10,000 cP.

    摘要翻译： 本发明提供一种涂料组合物，其制备方法，由其衍生的一种或多种涂层，以及包含一种或多种这样的涂层的制品。 根据本发明的涂料组合物包含：（a）10至90重量％的水性，高固体，无溶剂的醇酸树脂分散体，其包含：（i）40至70重量％的一种或多种醇酸树脂 基于分散体的总重量，其中每个所述一种或多种醇酸树脂的酸值小于20，分子量（Mn）在大于1000道尔顿范围内; （ii）基于分散体的总重量，少于10重量％的一种或多种表面活性剂; 和（iii）基于分散体的总重量的30至55重量％的水; 其中所述水性，高固体，无溶剂的醇酸树脂分散体的平均粒度直径为0.05-5μm; （b）10至90个一种或多种第二分散体，一种或多种第二乳液或其组合; 其中所述涂料组合物的固体含量为固体含量的25至65重量％，基于涂料组合物的总重量，并且涂料组合物的pH为7至11， 并且其中所述涂料组合物的体积平均粒度在0.03至5μm的范围内，并且其中所述涂料组合物具有在100至10,000cP范围内的粘度。

    Process for preparing thermoplastic vulcanizates
    3.
    发明授权
    Process for preparing thermoplastic vulcanizates 失效
    制备热塑性硫化胶的方法

    公开(公告)号：US06277916B1

    公开(公告)日：2001-08-21

    申请号：US09257771

    申请日：1999-02-25

    申请人： Robert H. Terbrueggen ,  Ray E. Drumright ,  Thoi H. Ho

    发明人： Robert H. Terbrueggen ,  Ray E. Drumright ,  Thoi H. Ho

    IPC分类号： C08L5300

    CPC分类号： C08K5/43 ,  C08F8/34 ,  C08F2800/20 ,  C08F2810/20 ,  C08F210/02 ,  C08F212/08 ,  C08F297/04 ,  C08F297/046 ,  C08F8/04 ,  C08F210/18

    摘要： This invention includes a process for forming a thermoplastic vulcanizate comprising: (a) admixing a C—H insertion curing agent with at least one elastomeric phase polymer to form a first admixture; (b) admixing at least one non-elastomeric polyolefin with the first admixture to form a second admixture; and (c) heating the second admixture to a temperature at least the decomposition temperature of the curing agent to crosslink the elastomeric phase while mixing the admixture to an extent sufficient to result in the formation of a thermoplastic material, hereinafter referred to as a thermoplastic vulcanizate, and optionally including an additional step (d) of shaping the resulting thermoplastic vulcanizate, especially by heating and foaming or molding the TPV. The C—H insertion curing agent is preferably selected from alkyl and aryl azides (R—N3), acyl azides (R—C(O)N3), azidoformates (R—O—C(O)—N3), sulfonyl azides (R—SO2—N3), phosphoryl azides ((RO)2—(PO)—N3), phosphinic azides (R2—P(O)—N3) and silyl azides (R3—Si—N3), with poly(sulfonyl azide) most preferred. Additionally, the invention includes a thermoplastic vulcanizate comprising a blend of: (1) an elastomeric phase crosslinked using a C—H insertion curing agent dispersed in; (2) at least one non-elastomeric thermoplastic polyolefin. The invention also includes a foamable composition comprising (1) an elastomeric phase crosslinked using a C—H insertion curing agent dispersed in; (2) at least one non-elastomeric thermoplastic polyolefin; and (3) from about 0.1 to about 25 percent by weight based on the combined weight of components (1) and (2) of at least one foaming agent as well as a fabricated part, cable jacket, cable insulation, or foam comprising the thermoplastic vulcanizate or the invention or resulting from the process of the invention.

    摘要翻译： 本发明包括形成热塑性硫化橡胶的方法，其包括：（a）将C-H嵌入固化剂与至少一种弹性体相聚合物混合以形成第一混合物; （b）将至少一种非弹性体聚烯烃与第一混合物混合以形成第二混合物; 和（c）将第二混合物加热到至少固化剂的分解温度的温度以交联弹性体相，同时将该混合物混合到足以导致形成热塑性材料的程度，以下称为热塑性硫化橡胶 并且任选地包括使得到的热塑性硫化橡胶成型的附加步骤（d），特别是通过加热和发泡或模制TPV。 CH插入固化剂优选选自烷基和芳基叠氮化物（R-N 3），酰基叠氮化物（RC（O）N 3），叠氮基甲酸酯（ROC（O）-N 3），磺酰基叠氮化物（R-SO 2 -N 3） 叠氮化物（（RO）2-（PO）-N3），次膦酸叠氮化物（R2-P（O）-N3）和甲硅烷基叠氮化物（R3-Si-N3），最优选为聚（磺酰基叠氮化物）。 另外，本发明包括热塑性硫化橡胶，其包含以下共混物：（1）使用分散在其中的C-H嵌入固化剂交联的弹性体相; （2）至少一种非弹性体热塑性聚烯烃。 本发明还包括可发泡组合物，其包含（1）使用分散在其中的C-H插入固化剂交联的弹性体相; （2）至少一种非弹性热塑性聚烯烃; 和（3）约0.1至约25重量％，基于至少一种发泡剂的组分（1）和（2）的组合重量，以及制造的部件，电缆护套，电缆绝缘或泡沫，其包含 热塑性硫化橡胶或本发明，或由本发明的方法得到。

    COATED CONTAINER DEVICE, METHOD OF MAKING THE SAME
    7.
    发明申请
    COATED CONTAINER DEVICE, METHOD OF MAKING THE SAME 审中-公开
    涂覆容器装置，其制造方法

    公开(公告)号：US20120118785A1

    公开(公告)日：2012-05-17

    申请号：US13386855

    申请日：2010-07-23

    申请人： Bernhard Kainz ,  Richard A. Lundgard ,  David L. Malotky ,  Jodi M. Mecca ,  Charles F. Diehl ,  Ray E. Drumright

    发明人： Bernhard Kainz ,  Richard A. Lundgard ,  David L. Malotky ,  Jodi M. Mecca ,  Charles F. Diehl ,  Ray E. Drumright

    IPC分类号： B65D79/00 ,  B21D51/00

    CPC分类号： B65D25/14 ,  B05D2202/00 ,  B05D2401/20 ,  B05D2701/00

    摘要： The instant invention provides a coated container device, and method of making the same. The coated container device according to the instant invention comprises: (1) a metal substrate; and (2) one or more crosslinked coating layers associated with the metal substrate, wherein the one or more crosslinked coating layers are derived from the application of one or more aqueous dispersions to at least one surface of the metal substrate, and wherein the one or more aqueous dispersion comprise: (a) one or more a base polymer; (b) one or more a stabilizing agent; (c) optionally one or more neutralizing agents, (d) one or more crosslinking agents; and (e) water.

    摘要翻译： 本发明提供一种涂覆容器装置及其制造方法。 根据本发明的涂布容器装置包括：（1）金属基板; 和（2）与金属基底相关联的一个或多个交联的涂层，其中所述一个或多个交联涂层是从一种或多种水分散体施加到金属基底的至少一个表面衍生的， 更多的水分散体包含：（a）一种或多种基础聚合物; （b）一种或多种稳定剂; （c）任选的一种或多种中和剂，（d）一种或多种交联剂; 和（e）水。

    HYBRID DISPERSIONS AND METHODS FOR PRODUCING THE SAME
    8.
    发明申请
    HYBRID DISPERSIONS AND METHODS FOR PRODUCING THE SAME 审中-公开
    混合分散体及其生产方法

    公开(公告)号：US20120046409A1

    公开(公告)日：2012-02-23

    申请号：US13262547

    申请日：2010-02-22

    申请人： Christian Piechocki ,  John N. Argyropoulos ,  Robert R. Bills ,  Ray E. Drumright

    发明人： Christian Piechocki ,  John N. Argyropoulos ,  Robert R. Bills ,  Ray E. Drumright

    IPC分类号： C09D175/04

    CPC分类号： C08G18/0866 ,  C08G18/36

    摘要： The instant invention is a hybrid dispersion, method of producing the same, articles made therefrom, and method of making such articles. The hybrid dispersion according to the present invention comprises the blending product of: (a) less than 30 percent by weight of a minor component comprising a hydrophobic polyurethane dispersion derived from one or more natural oil based polyols, based on the weight of the hybrid dispersion; and (b) less than 100 percent by weight of a major component selected from the group consisting of a latex emulsion, an epoxy, and a polyolefin dispersion; wherein the hybrid dispersion has a solid content in the range of 10 to 75 percent based on the weight of the hybrid dispersion.

    摘要翻译： 本发明是混合分散体，其制造方法，由其制成的制品及其制造方法。 根据本发明的混合分散体包含以下混合产物：（a）小于30重量％的少量组分，其包含衍生自一种或多种天然油基多元醇的疏水性聚氨酯分散体，基于混合分散体的重量 ; 和（b）小于100重量％的选自胶乳乳液，环氧树脂和聚烯烃分散体的主要组分; 其中所述混合分散体基于所述混合分散体的重量具有在10至75％范围内的固体含量。