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公开(公告)号：US06294640B1
公开(公告)日：2001-09-25
申请号：US09648147
申请日：2000-08-25
申请人： H. Clay Linstid, III , Dominick L. Cangiano , Ronald N. DeMartino , James E. Kuder , Vincent J. Provino , Randy Jester
发明人： H. Clay Linstid, III , Dominick L. Cangiano , Ronald N. DeMartino , James E. Kuder , Vincent J. Provino , Randy Jester
IPC分类号： C08G6300
CPC分类号： B32B27/08 , B32B27/306 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2323/04 , B32B2323/10 , B32B2331/04 , B32B2367/00 , B32B2377/00 , C08G63/605 , C08G69/44 , C08J5/18 , C08J2367/02 , D01F8/14
摘要： A stretchable liquid crystal polymer having recurring units derived from p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, at least one aromatic diacid and at least one aromatic diol and/or hydroxyamine component, at least a portion of which is 4,4′-biphenol, and one or more aromatic monomers that provide the polymers with selected 1,3-(meta-) linkages. Stretchable polymers are especially suitable for multilayer laminates and bicomponent fibers.
摘要翻译： 一种具有衍生自对羟基苯甲酸，6-羟基-2-萘甲酸，至少一种芳族二酸和至少一种芳族二醇和/或羟胺组分的重复单元的伸缩液晶聚合物，其至少一部分为4， 4'-联苯酚和一种或多种提供具有选定的1,3-（间 - ）键的聚合物的芳族单体。 可拉伸聚合物特别适用于多层层压材料和双组分纤维。
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2.发明授权Process for producing amorphous anisotropic melt-forming polymers having a high degree of stretchability 有权制造具有高伸缩性的无定形各向异性熔融形成聚合物的方法公开(公告)号：US06222000B1
公开(公告)日：2001-04-24
申请号：US09483103
申请日：2000-01-14
申请人： H. Clay Linstid, III , Dominick L. Cangiano , Ronald N. DeMartino , James E. Kuder , Vincent J. Provino
发明人： H. Clay Linstid, III , Dominick L. Cangiano , Ronald N. DeMartino , James E. Kuder , Vincent J. Provino
IPC分类号： C08G6300
CPC分类号： B32B27/08 , C08G63/605 , C08G69/44 , C08J5/18 , C08J2367/02 , D01F8/14 , Y10T428/249921 , Y10T428/31786
摘要： Process for producing highly stretchable, amorphous anisotropic melt-forming polymers having recurring units derived from p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, at least one aromatic diacid and at least one aromatic diol and/or hydroxyamine component, at least a portion of which is 4,4′-biphenol, which process comprises incorporating into such polymers recurring units derived from one or more aromatic monomers that provide the polymers with selected meta-linkages wherein each of said recurring units is present in the polymer in specific amounts.
摘要翻译： 至少一种芳族二酸和至少一种芳族二醇和/或羟胺组分的至少具有衍生自对羟基苯甲酸，6-羟基-2-萘甲酸和至少一种芳族二醇和/或羟胺组分的重复单元的高度可拉伸，无定形各向异性熔融形成聚合物的方法 其一部分是4,4'-联苯酚，该方法包括将这样的聚合物重复单元衍生自一种或多种提供聚合物的选择性间键的芳族单体，其中每个所述重复单元存在于聚合物中特定的 金额
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3.发明授权Process for producing amorphous anisotrophic melt-forming polymers having a high degree of stretchability and polymers produced by same 有权具有高伸缩性的无定形各向异性熔融形成性聚合物的制造方法和由其制造的聚合物
公开(公告)号：US6132884A
公开(公告)日：2000-10-17
申请号：US484120
申请日：2000-01-14
申请人： H. Clay Linstid, III , Dominick L. Cangiano , Ronald N. DeMartino , James E. Kuder , Vincent J. Provino
发明人： H. Clay Linstid, III , Dominick L. Cangiano , Ronald N. DeMartino , James E. Kuder , Vincent J. Provino
IPC分类号： C08J5/00 , B32B27/00 , C08G63/60 , C08G69/44 , C08J5/18 , D01F6/84 , D01F8/14 , B32B27/06 , C08G63/00
CPC分类号： C08G63/605 , Y10T428/29 , Y10T428/31786
摘要： Process for producing highly stretchable, amorphous anisotropic melt-forming polymers having recurring units derived from p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, at least one aromatic diacid and an aromatic diol and/or hydroxyamine component, at least a portion of which is 4,4'-biphenol, which comprises incorporating into such polymers recurring units derived from resorcinol and at least one additional monomer that provides the resulting polymer with selected meta linkages, wherein each of said recurring units is present in the polymer in specified amounts.
摘要翻译： 用于制备具有源自对羟基苯甲酸，6-羟基-2-萘甲酸，至少一种芳族二酸和芳族二醇和/或羟胺组分的重复单元的高度可拉伸，无定形各向异性熔融形成聚合物的方法，至少一部分 其中4,4'-联苯酚，其包括将衍生自间苯二酚的重复单元和至少一种额外的单体引入到这些聚合物中，所述至少一种另外的单体提供所选聚合物与所选择的间键，其中每个所述重复单元以特定的方式存在于聚合物中 金额
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公开(公告)号：US6114492A
公开(公告)日：2000-09-05
申请号：US483589
申请日：2000-01-14
CPC分类号： C08G63/605 , C08G63/826 , C08G63/83
摘要： A potassium catalyst is used in combination with a cobalt catalyst to increase the reaction rate and/or reduce the reaction temperature of a melt polymerization process for producing an anisotropic melt-phase forming polymer derived from p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, aromatic hydroxycarboxylic acid, aromatic diol, at least a portion of which is resorcinol and at least one aromatic dicarboxylic acid, compared to a like process wherein either catalyst is used alone.
摘要翻译： 钾催化剂与钴催化剂组合使用以提高反应速率和/或降低熔融聚合方法的反应温度，用于制备衍生自对羟基苯甲酸，6-羟基-2-羟基苯甲酸的各向异性熔融相形成聚合物， 萘甲酸，芳族羟基羧酸，芳族二醇，至少一部分为间苯二酚和至少一种芳族二羧酸，与其中单独使用催化剂的类似方法相比。
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5.发明授权
公开(公告)号：US5798432A
公开(公告)日：1998-08-25
申请号：US620780
申请日：1996-03-22
CPC分类号： C08G63/605 , C08G69/44 , C09K19/3809
摘要： Liquid crystalline polymers that are made from 4-hydroxybenzoic acid, 2,6-naphthalenedicarboxylic acid, terephthalic acid, hydroquinone, and N-acetyl-4-aminophenol by heating the monomers in the presence of acetic anhydride are more easily synthesized in high molecular weight if isophthalic acid is also included as a monomer at a level of about 0.5 mole % to about 10 mole %.
摘要翻译： 通过在乙酸酐存在下加热单体，由4-羟基苯甲酸，2,6-萘二羧酸，对苯二甲酸，氢醌和N-乙酰基-4-氨基苯酚制成的液晶聚合物更容易以高分子量 如果间苯二甲酸也以约0.5摩尔％至约10摩尔％的水平包含在单体中。
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公开(公告)号：US06666990B2
公开(公告)日：2003-12-23
申请号：US09783057
申请日：2001-02-14
IPC分类号： C09K1932
CPC分类号： B32B27/08 , B32B7/12 , B32B27/28 , B32B37/153 , B32B2038/0028 , B32B2307/7244 , B32B2439/46 , B32B2439/60 , B32B2439/70 , B32B2439/80 , C08G63/065 , C08G69/44 , Y10T428/10
摘要： The present invention relates to a stretchable polymer consisting essentially of recurring units derived from para-oxybenzoyl, 6-oxy-2-naphthoyl and meta-oxybenzoyl. The invention also relates to a process for stretching a multilayer laminate comprising the steps of providing a multilayer laminate comprising a layer of a thermoplastic and a layer of the stretchable polymer, and stretching the laminate greater than about 100% elongation at a temperature less than about 200° C.
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7.发明授权公开(公告)号：US06514611B1
公开(公告)日：2003-02-04
申请号：US09933645
申请日：2001-08-21
IPC分类号： B32B2708
CPC分类号： B32B27/08 , B32B27/32 , B32B27/36 , C08G63/605 , Y10T428/2929 , Y10T428/31786 , Y10T428/31797
摘要： Highly stretchable, anisotropic melt-forming polymers consisting essentially of recurring units derived from p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, isophthalic acid, terephthalic acid and hydroquinone are disclosed.
摘要翻译： 公开了高度可拉伸的各向异性熔体形成聚合物，其基本上由衍生自对羟基苯甲酸，6-羟基-2-萘甲酸，间苯二甲酸，对苯二甲酸和氢醌的重复单元组成。
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8.发明授权Adhesives for making multilayer films comprising liquid crystalline polymer and polypropylene 失效用于制造包含液晶聚合物和聚丙烯的多层膜的粘合剂
公开(公告)号：US6013373A
公开(公告)日：2000-01-11
申请号：US954378
申请日：1997-10-20
IPC分类号： B32B27/32 , B32B27/08 , B32B37/00 , C09J123/00 , C09J123/26 , C09J177/00 , B32B9/04
CPC分类号： B32B37/1207 , B32B27/08 , B29K2023/12 , B29K2105/0079 , B32B2037/1223 , B32B2309/02 , B32B2309/105 , B32B37/203 , Y10T428/31504
摘要： Multilayer films that include a thermotropic liquid crystalline polymer film layer and a polypropyene film layer are bound together using hot melt adhesives which may be either (1) a blend of poly(.alpha.-olefins), comprised of isotactic polypropylene, a polymer of a second lower poly(.alpha.-olefin), and a small amount of a higher poly(.alpha.-olefin), or (2) a blend of poly(propylene-graft-maleic anhydride) and a dimer acid based polyamide. These hot melt adhesives also act as compatiblizers for blends of polypropylene and thermotropic liquid crystalline polymers.
摘要翻译： 包括热致液晶聚合物膜层和聚丙烯膜层的多层膜使用热熔粘合剂结合在一起，其可以是（1）由全同立构聚丙烯组成的聚（α-烯烃）共混物，第二 低级聚（α-烯烃）和少量较高的聚（α-烯烃），或（2）聚（丙烯 - 接枝 - 马来酸酐）和二聚酸基聚酰胺的共混物。 这些热熔粘合剂也用作聚丙烯和热致液晶聚合物共混物的增容剂。
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9.发明授权Adhesives for making multilayer films comprising liquid crystalline polymers and poly(ethylene terephthalate) or polycarbonate 失效用于制造包含液晶聚合物和聚对苯二甲酸乙二醇酯或聚碳酸酯的多层膜的粘合剂
公开(公告)号：US06042902A
公开(公告)日：2000-03-28
申请号：US954997
申请日：1997-10-20
IPC分类号： B32B7/12 , B32B27/36 , C08L67/00 , C09J123/00 , C09J177/00 , C09K19/00
CPC分类号： B32B7/12 , B32B27/36 , C09K19/3809 , C09K2219/03 , Y10T428/105
摘要： Multilayer films that include a thermotropic liquid crystalline polymer film layer and a poly(ethylene terephthalate) or polycarbonate film layer are bound together using a hot melt adhesive, which may be either (1) a blend of poly(.alpha.-olefins) that includes isotactic polypropylene, a polymer of a second lower poly(.alpha.-olefin), and a small amount of a higher poly(.alpha.-olefin); or (2) a polyamide-based hot melt adhesive.
摘要翻译： 包括热致液晶聚合物膜层和聚（对苯二甲酸乙二醇酯）或聚碳酸酯膜层的多层膜使用热熔粘合剂结合在一起，热熔粘合剂可以是（1）包括全同立构的聚（α-烯烃）的共混物 聚丙烯，第二较低聚（α-烯烃）的聚合物和少量较高的聚（α-烯烃））; 或（2）聚酰胺类热熔粘合剂。
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10.发明授权Adhesives for making multilayer films comprising liquid crystalline polymers and polyethylene 失效用于制造包含液晶聚合物和聚乙烯的多层膜的粘合剂
公开(公告)号：US6015524A
公开(公告)日：2000-01-18
申请号：US954377
申请日：1997-10-20
IPC分类号： B29C65/40 , B29K23/00 , B29L9/00 , B32B7/12 , B32B27/32 , C08J5/12 , C08L23/06 , C08L101/00 , C09J5/06 , C09J123/08 , B29C47/06
CPC分类号： C08J5/124 , B29C66/45 , B29C66/71 , B32B37/04 , B32B37/12 , B32B7/12 , C09K19/3809 , B32B2305/55 , C09K2219/03
摘要： Multilayer films that include a thermotropic liquid crystalline polymer film layer and a polyethylene film layer are bound together using one of the following hot melt adhesives: ethylene-glycidyl methacrylate copolymer, ethylene-methyl acrylate-glycidyl methacrylate terpolymer, ethylene vinyl acetate copolymer, a polyolefin blend, ethylene-acrylic acid copolymer, and mixtures thereof.
摘要翻译： 包括热致液晶聚合物膜层和聚乙烯膜层的多层膜使用以下热熔粘合剂之一结合在一起：乙烯 - 甲基丙烯酸缩水甘油酯共聚物，乙烯 - 丙烯酸甲酯 - 甲基丙烯酸缩水甘油酯三元共聚物，乙烯 - 乙酸乙烯酯共聚物，聚烯烃 共混物，乙烯 - 丙烯酸共聚物及其混合物。
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