公开(公告)号：US3821328A

公开(公告)日：1974-06-28

申请号：US26517072

申请日：1972-06-22

申请人： HUELS CHEMISCHE WERKE AG

发明人： STRECK R ,  NORDSIEK K ,  WEBER H ,  MEYER K

IPC分类号： C08F36/00 ,  C08G61/08 ,  C08F29/02

CPC分类号： C08G61/08 ,  C08F36/00

摘要： Copolyalkenamers are produced by reacting a rubbery polybutadiene wherein more than 80 percent of the butadiene contact thereof is a 1,4-polymer, with a polyoctenamer or polydodecenamer or mixture thereof, in the presence of a mixed catalyst containing a compound of a metal of Subgroup 5 through 7 and a metal or a compound thereof of Main Group 1 through 4 of the Periodic Table.

公开(公告)号：US3816358A

公开(公告)日：1974-06-11

申请号：US26516772

申请日：1972-06-22

申请人： HUELS CHEMISCHE WERKE AG

发明人： NORDSIEK K ,  STRECK R

IPC分类号： C08L21/00 ,  C08L23/16 ,  C08L23/22 ,  C08D9/08 ,  C08C9/04 ,  C08C9/14

CPC分类号： C08L21/00 ,  C08K3/04 ,  C08K3/06 ,  C08K3/22 ,  C08K5/09 ,  C08L7/00 ,  C08L9/00 ,  C08L9/06 ,  C08L23/16 ,  C08L23/22 ,  C08L23/24 ,  C08L65/00 ,  C08L91/00 ,  C08L2312/00 ,  C08L2666/04 ,  Y10T152/1081 ,  Y10T152/10846 ,  C08L2666/14

摘要： Vulcanizable rubber mixtures having improved room temperature hardness containing 2-20% by weight, calculated on the rubber, of a polyoctenamer or polydodecenamer.

公开(公告)号：US3770694A

公开(公告)日：1973-11-06

申请号：US3770694D

申请日：1972-06-16

申请人： HUELS CHEMISCHE WERKE AG

发明人： BERG G ,  NORDSIEK K

IPC分类号： C08K5/17 ,  C08F45/60

CPC分类号： C08K5/17 ,  C08L21/00

摘要： POLYISOPRENE HAVING THE HIGH RESISTANCE TO THERMAL AND MECHANICAL STRESSES OF NATURAL RUBBER IS PRODUCED BY INCORPORATION INTO A SOLUTION OF THE POLYISOPRENE A MIXTURE OF A DIFUNCTIONAL SECONDARY ARYLAMINE OF THE FORMULA

(4-(R2-NH-)PHENYL)-NH-R1

WHEREIN R1 AND R2 ARE ALKYL, CYCLOALKYL OR ARYL, AND AN ALIPHATIC AMINE OF THE FORMULA RN(NH)N-1(NH2)X WHEREIN X IS 1 OR 2, N IS 1-10 AND R IS ALKYL WHEN N AND X BOTH ARE 1 AND ALKYLENE WHEN N IS GREATER THAN 1.

公开(公告)号：US3846365A

公开(公告)日：1974-11-05

申请号：US27000372

申请日：1972-07-10

申请人： HUELS CHEMISCHE WERKE AG

发明人： BERG G ,  NORDSIEK K ,  MAAHS G ,  SCHANZER W

IPC分类号： C08K5/19 ,  C08C2/06 ,  C08J3/16 ,  C08J3/215 ,  C08L21/00 ,  C08C11/10 ,  C08C11/18 ,  C08C11/22

CPC分类号： C08J3/16 ,  C08J3/215 ,  C08J2321/00 ,  C08L21/00 ,  C08L2666/02

摘要： Discrete, finely divided, tack-free elastomer particles are prepared from a filler-containing aqueous elastomer emulsion containing an aqueous emulsion of an elastomer dissolved in a volatile inert organic solvent having an emulsifying amount of a quaternary ammonium salt cationic surfactant and an aqueous suspension or dispersion of a solid, finely divided elastomer filler, which process comprises gradually introducing the fillercontaining aqueous elastomer emulsion into an aqueous alkali silicate solution while maintaining said solution at a pH greater than 2 and simultaneously evaporating the organic solvent to form discrete, finely divided, tack-free elastomer particles. The process can be applied to solid elastomers or to post-polymerization elastomer solutions, and is particularly suitable for preparing pourable, carbon black containing elastomer particles to be formed into shaped objects.

摘要翻译： 由含填料​​的水性弹性体乳液制备分散的，细分的，无粘性的弹性体颗粒，该含水弹性体乳液含有溶解在具有乳化量的季铵盐阳离子表面活性剂和水悬浮液的挥发性惰性有机溶剂中的弹性体的水性乳液，或 固体，细分散的弹性体填料的分散体，该方法包括将含填料的水性弹性体乳液逐渐引入含水碱性硅酸盐溶液中，同时将所述溶液保持在大于2的pH，同时蒸发有机溶剂以形成离散的，细分的 ，无粘性弹性体颗粒。

公开(公告)号：US3741927A

公开(公告)日：1973-06-26

申请号：US3741927D

申请日：1970-11-24

申请人： HUELS CHEMISCHE WERKE AG

发明人： NORDSIEK K ,  SOMMER N ,  SCHWESIG H

IPC分类号： C08L7/00 ,  B60C1/00 ,  B60C11/00 ,  C08J3/20 ,  C08L9/00 ,  C08L21/00 ,  C08F45/08 ,  C08F45/28

CPC分类号： C08L9/00 ,  B60C1/0016 ,  Y10S152/905

摘要： TIRE TREAD STRIPS FOR AUTOMOBILE TIRES HAVING A GOOD COMBINATION OF WEAR AND SKID RESISTANCE ARE FORMED OF A POLYBUTADIENE HOMOPOLYMER COMPOSITION CONSISTING ESSENTIALLY OF: (A) A HOMOPOLYMER OF 1,3-BUTADIENE HAVING AN AVERAGE VINYL GROUP CONTENT OF 25-50%, A CIS-1,4-DOUBLE BOND CONTENT OF 10-40%, A TRANS-1,4-DOUBLE BOND CONTENT OF 15-55%, A MOONEY VISCOSITY (ML-4) OF BETWEEN 40 AND 120, AND A DEFORMATION-ELASTICITY OF AT LEAST 25, WHOSE VINYL GROUPS ARE DISTRIBUTED ALONG THE LONGITUDINAL AXIS OF THE MACROMOLECULE TOWARD AN END THEREOF IN A SUBSTANTIALLY DECREASING MANNER, (B) 5-100 PARTS BY WEIGHT OF A PLASTICIZER, BASED ON 100 PARTS BY WEIGHT OF POLYBUTADIENE, AND (C) 30-120 PARTS BY WEIGHT OF A CARBON BLACK, BASED ON 100 PARTS BY WEIGHT OF POLYBUTADIENE.

公开(公告)号：US3829409A

公开(公告)日：1974-08-13

申请号：US30981772

申请日：1972-11-27

申请人： HUELS CHEMISCHE WERKE AG

发明人： SOMMER N ,  NORDSIEK K

IPC分类号： C08F4/00 ,  C08F4/42 ,  C08F36/00 ,  C08F136/06 ,  C08F297/00 ,  C08F297/02 ,  C08D1/20 ,  C08D3/06

CPC分类号： C08F136/06 ,  C08F4/48 ,  C08F2/001

摘要： BLOCK HOMOPOLUMERS OF 1,3-BUTADIENE HAVING A FIRST BLOCK WITH NONUFORM VINYL GROUP DISTRIBUTION AND A FURTHER BLOCK HAVING A UNIFORM VINYL GROUP DISTRIBUTION IN A MOLE RATIO OF 20:80 TO 95:5 RESPECTIVELY AND AN AVERAGE VINYL GROUP CONTENT OF 15-75%, PREFERABLY 2050%, ARE PREPARED BY ADIABATIC SOLLVENT POLYMERIZATION AT AN ASCENDING TEMPERATURE IN THE PRESENCE OF A CATALYST SYSTEM COMPRISING AN ORGANOLITHIUM COMPOUND AND A LEWIS BASE. THE POLYMERS HAVE IMPROVED PROCESSING PROPERTIES.

公开(公告)号：US3803080A

公开(公告)日：1974-04-09

申请号：US27293972

申请日：1972-07-05

申请人： HUELS CHEMISCHE WERKE AG

发明人： NORDSIEK K

IPC分类号： C08C19/00 ,  C08D5/02 ,  C08C11/18 ,  C08C11/22

CPC分类号： C08C19/00

摘要： The molecular weight of solid hydrocarbon elastomers, e.g., polybutadienes, is increased step-wise in a defined manner by subjecting them to thermal-mechanical treatment in which the elastomer is subjected to strong shearing forces at, e.g., 80*220* C., in the presence of a non-basic metallic compound as catalyst and a basic compound as cocatalyst.