公开(公告)号：US20150096169A1

公开(公告)日：2015-04-09

申请号：US14391892

申请日：2013-05-29

申请人： Hajime Hasegawa ,  Hiroki Kubo ,  Yuichi Hashimoto ,  Daichi Kosaka ,  Keisuke Watanabe ,  Tamito Igarashi ,  Mitsuyasu Sakuma

发明人： Hajime Hasegawa ,  Hiroki Kubo ,  Yuichi Hashimoto ,  Daichi Kosaka ,  Keisuke Watanabe ,  Tamito Igarashi ,  Mitsuyasu Sakuma

IPC分类号： H01M4/62 ,  H01M4/131 ,  H01M4/525 ,  H01M10/0562 ,  H01M10/058 ,  H01M4/505 ,  H01M4/04 ,  H01M4/1391

摘要： A slurry for a positive electrode for a sulfide-based solid-state battery contains at least a fluorine-based copolymer containing vinylidene fluoride monomer units, a positive electrode active material, and a solvent or a dispersion medium. When a dry volume of the slurry is set to 100% by volume, a content ratio of the fluorine-based copolymer is 1.5 to 10% by volume.

摘要翻译： 用于硫化物系固体电池用正极的浆料至少含有含有偏二氟乙烯单体单元的氟系共聚物，正极活性物质，溶剂或分散介质。 当将浆体的干体积设定为100体积％时，氟系共聚物的含有比例为1.5〜10体积％。

公开(公告)号：US07851084B2

公开(公告)日：2010-12-14

申请号：US11795595

申请日：2006-01-20

申请人： Mitsuyasu Sakuma ,  Tamito Igarashi ,  Aisaku Nagai ,  Nobuo Ahiko ,  Mayumi Sugahara

发明人： Mitsuyasu Sakuma ,  Tamito Igarashi ,  Aisaku Nagai ,  Nobuo Ahiko ,  Mayumi Sugahara

IPC分类号： H01M4/60

CPC分类号： H01G9/155 ,  C08F259/08 ,  C08L27/16 ,  C08L51/003 ,  C08L51/04 ,  H01G11/38 ,  H01G11/48 ,  H01M4/13 ,  H01M4/621 ,  H01M4/623 ,  H01M10/0525 ,  Y02E60/13 ,  Y10T428/2985 ,  Y10T428/2991 ,  Y10T428/3154 ,  C08L2666/24 ,  C08L2666/02

摘要： A core/shell polymer (A), comprising: a rubbery core comprising a crosslinked vinylidene fluoride copolymer (a) having a vinylidene fluoride content of 30-90 wt. % and a shell comprising a vinylidene fluoride polymer (b) having a vinylidene fluoride content which is larger than in the crosslinked vinylidene fluoride copolymer (a) and at least 80 wt. %, in a weight ratio (a)/(b) of 30/70-90/10. The vinylidene fluoride-based core/shell polymer (A) is excellent in mechanical properties including flexibility and resistance to nonaqueous electrolytic solutions, is capable of forming a composite electrode layer showing excellent flexibility and adhesion to an electroconductive substrate in combination with a powder active substance and is therefore suitable for use as a binder for nonaqueous electrochemical devices.

摘要翻译： 核/壳聚合物（A），其包含：包含偏氟乙烯含量为30-90重量％的交联偏二氟乙烯共聚物（a）的橡胶芯。 ％和包含偏二氟乙烯含量大于交联偏二氟乙烯共聚物（a）的偏二氟乙烯聚合物（b）的壳和至少80wt。 ％，重量比（a）/（b）为30 / 70-90 / 10。 基于偏二氟乙烯的核/壳聚合物（A）具有优异的机械性能，包括柔性和耐非水电解液的能力，能够形成复合电极层，其显示出优异的柔性和与导电基材的粘合性，与粉末活性物质 因此适合用作非水电化学装置的粘合剂。

公开(公告)号：US09236612B2

公开(公告)日：2016-01-12

申请号：US12742731

申请日：2008-11-12

申请人： Tamito Igarashi ,  Kuniyuki Saito ,  Mitsuyasu Sakuma

发明人： Tamito Igarashi ,  Kuniyuki Saito ,  Mitsuyasu Sakuma

IPC分类号： H01M4/60 ,  H01M4/62 ,  H01M4/04 ,  H01M4/131 ,  H01M4/1391

CPC分类号： H01M4/62 ,  H01M4/043 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/623 ,  H01M4/625 ,  Y02E60/122

摘要： A positive electrode mixture for nonaqueous batteries, is formed by adding 0.5 to 10 wt. parts of an organic acid per 100 wt. parts of an electroconductive additive, to a mixture of a composite metal oxide as a positive electrode active substance, a higher order-structured carbon black as the electroconductive additive, a binder of a fluorine-containing copolymer of at least three comonomers including vinylidene fluoride, tetrafluoroethylene and a flexibility-improving fluorine-containing monomer, and an organic solvent. Further, the mixture is applied on at least one side of an electroconductive sheet, and then dried and compressed to form a positive electrode mixture layer. As a result, it is possible to provide a positive electrode structure having a thick and sound positive electrode mixture layer of a high energy density.

摘要翻译： 通过添加0.5〜10重量％的非水电池用正极混合物， 每100重量份有机酸的份数 导电添加剂的一部分，作为正极活性物质的复合金属氧化物的混合物，作为导电添加剂的高级结构的炭黑，包含偏二氟乙烯的至少三种共聚单体的含氟共聚物的粘合剂， 四氟乙烯和柔软性改善性含氟单体和有机溶剂。 此外，将混合物施加到导电片的至少一侧，然后干燥并压缩以形成正极混合物层。 结果，可以提供具有高能量密度的厚且正确的正极合剂层的正电极结构。

公开(公告)号：US20100266882A1

公开(公告)日：2010-10-21

申请号：US12742731

申请日：2008-11-12

申请人： Tamito Igarashi ,  Kuniyuki Saito ,  Mitsuyasu Sakuma

发明人： Tamito Igarashi ,  Kuniyuki Saito ,  Mitsuyasu Sakuma

IPC分类号： H01M6/10 ,  H01M4/60 ,  H01B1/04 ,  H01M4/62

CPC分类号： H01M4/62 ,  H01M4/043 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/623 ,  H01M4/625 ,  Y02E60/122

摘要： A positive electrode mixture for nonaqueous batteries, is formed by adding 0.5 to 10 wt. parts of an organic acid per 100 wt. parts of an electroconductive additive, to a mixture of a composite metal oxide as a positive electrode active substance, a higher order-structured carbon black as the electroconductive additive, a binder of a fluorine-containing copolymer of at least three comonomers including vinylidene fluoride, tetrafluoroethylene and a flexibility-improving fluorine-containing monomer, and an organic solvent. Further, the mixture is applied on at least one side of an electroconductive sheet, and then dried and compressed to form a positive electrode mixture layer. As a result, it is possible to provide a positive electrode structure having a thick and sound positive electrode mixture layer of a high energy density.

摘要翻译： 通过添加0.5〜10重量％的非水电池用正极混合物， 每100重量份有机酸的份数 导电添加剂的一部分，作为正极活性物质的复合金属氧化物的混合物，作为导电添加剂的高级结构的炭黑，包含偏二氟乙烯的至少三种共聚单体的含氟共聚物的粘合剂， 四氟乙烯和柔软性改善性含氟单体和有机溶剂。 此外，将混合物施加到导电片的至少一侧，然后干燥并压缩以形成正极混合物层。 结果，可以提供具有高能量密度的厚且正确的正极合剂层的正电极结构。

公开(公告)号：US20080131776A1

公开(公告)日：2008-06-05

申请号：US11795595

申请日：2006-01-20

申请人： Mitsuyasu Sakuma ,  Tamito Igarashi ,  Aisaku Nagai ,  Nobuo Ahiko ,  Mayumi Sugahara

发明人： Mitsuyasu Sakuma ,  Tamito Igarashi ,  Aisaku Nagai ,  Nobuo Ahiko ,  Mayumi Sugahara

IPC分类号： H01M4/60 ,  C08L27/12

CPC分类号： H01G9/155 ,  C08F259/08 ,  C08L27/16 ,  C08L51/003 ,  C08L51/04 ,  H01G11/38 ,  H01G11/48 ,  H01M4/13 ,  H01M4/621 ,  H01M4/623 ,  H01M10/0525 ,  Y02E60/13 ,  Y10T428/2985 ,  Y10T428/2991 ,  Y10T428/3154 ,  C08L2666/24 ,  C08L2666/02

摘要： A core/shell polymer (A), comprising: a rubbery core comprising a crosslinked vinylidene fluoride copolymer (a) having a vinylidene fluoride content of 30-90 wt. % and a shell comprising a vinylidene fluoride polymer (b) having a vinylidene fluoride content which is larger than in the crosslinked vinylidene fluoride copolymer (a) and at least 80 wt. %, in a weight ratio (a)/(b) of 30/70-90/10. The vinylidene fluoride-based core/shell polymer (A) is excellent in mechanical properties including flexibility and resistance to nonaqueous electrolytic solutions, is capable of forming a composite electrode layer showing excellent flexibility and adhesion to an electroconductive substrate in combination with a powder active substance and is therefore suitable for use as a binder for nonaqueous electrochemical devices.

摘要翻译： 核/壳聚合物（A），其包含：包含偏氟乙烯含量为30-90重量％的交联偏二氟乙烯共聚物（a）的橡胶芯。 ％和包含偏二氟乙烯含量大于交联偏二氟乙烯共聚物（a）的偏二氟乙烯聚合物（b）和至少80wt。 ％，重量比（a）/（b）为30 / 70-90 / 10。 基于偏二氟乙烯的核/壳聚合物（A）具有优异的机械性能，包括柔性和耐非水电解液的能力，能够形成复合电极层，其显示出优异的柔性和与导电基材的粘合性，与粉末活性物质 因此适合用作非水电化学装置的粘合剂。

公开(公告)号：US09512255B2

公开(公告)日：2016-12-06

申请号：US13994982

申请日：2011-12-22

申请人： Keisuke Watanabe ,  Yuuki Sakai ,  Emi Sugawara ,  Shintarou Mutou ,  Tamito Igarashi

发明人： Keisuke Watanabe ,  Yuuki Sakai ,  Emi Sugawara ,  Shintarou Mutou ,  Tamito Igarashi

IPC分类号： C08F214/22 ,  H01M10/052 ,  C09D127/16 ,  H01M4/62

CPC分类号： C08F214/225 ,  C09D127/16 ,  H01M4/623 ,  H01M10/052 ,  H01M2220/20 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  C08F214/22 ,  C08F220/00

摘要： Provided are vinylidene fluoride copolymers exhibiting higher adhesion with respect to metal foils than do conventional vinylidene fluoride copolymers, and to provide uses of the vinylidene fluoride copolymers. The vinylidene fluoride copolymers are obtained by copolymerizing vinylidene fluoride with a compound represented by Formula (A). In Formula (A), R1, R2 and R3 are each independently a hydrogen atom, a chlorine atom or an alkyl group; and X is an atomic group with a molecular weight of not more than 500 containing a heteroatom and having a main chain composed of 1 to 20 atoms, or is a heteroatom.

摘要翻译： 提供的是与常规偏二氟乙烯共聚物相比，相对于金属箔显示更高粘附性的偏氟乙烯共聚物，并提供偏二氟乙烯共聚物的用途。 偏二氟乙烯共聚物通过使偏二氟乙烯与式（A）表示的化合物共聚而获得。 在式（A）中，R 1，R 2和R 3各自独立地为氢原子，氯原子或烷基; X是分子量不大于500的含有杂原子且具有1〜20个原子的主链的原子团，或是杂原子。

公开(公告)号：US20130273424A1

公开(公告)日：2013-10-17

申请号：US13994982

申请日：2011-12-22

申请人： Keisuke Watanabe ,  Yuuki Sakai ,  Emi Sugawara ,  Shintarou Mutou ,  Tamito Igarashi

发明人： Keisuke Watanabe ,  Yuuki Sakai ,  Emi Sugawara ,  Shintarou Mutou ,  Tamito Igarashi

IPC分类号： C08F214/22 ,  H01M4/62

CPC分类号： C08F214/225 ,  C09D127/16 ,  H01M4/623 ,  H01M10/052 ,  H01M2220/20 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011 ,  C08F214/22 ,  C08F220/00

摘要： Provided are vinylidene fluoride copolymers exhibiting higher adhesion with respect to metal foils than do conventional vinylidene fluoride copolymers, and to provide uses of the vinylidene fluoride copolymers. The vinylidene fluoride copolymers are obtained by copolymerizing vinylidene fluoride with a compound represented by Formula (A). In Formula (A), R1, R2 and R3 are each independently a hydrogen atom, a chlorine atom or an alkyl group; and X is an atomic group with a molecular weight of not more than 500 containing a heteroatom and having a main chain composed of 1 to 20 atoms, or is a heteroatom.

摘要翻译： 提供的是与常规偏二氟乙烯共聚物相比，相对于金属箔显示更高粘附性的偏氟乙烯共聚物，并提供偏二氟乙烯共聚物的用途。 偏二氟乙烯共聚物通过使偏二氟乙烯与式（A）表示的化合物共聚而获得。 在式（A）中，R 1，R 2和R 3各自独立地为氢原子，氯原子或烷基; X是分子量不大于500的含有杂原子且具有1〜20个原子的主链的原子团，或是杂原子。

公开(公告)号：US20120208085A1

公开(公告)日：2012-08-16

申请号：US13503876

申请日：2010-10-28

申请人： Tamito Igarashi ,  Hiroshi Sakabe ,  Emi Sugawara ,  Shintarou Mutou

发明人： Tamito Igarashi ,  Hiroshi Sakabe ,  Emi Sugawara ,  Shintarou Mutou

IPC分类号： H01M4/64 ,  C08K5/3415 ,  C08L27/16 ,  B32B5/16 ,  C08F114/22

CPC分类号： C08K5/3415 ,  H01G11/38 ,  H01G11/48 ,  H01M4/62 ,  H01M4/621 ,  Y02E60/13 ,  Y10T428/2982 ,  C08L27/16

摘要： Provided is a vinylidene fluoride polymer powder exhibiting excellent solubility in aprotic polar solvents, and a vinylidene fluoride polymer solution obtained from the powder and an aprotic polar solvent. The vinylidene fluoride polymer powder has an NMP penetration rate of 12 to 100% as measured by an NMP penetration test.

摘要翻译： 本发明提供一种在非质子极性溶剂中表现出优异溶解性的偏二氟乙烯聚合物粉末和由该粉末和非质子极性溶剂获得的偏二氟乙烯聚合物溶液。 偏二氟乙烯聚合物粉末通过NMP渗透试验测得的NMP渗透速率为12〜100％。

公开(公告)号：US09267016B2

公开(公告)日：2016-02-23

申请号：US13503876

申请日：2010-10-28

申请人： Tamito Igarashi ,  Hiroshi Sakabe ,  Emi Sugawara ,  Shintarou Mutou

发明人： Tamito Igarashi ,  Hiroshi Sakabe ,  Emi Sugawara ,  Shintarou Mutou

IPC分类号： H01M6/14 ,  H01M6/04 ,  C08K5/3415 ,  H01G11/38 ,  H01M4/62 ,  H01G11/48

CPC分类号： C08K5/3415 ,  H01G11/38 ,  H01G11/48 ,  H01M4/62 ,  H01M4/621 ,  Y02E60/13 ,  Y10T428/2982 ,  C08L27/16

摘要： Provided is a vinylidene fluoride polymer powder exhibiting excellent solubility in aprotic polar solvents, and a vinylidene fluoride polymer solution obtained from the powder and an aprotic polar solvent. The vinylidene fluoride polymer powder has an NMP penetration rate of 12 to 100% as measured by an NMP penetration test.

摘要翻译： 本发明提供一种在非质子极性溶剂中表现出优异溶解性的偏二氟乙烯聚合物粉末和由该粉末和非质子极性溶剂获得的偏二氟乙烯聚合物溶液。 偏二氟乙烯聚合物粉末通过NMP渗透试验测得的NMP渗透速率为12〜100％。

公开(公告)号：US20120213915A1

公开(公告)日：2012-08-23

申请号：US13503890

申请日：2010-10-28

申请人： Tamito Igarashi ,  Hiroshi Sakabe ,  Emi Sugawara ,  Shintarou Mutou

发明人： Tamito Igarashi ,  Hiroshi Sakabe ,  Emi Sugawara ,  Shintarou Mutou

IPC分类号： H01M4/60 ,  H01M4/04 ,  C08K5/3415 ,  C08F114/22 ,  C08L27/16

CPC分类号： C08L27/16 ,  C08J3/11 ,  C08J3/12 ,  C08J2327/16 ,  C08L2203/20 ,  H01G11/56 ,  H01M4/623

摘要： Provided is a process for producing vinylidene fluoride polymer powder that exhibits excellent solubility with respect to aprotic polar solvents, and a process for producing a vinylidene fluoride polymer solution using vinylidene fluoride polymer powder obtained by the polymer powder production process. The process for producing heat-treated vinylidene fluoride polymer powder includes heat treating raw vinylidene fluoride polymer powder at such a temperature that the temperature of the polymer powder is not less than 125° C. to less than the crystal melting temperature (Tm) of the polymer.

摘要翻译： 本发明提供一种相对于非质子极性溶剂表现出优异溶解性的偏二氟乙烯聚合物粉末的制造方法，以及使用通过聚合物粉末制造方法得到的偏二氟乙烯聚合物粉末的偏二氟乙烯聚合物溶液的制造方法。 制造热处理的偏二氟乙烯聚合物粉末的方法包括在聚合物粉末的温度不低于125℃至低于所述聚合物粉末的晶体熔融温度（Tm）的温度下热处理原始偏二氟乙烯聚合物粉末 聚合物。