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    Liquid tetrabutyl ammonium phenolate formulation
    6.
    发明授权
    Liquid tetrabutyl ammonium phenolate formulation 失效
    液体四丁基铵苯酚盐配方

    公开(公告)号：US07056855B1

    公开(公告)日：2006-06-06

    申请号：US09868489

    申请日：1999-12-09

    申请人： Carsten Hesse ,  Ursula Jansen ,  Johann Rechner

    发明人： Carsten Hesse ,  Ursula Jansen ,  Johann Rechner

    IPC分类号： B01J31/00

    CPC分类号： B01J31/0279 ,  C07C37/00 ,  Y02P20/52 ,  C07C39/04

    摘要： A process for preparing a formulation containing tetrabutylammonium phenolate and phenol is disclosed. The process entails combining a solution of tetrabutylammonium bromide in phenol with a solution of sodium phenolate to form a mixture, excess phenol is removed by distillation, and sodium bromide is filtered off. The formulation, that contains tetrabutylammonium phenolate and phenol in a weight ratio of 40:60 to 70:30, has a solidification point of less than 25° C. and finds use as a catalyst constituent.

    摘要翻译： 公开了一种制备含有四丁基苯酚铵和苯酚的制剂的方法。 该方法需要将苯酚中的四丁基溴化铵溶液与苯酚钠溶液混合以形成混合物，通过蒸馏除去过量的苯酚，并滤出溴化钠。 含有重量比为40:60〜70:30的苯酚四丁铵和苯酚的配方具有小于25℃的固化点，可用作催化剂成分。

    Process for the epoxidation of hydrocarbons
    7.
    发明授权
    Process for the epoxidation of hydrocarbons 失效
    烃类环氧化方法

    公开(公告)号：US06673949B2

    公开(公告)日：2004-01-06

    申请号：US10214073

    申请日：2002-08-07

    申请人： Ursula Jansen ,  Andreas Wegner

    发明人： Ursula Jansen ,  Andreas Wegner

    IPC分类号： C07D30108

    CPC分类号： C07D301/08 ,  B01J23/686 ,  B01J23/688 ,  B01J23/75 ,  B01J23/755 ,  B01J23/8432 ,  B01J23/864 ,  B01J23/866 ,  B01J23/8878 ,  B01J23/8896 ,  B01J23/89 ,  B01J23/8946 ,  B01J23/8966 ,  B01J23/8973 ,  B01J23/8993 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0205

    摘要： The present invention relates to a process for the epoxidation of hydrocarbons. This process comprises reacting at least one hydrocarbon with oxygen or air or nitrous oxide or other gaseous oxidants, in the presence of a mixture comprising at least two elements selected from the group consisting of Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Co, Ni, Sn, Pb, Sb, Bi and Se, on a support with a BET surface area of less than 200 m2/g. The present invention also relates to catalysts suitable for the epoxidation of hydrocarbons, wherein the catalyst comprises a mixture comprising at least two metals selected from the group consisting of Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Re, Fe, Co, Ni, Sn, Pb, Sb, Bi and Se, on a support with a BET surface area of less than 200 m2/g.

    摘要翻译： 本发明涉及烃的环氧化方法。 该方法包括使至少一种烃与氧或空气或一氧化二氮或其它气体氧化剂在包含选自Sc，Y，Ti，Zr，Hf，V，Nb中的至少两种元素的混合物存在下反应 ，Ta，Cr，Mo，W，Re，Fe，Co，Ni，Sn，Pb，Sb，Bi和Se，在BET表面积小于200m 2 / g的载体上。 本发明还涉及适用于烃类环氧化的催化剂，其中催化剂包括选自Sc，Y，Ti，Zr，Hf，V，Nb，Ta，Cr，Mo中的至少两种金属的混合物 ，W，Re，Fe，Co，Ni，Sn，Pb，Sb，Bi和Se在BET表面积小于200m 2 / g的载体上。

    Method for producing diaryl carbonates
    8.
    发明授权
    Method for producing diaryl carbonates 失效
    碳酸二芳基酯的制备方法

    公开(公告)号：US06469191B1

    公开(公告)日：2002-10-22

    申请号：US09868558

    申请日：2001-06-19

    申请人： Claus-Peter Reisinger ,  Ursula Jansen ,  Johann Rechner ,  Rob Eek

    发明人： Claus-Peter Reisinger ,  Ursula Jansen ,  Johann Rechner ,  Rob Eek

    IPC分类号： C07C6996

    CPC分类号： C07C68/005 ,  C07C69/96

    摘要： A process for the production of an aromatic carbonate is disclosed. Accordingly, an aromatic hydroxy compound is reacted with carbon monoxide and oxygen in the presence of a platinum group metal catalyst, a co-catalyst, a base, and optionally a quaternary salt as well as an inert organic solvent. The reaction is carried out under conditions whereby the inert organic solvent forms an azeotrope with the water arising during the reaction. The azeotrope is then removed from the reaction mixture.

    摘要翻译： 公开了一种生产芳族碳酸酯的方法。 因此，在铂族金属催化剂，助催化剂，碱，任选的季盐以及惰性有机溶剂的存在下，芳族羟基化合物与一氧化碳和氧反应。 该反应在惰性有机溶剂与反应期间产生的水形成共沸物的条件下进行。 然后从反应混合物中除去共沸物。

    Method for reprocessing reaction mixtures containing diaryl carbonate
    9.
    发明授权
    Method for reprocessing reaction mixtures containing diaryl carbonate 失效
    后处理含有碳酸二芳基酯的反应混合物的方法

    公开(公告)号：US06437166B1

    公开(公告)日：2002-08-20

    申请号：US09868412

    申请日：2001-06-14

    申请人： Carsten Hesse ,  Ursula Jansen ,  Johann Rechner ,  Claus-Peter Reisinger ,  Rob Eek ,  Kaspar Hallenberger ,  Martin Friedrich

    发明人： Carsten Hesse ,  Ursula Jansen ,  Johann Rechner ,  Claus-Peter Reisinger ,  Rob Eek ,  Kaspar Hallenberger ,  Martin Friedrich

    IPC分类号： C07C6996

    CPC分类号： C07C68/08 ,  C07C69/96

    摘要： A process for the work up of reaction mixtures containing diaryl carbonate, aromatic hydroxy compound, water, base and quaternary salt, which are obtained in the preparation of diaryl carbonates by direct carbonylation of aromatic hydroxy compounds, is described. In the process of the present invention an adduct of diaryl carbonate and aromatic hydroxy compound is crystallized from the reaction mixture. A distillate comprising aromatic hydroxy compound is removed from the liquid phase either prior to or after crystallization of the adduct of diaryl carbonate and aromatic hydroxy compound. The liquid phase remaining after the crystallization and distillation steps may be recycled, without further work up, back to the direct carbonylation process step by which the diaryl carbonate is initially prepared.

    摘要翻译： 描述了通过芳族羟基化合物的直接羰基化制备碳酸二芳酯中获得的包含碳酸二芳基酯，芳族羟基化合物，水，碱和季盐的反应混合物的处理方法。 在本发明的方法中，碳酸二芳酯和芳族羟基化合物的加合物从反应混合物中结晶。 在碳酸二芳基酯和芳族羟基化合物的加合物结晶之前或之后，从液相中除去包含芳族羟基化合物的馏出物。 在结晶和蒸馏步骤后残留的液相可以循环使用，而不需要进一步的后处理，回到最初制备碳酸二芳基酯的直接羰基化工艺步骤。