公开(公告)号：US09624622B2

公开(公告)日：2017-04-18

申请号：US13811956

申请日：2011-08-12

申请人： Harmin Müller ,  Paul Stuart Wormald ,  Paolo Bavaj

发明人： Harmin Müller ,  Paul Stuart Wormald ,  Paolo Bavaj

IPC分类号： D06N7/00

CPC分类号： D06N7/0063 ,  D06N7/0073 ,  D06N2203/042 ,  D06N2209/067 ,  Y10T428/23921

摘要： Disclosed are carpet products comprising at least one flexible substrate and at least one coating and/or adhesive layer associated with the at least one flexible substrate. The coating and/or adhesive layer is formed from an aqueous composition comprising: A) an emulsifier-stabilized vinyl acetate/ethylene (VAE) emulsion copolymer dispersion and B) at least one particulate filler material selected from particulate inorganic compounds and particulate plastic material. The vinyl acetate/ethylene copolymer in the copolymer dispersion has a selected ethylene content or glass transition temperature. It is also preferably substantially free of cross-linkable co-monomer moieties which generate formaldehyde upon curing and preferably has a particle size, dw, ranging from about 50 to about 500 nm. The carpet product is substantially free of polyvinyl chloride and bitumen and exhibits a Class B1 flame-retardancy in accordance with DIN 4102-14, corresponding to a critical heat flux of ≧about 4.5 kW/m2.

公开(公告)号：US20120009379A1

公开(公告)日：2012-01-12

申请号：US13148545

申请日：2010-02-06

申请人： Harmin Müller ,  Paul Stuart Wormald

发明人： Harmin Müller ,  Paul Stuart Wormald

IPC分类号： B32B5/02 ,  D03D9/00 ,  C09D131/04

CPC分类号： C08L23/0853 ,  C08F218/08 ,  D06N7/0073 ,  D06N2203/042 ,  D06N2203/045 ,  D06N2209/165 ,  Y10T428/23986 ,  Y10T442/10 ,  Y10T442/20 ,  C08L2666/02 ,  C08F210/02

摘要： The invention relates to vinyl acetate-ethylene copolymer dispersions suitable for treating textle web materials, and to textile web material treated therewith, being suitable in particular as floor coverings or as belts. The vinyl acetate-ethylene-copolymer dispersions are characterized by a low ethylene unit content, relatively high glass transition temperatures, and a small particle size.

摘要翻译： 本发明涉及适用于处理织物纤维网材料的乙酸乙烯酯 - 乙烯共聚物分散体以及其处理的织物纤维网材料，特别适用于地板覆盖物或带材。 乙酸乙烯酯 - 乙烯共聚物分散体的特征在于低乙烯单元含量，相对高的玻璃化转变温度和小的粒度。

公开(公告)号：US08785540B2

公开(公告)日：2014-07-22

申请号：US11835102

申请日：2007-08-07

申请人： Harmin Müller ,  Hans Uwe Faust ,  Martin Schäfer

发明人： Harmin Müller ,  Hans Uwe Faust ,  Martin Schäfer

IPC分类号： C08K3/20

CPC分类号： C08F218/08 ,  C08L29/06 ,  C08L31/04 ,  C08L2205/02 ,  C08L2666/04 ,  C09J131/04 ,  C08L2666/06

摘要： A description is given of an aqueous vinyl ester copolymer dispersion stabilized with a combination of at least one protective colloid and of at least one emulsifier, said dispersion having a viscosity of less than 8000 mPa*s, a weight average dw of the particle sizes of 0.5 to 10 μm, and a ratio of weight average to number average of the particle sizes, dw/dn, of at least 2.5, and the polymer possessing a glass transition temperature of between −30 and +15° C.The dispersion can be used as an adhesive for nozzle application processes.

摘要翻译： 给出了用至少一种保护胶体和至少一种乳化剂的组合稳定的乙烯基酯共聚物水分散体的分散体，所述分散体的粘度小于8000mPa * s，粒径的重量平均值dw 0.5〜10μm，粒径的重均数与dw / dn之比为2.5以上，聚合物的玻璃化转变温度为-30〜+ 15℃。分散液可以为 用作喷嘴应用过程的粘合剂。

公开(公告)号：US20130177733A1

公开(公告)日：2013-07-11

申请号：US13811962

申请日：2011-08-12

申请人： Harmin Müller ,  Paul Wormald ,  Paolo Bavaj

发明人： Harmin Müller ,  Paul Wormald ,  Paolo Bavaj

IPC分类号： D06N3/04 ,  D06N3/00

CPC分类号： D06N3/042 ,  D06N3/0006 ,  D06N3/0009 ,  D06N3/0011 ,  D06N3/004 ,  D06N7/0073 ,  D06N2203/042 ,  D06N2209/106 ,  Y10T428/23979 ,  Y10T428/23986

摘要： Disclosed are carpet products comprising at least one flexible substrate and at least one coating layer associated with the at least one flexible substrate. The coating layer is formed from an aqueous composition comprising: A) an emulsifier-stabilized vinyl acetate/ethylene (VAE) emulsion copolymer dispersion wherein the VAE copolymer therein comprises co-monomers which include at least vinyl acetate copolymerized with ethylene and optionally also with other additional functional and/or non-functional co-monomers; and B) at least one particulate filler material selected from particulate inorganic compounds and particulate plastic material. The vinyl acetate/ethylene copolymer in the copolymer dispersion has a particle size, dw, ranging from about 50 to about 500 nm as determined by Laser Aerosol Spectroscopy. Such carpet products maintain their integrity and appearance after multiple machine washing operations. Some of these carpet products which have backing coated with certain of the coating compositions used herein also exhibit desirable non-slip properties.

摘要翻译： 公开了包含至少一个柔性基底和与至少一个柔性基底相关联的至少一个涂层的地毯产品。 涂层由水性组合物形成，该组合物包含：A）乳化剂稳定的乙酸乙烯酯/乙烯（VAE）乳液共聚物分散体，其中其中的VAE共聚物包含共聚单体，其至少包括与乙烯共聚的乙酸乙烯酯， 附加功能和/或非功能性共聚单体; 和B）至少一种选自颗粒无机化合物和颗粒状塑料材料的颗粒填料。 通过激光气溶胶光谱测定，共聚物分散体中的乙酸乙烯酯/乙烯共聚物的粒度dw为约50至约500nm。 这样的地毯产品在多次洗衣操作后保持其完整性和外观。 这些具有背衬涂覆有本文所用的某些涂料组合物的这些地毯产品中的一些也表现出所需的防滑性能。

公开(公告)号：US07358297B2

公开(公告)日：2008-04-15

申请号：US10918121

申请日：2004-08-12

申请人： Harmin Müller

发明人： Harmin Müller

IPC分类号： B01J13/14

CPC分类号： C08F2/24

摘要： A description is given of a process for preparing bimodal or multimodal polymers from olefinically unsaturated monomers in an aqueous medium.The process features the introduction as initial charge of selected mixtures of polymeric stabilizers and of at least one selected ionic comonomer.In the polymerization process the monomer is metered continuously or discontinuously into the said initial charge.In this way it is possible by means of simple process measures to prepare bimodal or multimodal dispersions.

摘要翻译： 描述了在水性介质中由烯属不饱和单体制备双峰或多峰聚合物的方法。 该方法的特征在于引入作为聚合物稳定剂和至少一种选择的离子共聚单体的所选混合物的初始电荷。 在聚合过程中，将单体连续地或不连续地计量到所述初始电荷中。 以这种方式，可以通过简单的过程措施来制备双峰或多峰分散体。

公开(公告)号：US09816001B2

公开(公告)日：2017-11-14

申请号：US12584152

申请日：2009-09-01

申请人： Elizabeth A. Poole ,  Rajeev Farwaha ,  Brett C. Beauregard ,  Alexander Madl ,  Jörg L. Schulte ,  Harmin Müller ,  Kristy Jo Beckman

发明人： Elizabeth A. Poole ,  Rajeev Farwaha ,  Brett C. Beauregard ,  Alexander Madl ,  Jörg L. Schulte ,  Harmin Müller ,  Kristy Jo Beckman

IPC分类号： C09D131/04 ,  C09D133/08 ,  C08K3/00 ,  C08L31/04 ,  C08L33/08

CPC分类号： C09D131/04 ,  C08K3/013 ,  C08L31/04 ,  C08L33/08 ,  C09D133/08 ,  C08L2666/04

摘要： A water-based, low-emission latex paint formulation includes a vinyl acetate/ethylene (VAE) latex including a VAE resin with from 80 to 95 weight % vinyl acetate residue and from 5 to 20 weight % ethylene residue, optionally including additional monomers as well as a pigment composition including inorganic solids selected from inorganic pigments, inorganic fillers and mixtures thereof present in an amount such that the paint formulation has a pigment volume concentration (PVC) of from 25% to 85%. The formulations are suitable for eggshell and flat latex paints and exhibit surprising durability.

公开(公告)号：US07244812B2

公开(公告)日：2007-07-17

申请号：US10527178

申请日：2003-07-26

申请人： Harmin Müller ,  Martin Jakob ,  Carsten Heldmann ,  Thomas Wirth

发明人： Harmin Müller ,  Martin Jakob ,  Carsten Heldmann ,  Thomas Wirth

IPC分类号： C08F6/00

CPC分类号： C08F6/006

摘要： The invention relates to a method for reducing the amount of residual monomers in aqueous polymer dispersions means of chemical post-treatment. Post-treatment in the aqueous polymer dispersion is carried out by adding a redox system which contains a) 0.005-5 wt. % of an oxidation agent which contains an organic peroxide. and b) 0.005-5 wt. % of a reduction agent which contains sulfinic acids or salts thereof. Additionally the redox system can, optionally, contain catalytic amounts of a polyvalent metallic ion which can be treated in several valent stages. Post-treatment can be carried out at a temperature ranging from 20-100.degree. C. and at a PH-value ranging from 2-9. The invention also relates to the use of the inventive post-treated polymer dispersion for producing adhesives, coatings, powders, constructive chemical products or for refining textiles or paper.

摘要翻译： 本发明涉及减少聚合物水分散体中化学后处理方法中残余单体量的方法。 在聚合物水分散体中的后处理是通过加入氧化还原体系进行的，所述氧化还原体系含有：a）0.005-5wt。 含有有机过氧化物的氧化剂的％。 和b）0.005-5wt。 ％的还原剂含有亚磺酸或其盐。 此外，氧化还原体系可以任选地含有催化量的多价金属离子，其可以以数个阶段处理。 后处理可以在20-100度的温度范围内进行。 且PH值范围为2-9。 本发明还涉及本发明的后处理聚合物分散体用于生产粘合剂，涂料，粉末，建构性化学产品或用于精制纺织品或纸的用途。