摘要:
A system is proposed for the purification of exhaust gases from internal combustion engines, preferably the reduction of nitrogen oxides in exhaust gases from internal combustion engines in which nitrogen is selectively formed as substantially the only nitrogen-containing product. The exhaust gas is contacted at an elevated temperature with a noble metal in a reducing atmosphere, wherein nitrogen oxides are selectively converted to nitrogen as substantially the only nitrogen containing product, and/or is contacted with a noble metal in an oxidizing atmosphere, wherein carbon monoxide and unburned hydrocarbons are converted to carbon dioxide and water, said noble metal being distended on a microporous glass body. In a preferred embodiment the exhaust gas is contacted at an elevated temperature in a reducing atmosphere with ruthenium supported on a microporous glass body comprising a leached, phase-separated alkali borosilicate.
摘要:
The conversion of carbon monoxide and hydrogen to produce methane is catalyzed by a layered complex metal silicate composition characterized as having repeating units of the structural formula[(1-x)Ni.sup.a + xRu.sup.b ].sub.n (OH).sub.4 Si.sub.2 O.sub.5.wH.sub.2 Owhere x is a number from 0 to 1, this number expressing the atomic fraction of the metals nickel and ruthenium, a is the valence of nickel, b is the valence of ruthenium, n is a number equal in value to that defined by the ratio6/[a(1-x) + bx]And w is a number ranging from 0 to 4. Nickel chrysotile is the preferred catalyst.
摘要翻译:通过层状复合金属硅酸盐组合物催化一氧化碳和氢气转化产生甲烷的催化剂,其特征在于具有结构式[(1-X)N y + x(OH)4 Si 2 O 5·wH 2 O的重复单元,其中x是数 从0到1,这个数字表示金属镍和钌的原子分数,a是镍的化合价,b是钌的化合价,n是数值等于6 / [A( 1-X)+ BX],W是从0到4的范围。镍温石棉是优选的催化剂。
摘要:
The conversion of carbon monoxide and hydrogen to produce a mixture of low molecular weight hydrocarbons which, on a methane-free basis, contain a predominance of C.sub.2 -C.sub.6 paraffins is achieved using as the catalyst a rare earth metal promoted layered complex metal silicate composition characterized as having repeating units of the structural formula[(1-x)Ni.sup.a + xRu.sup.6 ].sub.n (OH).sub.4 Si.sub.2 O.sub.5.wH.sub.2 Owhere x is a number from 0 to 1, this number expressing the atomic fraction of the metals nickel and ruthenium; a is the valence of nickel; b is the valence of ruthenium; n is a number equal in value to that defined by the ratio6/[a(1-x) + bx]and w is a number ranging from 0 to 4. A rare earth promoted nickel chrysotile is the preferred catalyst.
摘要:
The conversion of carbon monoxide and hydrogen to produce methane is catalyzed by a layered complex metal silicate composition characterized as having repeating units of the structural formula[(1-x)Ni.sup..sup.+2 + xMg.sup..sup.+2 ].sub.3 (OH).sub.4 Si.sub.2 O.sub.5.wH.sub.2 Owhere x is a number from 0.01 to 0.6, this number expressing the atomic fraction of the metals nickel and magnesium and w is a number ranging from 0 to 4.
摘要:
A catalytically hydrogenated naphtha stream containing less than 10 ppm by weight of sulfur is pyrolyzed without added hydrogen to a product including ethylene. Selectivity to ethylene is increased by adding a sulfur compound to increase the sulfur content to above 20 ppm by weight based on hydrogenated naphtha. Addition of the sulfur compound increases the quality of hydrogenated naphtha as a pyrolysis feedstock nearly to that of a C.sub.2 to C.sub.5 paraffin stream.
摘要:
A process for preparing acrylonitrile which comprises passing a gaseous mixture comprising propylene, ammonia and molecular oxygen and an ammoxidation catalyst through a reaction zone while controlling the superficial linear gas velocity and solids feeds rate to achieve a state of fast fluidization.
摘要:
A process for the conversion of gas oil to a naphtha pyrolysis feedstock and needle coke comprising thermally cracking the gas oil to produce a product comprising cracked naphtha and aromatic tar oil, delay coking said aromatic tar oil to produce needle coke and coker naphtha, and hydrotreating said cracked naphtha and said coker naphtha at a temperature at least 50.degree. F. (28.degree. C.) lower than the temperature in the thermal cracking and coking zones to avoid hydrocarcking reactions and to produce a hydrogenated naphtha containing at least 10 volume percent of cycloparaffins. Said hydrogenated naphtha is thereupon passed through a pyrolysis zone without added molecular hydrogen and without a catalyst operated at a temperature between 1,300 and 2,300.degree. F. (704 and 1,260.degree. C.) and a residence between 0.05 and 2 seconds to produce a product containing ethylene. The ethylene yield can be increased by adding a sulfur compound to the hydrogenated naphtha stream flowing to the pyrolysis zone.
摘要:
When ethylene is telomerized to produce alpha-olefins in the presence of an organo-aluminum catalyst, the aluminum catalyst is present in the normally liquid alpha-olefin product and must be removed prior to distillation of that product. This removal is accomplished in two zones. Water is added to the alpha-olefin product containing the organo-aluminum catalyst in a first zone to produce an aqueous phase containing a suspension of aluminum hydroxide and an organic phase containing the alpha-olefins. After removal of the organic phase, a sufficient amount of an aqueous solution of a polyacrylamide in anionic form is added to the aqueous phase to result in at least 90 percent of the aluminum hydroxide settling in a time period of less than ten minutes at ambient conditions.
摘要:
The present invention is a method for obtaining an electrical signal from a patient that corresponds to a meridian. The present method contemplates locating a dermal area of a patient proximate a meridian. One embodiment of the present invention comprises locating a dermal area by iteratively measuring and comparing the conductivity of a patient's skin until a significant level of conductance is indicated. A probe may then be placed in contact with the dermal area, and actuated to obtain an electrical signal therefrom. The probe tip may be specially designed to apply an appropriate amount of pressure to the dermal area to directly sense a meridian, and configured to avoid erroneous measurements resulting from misalignment of the probe or probe tip.
摘要:
A statistically large population of particles of amorphous precipitated silica comprising pigmentary phase particles and glassy phase particles and having a glassy phase fraction in the range of from 0.3 to 30 area percent is useful as an abrasive for dentifrice compositions, especially toothpaste.