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公开(公告)号：US20100331995A1
公开(公告)日：2010-12-30
申请号：US12741431
申请日：2008-11-06
IPC分类号： A61F2/30 , A61F2/02 , C08L23/06 , A61L2/08 , C08K5/3435 , C08K5/3462
CPC分类号： C08J3/24 , A61L27/16 , A61L27/505 , C08F8/00 , C08J3/28 , C08J2323/06 , C08J2323/36 , C08K5/3435 , C08K5/3492 , C08K5/34926 , C08L23/06 , C08L2201/08 , C08L2203/02 , C08L2207/068 , C08L2666/02 , C08F110/02
摘要： The invention relates to a process for producing an (ultra) high molecular weight polyethylene (HMWPE) article comprising:—incorporating into the HMWPE resin a Hindered Amine Light Stabilizer (HALS) and—cross-link the (U)HMWPE during or after molding the (U)HMWPE resin. In particular the invention relates to a process comprising the following steps: a) incorporating into (U)HMWPE resin a Hindered Amine Light Stabilizer (HALS) according to one of the following general formulas or combinations hereof: wherein R1 up to and including R5 are herein independent substituents; for example containing hydrogen, ether, ester, amine, amide, alkyl, alkenyl, alkynyl, aralkyl, cycloalkyl and/or aryl groups, which substituents may in turn contain functional groups, for example alcohols, ketones, anhydrides, imines, siloxanes, ethers, carboxyl groups, aldehydes, esters, amides, imides, amines, nitriles, ethers, urethanes and any combination thereof; b) molding the (U)HMWPE resin comprising the HALS, resulting in an article; c) cross-linking and sterilizing the article via gamma radiation or electron beam radiation; d) optionally, if step b results in a stock shape, machining the stock shape into an article; wherein step c and step d can be performed in either order.
摘要翻译： 本发明涉及一种用于生产（超）高分子量聚乙烯（HMWPE）制品的方法，其包括： - 在成型期间或之后 - 将HMWPE树脂中的受阻胺光稳定剂（HALS）和 - 交联（U）HMWPE （U）HMWPE树脂。 具体而言，本发明涉及一种包括以下步骤的方法：a）根据以下通式或其组合之一将（U）HMWPE树脂掺入到受阻胺光稳定剂（HALS）中：其中R 1直至并包括R 5为 本文独立取代基; 例如含有氢，醚，酯，胺，酰胺，烷基，烯基，炔基，芳烷基，环烷基和/或芳基，该取代基又可包含官能团，例如醇，酮，酸酐，亚胺，硅氧烷，醚 羧基，醛，酯，酰胺，酰亚胺，胺，腈，醚，氨基甲酸酯及其任何组合; b）模制包含HALS的（U）HMWPE树脂，得到制品; c）通过伽马辐射或电子束辐射对制品进行交联和灭菌; d）任选地，如果步骤b导致坯料形状，将坯料加工成制品; 其中步骤c和步骤d可以以任何顺序执行。
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公开(公告)号：US09238719B2
公开(公告)日：2016-01-19
申请号：US12741431
申请日：2008-11-06
IPC分类号： C08F2/46 , C08L23/06 , C08K5/3435 , C08K3/28 , C08J3/28 , A61L27/16 , C08K5/3492
CPC分类号： C08J3/24 , A61L27/16 , A61L27/505 , C08F8/00 , C08J3/28 , C08J2323/06 , C08J2323/36 , C08K5/3435 , C08K5/3492 , C08K5/34926 , C08L23/06 , C08L2201/08 , C08L2203/02 , C08L2207/068 , C08L2666/02 , C08F110/02
摘要： The invention relates to a process for producing an (ultra) high molecular weight polyethylene (HMWPE) article comprising:—incorporating into the HMWPE resin a Hindered Amine Light Stabilizer (HALS) and—cross-link the (U)HMWPE during or after molding the (U)HMWPE resin. In particular the invention relates to a process comprising the following steps: a) incorporating into (U)HMWPE resin a Hindered Amine Light Stabilizer (HALS) according to one of the following general formulas or combinations hereof: wherein R1 up to and including R5 are herein independent substituents; for example containing hydrogen, ether, ester, amine, amide, alkyl, alkenyl, alkynyl, aralkyl, cycloalkyl and/or aryl groups, which substituents may in turn contain functional groups, for example alcohols, ketones, anhydrides, imines, siloxanes, ethers, carboxyl groups, aldehydes, esters, amides, imides, amines, nitriles, ethers, urethanes and any combination thereof; b) molding the (U)HMWPE resin comprising the HALS, resulting in an article; c) cross-linking and sterilizing the article via gamma radiation or electron beam radiation; d) optionally, if step b results in a stock shape, machining the stock shape into an article; wherein step c and step d can be performed in either order.
摘要翻译： 本发明涉及一种用于生产（超）高分子量聚乙烯（HMWPE）制品的方法，其包括： - 在成型期间或之后 - 将HMWPE树脂中的受阻胺光稳定剂（HALS）和 - 交联（U）HMWPE （U）HMWPE树脂。 具体而言，本发明涉及一种包括以下步骤的方法：a）根据以下通式或其组合之一将（U）HMWPE树脂掺入到受阻胺光稳定剂（HALS）中：其中R 1直至并包括R 5为 本文独立取代基; 例如含有氢，醚，酯，胺，酰胺，烷基，烯基，炔基，芳烷基，环烷基和/或芳基，该取代基又可包含官能团，例如醇，酮，酸酐，亚胺，硅氧烷，醚 羧基，醛，酯，酰胺，酰亚胺，胺，腈，醚，氨基甲酸酯及其任何组合; b）模制包含HALS的（U）HMWPE树脂，得到制品; c）通过伽马辐射或电子束辐射对制品进行交联和灭菌; d）任选地，如果步骤b导致坯料形状，将坯料加工成制品; 其中步骤c和步骤d可以以任何顺序执行。
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