公开(公告)号：US09238719B2

公开(公告)日：2016-01-19

申请号：US12741431

申请日：2008-11-06

Applicant: Harold Jan Smelt ,  Pieter Gijsman ,  Martin van Duin

Inventor： Harold Jan Smelt ,  Pieter Gijsman ,  Martin van Duin

IPC: C08F2/46 ,  C08L23/06 ,  C08K5/3435 ,  C08K3/28 ,  C08J3/28 ,  A61L27/16 ,  C08K5/3492

CPC classification number: C08J3/24 ,  A61L27/16 ,  A61L27/505 ,  C08F8/00 ,  C08J3/28 ,  C08J2323/06 ,  C08J2323/36 ,  C08K5/3435 ,  C08K5/3492 ,  C08K5/34926 ,  C08L23/06 ,  C08L2201/08 ,  C08L2203/02 ,  C08L2207/068 ,  C08L2666/02 ,  C08F110/02

Abstract: The invention relates to a process for producing an (ultra) high molecular weight polyethylene (HMWPE) article comprising:—incorporating into the HMWPE resin a Hindered Amine Light Stabilizer (HALS) and—cross-link the (U)HMWPE during or after molding the (U)HMWPE resin. In particular the invention relates to a process comprising the following steps: a) incorporating into (U)HMWPE resin a Hindered Amine Light Stabilizer (HALS) according to one of the following general formulas or combinations hereof: wherein R1 up to and including R5 are herein independent substituents; for example containing hydrogen, ether, ester, amine, amide, alkyl, alkenyl, alkynyl, aralkyl, cycloalkyl and/or aryl groups, which substituents may in turn contain functional groups, for example alcohols, ketones, anhydrides, imines, siloxanes, ethers, carboxyl groups, aldehydes, esters, amides, imides, amines, nitriles, ethers, urethanes and any combination thereof; b) molding the (U)HMWPE resin comprising the HALS, resulting in an article; c) cross-linking and sterilizing the article via gamma radiation or electron beam radiation; d) optionally, if step b results in a stock shape, machining the stock shape into an article; wherein step c and step d can be performed in either order.

Abstract translation: 本发明涉及一种用于生产（超）高分子量聚乙烯（HMWPE）制品的方法，其包括： - 在成型期间或之后 - 将HMWPE树脂中的受阻胺光稳定剂（HALS）和 - 交联（U）HMWPE （U）HMWPE树脂。 具体而言，本发明涉及一种包括以下步骤的方法：a）根据以下通式或其组合之一将（U）HMWPE树脂掺入到受阻胺光稳定剂（HALS）中：其中R 1直至并包括R 5为 本文独立取代基; 例如含有氢，醚，酯，胺，酰胺，烷基，烯基，炔基，芳烷基，环烷基和/或芳基，该取代基又可包含官能团，例如醇，酮，酸酐，亚胺，硅氧烷，醚 羧基，醛，酯，酰胺，酰亚胺，胺，腈，醚，氨基甲酸酯及其任何组合; b）模制包含HALS的（U）HMWPE树脂，得到制品; c）通过伽马辐射或电子束辐射对制品进行交联和灭菌; d）任选地，如果步骤b导致坯料形状，将坯料加工成制品; 其中步骤c和步骤d可以以任何顺序执行。

公开(公告)号：US20130203886A1

公开(公告)日：2013-08-08

申请号：US13582813

申请日：2011-03-04

Applicant: Nileshkumar Prakash Kukalyekar ,  Jan Stolk ,  Mitcha Sandor Nicolaas Mulders ,  Robert Hendrik Catharina Janssen ,  Harold Jan Smelt ,  Piotr Pawel Matloka

Inventor： Nileshkumar Prakash Kukalyekar ,  Jan Stolk ,  Mitcha Sandor Nicolaas Mulders ,  Robert Hendrik Catharina Janssen ,  Harold Jan Smelt ,  Piotr Pawel Matloka

IPC: C08F236/20

CPC classification number: C08F236/20 ,  A61F2/3094 ,  A61F2/389 ,  A61L27/16 ,  A61L2430/24 ,  C08F210/18 ,  C08L23/06 ,  C08F2500/12

Abstract: The invention relates to a process for the production of an article, wherein—ethylene is polymerized with a polyene and optionally another comonomer, resulting in a polymer with a MFI (21.6) between 0.05 dg/min and 100 dg/min,—melt processing the polymer into an article,—optionally crosslinking the polymer during or after melt processing the polymer and—optionally sterilizing the polymer article by high energy irradiation.

Abstract translation: 本发明涉及一种生产制品的方法，其中乙烯与多烯和任选的另一种共聚单体聚合，得到具有0.05dg / min至100dg / min的MFI（21.6）的聚合物， - 熔融加工 将聚合物转化成制品， - 在熔融加工聚合物期间或之后可选地使聚合物交联，并且通过高能量照射任选地灭菌聚合物制品。

公开(公告)号：US20110040381A1

公开(公告)日：2011-02-17

申请号：US12741681

申请日：2008-11-06

Applicant: Timothy James Kidd ,  Robert Hendrik Catharina Janssen ,  Filip Frederix ,  Jan Stolk ,  Harold Jan Smelt

Inventor： Timothy James Kidd ,  Robert Hendrik Catharina Janssen ,  Filip Frederix ,  Jan Stolk ,  Harold Jan Smelt

IPC: A61F2/44 ,  B29C45/00 ,  A61F2/32 ,  A61F2/40 ,  A61F2/38 ,  C08F136/20 ,  C08J3/28

CPC classification number: C08F210/02 ,  A61L27/16 ,  C08L23/06 ,  C08F236/20 ,  C08F2500/01 ,  C08F2500/14 ,  C08F236/06

Abstract: The invention relates to a process for the production of an ultra-high molecular weight polyethylene ((U)HMWPE) article comprising: —copolymerizing ethylene with a linear, branched or cyclic polyene having 3 to 100 carbon atoms, resulting in a copolymer of ethylene and polyene ((U)HMWPE-P), using such a content of polyene that the number of polyene branches in (U)HMWPE-P is 0.01 to 15 on the average per 1000 carbon atoms; —cross-link the (U)HMWPE-P during or after molding the (U)HMWPE-P.

Abstract translation: 本发明涉及一种制备超高分子量聚乙烯（（U）HMWPE）制品的方法，其包括：将具有3至100个碳原子的直链，支链或环状多烯的乙烯聚合，得到乙烯的共聚物 和（多）烯（（U）HMWPE-P）），使用这样的多烯含量，（U）HMWPE-P中的多烯分支数为每1000个碳原子平均为0.01至15; 在（U）HMWPE-P成型期间或之后 - （U）HMWPE-P交联。

公开(公告)号：US20100331995A1

公开(公告)日：2010-12-30

申请号：US12741431

申请日：2008-11-06

Applicant: Harold Jan Smelt ,  Pieter Gijsman ,  Martin van Duin

Inventor： Harold Jan Smelt ,  Pieter Gijsman ,  Martin van Duin

IPC: A61F2/30 ,  A61F2/02 ,  C08L23/06 ,  A61L2/08 ,  C08K5/3435 ,  C08K5/3462

CPC classification number: C08J3/24 ,  A61L27/16 ,  A61L27/505 ,  C08F8/00 ,  C08J3/28 ,  C08J2323/06 ,  C08J2323/36 ,  C08K5/3435 ,  C08K5/3492 ,  C08K5/34926 ,  C08L23/06 ,  C08L2201/08 ,  C08L2203/02 ,  C08L2207/068 ,  C08L2666/02 ,  C08F110/02

Abstract: The invention relates to a process for producing an (ultra) high molecular weight polyethylene (HMWPE) article comprising:—incorporating into the HMWPE resin a Hindered Amine Light Stabilizer (HALS) and—cross-link the (U)HMWPE during or after molding the (U)HMWPE resin. In particular the invention relates to a process comprising the following steps: a) incorporating into (U)HMWPE resin a Hindered Amine Light Stabilizer (HALS) according to one of the following general formulas or combinations hereof: wherein R1 up to and including R5 are herein independent substituents; for example containing hydrogen, ether, ester, amine, amide, alkyl, alkenyl, alkynyl, aralkyl, cycloalkyl and/or aryl groups, which substituents may in turn contain functional groups, for example alcohols, ketones, anhydrides, imines, siloxanes, ethers, carboxyl groups, aldehydes, esters, amides, imides, amines, nitriles, ethers, urethanes and any combination thereof; b) molding the (U)HMWPE resin comprising the HALS, resulting in an article; c) cross-linking and sterilizing the article via gamma radiation or electron beam radiation; d) optionally, if step b results in a stock shape, machining the stock shape into an article; wherein step c and step d can be performed in either order.

Abstract translation: 本发明涉及一种用于生产（超）高分子量聚乙烯（HMWPE）制品的方法，其包括： - 在成型期间或之后 - 将HMWPE树脂中的受阻胺光稳定剂（HALS）和 - 交联（U）HMWPE （U）HMWPE树脂。 具体而言，本发明涉及一种包括以下步骤的方法：a）根据以下通式或其组合之一将（U）HMWPE树脂掺入到受阻胺光稳定剂（HALS）中：其中R 1直至并包括R 5为 本文独立取代基; 例如含有氢，醚，酯，胺，酰胺，烷基，烯基，炔基，芳烷基，环烷基和/或芳基，该取代基又可包含官能团，例如醇，酮，酸酐，亚胺，硅氧烷，醚 羧基，醛，酯，酰胺，酰亚胺，胺，腈，醚，氨基甲酸酯及其任何组合; b）模制包含HALS的（U）HMWPE树脂，得到制品; c）通过伽马辐射或电子束辐射对制品进行交联和灭菌; d）任选地，如果步骤b导致坯料形状，将坯料加工成制品; 其中步骤c和步骤d可以以任何顺序执行。