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公开(公告)号：US5604288A
公开(公告)日：1997-02-18
申请号：US565652
申请日：1995-11-29
IPC分类号： C08L83/07 , C08G77/42 , C08G77/442 , C08G81/00 , C08G81/02 , C08L83/04 , C08L101/00 , C08K3/34
CPC分类号： C08G77/442 , C08G81/024
摘要： A method for preparing a thermoplastic resin composition, said method comprising hot-kneading, in the absence of a radical-generating catalyst,(A) 100 parts by weight of a thermoplastic resin; and(B) 0.1 to 200 parts by weight of an alkenyl-functional polyorganosiloxane filled with amorphous silica micropowder, wherein the weight ratio of said silica micropowder to said alkenyl-functional polyorganosiloxane is 0.01:100 to 50:100, whereby the polyorganosiloxane of component (B) is chemically bonded to resin (A).
摘要翻译： 一种制备热塑性树脂组合物的方法，所述方法包括在不存在自由基产生催化剂的情况下热捏合（A）100重量份的热塑性树脂; 和（B）0.1〜200重量份填充有无定形二氧化硅微粉末的烯基官能聚有机硅氧烷，其中所述二氧化硅微粉与所述烯基官能聚有机硅氧烷的重量比为0.01:100至50:100，由此组分的聚有机硅氧烷 （B）与树脂（A）化学键合。
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公开(公告)号：US5346941A
公开(公告)日：1994-09-13
申请号：US62674
申请日：1993-05-17
IPC分类号： C08K3/36 , C08K5/5419 , C08K9/04 , C08K9/06 , C08K9/08 , C08L83/04 , C08L101/00 , C09C1/28 , C08K5/54
摘要： A siloxane powder composition which can impart improved lubricity character to a thermoplastic resin is disclosed, said composition being prepared by mixing(A) 100 parts by weight of a liquid polydiorganosiloxane and(B) 40 to 200 parts by weight of a silica powder that has a specific surface of at least 50 m.sub.2 /g using sufficient shear to prepare a powder in which the surface of component (B) is coated with component (A), and then mixing this powder with(C) 10 to 50 parts by weight of a polyorganosiloxane resin which is a solid at room temperature, said resin consisting essentially of (R.sub.3 SiO.sub.1/2) siloxane units and (SiO.sub.2) siloxane units in the molar ratio of 1:4 to 1:1,where R is selected from the group consisting of alkyl radicals and phenyl radical.
摘要翻译： 公开了可赋予热塑性树脂改善的润滑性特征的硅氧烷粉末组合物，所述组合物通过将（A）100重量份的液体聚二有机硅氧烷和（B）40至200重量份的二氧化硅粉末 使用足够的剪切来制备至少50m 2 / g的比表面，以制备其中组分（B）的表面涂覆有组分（A）的粉末，然后将该粉末与（C）10至50重量份的 在室温下为固体的聚有机硅氧烷树脂，所述树脂基本上由摩尔比为1:4至1:1的（R3SiO1 / 2）硅氧烷单元和（SiO2）硅氧烷单元组成，其中R选自 的烷基和苯基。
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公开(公告)号：US5508335A
公开(公告)日：1996-04-16
申请号：US237534
申请日：1994-05-03
IPC分类号： C08K3/36 , C08K5/5419 , C08K9/04 , C08K9/06 , C08K9/08 , C08L83/04 , C08L101/00 , C09C1/28 , C08K3/34
摘要： A siloxane powder composition which can impart improved lubricity character to a thermoplastic resin is disclosed, said composition being prepared by mixing(A) 100 parts by weight of a liquid polydiorganosiloxane and(B) 40 to 200 parts by weight of a silica powder that has a specific surface of at least 50 m.sup.2 /g using sufficient shear to prepare a powder in which the surface of component (B) is coated with component (A), and then mixing this powder with(C) 10 to 50 parts by weight of a polyorganosiloxane resin which is a solid at room temperature, said resin consisting essentially of (R.sub.3 SiO.sub.1/2) siloxane units and (SiO.sub.2) siloxane units in the molar ratio of 1:4 to 1:1,where R is selected from the group consisting of alkyl radicals and phenyl radical.
摘要翻译： 公开了可赋予热塑性树脂改善的润滑性特征的硅氧烷粉末组合物，所述组合物通过将（A）100重量份的液体聚二有机硅氧烷和（B）40至200重量份的二氧化硅粉末 使用足够的剪切使至少50m 2 / g的比表面制备粉末，其中组分（B）的表面涂覆有组分（A），然后将该粉末与（C）10至50重量份的 在室温下为固体的聚有机硅氧烷树脂，所述树脂基本上由摩尔比为1:4至1:1的（R3SiO1 / 2）硅氧烷单元和（SiO2）硅氧烷单元组成，其中R选自 的烷基和苯基。
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公开(公告)号：US5654366A
公开(公告)日：1997-08-05
申请号：US604138
申请日：1996-02-20
CPC分类号： C08L55/02 , C08L25/12 , C08L83/04 , C08L83/10 , C08G77/442 , C08G77/452 , C08G77/70
摘要： There is disclosed a thermoplastic resin composition wherein the dispersion of a polyorganosiloxane in a thermoplastic resin is improved by the inclusion of a copolymer of an organosiloxane compound and an ester of a vinylcarboxylic acid or a copolymer of an aromatic vinyl compound, an unsaturated aliphatic nitrile compound and an organosiloxane compound. As a consequence of the excellent dispersion, the composition has improved moldability compared with conventional thermoplastic resins containing only polyorganosiloxane and yields moldings that have a releasability, lubricity, water repellency and mechanical strength superior to moldings from the conventional thermoplastic resins containing only polyorganosiloxane.
摘要翻译： 公开了一种热塑性树脂组合物，其中聚有机硅氧烷在热塑性树脂中的分散体通过包含有机硅氧烷化合物和乙烯基羧酸的酯的共聚物或芳族乙烯基化合物，不饱和脂族腈化合物 和有机硅氧烷化合物。 作为优异分散性的结果，与仅含有聚有机硅氧烷的常规热塑性树脂相比，组合物具有改进的成型性，并且得到具有优于仅含有聚有机硅氧烷的常规热塑性树脂的模制品的脱模性，润滑性，拒水性和机械强度的模制品。
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5.发明授权公开(公告)号：US10047199B2
公开(公告)日：2018-08-14
申请号：US13517279
申请日：2010-12-22
申请人： Tomohiro Iimura , Haruhiko Furukawa
发明人： Tomohiro Iimura , Haruhiko Furukawa
IPC分类号： A61K8/81 , A61Q1/00 , A61Q17/04 , A61Q1/06 , A61Q1/10 , A61Q15/00 , C08F230/08 , A61Q1/12 , C08G77/442 , A61K8/891 , C08L83/10 , A61Q1/02 , A61Q1/04
摘要： The present invention relates to a copolymer having a specified carbosiloxane dendrimer structure and a long-chain alkyl group with 14 to 22 carbon atoms in a specified ratio, and a cosmetic comprising the copolymer as a cosmetic raw material. The cosmetic raw material has good miscibility with other cosmetic raw materials, and therefore, can improve stability of the formulation in a cosmetic, as well as can provide good water resistance, sebum resistance, glossiness, tactile sensation and/or adhesive properties to the hair and/or skin to a cosmetic, and also provide a cosmetic formed by blending the aforementioned cosmetic raw material, which exhibits superior surface protective properties, outer appearance and/or sensation during use.
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公开(公告)号：US09221952B2
公开(公告)日：2015-12-29
申请号：US13513080
申请日：2010-12-02
IPC分类号： C08G77/04 , A61K8/58 , A61Q19/00 , C07F7/08 , A61Q1/02 , A61Q1/04 , A61Q5/06 , A61Q15/00 , A61Q17/04
CPC分类号： C08G77/045 , A61K8/585 , A61Q1/02 , A61Q1/04 , A61Q5/06 , A61Q15/00 , A61Q17/04 , A61Q19/00 , C07F7/0838
摘要： The present invention relates to a novel organopolysiloxane having a specified structure and a cosmetic containing the aforementioned organopolysiloxane. The novel organopolysiloxane according to the present invention is volatile, possesses stability at low temperature, provides superior glossiness, and has a superior property with respect to miscibility with a UV-ray absorber, and which is useful as a replacement of octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, or methyltrimethicone. The cosmetic according to the present invention can provide superior feeling to the touch during use and a superior outer appearance. Furthermore, a degree of freedom in blending various components such as UV-ray absorbers into the cosmetic according to the present invention is increased.
摘要翻译： 本发明涉及具有特定结构的新型有机聚硅氧烷和含有上述有机聚硅氧烷的化妆品。 本发明的新型有机聚硅氧烷是挥发性的，在低温下具有稳定性，提供优异的光泽度，并且在与紫外线吸收剂的混溶性方面具有优异的性能，可用作替代八甲基环四硅氧烷，十甲基环五硅氧烷或 甲基三甲基硅油。 根据本发明的化妆品可以在使用期间提供优异的触感和优异的外观。 而且，本发明的化妆品中，将紫外线吸收剂等各种成分的混合自由度提高。
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7.发明授权Thickener or gellant for oil materials, gel composition comprising same, and method of producing cosmetic material or topical agent 有权用于油料的增稠剂或胶凝剂，包含其的凝胶组合物，以及生产化妆品材料或外用剂的方法公开(公告)号：US08597619B2
公开(公告)日：2013-12-03
申请号：US13517055
申请日：2010-12-21
CPC分类号： C08G77/50 , A61K8/894 , A61K2800/10 , A61K2800/48 , A61Q1/02 , A61Q1/06 , A61Q1/10 , A61Q1/12 , A61Q5/06 , A61Q5/12 , A61Q19/00 , C08G77/14
摘要： This inventive thickener or gellant for oil materials is characterized by comprising (A) an high molecular weight organopolysiloxane that has a polyglycerol structure-containing hydrophilic group Q and that is represented by the following structural formula (1): R3-q(R11)qSi—O—(SiR112—O)n1—(SiR11Q-O)n2—(SiR11L-O)n3—Si(R)11)qR3-q wherein R11 is a monovalent hydrocarbyl group or a hydrogen atom; L is a chain organosiloxane group, n1, n2, and n3 are numbers in the ranges 200≦n1≦1000, 0≦n2≦20, and 0≦n3≦50; R is a group selected from L and Q; q is an integer in the range from 0 to 3; wherein when n2=0, q is an integer in the range from 1 to 3 and at least one R is Q. The thickener or gellant exhibits an excellent compatibility with a variety of oil systems.
摘要翻译： 本发明的油性物质增稠剂或胶凝剂的特征在于：（A）具有含聚甘油结构的亲水基团Q并由以下结构式（1）表示的高分子量有机聚硅氧烷：R3-q（R11）qSi -O-（SiR112-O）n1-（SiR11Q-O）n2-（SiR11L-O）n3-Si（R）11）qR3-q其中R11是一价烃基或氢原子; L是链有机硅氧烷基团，n1，n2和n3是范围200 @ n1 @ 1000,0 @ n2 @ 20和0 @ n3 @ 50中的数字; R是选自L和Q的基团; q是0〜3的整数; 其中当n 2 = 0时，q为1至3的整数，并且至少一个R为Q。增稠剂或胶凝剂与各种油系统表现出优异的相容性。
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公开(公告)号：US20100222474A1
公开(公告)日：2010-09-02
申请号：US12159410
申请日：2006-12-21
申请人： Masakazu Irie , Haruhiko Furukawa
发明人： Masakazu Irie , Haruhiko Furukawa
IPC分类号： C08K5/3472 , C08L83/04 , C08K5/24 , C08K5/092
CPC分类号： C08L23/02 , C08K5/25 , C08L23/06 , C08L23/16 , C08L79/06 , C08L83/04 , C08L2207/062 , C08L2207/066 , C08L83/00
摘要： A thermoplastic resin composition comprising (A) a polyolefin-type thermoplastic elastomer or a similar thermoplastic resin, (B) an organopolysiloxane represented by the following average unit formula: R1aSiO(4-a)/2 {where R1 is a univalent hydrocarbon group having 1 to 10 carbon atoms, and “a” is a number in the range of 1.95 to 2.05}, and (C) a metal deactivator; and a product molded from the aforementioned composition. The thermoplastic resin composition is suitable for obtaining molded products that are characterized by their ability to suppress development of defects on the product surfaces after long-term outdoor exposure.
摘要翻译： 一种热塑性树脂组合物，其包含（A）聚烯烃类热塑性弹性体或类似的热塑性树脂，（B）由以下平均单元式表示的有机聚硅氧烷：R1aSiO（4-a）/ 2 {其中R1是具有 1〜10个碳原子，“a”为1.95〜2.05的数值}，（C）金属钝化剂。 和由上述组合物模塑的产品。 热塑性树脂组合物适用于获得模制产品，其特征在于它们能够在长期室外暴露后抑制产品表面上的缺陷发展。
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9.发明申请Thermoplastic Elastomer Composition And Glass Panel Molding Assembly For A Vehicle 有权热塑性弹性体组合物和用于车辆的玻璃面板成型组件公开(公告)号：US20090269590A1
公开(公告)日：2009-10-29
申请号：US11910558
申请日：2006-04-07
申请人： Haruhiko Furukawa , Masakazu Irie
发明人： Haruhiko Furukawa , Masakazu Irie
CPC分类号： C08L51/06 , C08K3/22 , C08K5/20 , C08L23/10 , C08L53/02 , C08L71/12 , C08L83/04 , C08L91/00 , C08L2205/035 , C08L2666/24 , C08L2666/02
摘要： The present invention relates to a thermoplastic elastomer composition and a glass panel molding assembly for a vehicle. The thermoplastic elastomer composition comprising a polymer component (1) that comprises a styrene-type thermoplastic elastomer and a polyolefin-type polymer {except for the additives in item (5) below}, a non-aromatic-rubber softener (2), a higher fatty acid derivative (4), and at least one type of an additive (5) selected from (5-a) a vinyl polymer graft-olefin polymer, (5-b) a polyorganosiloxane cross-linked powder; and (5-c) a polyorganosiloxane graft-olefin polymer. And the glass panel molding assembly for a vehicle produced from the aforementioned composition.
摘要翻译： 本发明涉及一种热塑性弹性体组合物和用于车辆的玻璃面板模制组件。 包含苯乙烯类热塑性弹性体的聚合物组分（1）和聚烯烃类聚合物{除了下述（5）中的添加剂除外）的热塑性弹性体组合物，非芳香族橡胶软化剂（2）， 高分子量脂肪酸衍生物（4）和至少一种选自（5-a）乙烯基聚合物接枝烯烃聚合物，（5-b）聚有机硅氧烷交联粉末的添加剂（5） 和（5-c）聚有机硅氧烷接枝烯烃聚合物。 以及由上述组成制成的车辆玻璃面板成型组件。
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公开(公告)号：US06602949B2
公开(公告)日：2003-08-05
申请号：US10020715
申请日：2001-12-13
IPC分类号： C08F13008
CPC分类号： C09D143/04 , C08F230/08 , C08F246/00 , Y10T442/2164 , C08L2666/02
摘要： Stable vinyl copolymer emulsions are capable of forming strongly water repellent and highly water resistant films and coatings, and can be used as paint or coating additives. They are highly compatible with paint and coating compositions. The vinyl copolymer emulsions are produced by emulsion polymerizing (A) 50-99.9 weight percent of a vinyl monomer, (B) 0.1-50 weight percent of a branched organosilicon compound bearing a radically polymerizable organic group, where the sum of components (A) and (B) is 100 weight percent, and (C) a radically polymerizable surfactant used at 0.1-20 weight parts per 100 weight parts of the total amount of components (A) and (B).
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