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    Preparation of electrically conductive polymers
    5.
    发明授权
    Preparation of electrically conductive polymers 失效
    导电聚合物的制备

    公开(公告)号：US4412942A

    公开(公告)日：1983-11-01

    申请号：US373158

    申请日：1982-04-29

    申请人： Herbert Naarmann ,  Klaus Penzien ,  Johannes Schlag ,  Petr Simak

    发明人： Herbert Naarmann ,  Klaus Penzien ,  Johannes Schlag ,  Petr Simak

    IPC分类号： C08F8/00 ,  C08F8/30 ,  C08F8/42 ,  H01B1/12 ,  H01L51/30 ,  H01L51/42 ,  H01B1/06

    CPC分类号： H01B1/125 ,  C08F8/42 ,  H01L51/0041 ,  H01L51/42 ,  Y02E10/549

    摘要： A process for the preparation of stable electrically conductive polymers, having conductivities greater than 10.sup.-2 S/cm, wherein a polyacetylene is reacted with from 1 to 100, preferably from 10 to 33, % by weight of tosylmethyl isocyanide and from 0.1 to 70, preferably from 5 to 35, % by weight of an alkali metal or its amide, or of a Lewis acid. The polymers obtained can be used in electrical engineering for the production of solar cells, for the conversion and fixing of radiation and for the production of electrical and magnetic switches and electrical storage devices, and can also be used for the antistatic treatment of plastics.

    摘要翻译： 用于制备电导率大于10-2S / cm的稳定导电聚合物的方法，其中聚乙炔与1至100重量比，优选10至33重量％的甲苯磺酰甲基异氰化物和0.1至70重量％ ，优选5至35重量％的碱金属或其酰胺或路易斯酸。 获得的聚合物可用于生产太阳能电池的电气工程，用于辐射的转换和固定以及用于生产电磁开关和电存储装置，并且也可用于塑料的抗静电处理。

    Preparation of electrically conductive polyarylene compounds having electron-attracting side groups
    7.
    发明授权
    Preparation of electrically conductive polyarylene compounds having electron-attracting side groups 失效
    具有吸电子基团的导电聚亚芳基化合物的制备

    公开(公告)号：US4488986A

    公开(公告)日：1984-12-18

    申请号：US519507

    申请日：1983-08-02

    申请人： Herbert Naarmann ,  Petr Simak ,  Gernot Kohler

    发明人： Herbert Naarmann ,  Petr Simak ,  Gernot Kohler

    IPC分类号： C08L65/00 ,  C07C57/42 ,  C08F8/30 ,  C08F8/42 ,  C08F38/00 ,  C08G16/00 ,  C08G61/00 ,  C08L101/00 ,  H01B1/12 ,  H01M4/60 ,  H01B1/06

    CPC分类号： C07C255/00 ,  C07C57/42 ,  C08L101/00 ,  H01B1/128 ,  H01M4/60 ,  C08L2201/04

    摘要： Electrically conductive polymeric systems having electrical conductivities greater than 10.sup.-4 S/cm are prepared by a method wherein a polyarylene compound which contains one or more chain members of the formula ##STR1## where n is greater than 1, preferably from 5 to 50, R is a nitrile, acid amide, carboxyl or ester group, R.sup.1 and R.sup.2 are each hydrogen or a nitrile, acid amide, carboxyl or ester group, with the proviso that in each case one of the radicals R.sup.1 and R.sup.2 is hydrogen and the other is a nitrile, acid amide, carboxyl or ester group, and Y is an aromatic radical, preferably phenylene, is doped, in the absence of moisture and oxygen, with from 0.03 to 0.9 mole percent of an electron-attracting or electron-donating complexing agent. The resulting electrically conductive polymeric systems are useful in the electrical industry for the production of solar cells, for converting and fixing electromagnetic radiation and for the production of electrical and magnetic switches and electrical storage devices, and can be used for the antistatic treatment of plastics.

    摘要翻译： 电导率大于10 -4 S / cm的导电聚合体系通过一种方法制备，其中含有一个或多个下式的链成员的聚亚芳基化合物，其中n大于1，优选为5至50， R是腈，酰胺，羧基或酯基，R 1和R 2各自为氢或腈，酰胺，羧基或酯基，条件是在每种情况下，基团R 1和R 2中的一个为氢，另一个为氢 是腈，酰胺，羧基或酯基，并且Y是芳族基团，优选亚苯基，在没有水分和氧的情况下掺杂有0.03-0.9摩尔％的吸电子或给电子络合物 代理商 所得到的导电聚合物体系可用于电气工业中用于生产太阳能电池，用于转换和固定电磁辐射以及生产电磁开关和电存储装置，并可用于塑料的抗静电处理。