Triazolylalkenes as fungicides and plant growth regulants
    1.
    发明授权
    Triazolylalkenes as fungicides and plant growth regulants 失效
    三唑基烯烃作为杀真菌剂和植物生长调节剂

    公开(公告)号:US4497647A

    公开(公告)日:1985-02-05

    申请号:US466825

    申请日:1983-02-16

    摘要: The invention relates to novel azolyl-olefin derivatives of the general formula I ##STR1## wherein R.sub.1 is an azolyl group,R.sub.2 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by unsubstituted or substituted phenyl, C.sub.1 -C.sub.4 alkoxycarbonyl or C.sub.2 -C.sub.6 alkenyl, or is C.sub.3 -C.sub.8 cycloalkyl which is substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl groups,R.sub.3 is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl which is substituted by 1 to 4 C.sub.1 -C.sub.4 alkyl groups, or is the --C(R.sub.4)(R.sub.5)--[CH(R.sub.4)].sub.n --X--R.sub.6 group, wherein n is 0 or 1 andR.sub.4 and R.sub.5, each independently of the other, are hydrogen or C.sub.1 -C.sub.4 alkyl,X is oxygen or sulfur,R.sub.6 is a radical selected from the group consisting of C.sub.1 -C.sub.8 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl, phenyl, naphthyl, biphenyl, benzylphenyl, benzoxyphenyl, phenoxyphenyl and aralkyl, which radical is substituted by one or more of halogen, cyano, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.5 alkoxy, C.sub.1 -C.sub.5 haloalkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 haloalkylthio, nitro, --COOR.sub.7 or --CON(R.sub.8)(R.sub.9), whereinR.sub.7 is C.sub.1 -C.sub.4 alkyl andR.sub.8 and R.sub.9, each independently of the other, are hydrogen or C.sub.1 -C.sub.4 alkyl, and the acid addition salts quaternary azolium salts and metal complexes thereof.The invention also describes methods of preparing these compounds as well as agrochemical compositions which contain one of said compounds as active ingredient. The invention further describes a method of controlling phytopathogenic microorganisms and/or of regulating plant growth which comprises the use of the novel compounds.

    摘要翻译: 本发明涉及通式Ⅰ(I)的新的唑基 - 烯烃衍生物,其中R1是唑基,R2是C1-C12烷基,C3-C8环烷基,被未取代或取代的苯基取代的C1-C4烷基,C1-C4烷氧基羰基 或C 2 -C 6烯基,或者是被1至4个C 1 -C 4烷基取代的C 3 -C 8环烷基,R 3是C 1 -C 12烷基,被1至4个C 1 -C 4烷基取代的C 3 -C 8环烷基,或者是-C )(R5) - [CH(R4)] nX-R6基团,其中n为0或1,R4和R5各自独立地为氢或C1-C4烷基,X为氧或硫,R6为自由基 选自C 1 -C 8烷基,C 3 -C 8环烷基,C 3 -C 6烯基,C 3 -C 6炔基,苯基,萘基,联苯基,苄基苯基,苯氧基苯基,苯氧基苯基和芳烷基,该基团被一个或多个卤素,氰基, C 1 -C 4烷基,C 1 -C 5烷氧基,C 1 -C 5卤代烷氧基,C 1 -C 3烷硫基,C 1 -C 3卤代烷基,C 1 -C 3卤代烷硫基,硝基,-COOR 7或-CON(R 8)(R 9) 9,各自独立地是氢或C 1 -C 4烷基,和酸加成盐季氮鎓盐及其金属络合物。 本发明还描述了制备这些化合物的方法以及含有所述化合物之一作为活性成分的农药组合物。 本发明还描述了一种控制植物病原微生物和/或调节植物生长的方法,其包括使用新化合物。

    Herbicidal epoxides
    2.
    发明授权
    Herbicidal epoxides 失效
    除草环氧化物

    公开(公告)号:US4849007A

    公开(公告)日:1989-07-18

    申请号:US934298

    申请日:1986-11-24

    IPC分类号: A01N43/20 C07D303/32

    CPC分类号: A01N43/20 C07D303/32

    摘要: The invention relates to a herbicidal and plant growth regulating composition which contains as active ingredient a 2-benzoyl-2-phenyloxirane of formula I; ##STR1## wherein each of m and n independently of the other is 0, 1, 2 or 3 and each of R and R' independently of the other is a halogen atom, a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy group or the nitro or cyano group or a phenoxy group which is substituted by (R).sub.m, in the form of a racemate or an optically active enantiomer.Some oxiranes are known as intermediates for the preparation of fungicides and others are novel. The herbicidal composition has selective action in rice crops and is active against grasses.

    摘要翻译: 本发明涉及含有式I的2-苯甲酰基-2-苯基环氧乙烷作为活性成分的除草和植物生长调节组合物; (I)其中m和n彼此独立地为0,1,2或3,R和R'各自独立地为卤原子,C 1 -C 4烷基,C 1 -C 4烷氧基,C 1 -C 4卤代烷基或C 1 -C 4卤代烷氧基或硝基或氰基或被(R)m取代的外消旋体或光学活性对映异构体形式的苯氧基。 一些环氧乙烷被称为制备杀真菌剂的中间体,而另一些则是新的。 除草组合物在水稻作物中具有选择性作用,并且对草有活性。

    Herbicidal epoxides
    3.
    发明授权
    Herbicidal epoxides 失效
    除草环氧化物

    公开(公告)号:US4894083A

    公开(公告)日:1990-01-16

    申请号:US161812

    申请日:1988-02-29

    IPC分类号: A01N43/20 C07D303/32

    CPC分类号: A01N43/20 C07D303/32

    摘要: The invention relates to a herbicidal and plant growth regulating composition which contains as active ingredient a 2-benzoyl-2-phenyloxirane of formula I ##STR1## wherein each of m and n independently of the other is 0, 1, 2 or 3 and each of R and R' independently of the other is a halogen atom, a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl or C.sub.1 -C.sub.4 haloalkoxy group or the nitro or cyano group or a phenoxy group which is substituted by (R).sub.m, in the form of a racemate or an optically active enantiomer.Some oxiranes are known as intermediates for the preparation of fungicides and others are novel. The herbicidal composition has selective action in rice crops and is active against grasses.

    2-analino pyrimidine compounds
    4.
    发明授权
    2-analino pyrimidine compounds 失效
    2-分析嘧啶化合物

    公开(公告)号:US5159078A

    公开(公告)日:1992-10-27

    申请号:US569319

    申请日:1990-08-17

    摘要: The present invention relates to novel N-phenyl-N-pyrimidin-2-ylureas having a herbicidal and plant growth-regulating activity, to agrochemical compositions containing those substances as active ingredients, to the use of the novel ureas for controlling weeds or for regulating plant growth, and to processes for the preparation of the novel compounds. The invention also relates to novel intermediates and to processes for the preparation thereof.The novel compounds correspond to formula I ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are each, independently of the others, hydrogen; halogen; C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 alkoxy; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.4 haloalkoxy; C.sub.1 -C.sub.4 alkyl-S(O).sub.n -; nitro; cyano; C.sub.1 -C.sub.4 alkoxycarbonyl; C.sub.1 -C.sub.4 alkylcarbonyl; di-(C.sub.1 -C.sub.4 alkylamino)-carbonyl; mono-(C.sub.1 -C.sub.4 alkylamino)carbonyl; carbamoyl; C.sub.1 -C.sub.4 -haloalkyl-S(O).sub.n -; or -PO[O-(C.sub.1 -C.sub.4)-alkyl].sub.2 ;R.sup.4 is C.sub.1 -C.sub.6 alkyl; C.sub.1 -C.sub.4 alkoxy; C.sub.1 -C.sub.4 alkyl-S(O).sub.n -; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.4 haloalkoxy; phenyl that is unsubstituted or is substituted by up to three identical or different substituents from halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl and C.sub.1 -C.sub.4 alkoxy; 2-furanyl; 2-thienyl; 3-thienyl; C.sub.3 -C.sub.6 -cycloalkyl that is unsubstituted or is substituted by up to three identical or different C.sub.1 -C.sub.4 alkyl radicals; cyano; C.sub.2 -C.sub.4 haloalkenyl; C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.4 alkoxy; or halogen-C.sub.1 -C.sub.4 alkylthio;R.sup.5 is hydrogen; C.sub.1 -C.sub.3 alkyl; C.sub.1 -C.sub.3 haloalkyl; halogen; or C.sub.1 -C.sub.3 haloalkoxy; andn is 0, 1 or 2,with the proviso that when one of the radicals R.sup.1, R.sup.2 and R.sup.3 is nitro, that substituent may not be bonded in the 2- or 6-position of the phenyl ring.

    摘要翻译: 本发明涉及具有除草和植物生长调节活性的新型N-苯基-N-嘧啶-2-基脲,含有这些物质作为活性成分的农用化学组合物,用于控制杂草或用于调节 植物生长,以及制备新化合物的方法。 本发明还涉及新型中间体及其制备方法。 该化合物对应于式Ⅰ(I)其中R1,R2和R3各自独立地为氢; 卤素; C 1 -C 4烷基; C1-C4烷氧基; C 1 -C 4卤代烷基; C1-C4卤代烷氧基; C 1 -C 4烷基-S(O)n - ; 硝基 氰基; C1-C4烷氧基羰基; C1-C4烷基羰基; 二(C 1 -C 4烷基氨基) - 羰基; 单(C 1 -C 4烷基氨基)羰基; 氨基甲酰基; C 1 -C 4卤代烷基-S(O)n - ; 或-PO [O-(C 1 -C 4) - 烷基] 2; R4是C1-C6烷基; C1-C4烷氧基; C 1 -C 4烷基-S(O)n - ; C 1 -C 4卤代烷基; C1-C4卤代烷氧基; 未被取代或被卤素,C1-C4烷基,C1-C4卤代烷基和C1-C4烷氧基中最多三个相同或不同的取代基取代的苯基; 2-呋喃基; 2-噻吩基; 3-噻吩基; 未被取代或被至多三个相同或不同的C 1 -C 4烷基取代的C 3 -C 6环烷基; 氰基; C 2 -C 4卤代烯基; C 1 -C 4烷氧基-C 1 -C 4烷基; C1-C4烷氧基-C1-C4烷氧基; 或卤素-C 1 -C 4烷硫基; R5是氢; C1-C3烷基; C 1 -C 3卤代烷基; 卤素; 或C 1 -C 3卤代烷氧基; 并且n为0,1或2,条件是当基团R 1,R 2和R 3中的一个为硝基时,该取代基不能键合在苯环的2-或6-位。

    N-(2-nitrophenyl)-N-pyrimidin-2-ylureas
    5.
    发明授权
    N-(2-nitrophenyl)-N-pyrimidin-2-ylureas 失效
    N-(2-硝基苯基)-N-嘧啶-2-基脲

    公开(公告)号:US4999046A

    公开(公告)日:1991-03-12

    申请号:US333377

    申请日:1989-04-05

    申请人: Hermann Rempfler

    发明人: Hermann Rempfler

    IPC分类号: A01N47/36 C07D239/42

    CPC分类号: C07D239/42

    摘要: The present invention relates to novel N-(2-nitrophenyl)-N-pyrimidin-2-ylureas having a herbicidal and plant growth-regulating activity, to agrochemical compositions containing those substances as active ingredients, to the use of the novel ureas for controlling weeds or for regulating plant growth, and to processes for the preparation of the novel compounds. The invention also relates to novel intermediates and to processes for the preparation thereof.The novel compounds correspond to formula I ##STR1## in which R.sup.1 is hydrogen, methyl, fluorine, chlorine or bromine,R.sup.2 is C.sub.1 -C.sub.2 haloalkyl having at least 2 fluorine atoms, andR.sup.3 is C.sub.1 -C.sub.4 alkyl,with the proviso that R.sup.2 is not trifluoromethyl when R.sup.3 is methyl.

    摘要翻译: 本发明涉及具有除草和植物生长调节活性的新型N-(2-硝基苯基)-N-嘧啶-2-基脲,含有这些物质作为活性成分的农用化学组合物,用于新颖的脲用于控制 杂草或调节植物生长,以及制备新化合物的方法。 本发明还涉及新型中间体及其制备方法。 所述新化合物对应于其中R 1为氢,甲基,氟,氯或溴的式I(I),R 2为具有至少2个氟原子的C 1 -C 2卤代烷基,且R 3为C 1 -C 4烷基,条件是 当R 3为甲基时,R 2不是三氟甲基。

    Pyrimidine-2-phenylamino derivatives
    6.
    发明授权
    Pyrimidine-2-phenylamino derivatives 失效
    嘧啶-2-苯基氨基衍生物

    公开(公告)号:US4904778A

    公开(公告)日:1990-02-27

    申请号:US262122

    申请日:1988-10-24

    摘要: The invention relates to ureas having a herbicidal and plant growth-regulating action of the formula ##STR1## in which R.sup.1 and R.sup.2 each represent, independently of the other, hydrogen, halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxy-(C.sub.1 -C.sub.4)-alkyl, nitro or cyano, andR.sup.3 and R.sup.4 each represents, independently of the other, hydrogen, halogen, cyano, OH, SH, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, amino, mono-C.sub.1 -C.sub.4 -alkylamino, di-C.sub.1 -C.sub.4 -alkylamino, C.sub.1 -C.sub.4 -alkoxycarbonyl or C.sub.1 -C.sub.4 -alkoxy-(C.sub.1 -C.sub.4)-alkyl,processes and intermediates for the preparation thereof, and herbicidal and plant growth-regulating compositions containing a compound of the formula I.

    Microbicidal and growth-regulating compositions
    7.
    发明授权
    Microbicidal and growth-regulating compositions 失效
    杀菌和生长调节组合物

    公开(公告)号:US4758670A

    公开(公告)日:1988-07-19

    申请号:US567998

    申请日:1984-01-04

    摘要: Fluoroazolylpropane derivatives of the formula I ##STR1## are described, in which Az is imidazolyl or triazolyl, R.sup.1 is hydrogen, alkyl or aralkyl which is unsubstituted or substituted by halogen, alkyl, alkoxy, halogenoalkyl, nitro, cyano, carboxyl or alkoxycarbonyl, R.sup.2 is C.sub.1 -C.sub.10 -alkyl which is unsubstituted or substituted by alkoxy, aralkoxy or phenyl, it being possible for the aromatic nuclei of aralkoxy and phenyl in turn to be unsubstituted or substituted by halogen, alkyl, alkoxy, halogenoalkyl, cyano, carboxyl or alkoxycarbonyl, R.sup.3 is hydrogen, alkyl, alkylcarbonyl or aralkyl which is unsubstituted or substituted by halogen, alkoxy, alkyl, halogenoalkyl, cyano, carboxyl or alkoxycarbonyl, R.sup.5 is an unsubstituted or monosubstituted or polysubstituted radical selected from the series comprising C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, phenyl, naphthyl, biphenyl, benzylphenyl, benzyloxyphenyl, phenoxyphenyl and aralkyl, and X is oxygen or sulfur; including the acid addition salts, quaternary azolium salts and metal complexes.Methods of preparing these products are also disclosed, as are agrochemical compositions containing one of these compounds as the active substance. A process for controlling phytopathogenic microorganisms and/or for regulating plant growth by means of these substances is also described.

    摘要翻译: 描述了式I的氟唑基丙烷衍生物,其中Az是咪唑基或三唑基,R1是氢,未被取代或被卤素,烷基,烷氧基,卤代烷基,硝基,氰基,羧基或烷氧基羰基取代的烷基或芳烷基,R2 是未被取代或被烷氧基,芳烷氧基或苯基取代的C 1 -C 10 - 烷基,芳烷氧基和苯基的芳族核可能是未被取代的或被卤素,烷基,烷氧基,卤代烷基,氰基,羧基或烷氧基羰基 R 3是未取代的或被卤素,烷氧基,烷基,卤代烷基,氰基,羧基或烷氧基羰基取代的烷基,烷基,烷基羰基或芳烷基,R 5是未取代的或单取代的或多取代的基团,其选自包括C 1 -C 8烷基, C 3 -C 8 - 环烷基,C 3 -C 6 - 烯基,C 3 -C 6炔基,苯基,萘基,联苯基,苄基苯基,苄氧基苯基,苯氧基苯基和芳烷基,X是氧或硫; 包括酸加成盐,季铵盐和金属络合物。 还公开了制备这些产物的方法,以及含有这些化合物之一作为活性物质的农药组合物。 还描述了通过这些物质控制植物病原微生物和/或调节植物生长的方法。

    Certain 5-(pyridyl-2'-oxy)-2-nitrobenzoic acid ester derivatives
herbicidal compositions containing same and their herbicidal use
    8.
    发明授权
    Certain 5-(pyridyl-2'-oxy)-2-nitrobenzoic acid ester derivatives herbicidal compositions containing same and their herbicidal use 失效
    某些5-(吡啶基-2'-氧)-2-硝基苯甲酸酯衍生物除草组合物及其除草用途

    公开(公告)号:US4626275A

    公开(公告)日:1986-12-02

    申请号:US530802

    申请日:1983-09-09

    申请人: Hermann Rempfler

    发明人: Hermann Rempfler

    CPC分类号: C07D213/643 A01N43/40

    摘要: The invention relates to 5-(pyridyl-2'-oxy)-2-nitrobenzoic acid derivatives of the formula ##STR1## wherein A is the cyano group, the carboxyl group or a salt, an ester, a thioester or an amide thereof, X is halogen or a halomethyl group, Y is hydrogen, halogen or a halomethyl group. These compounds have herbicidal properties and are suitable for selectively controlling weeds in crops of useful plants, especially in soybeans, cereals and rice crops.

    摘要翻译: 本发明涉及下式的5-(吡啶基-2'-氧)-2-硝基苯甲酸衍生物,其中A是氰基,羧基或其盐,酯,硫酯或酰胺, X是卤素或卤代甲基,Y是氢,卤素或卤代甲基。 这些化合物具有除草性质,适用于有选择地控制有用植物作物中的杂草,特别是在大豆,谷类和水稻作物中。