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公开(公告)号：US3971723A
公开(公告)日：1976-07-27
申请号：US505292
申请日：1974-09-12
IPC分类号： C03C3/064 , C03C3/068 , C03C3/091 , C03C4/00 , G02F1/00 , H01F1/00 , C03C3/04 , C03C3/08 , C03C3/30
CPC分类号： G02F1/0036 , C03C3/064 , C03C3/068 , C03C3/091 , C03C4/00
摘要： Glass for use as an element of a Faraday rotator, consisting essentially of, by mol%, 10-30 Tb.sub.2 O.sub.3, 10-30 Al.sub.2 O.sub.3, and 30-80 SiO.sub.2 + B.sub.2 O.sub.3, with the proviso that SiO.sub.2 .gtoreq.15 and B.sub.2 O.sub.3 .gtoreq.10, and as optional components 0-5 ZrO.sub.2, 0-1 Sb.sub.2 O.sub.3, 0-1 As.sub.2 O.sub.3, and 0-2 AlF.sub.3. The glass has a large Verdet constant and a reduced absorption of light in the visible and infrared wavelength regions.
摘要翻译： 用作法拉第旋转器的元件的玻璃，其摩尔％基本上由10-30 Tb 2 O 3，10-30 Al 2 O 3和30-80 SiO 2 + B 2 O 3组成，条件是SiO 2≥15和B 2 O 3> / = 10，作为任选的组分0-5 ZrO 2，0-1 Sb 2 O 3，0-1 As 2 O 3和0-2 AlF 3。 玻璃具有较大的Verdet常数，并减少了可见光和红外波长区域的光吸收。
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2.发明授权Process for producing transparent glass product having refractive index gradient 失效具有折射率梯度的透明玻璃制品的制造方法
公开(公告)号：US4767435A
公开(公告)日：1988-08-30
申请号：US937468
申请日：1986-12-02
申请人： Shigeaki Omi , Yoshiyuki Asahara , Seiichi Shingaki , Shin Nakayama , Kenji Nakagawa , Tetsuro Izumitani , Hiroyuki Sakai
发明人： Shigeaki Omi , Yoshiyuki Asahara , Seiichi Shingaki , Shin Nakayama , Kenji Nakagawa , Tetsuro Izumitani , Hiroyuki Sakai
IPC分类号： C03B8/00 , C03B20/00 , C03B37/014 , C03C3/06 , C03C21/00 , C03C23/00 , G02B6/00 , C03C15/00 , C03C17/00 , C03C25/00
CPC分类号： C03C23/0095 , Y10S65/90
摘要： A process for producing a transparent glass product having a refractive index gradient by the molecular stuffing method is described. A thallium compound is used as a dopant and, after a concentration gradient of the thallium dopant is formed, the porous glass product is heated up to the temperature region of 350.degree. to 550.degree. C. at a temperature-rising rate of 25.degree. to 150.degree. C./hour in a reducing gas atmosphere and then heat treated above 550.degree. C. in an inert gas atmosphere to collapse micropores in the porous glass product, thereby obtaining a glass product having a refractive index gradient which is transparent and free of light-scattering and coloration. The glass product is suitable as materials (preforms) for optical fibers or materials for rod-shaped lenses, particularly rod-shaped microlenses for microlens arrays and microlenses for coupling an optical fiber and a light source.
摘要翻译： 描述了通过分子填充方法制造具有折射率梯度的透明玻璃制品的方法。 使用铊化合物作为掺杂剂，并且在形成铊掺杂剂的浓度梯度之后，将多孔玻璃产物以25℃至25℃的升温速率加热到350℃至550℃的温度区域 150℃/小时，然后在惰性气体气氛中在550℃以上进行热处理，使多孔玻璃制品中的微孔塌陷，得到折射率梯度为透明且无 光散射和着色。 玻璃制品适用于用于光纤的材料（预型件）或用于棒状透镜的材料，特别是用于微透镜阵列的棒状微透镜和用于耦合光纤和光源的微透镜。
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公开(公告)号：US3966447A
公开(公告)日：1976-06-29
申请号：US499097
申请日：1974-08-20
CPC分类号： C03C8/24 , C03C27/00 , C03C4/082 , Y10S501/904 , Y10S65/04
摘要： A sealing method for a laser glass which provides a high bonding strength comprising applying a powder mixture of (1) a low melting glass containing an infrared absorbing component and (2) a low expansion high melting glass containing an infrared absorbing component to a laser glass and welding the powder mixture to the laser glass by heating.
摘要翻译： 一种提供高粘合强度的激光玻璃的密封方法，包括将（1）含有红外吸收组分的低熔点玻璃和（2）含有红外线吸收组分的低膨胀高熔点玻璃的粉末混合物施加到激光玻璃上 并通过加热将粉末混合物焊接到激光玻璃。
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公开(公告)号：US4415464A
公开(公告)日：1983-11-15
申请号：US357447
申请日：1982-03-12
摘要： A Faraday rotation glass comprising, in mole %,______________________________________ P.sub.2 O.sub.5 5 to 30% where up to 5/6 on a molar basis of the P.sub.2 O.sub.5 can be replaced by B.sub.2 O.sub.3 ; TbF.sub.3 11.4 to 45%; AlF.sub.3 0 to 25%; and RF at least 40% ______________________________________ where RF includes at least 3% BaF.sub.2, 0 to 64% MgF.sub.2, 0 to 32% NaF, 0 to 40% SrF.sub.2, 0 to 26% CaF.sub.2, 0 to 20% LiF and 0 to 20% KF.
摘要翻译： 一种法拉第旋转玻璃可以用B 2 O 3代替，摩尔％的P 2 O 5为5-30％，其中高达5/6摩尔的P 2 O 5。 -TbF3 11.4〜45％; -AlF 3 0〜25％; 和-RF至少40％ - 其中RF包括至少3％的BaF 2，0至64％的MgF 2，0至32％的NaF，0至40％的SrF 2，0至26％的CaF 2，0至20％的LiF和0至20 ％KF。
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公开(公告)号：US3966448A
公开(公告)日：1976-06-29
申请号：US499098
申请日：1974-08-20
CPC分类号： C03C17/02 , C03C27/00 , C03C8/24 , Y10S501/904 , Y10S65/04
摘要： A sealing method for a laser glass which provides a high bonding strength comprising applying a powder mixture of (1) a low melting glass for sealing a glass laser and (2) a glass having a higher melting point and lower expansion coefficient than those of the low melting glass, to a laser glass and welding the powder mixture to the laser glass by heating.
摘要翻译： 一种提供高粘合强度的激光玻璃的密封方法，包括施加（1）用于密封玻璃激光的低熔点玻璃的粉末混合物和（2）具有比所述玻璃激光器更高的熔点和更低的膨胀系数的玻璃 低熔点玻璃，激光玻璃，并通过加热将粉末混合物焊接到激光玻璃上。
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公开(公告)号：US4108621A
公开(公告)日：1978-08-22
申请号：US751300
申请日：1976-12-16
IPC分类号： C03C3/076 , C03C3/078 , C03C21/00 , G02B5/00 , G02B5/22 , G02B27/58 , H01S3/17 , C03C15/00 , C03B11/08 , C03C19/00
CPC分类号： C03C21/005 , G02B27/58 , G02B5/005 , Y10S359/90
摘要： A process for producing a soft aperture filter having high acid and heat resistance as well as a desired colored layer thickness comprising heat-treating a glass, having a base composition of 55 to 72 mole percent SiO.sub.2, 15 to 35 mole percent Na.sub.2 O, 0 to 5 percent di-valent oxides other than ZnO, 4 to 15 mole percent ZnO, and 0 to 5 mole percent Al.sub.2 O.sub.3 with Sb.sub.2 O.sub.3 and/or As.sub.2 O.sub.3 additionally present in an amount of 2 to 5 weight percent of the base composition, in a fused bath containing 14 to 60 mole percent of a silver salt, and optionally with NaNO.sub.3 and/or Na.sub.2 SO.sub.4.
摘要翻译： 一种生产具有高耐酸性和耐热性的软孔过滤器以及所需着色层厚度的方法，包括热处理玻璃，其基本组成为55至72摩尔％SiO 2，15至35摩尔％Na 2 O，0至 在氧化锌中的5％的二价氧化物，4至15摩尔％的ZnO和0至5摩尔％的Al 2 O 3与Sb 2 O 3和/或As 2 O 3以基础组合物的2至5重量％的量存在于熔融浴中 含有14至60摩尔％的银盐，以及任选地含有NaNO 3和/或Na 2 SO 4。
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公开(公告)号：US4042526A
公开(公告)日：1977-08-16
申请号：US566577
申请日：1975-04-08
CPC分类号： G11B7/243 , G03C1/705 , G11B2007/24304 , G11B2007/24308 , G11B2007/24314 , G11B2007/24316
摘要： A non-crystalline substance for use in an optical memory device which consists of an As-Se system non-crystalline material and the additional third component(s) Zn, Au, or Ag and/or Cu. The substance is characterized by its transmission ability in the visible region as well as in the I.R. region and its extreme reduction of transmittance upon irradiation with, e.g., a laser beam.
摘要翻译： 一种用于光学存储器件的非结晶物质，其由As-Se系非结晶材料和另外的第三成分Zn，Au或Ag和/或Cu组成。 该物质的特征在于其在可见区域和I.R.中的传播能力。 区域，并且当例如激光束照射时其透射率的极度降低。
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公开(公告)号：US4844724A
公开(公告)日：1989-07-04
申请号：US129287
申请日：1987-12-07
CPC分类号： C03C23/00 , C03B32/00 , C03C21/005 , G02B6/1345
摘要： The refractive index distribution in refractive index distribution lenses may be adjusted to better approach an ideal by heating the refractive index distribution lens. When the refractive index distribution lens was created by diffusion of refractive index changing ions into a body, further heating in an environment in which no additional ions can diffuse into the body causes further migration of ions within the body so that its refractive index distribution approaches an ideal.
摘要翻译： 可以通过加热折射率分布透镜来调节折射率分布透镜中的折射率分布以更好地接近理想。 当折射率分布透镜由折射率变化的离子扩散到体内而产生时，在没有其他离子可以扩散到体内的环境中的进一步加热导致体内离子的进一步迁移使其折射率分布接近 理想。
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公开(公告)号：US5125944A
公开(公告)日：1992-06-30
申请号：US766066
申请日：1991-09-27
CPC分类号： G02B6/1345 , C03C21/005
摘要： A buried wave guide device is produced by immersing a phosphate glass containing exchangeable ions in a molten salt. Ions are exchanged from the phosphate glass to give a wave guide whose refractive index increases sharply from a first surface to a maximum at a depth below the first surface then decreases gradually in the direction of the opposite surface.
摘要翻译： 通过将含有可交换离子的磷酸盐玻璃浸入熔融盐中来制造掩埋波导装置。 从磷酸盐玻璃交换离子，得到在第一面以下的折射率从第一面到最大的波导，然后在相对面的方向上逐渐减小。
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公开(公告)号：US4851024A
公开(公告)日：1989-07-25
申请号：US148570
申请日：1988-01-26
CPC分类号： C03C21/001
摘要： A uniform refractive index-type glass is prepared by ion exchange in which a glass containing ions of a first type is immersed in a molten salt containing ions of a second type, the ions in the molten salt having a higher refractive index than the ions in the glass. The glass is removed from the molten salt at a predetermined point and before the saturation point or equilibrium and the ion distribution becomes uniform throughout the glass. The concentration of first and second ions is not uniform from the center of the glass to its outer surface. The glass is next heated to make the concentrations of the first and second ions substantially uniform throughout the glass from the center to the outer surface. Optionally, this glass is then immersed in a molten salt containing a third type of ion having a lower refractive index than the second ion for exchange with part of the ions in the second type. A gradient refractive index-type glass in which the concentration of the second type of ions decreases parabolically from the center of the glass to the outer surface while the concentration of the third type of ions increases parabolically from the center of the glass to the outer surface.
摘要翻译： 通过离子交换制备均匀的折射率型玻璃，其中将含有第一类型的离子的玻璃浸入含有第二类离子的熔盐中，熔融盐中的离子的折射率高于 玻璃。 在预定点和饱和点或平衡之前从熔融盐中除去玻璃，并且整个玻璃中的离子分布变得均匀。 第一和第二离子的浓度从玻璃的中心到其外表面是不均匀的。 接着加热玻璃使得第一和第二离子的浓度在整个玻璃中从中心到外表面基本上均匀。 任选地，将该玻璃浸入含有比第二离子低的折射率的第三类离子的熔盐中，以与第二类型的部分离子交换。 梯度折射率型玻璃，其中第二类离子的浓度从玻璃的中心向抛物线减少到外表面，同时第三类离子的浓度从玻璃的中心向抛物面增加到外表面 。
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