Process for producing optical glass
    1.
    发明授权
    Process for producing optical glass 失效
    光学玻璃生产工艺

    公开(公告)号:US4851024A

    公开(公告)日:1989-07-25

    申请号:US148570

    申请日:1988-01-26

    CPC分类号: C03C21/001

    摘要: A uniform refractive index-type glass is prepared by ion exchange in which a glass containing ions of a first type is immersed in a molten salt containing ions of a second type, the ions in the molten salt having a higher refractive index than the ions in the glass. The glass is removed from the molten salt at a predetermined point and before the saturation point or equilibrium and the ion distribution becomes uniform throughout the glass. The concentration of first and second ions is not uniform from the center of the glass to its outer surface. The glass is next heated to make the concentrations of the first and second ions substantially uniform throughout the glass from the center to the outer surface. Optionally, this glass is then immersed in a molten salt containing a third type of ion having a lower refractive index than the second ion for exchange with part of the ions in the second type. A gradient refractive index-type glass in which the concentration of the second type of ions decreases parabolically from the center of the glass to the outer surface while the concentration of the third type of ions increases parabolically from the center of the glass to the outer surface.

    摘要翻译: 通过离子交换制备均匀的折射率型玻璃,其中将含有第一类型的离子的玻璃浸入含有第二类离子的熔盐中,熔融盐中的离子的折射率高于 玻璃。 在预定点和饱和点或平衡之前从熔融盐中除去玻璃,并且整个玻璃中的离子分布变得均匀。 第一和第二离子的浓度从玻璃的中心到其外表面是不均匀的。 接着加热玻璃使得第一和第二离子的浓度在整个玻璃中从中心到外表面基本上均匀。 任选地,将该玻璃浸入含有比第二离子低的折射率的第三类离子的熔盐中,以与第二类型的部分离子交换。 梯度折射率型玻璃,其中第二类离子的浓度从玻璃的中心向抛物线减少到外表面,同时第三类离子的浓度从玻璃的中心向抛物面增加到外表面 。

    Process for producing glass product having gradient of refractive index
    5.
    发明授权
    Process for producing glass product having gradient of refractive index 失效
    制备具有折射率梯度的玻璃制品的方法

    公开(公告)号:US4525189A

    公开(公告)日:1985-06-25

    申请号:US488809

    申请日:1983-04-26

    摘要: A process for producing a glass product having .DELTA.n, the difference between the central and peripheral portions of the glass, greater than 0.04. This process utilizes a porous glass body which is produced via a phase separation technique. A dopant selected from the group consisting of (1) TlNO.sub.3, (2) TlNO.sub.3 and an alkali metal compound and (3) TlNO.sub.3, Pb(NO.sub.3).sub.2 and an alkali metal compound is then permeated into the micropores of the porous glass product. A concentration gradient of the dopant is then formed by leaching out a portion of the dopant from the micropores. After the dopant is solidified in the micropores, the porous glass product is dried. A heat-treatment step then serves to collapse the micropores. A glass product having a gradient of refractive indices is thereby obtained.

    摘要翻译: 一种玻璃制品的制造方法,其具有DELTA n,玻璃的中心部分和周边部分之间的差异大于0.04。 该方法利用通过相分离技术生产的多孔玻璃体。 选自(1)TlNO3,(2)TlNO3和碱金属化合物和(3)TlNO3,Pb(NO3)2和碱金属化合物的掺杂剂然后渗透到多孔玻璃产品的微孔中。 然后通过从微孔中浸出一部分掺杂剂形成掺杂剂的浓度梯度。 在微孔中固化掺杂剂之后,干燥多孔玻璃制品。 然后热处理步骤用于折叠微孔。 由此获得具有折射率梯度的玻璃制品。

    Gradient refractive index type anamorphic planar microlens and method of
producing the same
    7.
    发明授权
    Gradient refractive index type anamorphic planar microlens and method of producing the same 失效
    梯度折射率型变形平面微透镜及其制造方法

    公开(公告)号:US4805997A

    公开(公告)日:1989-02-21

    申请号:US868696

    申请日:1986-05-30

    IPC分类号: G02B3/00 G02B6/42 G02B13/08

    摘要: The present invention provides a gradient refractive index type anamorphic planar microlens which can be utilized for collimating an elliptical beam radiated from a semiconductor laser, or the like, and a method of producing such a lens. To collimate light rays, in which astigmatism exists, it is necessary to use a lens in which the respective focal distances in the directions perpendicular to an optical axis are different from each other. It includes a semiellipsoidal refractive index distribution region formed in a transparent substrate so as to have a major axis and a minor axis on a surface of the transparent substrate.

    摘要翻译: 本发明提供了可用于校准从半导体激光器辐射的椭圆形光束等的梯度折射率型变形平面微透镜,以及制造这种透镜的方法。 为了准直存在散光的光线,需要使用其中在与光轴垂直的方向上的各个焦距彼此不同的透镜。 它包括半透明折射率分布区域,形成在透明基板中,以在透明基板的表面上具有长轴和短轴。

    Method of producing gradient-index lens
    8.
    发明授权
    Method of producing gradient-index lens 失效
    梯度折射率透镜的制作方法

    公开(公告)号:US4902330A

    公开(公告)日:1990-02-20

    申请号:US228780

    申请日:1988-08-04

    摘要: A method of producing a gradient-index lens includes a first step in which a glass body is immersed into a molten salt containing ions which are able to provide a refractive index higher than that of ions constituting the glass body, in order to perform ion diffusion into the glass body. Thereafter, in a second step the glass body obtained from the first step is immersed into a molten salt containing ions which provide a refractive index lower than that of the ions of the molten salt used in the first step. In this way there is formed a predetermined refractive index distribution in the glass body.

    摘要翻译: 制造梯度折射率透镜的方法包括:第一步骤,其中将玻璃体浸入含能够提供折射率高于构成玻璃体的离子的离子的熔盐中,以进行离子扩散 进入玻璃体。 此后,在第二步骤中,将从第一步骤获得的玻璃体浸入含有离子的熔盐中,所述离子的折射率低于第一步骤中使用的熔融盐的离子的折射率。 以这种方式,在玻璃体中形成预定的折射率分布。

    Process for producing transparent glass product having refractive index
gradient
    10.
    发明授权
    Process for producing transparent glass product having refractive index gradient 失效
    具有折射率梯度的透明玻璃制品的制造方法

    公开(公告)号:US4767435A

    公开(公告)日:1988-08-30

    申请号:US937468

    申请日:1986-12-02

    CPC分类号: C03C23/0095 Y10S65/90

    摘要: A process for producing a transparent glass product having a refractive index gradient by the molecular stuffing method is described. A thallium compound is used as a dopant and, after a concentration gradient of the thallium dopant is formed, the porous glass product is heated up to the temperature region of 350.degree. to 550.degree. C. at a temperature-rising rate of 25.degree. to 150.degree. C./hour in a reducing gas atmosphere and then heat treated above 550.degree. C. in an inert gas atmosphere to collapse micropores in the porous glass product, thereby obtaining a glass product having a refractive index gradient which is transparent and free of light-scattering and coloration. The glass product is suitable as materials (preforms) for optical fibers or materials for rod-shaped lenses, particularly rod-shaped microlenses for microlens arrays and microlenses for coupling an optical fiber and a light source.

    摘要翻译: 描述了通过分子填充方法制造具有折射率梯度的透明玻璃制品的方法。 使用铊化合物作为掺杂剂,并且在形成铊掺杂剂的浓度梯度之后,将多孔玻璃产物以25℃至25℃的升温速率加热到350℃至550℃的温度区域 150℃/小时,然后在惰性气体气氛中在550℃以上进行热处理,使多孔玻璃制品中的微孔塌陷,得到折射率梯度为透明且无 光散射和着色。 玻璃制品适用于用于光纤的材料(预型件)或用于棒状透镜的材料,特别是用于微透镜阵列的棒状微透镜和用于耦合光纤和光源的微透镜。