Abstract:
A negative-electrode active material for nonaqueous electrolyte secondary battery, comprising a silicon compound capable of inserting and extracting lithium ion, wherein the silicon compound contains silicon-hydrogen bonds and the silicon-hydrogen bonds are introduced into the compound by reduction of at least one compound selected from the group consisting of silicon oxide, silicon nitride and silicon carbide with hydrogen, and a negative electrode for nonaqueous electrolyte secondary battery having a layer containing the negative-electrode active material in the above arrangement formed on a current collector.
Abstract:
A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive and negative electrodes, and a non-aqueous electrolyte. The negative electrode includes composite particles and a binder. Each of the composite particles includes: a negative electrode active material including an element capable of being alloyed with lithium; carbon nanofibers that are grown from a surface of the negative electrode active material; and a catalyst element for promoting the growth of the carbon nanofibers. The binder comprises at least one polymer selected from the group consisting of polyimide, polyamide imide, polyamide, aramid, polyarylate, polyether ether ketone, polyether imide, polyether sulfone, polysulfone, polyphenylene sulfide, and polytetrafluoroethylene.
Abstract:
A composite particle for an electrode including an active material particle, carbon nanofibers bonded to the surface of the active material particle, and a catalyst element for promoting the growth of the carbon nanofibers, wherein the active material particle includes an electrochemically active phase. As the catalyst element, for example, Au, Ag, Pt, Ru, Ir, Cu, Fe, Co, Ni, Mo, Mn and the like are used. The composite particle for an electrode may be produced, for example, by means of a method which includes: a step of preparing an active material particle including a catalyst element for promoting the growth of carbon nanofibers at least in the surface layer of the active material particle; and a step of growing carbon nanofibers on the surface of the active material particle in an atmosphere including a raw material gas.
Abstract:
A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive and negative electrodes, and a non-aqueous electrolyte. The positive and negative electrodes are wound together with the separator. The negative electrode includes composite particles and a binder. Each of the composite particles includes: a negative electrode active material including an element capable of being alloyed with lithium; carbon nanofibers that are grown from a surface of the negative electrode active material; and a catalyst element for promoting the growth of the carbon nanofibers. The binder comprises a polymer having at least one selected from the group consisting of an acrylic acid unit, an acrylic acid salt unit, an acrylic acid ester unit, a mathacrylic acid unit, a methacrylic acid salt unit, and a mathacrylic acid ester unit.
Abstract:
Disclosed is a composite electrode active material for non-aqueous electrolyte secondary batteries or non-aqueous electrolyte electrochemical capacitors which contains a material A containing an element capable of forming an alloy with lithium, a material B containing carbon excluding carbon nanofiber, a catalyst element for promoting the growth of carbon nanofiber, and carbon nanofibers grown on at least one selected from the surface of the material A and the surface of the material B.
Abstract:
A negative-electrode active material for nonaqueous electrolyte secondary battery, comprising a silicon compound capable of inserting and extracting lithium ion, wherein the silicon compound contains silicon-hydrogen bonds and the silicon-hydrogen bonds are introduced into the compound by reduction of at least one compound selected from the group consisting of silicon oxide, silicon nitride and silicon carbide with hydrogen, and a negative electrode for nonaqueous electrolyte secondary battery having a layer containing the negative-electrode active material in the above arrangement formed on a current collector.
Abstract:
A negative electrode for non-aqueous electrolyte secondary batteries has a mixture layer including a composite negative electrode active material which is composed of active material cores capable of charging and discharging at least lithium ions; carbon nanofibers; and catalyst elements. The carbon nanofibers are attached to the surfaces of the active material cores. The catalyst elements are at least one selected from the group consisting of copper, iron, cobalt, nickel, molybdenum, and manganese, and promote the growth of the carbon nanofibers. The active material cores have the carbon nanofibers therebetween.
Abstract:
A positive electrode for a rechargeable lithium battery includes a positive active material and activated carbon, wherein an average particle diameter of the activated carbon is about 100% to about 160% relative to 100% of an average particle diameter of the positive active material.
Abstract:
A negative electrode for a rechargeable lithium battery and a rechargeable lithium battery including the same, the negative electrode including a negative active material; and a lithium ion adsorbent having a specific surface area of about 10 m2/g to about 100 m2/g.