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公开(公告)号：US09321884B2
公开(公告)日：2016-04-26
申请号：US13879279
申请日：2011-10-14
CPC分类号： C08G64/205 , B01J19/247 , B01J2219/32286 , B01J2219/32408 , C08G63/785 , C08G69/00
摘要： A method for producing a condensation polymerization reaction polymer, comprising a guide polymerization step in which a molten prepolymer is supplied to the top edge of a wire guide to obtain the condensation polymerization reaction polymer, the wire guide comprising a vertical wire group consisting of a plurality of vertical wires extending in the vertical direction, which are mutually spaced in alignment at an arrangement pitch L1 (mm). In the guide polymerization step, the molten prepolymer aggregates so that a molten prepolymer mass is formed on the vertical wire, and a molten prepolymer mass is formed wherein, the width of the molten prepolymer mass measured in an alignment direction of the vertical wires at a position 200 mm below the top edge being represented as L2 (mm), the width L2 of at least a portion of the molten prepolymer mass satisfies the inequality (1). L1
摘要翻译： 一种制备缩聚反应聚合物的方法，其包括引导聚合步骤，其中将熔融预聚物供给到导线引导件的顶部边缘以获得缩聚反应聚合物，所述导线器包括由多个组成的垂直导线组 垂直线在垂直方向上延伸，并以排列间距L1（mm）相互间隔开。 在引导聚合步骤中，熔融预聚物聚集，使得在垂直导线上形成熔融预聚物物质，形成熔融预聚物物质，其中熔融预聚物物质的宽度在垂直丝线的排列方向上测量为a 顶部边缘以下200mm的位置表示为L2（mm），熔融预聚物物质的至少一部分的宽度L2满足不等式（1）。 L1
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公开(公告)号：US20080260979A1
公开(公告)日：2008-10-23
申请号：US11791842
申请日：2005-11-29
CPC分类号： B29C31/04 , B29B2911/1402 , B29B2911/14026 , B29B2911/14033 , B29B2911/1404 , B29B2911/14106 , B29B2911/14133 , B29B2911/14213 , B29C45/18 , B29C49/0005 , B29C49/06 , B29C49/12 , B29C2045/1883 , B29K2067/00 , B29K2105/253 , C08G63/785 , C08G63/80 , Y10T428/1352 , Y10T428/2982
摘要： A polyethylene terephthalate resin which is obtained by melt polymerization at a reduced pressure or in an inert gas atmosphere and has the following properties (A) to (F): (A) the intrinsic viscosity [η] is 0.4-2.5 Dl/g; (B) the content of carboxy groups present at polymer ends is 30 meq/kg or lower; (C) the acetaldehyde content is 10 ppm or lower; (D) a hexafluoroisopropanol solution of the resin, when analyzed by the transmission method, has a hue which has an L value of 99 or larger and a b value of 0.4 or smaller; (E) the Mw/Mn is 1.8-2.3; and (F) the cyclic trimer content is 5 wt. % or lower.
摘要翻译： 通过在减压或惰性气体气氛中熔融聚合得到的具有以下特性（A）至（F））的聚对苯二甲酸乙二醇酯树脂：（A）特性粘度η为0.4-2.5Dl / g; （B）存在于聚合物末端的羧基含量为30meq / kg以下; （C）乙醛含量为10ppm以下; （D）当通过透射法分析时，树脂的六氟异丙醇溶液具有L值为99以上且b值为0.4以下的色调。 （E）Mw / Mn为1.8-2.3; 和（F）环状三聚体含量为5wt。 ％以下。
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公开(公告)号：US06320015B1
公开(公告)日：2001-11-20
申请号：US09674435
申请日：2000-11-01
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Disclosed is a method for producing an aromatic polycarbonate, which comprises treating a molten aromatic polycarbonate prepolymer (obtained by reacting an aromatic dihydroxy compound with a diaryl carbonate) with an inert gas under a predetermined pressure to thereby cause the molten prepolymer to absorb the inert gas, and subjecting the resultant molten prepolymer having the inert gas absorbed therein to polymerization, under a pressure lower than the above-mentioned predetermined pressure employed for the inert gas absorption, to thereby polymerize the prepolymer to a predetermined degree of polymerization. By the method of the present invention, a high quality aromatic polycarbonate which is colorless and has excellent mechanical properties can be produced at high polymerization rate even without using a large amount of an inert gas. Further, even if the production of an aromatic polycarbonate is conducted in a continuous manner, the molecular weight of the produced aromatic polycarbonate can be maintained at a desired level, so that the high quality polycarbonate can be stably produced for a prolonged period of time. Therefore, the method of the present invention is commercially very advantageous.
摘要翻译： 公开了一种芳族聚碳酸酯的制造方法，其包括将熔融芳族聚碳酸酯预聚物（通过芳香族二羟基化合物与碳酸二芳基酯反应得到）与惰性气体在规定压力下进行处理，使熔融预聚物吸收惰性气体 并且在低于上述用于惰性气体吸收的预定压力的压力下，将其中吸收有惰性气体的所得熔融预聚物进行聚合，从而将预聚物聚合至预定聚合度。 通过本发明的方法，即使不使用大量的惰性气体，也可以高聚合速度生产无色且机械性能优异的高品质芳族聚碳酸酯。 此外，即使以连续的方式进行芳族聚碳酸酯的制造，也可以将所制造的芳香族聚碳酸酯的分子量保持在期望的水平，从而能够长时间稳定地制造高品质的聚碳酸酯。 因此，本发明的方法在商业上非常有利。
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公开(公告)号：US4399272A
公开(公告)日：1983-08-16
申请号：US204085
申请日：1980-11-04
摘要： A process for producing a polyacetal copolymer, which comprises copolymerizing formaldehyde and a compound selected from the group consisting of alkylene oxides, poly(alkylene oxides), cyclic formals and poly (cyclic formals) in the presence of a Lewis acid and an anionic polymerization catalyst with the exception of metal chelate compounds.
摘要翻译： 一种制备聚缩醛共聚物的方法，其包括在路易斯酸和阴离子聚合催化剂存在下使甲醛和选自环氧烷烃，聚（环氧烷烃），环状缩醛和聚（环状缩甲醛）的化合物共聚合 金属螯合物除外。
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公开(公告)号：US06265526B1
公开(公告)日：2001-07-24
申请号：US09674719
申请日：2000-11-06
申请人： Kyosuke Komiya , Muneaki Aminaka
发明人： Kyosuke Komiya , Muneaki Aminaka
IPC分类号： C08G6400
CPC分类号： C08G69/04 , C08G63/785 , C08G64/205 , C08G69/28 , C08G85/00
摘要： Disclosed is a system for producing a polycondensation polymer comprising (A) an inert gas absorption device for causing a molten polycondensation prepolymer to absorb an inert gas to thereby obtain (&agr;) a molten prepolymer having the inert gas absorbed therein, (B) a polymerizer device for polymerizing inert gas-absorbed molten prepolymer (&agr;) under reduced pressure, and (C) a pipe for transferring inert gas-absorbed molten prepolymer (&agr;) from absorption device (A) to polymerizer device (B), wherein absorption device (A) and polymerizer device (B) are arranged in this order and connected to each other through pipe (C). Also disclosed is a method for producing a polycondensation polymer by using the above-mentioned system. By the use of the system or method of the present invention, it has become possible to produce a colorless, high quality polycondensation polymer at high polymerization rate even without using a large amount of an inert gas.
摘要翻译： 本发明公开了一种缩聚聚合物的制造方法，其特征在于，包括：（A）使熔融缩聚预聚物吸收惰性气体的惰性气体吸收装置，从而得到（α）吸收有惰性气体的熔融预聚物，（B）聚合反应器 用于在减压下聚合惰性气体吸收的熔融预聚物（α）的装置，和（C）用于将惰性气体吸收的熔融预聚物（α）从吸收装置（A）转移到聚合反应器装置（B）的管道，其中吸收装置 A）和聚合反应器装置（B）按顺序排列并通过管道（C）彼此连接。 还公开了通过使用上述系统制备缩聚聚合物的方法。 通过使用本发明的系统或方法，即使不使用大量的惰性气体，也可以以高聚合速率制备无色高品质的缩聚聚合物。
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公开(公告)号：US5912318A
公开(公告)日：1999-06-15
申请号：US54506
申请日：1998-04-03
申请人： Kazumi Hasegawa , Kyosuke Komiya , Muneaki Aminaka
发明人： Kazumi Hasegawa , Kyosuke Komiya , Muneaki Aminaka
CPC分类号： C08G64/307 , C08G64/205
摘要： A method for producing an aromatic polycarbonate which comprises subjecting to a transesterification polymerization reaction at least one polymerizable material for an aromatic polycarbonate, the transesterification reaction being performed in one or more polymerizers which is or are connected through a pipeline system toward an outlet for a final aromatic polycarbonate product, wherein the pipeline system comprises one or more pipes, through which a molten aromatic polycarbonate having a number average molecular weight increased by the transesterification polymerization reaction is passed while contacting an inner wall of the pipe or pipes, the pipeline system having at least one viscous polycarbonate passage region in which a molten aromatic polycarbonate having a number average molecular weight of 6,000 or more is passed through the pipe, wherein the pipe in the at least one viscous polycarbonate passage region is heated to provide a temperature difference in the range of from -3.degree. C. to 50.degree. C. between the temperature (.degree.C.) of the outer wall of the pipe and the temperature (.degree.C.) of the aromatic polycarbonate in the polymerizer from which the aromatic polycarbonate is passed through the pipe. By the method of the present invention, a high quality aromatic polycarbonate which is not only highly colorless but also has a low foreign matter content can be easily produced.
摘要翻译： 一种芳族聚碳酸酯的制造方法，其特征在于，对至少一种芳族聚碳酸酯的聚合性材料进行酯交换聚合反应，所述酯交换反应是在一个或多个聚合反应器中进行的，所述聚合反应器是通过管道系统连接到出口， 芳族聚碳酸酯产品，其中管道系统包括一个或多个管道，使通过酯交换聚合反应增加数均分子量的熔融芳族聚碳酸酯通过该管道接触管道或管道的内壁，管道系统具有 至少一个粘性聚碳酸酯通道区域，其中数均分子量为6000以上的熔融芳族聚碳酸酯通过管，其中加热至少一个粘性聚碳酸酯通道区域中的管道以提供在该范围内的温度差 的-3 DE 在管道外壁的温度（℃）和温度（℃）之间，在聚合器中芳族聚碳酸酯通过管道的温度（℃）之间变化到50℃。 通过本发明的方法，可以容易地制备高品质的芳族聚碳酸酯，其不仅高度无色，而且异物含量低。
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7.发明授权Process for producing polyalkylene terephthalate, process for producing polyalkylene terephthalate molding and polyalkylene terephthalate molding 有权聚对苯二甲酸亚烷基酯的制造方法，聚对苯二甲酸亚烷基酯成型体的制造方法和聚对苯二甲酸亚烷公开(公告)号：US08013107B2
公开(公告)日：2011-09-06
申请号：US10575226
申请日：2004-10-07
CPC分类号： C08G63/183 , C08G63/785 , Y10T428/1397 , Y10T428/2913 , Y10T428/2927
摘要： The present invention provides a method of producing polyalkylene terephthalate, which comprises: introducing a prepolymer of polyalkylene terephthalate that is in a molten state comprising 70 mol % or more of ethylene terephthalate or 1,4-butylene terephthalate repeating units and having an intrinsic viscosity [η] between 0.2 and 2 dl/g through a feed opening to a polymerization reactor; discharging the introduced prepolymer from holes of a perforated plate; and polymerizing the prepolymer under reduced pressure, while allowing the prepolymer to fall along the surface of a support that is open towards the outside at a temperature between the [crystalline melting point−10° C.] of the prepolymer or higher and the [crystalline melting point+30° C.] of the prepolymer or lower under the conditions represented by a formula S1/S2>1, wherein S1 is the surface area of falling polyalkylene terephthalate, and S2 is the area where the support is in contact with polyalkylene terephthalate.
摘要翻译： 本发明提供一种聚对苯二甲酸亚烷基酯的制造方法，其特征在于，包括：引入聚对苯二甲酸亚烷基酯的预聚物，所述聚对苯二甲酸亚烷基酯处于熔融状态，所述聚对苯二甲酸亚烷基酯包含70摩尔％ 通过进入聚合反应器的进料口在0.2和2dl / g之间; 从多孔板的孔排出引入的预聚物; 并且在减压下聚合预聚物，同时允许预聚物在预聚物的[结晶熔点-10℃]之间或更高的[温度]之间的温度沿着向外开口的载体表面落下 熔点+ 30℃]的预聚物，或者在由式S1 / S2> 1表示的条件下更低，其中S1是下降的聚对苯二甲酸亚烷基酯的表面积，S2是载体与聚亚烷基接触的面积 对苯二甲酸酯。
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8.发明申请Method And Apparatus For Producing Polycondensation Polymer And Molded Article Thereof 审中-公开制造缩聚聚合物及其成型品的方法和装置公开(公告)号：US20080090975A1
公开(公告)日：2008-04-17
申请号：US11665173
申请日：2005-11-25
申请人： Hiroshi Yokoyama , Muneaki Aminaka
发明人： Hiroshi Yokoyama , Muneaki Aminaka
CPC分类号： C08G63/785
摘要： A method for producing a polycondensation polymer, which comprises: introducing a prepolymer of a polycondensation polymer into a polymerization reactor through a feed opening in a molten state; discharging the introduced prepolymer through holes of a perforated plate; and then polycondensing the prepolymer under reduced pressure, while allowing the prepolymer to fall along a support, wherein the perforated plate has two or more areas and polycondensation is performed by introducing a prepolymer and/or a polymer modifier into each of the areas and discharging the introduced prepolymer and/or polymer modifier through holes of each of the areas.
摘要翻译： 一种缩聚聚合物的制造方法，其特征在于，包括：通过熔融状态的进料口将缩聚聚合物的预聚物引入聚合反应器中; 通过多孔板的孔排出引入的预聚物; 然后在减压下将预聚物缩聚，同时使预聚物沿着载体落下，其中多孔板具有两个或更多个区域，并且通过将预聚物和/或聚合物改性剂引入每个区域并将 通过每个区域的孔引入预聚物和/或聚合物改性剂。
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9.发明申请Process for Producing Polyalkylene Terephthalate, Process for Producing Polyalkylene Terephthalate Molding and Polyalkylene Terephthalate Molding 有权生产聚对苯二甲酸亚烷基酯的方法，用于生产聚对苯二甲酸亚烷基酯成型和聚对苯二甲酸亚烷基酯成型的方法公开(公告)号：US20080274320A1
公开(公告)日：2008-11-06
申请号：US10575226
申请日：2004-10-07
IPC分类号： B29D22/00 , C08G63/183
CPC分类号： C08G63/183 , C08G63/785 , Y10T428/1397 , Y10T428/2913 , Y10T428/2927
摘要： The present invention provides a method of producing polyalkylene terephthalate, which comprises: introducing a prepolymer of polyalkylene terephthalate that is in a molten state comprising 70 mol % or more of ethylene terephthalate or 1,4-butylene terephthalate repeating units and having an intrinsic viscosity [η] between 0.2 and 2 dl/g through a feed opening to a polymerization reactor; discharging the introduced prepolymer from holes of a perforated plate; and polymerizing the prepolymer under reduced pressure, while allowing the prepolymer to fall along the surface of a support that is open towards the outside at a temperature between the [crystalline melting point−10° C.] of the prepolymer or higher and the [crystalline melting point+30° C.] of the prepolymer or lower under the conditions represented by a formula S1/S2>1, wherein S1 is the surface area of falling polyalkylene terephthalate, and S2 is the area where the support is in contact with polyalkylene terephthalate.
摘要翻译： 本发明提供一种聚对苯二甲酸亚烷基酯的制造方法，其特征在于，包括：引入聚对苯二甲酸亚烷基酯的预聚物，所述聚对苯二甲酸亚烷基酯处于熔融状态，所述聚对苯二甲酸亚烷基酯包含70摩尔％ eta]为0.2-2d / g，通过聚合反应器的进料口; 从多孔板的孔排出引入的预聚物; 并且在减压下聚合预聚物，同时允许预聚物在预聚物的[结晶熔点-10℃]之间或更高的[温度]之间的温度沿着向外开口的载体表面落下 熔点+ 30℃]，或者在由式S 1 / S 2 1表示的条件下更低，其中S 1， SUB>是下降的聚对苯二甲酸亚烷基酯的表面积，S 2 O 2是支撑体与聚对苯二甲酸亚烷基酯接触的区域。
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公开(公告)号：US20080128949A1
公开(公告)日：2008-06-05
申请号：US11791771
申请日：2005-11-29
申请人： Hiroshi Yokoyama , Hiroshige Okamoto , Muneaki Aminaka , Kouji Takeuchi , Hironobu Yamauchi , Ken Someya
发明人： Hiroshi Yokoyama , Hiroshige Okamoto , Muneaki Aminaka , Kouji Takeuchi , Hironobu Yamauchi , Ken Someya
IPC分类号： B29C45/00
CPC分类号： C08G63/785
摘要： A method for producing a molded product consisting of a resin polymerized by a melt polycondensation reaction, comprising continuous feeding of a prepolymer in molten state from a prepolymer feeding port to a polymerization reactor, discharging from holes of a porous plate, followed by polymerization while dropping along a supporting substrate under reduced pressure, and molding by transferring to at least one molding machine in molten state without solidification, wherein transfer pressure to said molding machine is controlled so as to maintain at an arbitrary pressure from 0.1 to 100 MPa (absolute pressure).
摘要翻译： 一种制备由熔融缩聚反应聚合的树脂组成的模制产品的方法，包括将熔融状态的预聚物从预聚物进料口连续供入聚合反应器，从多孔板的孔排出，然后滴加聚合 在减压下沿着支撑基板进行模塑，并且通过在熔融状态下转移至至少一个成型机而不固化而成型，其中控制到所述成型机的转印压力以保持在0.1〜100MPa（绝对压力）的任意压力， 。
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