Photocatalyst-containing coating composition
    1.
    发明授权
    Photocatalyst-containing coating composition 有权
    含光催化剂的涂料组合物

    公开(公告)号:US5981425A

    公开(公告)日:1999-11-09

    申请号:US285056

    申请日:1999-04-02

    CPC分类号: B01J35/004 B01J35/002

    摘要: A coating composition which is excellent in water resistance, weatherability and durability and can maintain its appearance for a prolonged period of time can be provided. A coating composition comprising a coating component and a photocatalyst containing calcium phosphate and titanium oxide is disclosed. As the photocatalyst, use is made of titanium oxide particles partially covered thereon with calcium phosphate, or porous body coated thereon with a film of titanium oxide, the film of titanium oxide being further covered partially thereon with calcium phosphate. The crystal form of titanium oxide is preferably anatase. The organic coating includes vinyl-type synthetic resin emulsions, and the inorganic coating is e.g. a solution containing a metal alkoxide for forming a film by a sol-gel method.

    摘要翻译: 可以提供耐水性,耐气候性和耐久性优异并能够长时间保持其外观的涂料组合物。 公开了一种包含涂料组分和含有磷酸钙和氧化钛的光催化剂的涂料组合物。 作为光催化剂,使用部分被磷酸钙覆盖的氧化钛粒子或其上涂覆有氧化钛膜的多孔体,二氧化钛膜还被磷酸钙部分地覆盖。 氧化钛的晶体形式优选为锐钛矿型。 有机涂层包括乙烯基型合成树脂乳液,无机涂层是例如。 含有通过溶胶 - 凝胶法形成膜的金属醇盐的溶液。

    Lactone-modified alicyclic composition and an epoxidized composition
thereof
    2.
    发明授权
    Lactone-modified alicyclic composition and an epoxidized composition thereof 失效
    内酯改性脂环族组合物及其环氧化组合物

    公开(公告)号:US5338879A

    公开(公告)日:1994-08-16

    申请号:US930094

    申请日:1992-08-13

    摘要: A composition comprising a lactone-modified alicyclic compound (I), or an epoxidized lactone-modified alicyclic compound (II) of the following formulae: ##STR1## wherein R is an alkyl group, an aromatic group or an alkenyl group having carbon number of from 1 to 30, Y.sup.1 is at least one of the structural groups; ##STR2## Y.sup.2 is at least one of the structural group; ##STR3## X is the structural group; ##STR4## and R.sup.a and R.sup.b each independently is hydrogen or a methyl group, c and c' represent a number of from 4 to 8, from n1 to nL represents 0 or a number of more than 0, respectively, and n1+n2+n3+ . . . +nL corresponds to the total mole numbers of a lactone introduced into one molecule.These compositions can be made into a heat-curable composition, a photo-curable composition, a polymerizable composition and another photo-curable composition.

    摘要翻译: 含有内酯改性脂环族化合物(I)或下式的环氧化内酯改性脂环族化合物(II)的组合物:其中R为烷基,芳香族 碳原子数为1〜30的烯基,Y 1为结构基中的至少一个。 Y2是至少一个结构组; X是结构组; 并且R a和R b各自独立地为氢或甲基,c和c'表示4至8的数,从n1至nL分别表示0或大于0的数,并且n1 + n2 + n3 +。 。 。 + nL对应于引入一个分子的内酯的总摩尔数。 这些组合物可以制成热固化组合物,光固化组合物,可聚合组合物和另一种可光固化组合物。

    Process for preparing acetic acid
    3.
    发明授权
    Process for preparing acetic acid 失效
    制备乙酸的方法

    公开(公告)号:US4996357A

    公开(公告)日:1991-02-26

    申请号:US717629

    申请日:1985-03-29

    CPC分类号: C07C51/353

    摘要: Acetic acid is advantageously prepared from a starting material having a formic acid moiety and a methyl ester moiety by heating said starting material in the presence of (1) carbon monoxide, (2) at least one of (2-a) a metal accelerator selected from beryllium, a metal belonging to the group IIIA, IVB, VB, VIB or IIA of the Periodic Table, a lanthanide metal and an actinide metal and (2-b) an onium compound or a precursor for the onium compound, (3) a rhodium catalyst and (4) an iodine compound.

    摘要翻译: 乙酸有利地由具有甲酸部分和甲酯部分的原料制备,通过在(1)一氧化碳的存在下加热所述原料,(2)选自(2-a)金属加速剂中的至少一种 铍,属于元素周期表IIIA族,IVB族,VB族,VIB族或IIA族的金属,镧系金属和锕系金属和(2-b)鎓化合物或鎓化合物的前体,(3) 铑催化剂和(4)碘化合物。

    Lactone-modified diketene (meth)acrylate compound, a process for the
preparation thereof, and a (co)polymer
    5.
    发明授权
    Lactone-modified diketene (meth)acrylate compound, a process for the preparation thereof, and a (co)polymer 失效
    内酯改性的二烯丙基(甲基)丙烯酸酯化合物,其制备方法和(共)聚合物

    公开(公告)号:US5721329A

    公开(公告)日:1998-02-24

    申请号:US754288

    申请日:1996-11-20

    IPC分类号: C07C69/72 C08F20/28 C08F16/36

    CPC分类号: C08F20/28 C07C69/72

    摘要: Disclosed are a novel lactone-modified diketene (meth)acrylate compound having an active methylene group in the molecule and a process for the preparation thereof. The novel lactone-modified diketene (meth)acrylate compound of the present invention can be preferably used as resins for coatings, adhesives, inks, photosensitive materials for photographs, dispersants for pigments, agents for processing fibers, and modifiers for rubbers. Furthermore, disclosed is a novel (co)polymer which comprises the novel lactone-modified diketene (meth)acrylate compound and, optionally, a polymerizable monomer having an ethylenically unsaturated double bond. Still further, disclosed is a curable composition which comprises a lactone-modified diketene (meth)acrylate compound and at least one selected from the group consisting of a melamine, an isocyanate, and aldehyde, and an amine.

    摘要翻译: 公开了分子中具有活性亚甲基的新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物及其制备方法。 本发明的新型内酯改性双烯酮(甲基)丙烯酸酯化合物可以优选用作涂料,粘合剂,油墨,照相感光材料,颜料用分散剂,纤维加工剂和橡胶改性剂的树脂。 此外,公开了一种新型(共)聚合物,其包含新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物和任选的具有烯键式不饱和双键的可聚合单体。 此外,还公开了包含内酯改性的二烯酮(甲基)丙烯酸酯化合物和选自三聚氰胺,异氰酸酯和醛和胺中的至少一种的可固化组合物。

    Lactone-modified diketene(meth)acrylate compound, a process for the
preparation thereof, and a (co)polymer
    6.
    发明授权
    Lactone-modified diketene(meth)acrylate compound, a process for the preparation thereof, and a (co)polymer 失效
    内酯改性的二烯丙基(甲基)丙烯酸酯化合物,其制备方法和(共)聚合物

    公开(公告)号:US5631342A

    公开(公告)日:1997-05-20

    申请号:US562113

    申请日:1995-11-22

    IPC分类号: C07C69/72 C08F20/28 C08G18/10

    CPC分类号: C08F20/28 C07C69/72

    摘要: Disclosed are a novel lactone-modified diketene (meth)acrylate compound having an active methylene group in the molecule and a process for the preparation thereof.The novel lactone-modified diketene(meth)acrylate compound of the present invention can be preferably used as resins for coatings, adhesives, inks, photosensitive materials for photographs, dispersants for pigments, agents for processing fibers, and modifiers for rubbers.Furthermore, disclosed is a novel (co)polymer which comprises the novel lactone-modified diketene(meth)acrylate compound and, optionally, a polymerizable monomer having an ethylenically unsaturated double bond.Still further, disclosed is a curable composition which comprises a lactone-modified diketene(meth)acrylate compound and at least one selected from the group consisting of a melamine, an isocyanate, and aldehyde, and an amine.

    摘要翻译: 公开了分子中具有活性亚甲基的新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物及其制备方法。 本发明的新型内酯改性双烯酮(甲基)丙烯酸酯化合物可以优选用作涂料,粘合剂,油墨,照相感光材料,颜料用分散剂,纤维加工剂和橡胶改性剂的树脂。 此外,公开了一种新型(共)聚合物,其包含新的内酯改性的二烯丙基(甲基)丙烯酸酯化合物和任选的具有烯键式不饱和双键的可聚合单体。 此外,还公开了包含内酯改性的二烯酮(甲基)丙烯酸酯化合物和选自三聚氰胺,异氰酸酯和醛和胺中的至少一种的可固化组合物。

    Acrylic monomer
    9.
    发明授权
    Acrylic monomer 失效
    丙烯酸单体

    公开(公告)号:US5650532A

    公开(公告)日:1997-07-22

    申请号:US568817

    申请日:1995-12-07

    IPC分类号: C07C69/96

    CPC分类号: C07C69/96

    摘要: A novel acrylic monomer is produced by addition reacting a hydroxyalkyl (meth)acrylate or its lactone adduct with a cyclic alkylene carbonate, and then acylating the terminal hydroxyl group of the reaction product with a reactive derivative of a monobasic alkanoic acid or a dicarboxylic acid anhydride.

    摘要翻译: 通过使(甲基)丙烯酸羟烷基酯或其内酯加合物与环状碳酸亚烷基酯加成反应,然后用反应性的一元链烷酸或二羧酸酐的反应性衍生物酰化反应产物的末端羟基来制备新的丙烯酸类单体 。

    Lactone-modified polyvinyl acetal resin and process for the preparation
thereof
    10.
    发明授权
    Lactone-modified polyvinyl acetal resin and process for the preparation thereof 失效
    内酯改性聚乙烯醇缩醛树脂及其制备方法

    公开(公告)号:US5574098A

    公开(公告)日:1996-11-12

    申请号:US319452

    申请日:1994-10-06

    IPC分类号: C08F8/14 C08F8/16 C08F8/00

    CPC分类号: C08F8/14 C08F8/16

    摘要: A novel lactone-modified polyvinyl acetal resin and a novel carboxyl-modified resin thereof are disclosed.The novel resins of the present invention can be used as a polyol resin for coatings curable at ordinary temperatures or heating, adhesives, binders, a processing agent for fibers, a curable resin composition by mixing with a curing agent which can react to hydroxyl groups, and a composition for a magnetic recording medium, etc.The novel resins of the present invention have graft chains containing primary hydroxyl groups bonded to the ester group derived from a lactone compound, or the primary hydroxyl groups and carboxylic groups.

    摘要翻译: 公开了一种新的内酯改性的聚乙烯醇缩醛树脂及其新的羧基改性树脂。 本发明的新型树脂可以用作常温或加热下可固化的涂料的多元醇树脂,粘合剂,粘合剂,纤维加工剂,可与可与羟基反应的固化剂混合的可固化树脂组合物, 和用于磁记录介质的组合物等。本发明的新型树脂具有含有与衍生自内酯化合物的酯基或伯羟基和羧基键合的伯羟基的接枝链。