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公开(公告)号：US20050107505A1
公开(公告)日：2005-05-19
申请号：US10503225
申请日：2003-01-31
IPC分类号： C08L67/06 , C08F299/02 , C08G69/40 , C08J5/18 , C08K5/00 , C08K5/05 , C08K5/09 , C08K5/14 , C08L1/12 , C08L29/04 , C08L67/00 , C08L67/02 , C08L67/04 , C08L77/00 , C08L77/08 , C08L101/00 , C08L101/12 , C08L101/16
CPC分类号： C08L67/02 , C08G69/40 , C08J5/18 , C08J2367/04 , C08K5/00 , C08K5/14 , C08L1/12 , C08L29/04 , C08L67/00 , C08L67/04 , C08L67/06 , C08L77/00 , C08L101/00 , C08L2201/06 , C08L2666/02 , C08L2666/14
摘要： A resin composition (AA) comprising an aliphatic polyester or aliphatic polyamide (component (A)), a plastic having a melting point or glass transition temperature (Tg) of −10° C. or more (component (B)) and a radical generating agent (C), wherein the compounding ratio of the component (A), the component (B) and the radical generating agent (C), based on the total weight thereof, is: 1 to 98.995% by weight of the component (A), 98.995 to 1% by weight of the component (B), and 0.005 to 5% by weight of the radical generating agent (C), and an aliphatic unsaturated polybasic acid (a) is contained in the polymer constituent of the component (A) and/or the component (B). The resin composition is suitable as a starting material of biodegradable material which maintains transparency, is free of bleeding of a plasticizer, is endowed with flexibility and has other advantageous characteristics so that it can be used in various fields.
摘要翻译： 包含脂族聚酯或脂肪族聚酰胺（组分（A））的树脂组合物（AA），熔点或玻璃化转变温度（Tg）为-10℃以上的组分（组分（B））和基团 （C），其中组分（A），组分（B）和自由基产生剂（C）的配混比基于其总重量计为：组分（1）的1-98.995重量％ A），98.995〜1重量％的组分（B）和0.005-5重量％的自由基产生剂（C）和脂族不饱和多元酸（a）包含在组分 （A）和/或组分（B）。 该树脂组合物适合作为可保持透明性，不含增塑剂渗色性的生物降解材料的起始材料，具有柔软性并具有其它有利特征，因此可用于各种领域。
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公开(公告)号：US20070160861A1
公开(公告)日：2007-07-12
申请号：US10589431
申请日：2005-02-09
申请人： Hosei Shinoda , Takeshi Kashima , Masahiro Enna , Shinichi Kojoh , Hideyuki Kaneko , Shingo Matsuo , Nobuo Kawahara , Tomoaki Matsugi , Yuichi Matsuda , Takayuki Onogi , Fumio Kageyama
发明人： Hosei Shinoda , Takeshi Kashima , Masahiro Enna , Shinichi Kojoh , Hideyuki Kaneko , Shingo Matsuo , Nobuo Kawahara , Tomoaki Matsugi , Yuichi Matsuda , Takayuki Onogi , Fumio Kageyama
IPC分类号： B32B27/30
CPC分类号： C08L51/06 , C08L23/00 , C08L23/02 , C08L67/02 , C08L69/00 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938 , C08L2666/24 , C08L2666/18 , C08L2666/14 , C08L2666/02
摘要： A modified polyolefin resin comprising a copolymer having a structure that a propylene-based polyolefin segment (a) and a segment (b) containing a lactic acid as a constituent are bonded in a block state and/or a graft state through a vinyl monomer having a hydroxyl group, wherein a number average molecular weight of the propylene-based polyolefin segment (a) is from 1,000 to 100,000, a number average molecular weight of the segment (b) containing lactic acid as a constituent is from 1,000 to 200,000, and a weight composition of the propylene-based polyolefin segment (a) and the segment (b) containing lactic acid as a constituent is from 10/90 to 90/10. The modified polyolefin resin can be used in a resin composition containing an aliphatic polyester resin (A), a polyolefin resin (B) and the modified polyolefin resin (C). The composition can exhibit excellent heat resistance and impact resistance and can be used for molding various parts.
摘要翻译： 包含具有丙烯类聚烯烃链段（a）和含有乳酸作为组分的链段（b）的结构的共聚物的改性聚烯烃树脂以嵌段状态和/或接枝状态通过具有 羟基，其中丙烯类聚烯烃链段（a）的数均分子量为1,000〜100,000，以乳酸为成分的链段（b）的数均分子量为1,000〜200,000，以及 丙烯类聚烯烃链段（a）和含有乳酸作为成分的链段（b）的重量组成为10/90〜90/10。 改性聚烯烃树脂可用于含有脂族聚酯树脂（A），聚烯烃树脂（B）和改性聚烯烃树脂（C）的树脂组合物中。 该组合物可以表现出优异的耐热性和抗冲击性，并且可用于各种部件的成型。
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公开(公告)号：US07847021B2
公开(公告)日：2010-12-07
申请号：US10589431
申请日：2005-02-09
申请人： Hosei Shinoda , Takeshi Kashima , Masahiro Enna , Shinichi Kojoh , Hideyuki Kaneko , Shingo Matsuo , Nobuo Kawahara , Tomoaki Matsugi , Yuichi Matsuda , Takayuki Onogi , Fumio Kageyama
发明人： Hosei Shinoda , Takeshi Kashima , Masahiro Enna , Shinichi Kojoh , Hideyuki Kaneko , Shingo Matsuo , Nobuo Kawahara , Tomoaki Matsugi , Yuichi Matsuda , Takayuki Onogi , Fumio Kageyama
CPC分类号： C08L51/06 , C08L23/00 , C08L23/02 , C08L67/02 , C08L69/00 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938 , C08L2666/24 , C08L2666/18 , C08L2666/14 , C08L2666/02
摘要： A modified polyolefin resin comprising a copolymer having a structure that a propylene-based polyolefin segment (a) and a segment (b) containing a lactic acid as a constituent are bonded in a block state and/or a graft state through a vinyl monomer having a hydroxyl group, wherein a number average molecular weight of the propylene-based polyolefin segment (a) is from 1,000 to 100,000, a number average molecular weight of the segment (b) containing lactic acid as a constituent is from 1,000 to 200,000, and a weight composition of the propylene-based polyolefin segment (a) and the segment (b) containing lactic acid as a constituent is from 10/90 to 90/10. The modified polyolefin resin can be used in a resin composition containing an aliphatic polyester resin (A), a polyolefin resin (B) and the modified polyolefin resin (C). The composition can exhibit excellent heat resistance and impact resistance and can be used for molding various parts.
摘要翻译： 包含具有丙烯类聚烯烃链段（a）和含有乳酸作为组分的链段（b）的结构的共聚物的改性聚烯烃树脂以嵌段状态和/或接枝状态通过具有 羟基，其中丙烯类聚烯烃链段（a）的数均分子量为1,000〜100,000，以乳酸为成分的链段（b）的数均分子量为1,000〜200,000，以及 丙烯类聚烯烃链段（a）和含有乳酸作为成分的链段（b）的重量组成为10/90〜90/10。 改性聚烯烃树脂可用于含有脂族聚酯树脂（A），聚烯烃树脂（B）和改性聚烯烃树脂（C）的树脂组合物中。 该组合物可以表现出优异的耐热性和抗冲击性，并且可用于各种部件的成型。
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公开(公告)号：US5714230A
公开(公告)日：1998-02-03
申请号：US340902
申请日：1994-11-15
IPC分类号： B32B27/10 , B32B27/36 , C08G63/16 , C08G63/60 , C08G63/81 , C08L67/00 , C08L67/02 , D04H1/42 , D04H13/00 , D06N7/04 , B32B00/00
CPC分类号： C08L67/02 , B32B27/10 , B32B27/36 , C08G63/16 , C08G63/60 , C08G63/81 , C08L67/00 , D04H1/4258 , D04H1/435 , C08L2201/06 , Y10T428/24355 , Y10T428/249921 , Y10T428/2913 , Y10T428/3179
摘要： Formed products such as foams, fabrics for industrial materials, filaments, nonwoven fabrics, composite materials and films which are degradable after use with ease in the natural environment are prepared by using a high molecular weight aliphatic polyester obtained by direct polycondensation of an aliphatic polyhydric alcohol with aliphatic polybasic acid or additionally hydroxycarboxylic acid or oligomers of these materials in a reaction mixture containing a solvent. Foams have excellent thermal insulation and strength; fabrics are excellent in thermal insulation, strength and elongation and can be used for industrial materials; filaments have sufficient strength, flexibility and degradability in a living body and can be used for bioabsorbable surgical filament and fishing lines; nonwoven fabrics can be obtained by bonding a web of filaments and have excellent strength and feeling; composite materials can be prepared by adhering or impregnating fiber, paper, film and others of cellulosics and have excellent strength and water resistance, good flexibility and folding resistance, simultaneously have degradability in the natural environment, and can dissolve polymer films on the surface with ease under alkaline conditions to recover cellulosics alone; and films are excellent in heat resistance and strength.
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公开(公告)号：US5428126A
公开(公告)日：1995-06-27
申请号：US368879
申请日：1995-01-05
摘要： A preparation process of aliphatic polyester having a weight average molecular weight of 15,000 or more by conducting a direct polycondensation reaction of an aliphatic polyhydric alcohol or a mixed aliphatic polyhydric alcohol and an aliphatic polybasic acid or a mixed aliphatic polybasic acid, or additionally a hydroxycarboxylic acid or a mixed hydroxycarboxylic acid or an oligomer of the hydroxycarboxylic acid in a reaction mixture containing an organic solvent.The aliphatic polyester thus obtained contains an extremely small amount of impurities, has low color and can exhibit satisfactory strength in the form of films, filaments and other shaped articles.
摘要翻译： 通过进行脂肪族多元醇或混合脂肪族多元醇与脂肪族多元酸或混合脂肪族多元酸的直接缩聚反应，或另外添加羟基羧酸，进行重均分子量为15000以上的脂肪族聚酯的制备方法 或羟基羧酸的混合羟基羧酸或低聚物在含有机溶剂的反应混合物中。 由此获得的脂肪族聚酯含有极少量的杂质，颜色低，并且可以以薄膜，长丝和其它成型制品的形式显示令人满意的强度。
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6.发明授权
公开(公告)号：US6001891A
公开(公告)日：1999-12-14
申请号：US865128
申请日：1997-05-29
CPC分类号： C08G63/81 , C08G63/52 , C08G63/676
摘要： A biodegradable aliphatic polyester elastomer which has rubber-like elasticity, hardness of 80 or less in accordance with ASTM D 676-58T, and elastic modulus from 1.times.10.sup.5 Pa to 1.times.10.sup.8 Pa at 25.degree. C., and decomposes with ease in the natural environment, under composting conditions or under hydrolysis conditions. The biodegradable aliphatic elastomer can be obtained by crosslinking aliphatic polyester containing aliphatic unsaturated polybasic acid as a polymer constituting ingredient and having a weight average molecular weight of 15,000 or more.
摘要翻译： 具有橡胶状弹性，根据ASTM D 676-58T的硬度为80以下的生物降解性脂肪族聚酯弹性体，25℃下的弹性模量为1×10 5 Pa〜1×10 8 Pa，在自然环境中容易分解， 在堆肥条件下或在水解条件下。 可生物降解的脂肪族弹性体可以通过将含有脂肪族不饱和多元酸的脂肪族聚酯作为构成成分的聚合物交联而获得，重均分子量为15000以上。
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公开(公告)号：US5817728A
公开(公告)日：1998-10-06
申请号：US610240
申请日：1996-03-04
申请人： Chojiro Higuchi , Hiroshi Suizu , Masatoshi Takagi , Takeshi Kashima , Yuji Terado , Ikumi Kitada , Masanobu Ajioka , Akihiro Yamaguchi , Taiji Kameoka
发明人： Chojiro Higuchi , Hiroshi Suizu , Masatoshi Takagi , Takeshi Kashima , Yuji Terado , Ikumi Kitada , Masanobu Ajioka , Akihiro Yamaguchi , Taiji Kameoka
IPC分类号： C08B3/16 , C08B13/00 , C08B31/02 , C08G63/664 , C08G63/672 , C08G63/81 , C08B3/00
CPC分类号： C08G63/81 , C08B13/00 , C08B3/16 , C08B31/02 , C08G63/664 , C08G63/672
摘要： A preparation process of a degradable copolymer comprising carrying out dehydration polycondensation of polysaccharide (A) with one or more compounds (B) selected from the group consisting of: (b1) hydroxycarboxylic acid, (b2) polyhydroxycarboxylic acid, (b3) aliphatic polyhydric alcohol and aliphatic polybasic acid, and (b4) aliphatic polyester derived from aliphatic polyhydric alcohol and aliphatic polybasic acid. A copolymer having a high molecular weight, excellent toughness, transparency and heat resistance, and additionally having a high melt tension can be obtained with a reaction time less than a half of the conventional process. The copolymer obtained by the invention is a material suited for injection molding, extrusion, calendaring, blow forming, balloon forming, vacuum forming and foaming. Particularly, the copolymer obtained by the invention has a high melt tension and thus the molten copolymer is difficult to sag and flow and can be processed with ease into foams and blow bottles.
摘要翻译： 一种可降解共聚物的制备方法，包括进行多糖（A）与一种或多种选自以下的化合物（B）的脱水缩聚：（b1）羟基羧酸，（b2）聚羟基羧酸，（b3）脂肪族多元醇 和脂族多元酸，和（b4）衍生自脂肪族多元醇和脂肪族多元酸的脂肪族聚酯。 可以获得具有低于常规方法的一半的反应时间的具有高分子量，优异的韧性，透明性和耐热性以及额外具有高熔体张力的共聚物。 通过本发明获得的共聚物是适于注射成型，挤出，压延，吹塑成型，球形成型，真空成型和发泡的材料。 特别地，本发明获得的共聚物具有高熔体张力，因此熔融共聚物难以下垂和流动，并且可以容易地加工成泡沫和吹塑瓶。
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公开(公告)号：US5763098A
公开(公告)日：1998-06-09
申请号：US892265
申请日：1997-07-14
IPC分类号： B32B27/10 , B32B27/36 , C08G63/16 , C08G63/60 , C08G63/81 , C08L67/00 , C08L67/02 , D04H1/42 , D04H13/00 , D06N7/04 , C08G63/02
CPC分类号： C08L67/02 , B32B27/10 , B32B27/36 , C08G63/16 , C08G63/60 , C08G63/81 , C08L67/00 , D04H1/4258 , D04H1/435 , C08L2201/06 , Y10T428/24355 , Y10T428/249921 , Y10T428/2913 , Y10T428/3179
摘要： Formed products such as foams, fabrics for industrial materials, filaments, nonwoven fabrics, composite materials and films which are degradable after use with ease in the natural environment are prepared by using a high molecular weight aliphatic polyester obtained by direct polycondensation of an aliphatic polyhydric alcohol with aliphatic polybasic acid or additionally hydroxycarboxylic acid or oligomers of these materials in a reaction mixture containing a solvent. Foams have excellent thermal insulation and strength; fabrics are excellent in thermal insulation, strength and elongation and can be used for industrial materials; filaments have sufficient strength, flexibility and degradability in a living body and can be used for bioabsorbable surgical filament and fishing lines; nonwoven fabrics can be obtained by bonding a web of filaments and have excellent strength and feeling; composite materials can be prepared by adhering or impregnating fiber, paper, film and others of cellulosics and have excellent strength and water resistance, good flexibility and folding resistance, simultaneously have degradability in the natural environment, and can dissolve polymer films on the surface with ease under alkaline conditions to recover cellulosics alone; and films are excellent in heat resistance and strength.
摘要翻译： 通过使用通过脂肪族多元醇的直接缩聚得到的高分子量脂肪族聚酯，可以制备如在天然环境中容易使用后可降解的泡沫，工业用材料，长丝，无纺布，复合材料和薄膜等成型产品 与脂族多元酸或另外的羟基羧酸或这些物质的低聚物在含有溶剂的反应混合物中。 泡沫具有优良的保温和强度; 织物绝热性，强度和伸长率优良，可用于工业材料; 细丝在活体中具有足够的强度，柔韧性和降解性，可用于生物可吸收的手术细丝和钓鱼线; 非织造织物可以通过粘合丝网而获得，并且具有优异的强度和感觉; 复合材料可以通过粘合或浸渍纤维素的纤维，纸，膜等而具有优异的强度和耐水性，良好的柔韧性和耐折叠性，同时在天然环境中具有降解性，并且可以容易地溶解表面上的聚合物膜 在碱性条件下单独回收纤维素; 并且膜的耐热性和强度优异。
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公开(公告)号：US5401796A
公开(公告)日：1995-03-28
申请号：US219344
申请日：1994-03-29
摘要： A preparation process of aliphatic polyester having a weight average molecular weight of 15,000 or more by conducting a direct polycondensation reaction of an aliphatic polyhydric alcohol or a mixed aliphatic polyhydric alcohol and an aliphatic polybasic acid or a mixed aliphatic polybasic acid, or additionally a hydroxycarboxylic acid or a mixed hydroxycarboxylic acid or an oligomer of the hydroxycarboxylic acid in a reaction mixture containing an organic solvent.The aliphatic polyester thus obtained contains an extremely small amount of impurities, has low color and can exhibit satisfactory strength in the form of films, filaments and other shaped articles.
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