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公开(公告)号:US4480125A
公开(公告)日:1984-10-30
申请号:US322066
申请日:1981-11-16
IPC分类号: C08F22/38 , C07C102/00
CPC分类号: C08F22/38
摘要: The present invention relates to itaconamide compounds of the formula ##STR1## wherein R is hydrogen, alkyl, aryl, alkaryl, or aralkyl and to a method of preparing the subject compounds which comprises preparing a mixed anhydride of 2-methylenesuccinamic acid and reacting the mixed anhydride with a compound of the formula RNH.sub.2, wherein R is as previously defined, to provide the corresponding itaconamide compound.
摘要翻译: 本发明涉及式IMAMA的其他酰胺化合物,其中R是氢,烷基,芳基,烷芳基或芳烷基,以及制备本发明化合物的方法,包括制备2-甲基琥珀酰胺酸的混合酸酐,并使混合 酸酐与式RNH2的化合物反应,其中R如前所定义,以提供相应的itaconamide化合物。
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公开(公告)号:US4227013A
公开(公告)日:1980-10-07
申请号:US35705
申请日:1979-05-03
申请人: Howard C. Haas , Robert D. Moreau
发明人: Howard C. Haas , Robert D. Moreau
IPC分类号: C07C317/04 , C07C69/34 , C07C102/00 , C07C147/14
CPC分类号: C07C317/04
摘要: A process for preparing polyfunctional methylene-bridged compounds is disclosed. A difunctional methylene-bridged compound having acidic protons and having the formula X--CH.sub.2 --X is reacted with an alkali metal in the presence of a disubstituted formamide to provide a methylene-bridged polyfunctional compound having the formula ##STR1## wherein X is an electron-withdrawing group such as --CONH.sub.2, --COOR or --SO.sub.2 R where R is alkyl. The polyfunctional compounds prepared by the process of the present invention are useful in the production of metal complexing or sequestering agents, acidulents, cross-linking agents for polymeric reactions and in applications where a polyfunctional compound is desirably employed.
摘要翻译: 公开了制备多官能亚甲基桥接化合物的方法。 具有酸性质子且具有式X-CH 2 -X的双官能亚甲基桥接化合物在二取代甲酰胺存在下与碱金属反应,得到具有下式的亚甲基桥连多官能化合物,其中X是电子 - 取代基如-CONH 2,-COOR或-SO 2 R,其中R是烷基。 通过本发明的方法制备的多官能化合物可用于生产金属络合剂或螯合剂,酸性剂,聚合反应的交联剂和期望使用多官能化合物的应用。
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公开(公告)号:US4035319A
公开(公告)日:1977-07-12
申请号:US356341
申请日:1973-05-02
申请人: Howard C. Haas
发明人: Howard C. Haas
摘要: A copolymer soluble in aqueous and/or partially aqueous solution and having a chain comprising the entities A and B defined below: ##STR1## WHEREIN: M is hydrogen or methyl;R is an alkylene group comprising less than six carbon atoms or a substituted alkylene group;Each D is hydrogen, methyl or ethyl; andn is the total number of A and B residues in the polymer chain.The copolymers are useful as hardeners for protein-containing emulsions, especially, for example, gelatin emulsions employed in the photographic art. The copolymers of the present invention can also be advantageously employed to selectively adjust the viscosity of protein-containing emulsions to predetermined levels.
摘要翻译: 可溶于水和/或部分水溶液的共聚物,其具有包含以下定义的实体A和B的链:
WHEREIN: -
公开(公告)号:US4278803A
公开(公告)日:1981-07-14
申请号:US109811
申请日:1980-01-07
IPC分类号: C07F7/08 , C07C102/00
CPC分类号: C07F7/0818
摘要: A process for preparing 2-methylene-1,3-propanediamide is disclosed which comprises providing a solution of a novel compound of the formula ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 can each independently be lower alkyl of from 1 to 10 carbon atoms, aryl, alkaryl, aralkyl, or halogen and X is an electron-accepting leaving group, in an inert, aprotic organic solvent, and subjecting the compound in solution to .beta.-elimination reaction conditions effective to eliminate the silyl group ##STR2## and the electron-accepting leaving group--Xfrom the compound to form a double bond between those carbon atoms to which the silyl group and the electron-accepting leaving group were bonded, thereby forming 2-methylene-1,3-propanediamide. 2-Methylene-1,3-propanediamide is useful in preparing polymers which can be used in preparing coating compositions, films, and filaments.
摘要翻译: 公开了一种制备2-亚甲基-1,3-丙二酰胺的方法,其包括提供下式的新化合物的溶液:其中R 1,R 2和R 3可各自独立地为具有1至10个碳原子的低级烷基 ,芳基,烷芳基,芳烷基或卤素,X是电子接受离去基团,在惰性的非质子有机溶剂中,并使化合物在溶液中经受有效消除甲硅烷基的β-烯化反应条件
和 电子接受离子基团-X从化合物形成在与甲硅烷基和受电子离子基团结合的那些碳原子之间的双键,从而形成2-亚甲基-1,3-丙二酰胺。 2-亚甲基-1,3-丙二酰胺可用于制备可用于制备涂料组合物,薄膜和长丝的聚合物。 -
公开(公告)号:US4182805A
公开(公告)日:1980-01-08
申请号:US911445
申请日:1978-06-01
申请人: Howard C. Haas , Robert D. Moreau
发明人: Howard C. Haas , Robert D. Moreau
IPC分类号: C01C3/14 , C07D213/20 , C07D215/10 , C07D217/10 , C08F8/00 , C08F8/44 , C08F8/30
CPC分类号: C08F8/00 , C01C3/14 , C07D213/20 , C07D215/10 , C07D217/10 , C08F8/44
摘要: Processes are disclosed for providing in situ generated cyanic acid and simultaneously preparing certain carboxamides which have a tertiary aliphatic substituted ammonium or pyridinium group substituted on the alpha carbon atom.
摘要翻译: 公开了用于提供原位产生的氰酸并同时制备具有在α碳原子上取代的叔脂族取代的铵或吡啶鎓基团的某些羧酰胺的方法。
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公开(公告)号:US4144063A
公开(公告)日:1979-03-13
申请号:US507257
申请日:1974-09-18
申请人: Howard C. Haas
发明人: Howard C. Haas
摘要: This invention relates to methods of generating colored images by treatment of maleimide copolymers with ammonia or organic amines.
摘要翻译: 本发明涉及通过用氨或有机胺处理马来酰亚胺共聚物产生着色图像的方法。
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公开(公告)号:US4377654A
公开(公告)日:1983-03-22
申请号:US322065
申请日:1981-11-16
申请人: Howard C. Haas , Robert D. Moreau
发明人: Howard C. Haas , Robert D. Moreau
摘要: Alkyl ammonium nitrate fused salts of the formula ##STR1## wherein R.sup.1 is a substituted or unsubstituted alkyl group and R.sup.2 and R.sup.3 are each independently hydrogen or a substituted or unsubstituted alkyl group, which fused salts have melting points of up to about 125.degree. C., are disclosed for use as solvents or swelling agents for polymers and as polymerization media for the conduct of polymerization reactions.
摘要翻译: 其中R 1是取代或未取代的烷基,R 2和R 3各自独立地为氢或取代或未取代的烷基,所述稠合盐的熔点高达约125℃。 被公开用作聚合物的溶剂或溶胀剂以及用于进行聚合反应的聚合介质。
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公开(公告)号:US4155937A
公开(公告)日:1979-05-22
申请号:US821511
申请日:1969-05-02
申请人: Howard C. Haas
发明人: Howard C. Haas
IPC分类号: C07C409/34 , C07C409/40 , C07C179/14
CPC分类号: C07C409/34
摘要: Benzoyl peroxide compounds containing reactive substituents are used to initiate the formation of telechelic polymers.
摘要翻译: 含有反应性取代基的过氧化苯甲酰化合物被用于引发遥爪聚合物的形成。
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公开(公告)号:US4110424A
公开(公告)日:1978-08-29
申请号:US725571
申请日:1976-09-22
申请人: Howard C. Haas , Robert D. Moreau
发明人: Howard C. Haas , Robert D. Moreau
IPC分类号: C01C3/14 , C07D213/20 , C07D215/10 , C07D217/10 , C08F8/00 , C08F8/44 , C01B21/12 , C07D211/00 , C07D401/00
CPC分类号: C08F8/00 , C01C3/14 , C07D213/20 , C07D215/10 , C07D217/10 , C08F8/44
摘要: Processes are disclosed for providing in situ generated cyanic acid and simultaneously preparing certain carboxamides which have a tertiary aliphatic substituted ammonium or pyridinium group substituted on the alpha carbon atom.
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