Silane grafted copolymers of an alpha-olefin and a vinyl aromatic monomer
    1.
    发明授权
    Silane grafted copolymers of an alpha-olefin and a vinyl aromatic monomer 有权
    α-烯烃和乙烯基芳族单体的硅烷接枝共聚物

    公开(公告)号:US06590039B1

    公开(公告)日:2003-07-08

    申请号:US09913948

    申请日:2002-06-24

    IPC分类号: C08F27500

    摘要: Curable silylated copolymers based on olefin copolymers comprising at least one alpha-olefin and a vinyl aromatic monomer (alkyl styrene) are prepared by reacting the olefin copolymer with an olefinically unsaturated hydrolyzable silane in the presence of a free radical generating agent. The silylated copolymers are readily curable by contact with water (moisture) and a silanol condensation catalyst and are particularly useful as the polymeric component in sealant, caulking, adhesive and coating formulations.

    摘要翻译: 包含至少一种α-烯烃和乙烯基芳族单体(烷基苯乙烯)的基于烯烃共聚物的可固化甲硅烷基化共聚物通过烯烃共聚物与烯属不饱和可水解硅烷在自由基生成剂的存在下反应来制备。 甲硅烷基化共聚物可通过与水(水分)和硅烷醇缩合催化剂接触而容易地固化,并且特别可用作密封剂,填缝剂,粘合剂和涂料配方中的聚合物组分。

    Polyisobutylene copolymers having reactive silyl grafts
    2.
    发明授权
    Polyisobutylene copolymers having reactive silyl grafts 有权
    具有反应性甲硅烷基接枝的聚异丁烯共聚物

    公开(公告)号:US06380316B1

    公开(公告)日:2002-04-30

    申请号:US09260456

    申请日:1999-03-02

    IPC分类号: C08F800

    摘要: A copolymer of isobutylene with 0.5 to 15 mole percent of a conjugated diene (i.e., a butyl rubber) is reacted with a silane having both an alkenyl group as well as at least two silicon-bonded hydrolyzable group, the reaction taking place in the presence of a free-radical generator, to provide a modified copolymer having reactive silyl groups grafted thereto. The modified copolymer exhibits a reduced molecular weight relative to the starting copolymer and may be used to formulate moisture-curable sealants, caulks, adhesive and coatings.

    摘要翻译: 将异丁烯与0.5〜15摩尔%的共轭二烯(即丁基橡胶)的共聚物与具有链烯基以及至少两个硅键合的可水解基团的硅烷反应,反应在存在下进行 的自由基发生剂,以提供具有接枝到其上的反应性甲硅烷基的改性共聚物。 改性共聚物相对于起始共聚物显示出降低的分子量,并可用于配制可湿气固化的密封剂,填缝剂,粘合剂和涂料。

    Silane grafted copolymers of an isomonoolefin and a vinyl aromatic monomer
    3.
    发明授权
    Silane grafted copolymers of an isomonoolefin and a vinyl aromatic monomer 有权
    异单烯烃和乙烯基芳族单体的硅烷接枝共聚物

    公开(公告)号:US06177519B1

    公开(公告)日:2001-01-23

    申请号:US09260455

    申请日:1999-03-02

    IPC分类号: C08F820

    摘要: Curable silylated copolymers based on olefin copolymers comprising at least one C4 to C7 isomonoolefin and a vinyl aromatic monomer (alkyl styrene) are prepared by reacting the olefin copolymer with an olefinically unsaturated hydrolyzable silane in the presence of a free radical generating agent. The silylated copolymers are readily curable by contact with water (moisture) and a silanol condensation catalyst and are particularly useful as the polymeric component in sealant, caulking, adhesive and coating formulations.

    摘要翻译: 通过使烯烃共聚物与烯属不饱和的可水解硅烷在自由基生成剂的存在下反应来制备基于烯烃共聚物的可固化甲硅烷基化共聚物,其包含至少一种C 4 -C 7异单烯烃和乙烯基芳族单体(烷基苯乙烯)。 甲硅烷基化共聚物可通过与水(水分)和硅烷醇缩合催化剂接触而容易地固化,并且特别可用作密封剂,填缝剂,粘合剂和涂料配方中的聚合物组分。

    Random isomonoolefin/allyl styrene copolymers and functionalized derivatives thereof
    7.
    发明授权
    Random isomonoolefin/allyl styrene copolymers and functionalized derivatives thereof 有权
    无规异构烯烃/烯丙基苯乙烯共聚物及其官能化衍生物

    公开(公告)号:US06274689B1

    公开(公告)日:2001-08-14

    申请号:US09167787

    申请日:1998-10-07

    IPC分类号: C08F23620

    摘要: The invention provides a copolymer of an isomonoolefin having from 4 to 7 carbon atoms and containing a copolymerized alkenyl styrene moiety represented by the formula I: where m=0-2, n=0-20, each of R1 through R7 are independently selected from the group consisting of hydrogen, C1 to C10 alkyl and C1 to C10 primary or secondary alkyl halides, and at least one of R1, R2 or R3 is hydrogen, and when m=1 or 2, R3 and R1 are —CH2—.

    摘要翻译: 本发明提供了具有4至7个碳原子的异源烯烃的共聚物,并且含有由式I表示的共聚烯基苯乙烯部分:其中m = 0-2,n = 0-20,R 1至R 7各自独立地选自 由氢,C1至C10烷基和C1至C10伯或仲烷基卤化物组成的组,R1,R2或R3中的至少一个为氢,当m = 1或2时,R3和R1为-CH2-。