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119 条记录 (耗时 0.044 秒)

    Three-dimensional copolymers of polyphenylene ether resinsand sytrenic resins
    1.
    发明授权
    Three-dimensional copolymers of polyphenylene ether resinsand sytrenic resins 有权
    聚苯醚树脂苯乙烯树脂的三维共聚物

    公开(公告)号：US06608166B2

    公开(公告)日：2003-08-19

    申请号：US09943159

    申请日：2001-08-30

    申请人： Hua Guo ,  Manuel Cavazos ,  John B. Yates, III

    发明人： Hua Guo ,  Manuel Cavazos ,  John B. Yates, III

    IPC分类号： C08G6378

    CPC分类号： C08F290/062 ,  H05K1/0326

    摘要： A three dimensional copolymer network of polyphenylene ether segments and styrenic resins such as styrene/acrylonitrile copolymers provide articles of high heat reesistance and dielectric properties suitable for use in electronic components. Methods for preparing the copolymers employ polyphenylene ether polymers with end caps having at least one pair of unsaturated aliphatic carbon atoms, i.e. carbon-carbon double bond, and polymerize styrene monomers and acrylonitrile monomers or styrene/acrylonitrile copolymers or both in the presence of these polyphenylene ether polymers.

    摘要翻译： 聚苯醚链段和苯乙烯类树脂如苯乙烯/丙烯腈共聚物的三维共聚物网络提供了适用于电子部件的高耐热性和介电性能的产品。 制备共聚物的方法采用具有至少一对不饱和脂族碳原子（即碳 - 碳双键）的端盖的聚苯醚聚合物，并且在这些聚亚苯基存在下聚合苯乙烯单体和丙烯腈单体或苯乙烯/丙烯腈共聚物或二者 醚聚合物。

    Poly(phenylene ether)-polysiloxane composition and method
    5.
    发明授权
    Poly(phenylene ether)-polysiloxane composition and method 有权
    聚（苯醚） - 聚硅氧烷组合物和方法

    公开(公告)号：US08722837B2

    公开(公告)日：2014-05-13

    申请号：US13362426

    申请日：2012-01-31

    申请人： Alvaro Carrillo ,  Hua Guo ,  Scott Fisher

    发明人： Alvaro Carrillo ,  Hua Guo ,  Scott Fisher

    IPC分类号： C08G65/38 ,  C08G77/46

    CPC分类号： C08L83/12 ,  C08G65/44 ,  C08G77/46 ,  C08K5/34924 ,  C08L25/00 ,  C08L27/00 ,  C08L71/12 ,  C08L71/123 ,  C08L71/126

    摘要： A composition is prepared by oxidative copolymerization of specific amounts of 2,6-dimethylphenol, 2,3,6-trimethylphenol, and a hydroxyaryl-terminated polysiloxane. The composition exhibits an increased heat resistance relative to a corresponding composition prepared by copolymerizing 2,6-dimethylphenol and hydroxyaryl-terminated polysiloxane, without 2,3,6-trimethylphenol. The composition is useful as a flame-retardant additive in polymer compositions that require high heat resistance.

    摘要翻译： 通过特定量的2,6-二甲基苯酚，2,3,6-三甲基苯酚和羟基芳基封端的聚硅氧烷的氧化共聚制备组合物。 该组合物相对于不含2,3,6-三甲基苯酚共聚2,6-二甲基苯酚和羟基芳基封端的聚硅氧烷制备的相应组合物，具有增加的耐热性。 该组合物可用作需要高耐热性的聚合物组合物中的阻燃添加剂。

    Poly(arylene ether)-polysiloxane composition and method
    6.
    发明授权
    Poly(arylene ether)-polysiloxane composition and method 有权
    聚（亚芳基醚） - 聚硅氧烷组合物和方法

    公开(公告)号：US08669332B2

    公开(公告)日：2014-03-11

    申请号：US13169137

    申请日：2011-06-27

    申请人： Alvaro Carrillo ,  Hua Guo

    发明人： Alvaro Carrillo ,  Hua Guo

    IPC分类号： C08L71/12 ,  C08G77/46

    CPC分类号： C08G77/46 ,  C08G77/16 ,  C08G77/80 ,  C08G81/00 ,  C08G2261/126 ,  C08L71/12 ,  C08L83/12 ,  C08L2205/05 ,  C08L83/04

    摘要： A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.

    摘要翻译： 包括聚（亚芳基醚） - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 氧化聚合包括一元酚添加时间，其特征在于第一温度，加入时间之后的生成周期，并且特征在于大于第一温度的第二温度，以及添加周期和构建周期之间的温度斜坡期间。 在温度升高期间，温度以每分钟约0.01至约0.35℃的平均速率增加，这提高了聚（亚芳基醚） - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率 。

    POLY(ARYLENE ETHER)-POLYSILOXANE COMPOSITION AND METHOD
    7.
    发明申请
    POLY(ARYLENE ETHER)-POLYSILOXANE COMPOSITION AND METHOD 有权
    聚（亚乙基醚） - 聚硅氧烷组合物和方法

    公开(公告)号：US20120329961A1

    公开(公告)日：2012-12-27

    申请号：US13169137

    申请日：2011-06-27

    申请人： Alvaro Carrillo ,  Hua Guo

    发明人： Alvaro Carrillo ,  Hua Guo

    IPC分类号： C08L83/12 ,  C08L71/12 ,  C08L25/06 ,  C08L77/00 ,  C08L23/02 ,  C08G77/46 ,  C08L67/00

    CPC分类号： C08G77/46 ,  C08G77/16 ,  C08G77/80 ,  C08G81/00 ,  C08G2261/126 ,  C08L71/12 ,  C08L83/12 ,  C08L2205/05 ,  C08L83/04

    摘要： A thermoplastic composition that includes a poly(arylene ether)-polysiloxane block copolymer is prepared by a method that includes oxidatively copolymerizing a monohydric phenol and a hydroxyaryl-terminated polysiloxane. The oxidative polymerization includes a monohydric phenol addition period characterized by a first temperature, a build period following the addition period and characterized by a second temperature greater than the first temperature, and a temperature ramp period between the addition period and the build period. During the temperature ramp period, the temperature is increased at an average rate of about 0.01 to about 0.35° C. per minute, which improves the efficiency with which the hydroxyaryl-terminated polysiloxane is incorporated into the poly(arylene ether)-polysiloxane block copolymer.

    摘要翻译： 包含聚（亚芳基醚） - 聚硅氧烷嵌段共聚物的热塑性组合物通过包括使一元酚和羟基芳基封端的聚硅氧烷氧化共聚的方法制备。 氧化聚合包括一元酚添加时间，其特征在于第一温度，加入时间之后的生成周期，并且特征在于大于第一温度的第二温度，以及添加周期和构建周期之间的温度斜坡期间。 在温度升高期间，温度以每分钟约0.01至约0.35℃的平均速率增加，这提高了聚（亚芳基醚） - 聚硅氧烷嵌段共聚物中加入羟基芳基封端的聚硅氧烷的效率 。

    Morpholine-substituted poly(arylene ether) and method for the preparation thereof
    9.
    发明授权
    Morpholine-substituted poly(arylene ether) and method for the preparation thereof 有权
    吗啉取代的聚（亚芳基醚）及其制备方法

    公开(公告)号：US08017716B2

    公开(公告)日：2011-09-13

    申请号：US12495980

    申请日：2009-07-01

    申请人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

    发明人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

    IPC分类号： C08G65/38 ,  C08G63/02

    CPC分类号： C08G65/46

    摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

    摘要翻译： 使用含吗啉的聚合催化剂制备的聚（2,6-二甲基-1,4-亚苯基醚）具有单分子分子量分布，具有非常高的分子量物质含量降低。 它还表现出高分子量级分中增加的吗啉掺入。 与使用含有二正丁胺的聚合催化剂制备的市售聚（2,6-二甲基-1,4-亚苯基醚）相比，聚（2,6-二甲基-1,4-亚苯基醚） 发明显示减少的气味。 与使用含吗啉的聚合催化剂制备的其它聚（2,6-二甲基-1,4-亚苯基醚）相比，本发明的聚（2,6-二甲基-1,4-亚苯基醚）表现出改善的分子量 在复合期间建立并改善与聚酰胺的相容性。

    MORPHOLINE-SUBSTITUTED POLY(ARYLENE ETHER) AND METHOD FOR THE PREPARATION THEREOF
    10.
    发明申请
    MORPHOLINE-SUBSTITUTED POLY(ARYLENE ETHER) AND METHOD FOR THE PREPARATION THEREOF 有权
    吗啉取代的聚（亚乙基醚）及其制备方法

    公开(公告)号：US20110003962A1

    公开(公告)日：2011-01-06

    申请号：US12495980

    申请日：2009-07-01

    申请人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

    发明人： Alvaro Carrillo ,  Stephen M. Farnell ,  Hua Guo

    IPC分类号： C08G65/00

    CPC分类号： C08G65/46

    摘要： A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.

    摘要翻译： 使用含吗啉的聚合催化剂制备的聚（2,6-二甲基-1,4-亚苯基醚）具有单分子分子量分布，具有非常高的分子量物质含量降低。 它还表现出高分子量级分中增加的吗啉掺入。 与使用含有二正丁胺的聚合催化剂制备的市售聚（2,6-二甲基-1,4-亚苯基醚）相比，聚（2,6-二甲基-1,4-亚苯基醚） 发明显示减少的气味。 与使用含吗啉的聚合催化剂制备的其它聚（2,6-二甲基-1,4-亚苯基醚）相比，本发明的聚（2,6-二甲基-1,4-亚苯基醚）表现出改善的分子量 在复合期间建立并改善与聚酰胺的相容性。