摘要:
Low molecular weight polymers of acrylic esters which are suitable for use as external plasticizers in coated compositions on a synthetic resin basis are obtainable by subjecting(a) from 80 to 100% by weight of at least one acrylic ester of C.sub.1 -C.sub.8 -alkanol (monomer I) and(b) 0 to 20% by weight of one or more other copolymerizable monomers (monomer II)to a free radical polymerization in a solution in isopropanol in a pressure vessel at 130.degree.-140.degree. C. by introducing first from 70 to 95% by weight of a solvent and adding the remainder of the polymerization batch continuously over 3-7 hours in separate portions of which one contains the monomers and, after the polymerization has ended, distilling off the solvent under reduced pressure, the weight proportion of solvent being 5-15% by weight based on the monomers, the weight proportion of initiator being 0.5-3% by weight based on the monomers, and the half-life of the initiator at the polymerization temperature being from 10 seconds to 3 hours.
摘要:
Adhesives containing polyvinyl ether copolymers having a weight average molecular weight of >10,000, comprisea) from 0 to 95% by weight of vinyl ethers of the formula IH.sub.2 C.dbd.CH--O--Rb) from 5 to 100% by weight of hydrophilic vinyl ethers of the formula IIH.sub.2 C.dbd.CH--O--R.sup.1andc) from 0 to 30% by weight of further monomers,where R is C.sub.1 -C.sub.20 -alkyl and R.sup.1 is an aliphatic or cycloaliphatic radical which may be substituted by hydroxyl groups or interrupted by nonadjacent groups --Y--, Y is oxygen, sulfur or a group NR.sup.2 or N.sup.+ R.sup.2 R.sup.3 X.sup.-, R.sup.2 and R.sup.3 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl and X.sup.- is a counter-anion, and the molar ratio of carbon atoms to the sum of groups Y and hydroxyl groups in the aliphatic or cycloaliphatic radical is from 1.01:1 to 6.5:1.
摘要:
The invention relates to the aqueous preparation of a polymer. Said preparation contains a copolymer consisting of a) 30 to 79.5 wt. % N-vinylpyrrolidone, b) 20 to 69.5 wt. % vinylacetate, c) 0.5 to 25 wt % of a monovinyl ester of a C4 to C20 monocarboxylic acid and d) 0 to 40 wt. % of an additional, copolymerisable, ethylenically unsaturated compound.
摘要:
Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where the initiator is introduced into the polymerization mixture from below.
摘要:
A control device, particularly a rotary controller for manual entry of information into an electronic device, has a setting member the position of which can be changed under the effect of an actuating force. The setting member is connected with a generator for producing electric signals which characterize the position of the setting member. A drive element is connected with the setting member and, under the control of the electric signals, exerts a force on the setting member which acts in the same direction as or in the direction opposite to the actuating force, depending on the position of the setting member for haptic acknowledgement of the operation of the setting member.
摘要:
Methods of producing vinyllactam copolymers which include: providing at least one water-soluble N-vinyllactam; providing at least one hydrophobic comonomer; and subjecting the at least one water-soluble N-vinyllactam and the at least one hydrophobic comonomer to free-radical polymerization in an organic solvent in the presence of an initiator, under a combination of process measures selected from the group consisting of A and B; wherein: (A) comprises (i) polymerization under reflux, and at least two of (ii), (iii), (iv), (v), (vi), and (vii), wherein (ii) comprises an addition of at least 5 mol % of N-vinyllactam to the polymerization mixture if at least 70 mol % of the total amount of hydrophobic monomer used have completely reacted, (iii) comprises return of condensate formed in the reflux from below to the polymerization mixture, (iv) comprises introduction of the initiator in the form of a solution in an organic solvent from below into the polymerization mixture, (v) comprises addition of N-vinyllactam to the reflux, (vi) comprises distilling off a portion of the organic solvent and continuing the polymerization following conversion of 70 to 99% by weight of the N-vinyllactam used, and (vii) comprises introduction of at least one monomer from below into the polymerization mixture; and wherein (B) comprises (viii) polymerization under a superatmospheric pressure such that vaporization of the polymerization components is avoided, and at least one of (i), (ii), (iii), (iv), (v), (vi), and (vii), with the proviso that a combination of (viii) with any of (i), (iii) or (v) is carried out sequentially.
摘要:
A steering column switch, especially for a motor vehicle, contains a switch lever, which is activated transversely and which has a magnetic signal transmitter, to which several stationary magnetic-field sensors coupled to an evaluation unit are allocated for determining the switch positions of the switch lever. The switch lever supports a rotary switch and the signal transmitter and also the magnetic-field sensors are used for determining the switch positions of the rotary switch.
摘要:
A control circuit for a piezoelectric buzzer, notably for automobiles, comprises a circuit for generating alternately two different frequencies and features two input supply terminals (1, 2) and two output terminals (4, 5) for buzzer activation. The control circuit includes a first flip-flop with a first and a second output, of which one carries positive and the other negative voltage. Also provided is a second flip-flop with a first input and an output, the first input connecting to the first and second outputs of the first flip-flop, each via a resistor (R4, R3). The second flip-flop consists of a parallel wiring of a first series connection of a capacitor (C2) and an inverter with Schmitt trigger input (IC1C), and a second series connection of a resistor (R5) and an inverter with Schmitt trigger input (IC1D), while a resistor is wired in parallel with the second series connection. Once a positive supply voltage is applied and grounding established, the buzzer sounds, generating alternately different frequencies f1 and f2.
摘要:
Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where the initiator is introduced into the polymerization mixture from below.
摘要:
Method of producing vinyllactam copolymers by free-radical polymerization of at least one water-soluble N-vinyllactam and at least one hydrophobic comonomer in an organic solvent in the presence of an initiator under reflux conditions, where the condensate formed in the reflux is returned to the polymerization mixture from below.