公开(公告)号：US5504053A

公开(公告)日：1996-04-02

申请号：US502187

申请日：1990-04-03

申请人： Pen-Yuan Chou ,  Madan M. Bhasin ,  Hwaili Soo ,  Erlind M. Thorsteinson

发明人： Pen-Yuan Chou ,  Madan M. Bhasin ,  Hwaili Soo ,  Erlind M. Thorsteinson

IPC分类号： B01J23/66 ,  B01J20060101 ,  B01J23/06 ,  B01J23/68 ,  B01J27/053 ,  C07D301/10 ,  C22B20060101 ,  B01J23/50

CPC分类号： B01J23/68 ,  C07D301/10 ,  Y02P20/52

摘要： Catalysts for the production of alkylene oxide by the epoxidation of alkene with oxygen comprise a silver impregnated support containing a sufficient amount of manganese component to enhance at least one of activity and/or efficiency and/or stability as compared to a similar catalyst which does not contain manganese component.

摘要翻译： 用于通过用氧环氧化烯烃生产环氧烷的催化剂包含含有足够量的锰组分的银浸渍载体，以增加活性和/或效率和/或稳定性中的至少一种，与不使用的类似催化剂相比，活性和/或效率和/或稳定性中的至少一种 含锰成分。

公开(公告)号：US5102848A

公开(公告)日：1992-04-07

申请号：US589213

申请日：1990-09-28

申请人： Hwaili Soo ,  Pen-Yuan Chou ,  Madan M. Bhasin

发明人： Hwaili Soo ,  Pen-Yuan Chou ,  Madan M. Bhasin

IPC分类号： B01J23/68 ,  B01J27/055 ,  B01J27/12 ,  C07D301/10

CPC分类号： C07D301/10 ,  B01J23/682 ,  B01J23/683 ,  B01J27/055 ,  B01J27/12

摘要： Catalysts for the epoxidation of ethylene in the vapor phase comprise silver impregnated support having thereon at least one cation promoter and oxyanion promoter comprising (i) sulfate anion, (ii) fluoride anion and (iii) oxyanion of an element of Group 3b to 6b, inclusive, of the Periodic Table, wherein the amount of fluoride anion is sufficient to reduce ethylene oxide burning.

摘要翻译： 用于气相中乙烯环氧化的催化剂包括其上具有至少一个阳离子促进剂和氧阴离子促进剂的银浸渍的载体，其包含（i）硫酸根阴离子，（ii）氟化物阴离子和（iii）第3b至6b族元素的氧阴离子， 包括式，其中氟阴离子的量足以减少环氧乙烷的燃烧。

公开(公告)号：US20190118167A1

公开(公告)日：2019-04-25

申请号：US16176786

申请日：2018-10-31

申请人： Manuel A.W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A.W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/055 ,  B01J23/58 ,  C07C209/60 ,  B01J37/02 ,  B01J35/02 ,  B01J23/68 ,  C07D301/10 ,  B01J23/50 ,  B01J21/04 ,  B01J37/16

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

公开(公告)号：US20160082423A9

公开(公告)日：2016-03-24

申请号：US13624131

申请日：2012-09-21

申请人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/055 ,  B01J23/68 ,  C07D301/10 ,  C07C29/10 ,  B01J35/02 ,  C07C41/02 ,  B01J37/02 ,  B01J23/66 ,  C07C209/16

CPC分类号： B01J27/055 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/688 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0244 ,  B01J37/16 ,  C07C209/60 ,  C07D301/10 ,  Y02P20/52

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

公开(公告)号：US20110082029A1

公开(公告)日：2011-04-07

申请号：US12947446

申请日：2010-11-16

申请人： Erlind M. Thorsteinson ,  Madan M. Bhasin ,  Albert Cheng-Yu Liu ,  Juliana G. Serafin ,  Seyed R. Seyedmonir ,  Hwaili Soo

发明人： Erlind M. Thorsteinson ,  Madan M. Bhasin ,  Albert Cheng-Yu Liu ,  Juliana G. Serafin ,  Seyed R. Seyedmonir ,  Hwaili Soo

IPC分类号： B01J27/055 ,  B01J32/00 ,  B01J37/08 ,  B01J27/25

CPC分类号： B01J23/50 ,  B01J21/04 ,  B01J21/12 ,  B01J23/66 ,  B01J23/688 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/06

摘要： An improved carrier useful for preparing a catalyst having excellent catalytic performance when used in the production of alkylene oxide, such as ethylene oxide. The carrier is obtained by a) impregnating a preformed alpha-alumina carrier with at least one modifier selected from among alkali metal silicates and alkaline earth metal silicates, b) drying the impregnated carrier; and c) calcining dried carrier. The carrier may optionally be washed, prior to being impregnated by conventional catalytic material and/or promoter material.

摘要翻译： 一种改进的载体，可用于制备当用于生产环氧烷烃如环氧乙烷时具有优异催化性能的催化剂。 载体通过以下方法获得：a）用至少一种选自碱金属硅酸盐和碱土金属硅酸盐的改性剂浸渍预制的α-氧化铝载体，b）干燥浸渍的载体; 和c）煅烧干燥的载体。 在用常规催化材料和/或促进剂材料浸渍之前，载体可以任选地被洗涤。

公开(公告)号：US20140088316A1

公开(公告)日：2014-03-27

申请号：US13624131

申请日：2012-09-21

申请人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/02 ,  B01J23/68 ,  C07C41/02 ,  C07C29/10 ,  C07C209/16 ,  B01J23/66 ,  C07D301/10

CPC分类号： B01J27/055 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/688 ,  B01J35/0013 ,  B01J35/006 ,  B01J35/023 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0244 ,  B01J37/16 ,  C07C209/60 ,  C07D301/10 ,  Y02P20/52

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

摘要翻译： 负载型银催化剂及其在通过氧气或含氧气体直接氧化亚烷基的环氧乙烷生产方法中的用途，其中催化剂提供改进的稳定性和改善对反应器不稳定性的回弹性， 及时恢复，以大大预测催化剂活性和/或效率的水平。 在一些实施方案中，催化剂还表现出改进的活性。 能够以至少87％的选择性生产环氧乙烷的催化剂，同时在不高于235℃的温度下实现至少184kg / h / m3的工作速率，当在进料进料至 含有催化剂的反应器包括乙烯，氧气和二氧化碳，其中入口进料中二氧化碳的浓度大于或等于2摩尔％。

公开(公告)号：US10159961B2

公开(公告)日：2018-12-25

申请号：US13624131

申请日：2012-09-21

申请人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： B01J27/055 ,  C07D301/10 ,  B01J37/02 ,  B01J37/16 ,  B01J21/04 ,  B01J23/50 ,  B01J23/58 ,  B01J23/68 ,  C07C209/60 ,  B01J35/02 ,  B01J35/00

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

公开(公告)号：US20090177000A1

公开(公告)日：2009-07-09

申请号：US12297331

申请日：2007-04-17

申请人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

发明人： Manuel A. W. Natal ,  Madan M. Bhasin ,  Hwaili Soo ,  Albert C. Liu

IPC分类号： C07D301/10 ,  B01J23/66 ,  B01J23/68 ,  B01J27/051 ,  B01J27/02 ,  B01J21/04 ,  B01J37/02

CPC分类号： B01J23/688 ,  B01J21/04 ,  B01J37/0205 ,  B01J37/024 ,  B01J37/06 ,  C07D301/10 ,  Y02P20/52

摘要： A supported silver catalyst and use thereof in a process for producing an alkylene oxide, such as ethylene oxide, by the direct oxidation of an alkylene with oxygen or an oxygen-containing gas, wherein the catalyst provides improved stability and improved resilience to reactor upsets and timely recovery to substantially pre-upset levels of catalyst activity and/or efficiency. In some embodiments, the catalyst also exhibits improved activity. A catalyst capable of producing ethylene oxide at a selectivity of at least 87 percent while achieving a work rate of at least 184 kg/h/m3 at a temperature of no greater than 235° C. when operated in a process where the inlet feed to a reactor containing the catalyst comprises ethylene, oxygen, and carbon dioxide, wherein the concentration of carbon dioxide in the inlet feed is greater than or equal to 2 mole percent.

摘要翻译： 负载型银催化剂及其在通过氧气或含氧气体直接氧化亚烷基的环氧乙烷生产方法中的用途，其中催化剂提供改进的稳定性和改善对反应器不稳定性的回弹性， 及时恢复，以大大预测催化剂活性和/或效率的水平。 在一些实施方案中，催化剂还表现出改进的活性。 能够以至少87％的选择性生产环氧乙烷的催化剂，同时在不高于235℃的温度下实现至少184kg / h / m3的工作速率，当在进料进料至 含有催化剂的反应器包括乙烯，氧气和二氧化碳，其中入口进料中二氧化碳的浓度大于或等于2摩尔％。

公开(公告)号：US08845975B2

公开(公告)日：2014-09-30

申请号：US12974439

申请日：2010-12-21

申请人： William H. Henstock ,  Juliana G. Serafin ,  Albert C. Liu ,  Hwaili Soo ,  Yujun Liu ,  Manuk Colakyan ,  Sagar Petkar

发明人： William H. Henstock ,  Juliana G. Serafin ,  Albert C. Liu ,  Hwaili Soo ,  Yujun Liu ,  Manuk Colakyan ,  Sagar Petkar

IPC分类号： B01J8/00 ,  C07D301/03 ,  C07D301/10 ,  C07D301/36 ,  C07D301/32

CPC分类号： C07D301/10 ,  C07D301/32 ,  C07D301/36 ,  Y02P20/582

摘要： A plant and process for producing alkylene oxides to control the production of silver chloride on a high efficiency silver catalyst is disclosed and described. The process involves reacting an alkylene and an organic chloride gas phase promoter with oxygen over the high efficiency silver catalyst. The sulfur concentration in the alkylene oxide reactor feed is controlled to reduce the production of silver chloride which acts as a catalyst poison.

摘要翻译： 公开和描述了一种用于生产烯化氧以控制高效率银催化剂上的氯化银生产的设备和方法。 该方法包括在高效率银催化剂上使亚烷基和有机氯化物气相促进剂与氧反应。 控制环氧烷反应器进料中的硫浓度以减少作为催化剂毒物的氯化银的产生。

公开(公告)号：US20140024846A1

公开(公告)日：2014-01-23

申请号：US13994233

申请日：2011-12-01

申请人： Arun G. Basrur ,  Ravindra R. Tupe ,  Hwaili Soo ,  Paul V. Hinman

发明人： Arun G. Basrur ,  Ravindra R. Tupe ,  Hwaili Soo ,  Paul V. Hinman

IPC分类号： C07D301/10

CPC分类号： C07D301/10 ,  Y02P20/582

摘要： A method for starting-up a high efficiency alkylene oxide catalyst is described. A feed gas comprising an alkylene, oxygen, and at least one organic chloride is introduced to the catalyst. The molar ratio of oxygen to alkylene, reaction temperature, and overall chloriding effectiveness are adjusted to specified ranges of values within a specified catalyst aging period.

摘要翻译： 描述了一种启动高效环氧烷催化剂的方法。 将包含亚烷基，氧和至少一种有机氯化物的进料气体引入催化剂中。 氧气与亚烷基的摩尔比，反应温度和总氯化效果在规定的催化剂老化时段内调整到规定的数值范围。