公开(公告)号：US09718050B2

公开(公告)日：2017-08-01

申请号：US14367260

申请日：2012-11-23

申请人： IFP ENERGIES NOUVELLES

发明人： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC分类号： B01J29/80 ,  C10G47/20 ,  C10G65/12 ,  B01J29/16 ,  B01J29/076

CPC分类号： B01J29/80 ,  B01J29/076 ,  B01J29/14 ,  B01J29/146 ,  B01J29/166 ,  C10G47/20 ,  C10G65/12

摘要： The invention relates to a catalyst comprising at least one metal selected from the group formed by metals of group VIB and of group VIII of the periodic table, used alone or as a mixture, and a support comprising at least one zeolite NU-86, at least one zeolite Y and at least one porous mineral matrix containing at least aluminum and/or at least silicon. The invention also relates to a process for hydrocracking of hydrocarbon feeds employing said catalyst.

公开(公告)号：US10758892B2

公开(公告)日：2020-09-01

申请号：US15749298

申请日：2016-07-26

申请人： IFP Energies Nouvelles

发明人： Audrey Bonduelle ,  Alexandra Chaumonnot ,  Damien Delcroix ,  Christophe Vallee ,  Souad Rafik-Clement ,  Severine Forget

IPC分类号： C07C6/04 ,  B01J23/28 ,  B01J37/02 ,  B01J27/19 ,  B01J23/881 ,  B01J23/882 ,  B01J35/10 ,  B01J37/08 ,  B01J23/885 ,  B01J23/30 ,  B01J23/883 ,  B01J21/04 ,  B01J21/08

摘要： The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and silicon, said elements being incorporated into said matrix by means of at least two precursors of which at least one precursor contains molybdenum and at least one precursor contains silicon.

公开(公告)号：US10322984B2

公开(公告)日：2019-06-18

申请号：US15749368

申请日：2016-07-26

申请人： IFP Energies nouvelles

发明人： Audrey Bonduelle ,  Alexandra Chaumonnot ,  Damien Delcroix ,  Christophe Vallee

IPC分类号： C07C6/04 ,  B01J23/28 ,  B01J27/19 ,  B01J35/10 ,  B01J37/08 ,  B01J37/02 ,  B01J23/00 ,  B01J23/882 ,  B01J37/00 ,  B01J21/02 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

摘要： The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and aluminum, said elements being incorporated into said matrix by means of at least two precursors of which at least one precursor contains molybdenum and at least one precursor contains aluminum.

公开(公告)号：US09925533B2

公开(公告)日：2018-03-27

申请号：US14366292

申请日：2012-11-23

申请人： IFP ENERGIES NOUVELLES

发明人： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC分类号： B01J37/02 ,  B01J29/78 ,  B01J31/02 ,  B01J29/76 ,  C10G47/20 ,  B01J35/00 ,  C10G65/10 ,  C10G47/18

CPC分类号： B01J37/0236 ,  B01J29/76 ,  B01J29/78 ,  B01J31/0201 ,  B01J35/002 ,  B01J37/0201 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/18 ,  C10G47/20 ,  C10G65/10

摘要： The invention relates to a method of preparing a catalyst comprising a) preparation of a support comprising 0.2 to 30 wt % of zeolite NU-86 and from 70 to 99.8 wt % of a porous mineral matrix, the percentages by weight being expressed relative to the total weight of said support, b) impregnation of the support prepared according to step a) with at least one solution containing at least one precursor of at least one metal selected from group VIII metals and group VIB metals, used alone or as a mixture, c) at least one ripening step, and d) at least one drying step carried out at a temperature below 150° C., without a subsequent calcining step. The present invention also relates to a process for hydrocracking hydrocarbon feeds using the catalyst prepared according to the method of preparation according to the invention.

公开(公告)号：US09579642B2

公开(公告)日：2017-02-28

申请号：US14265655

申请日：2014-04-30

申请人： IFP ENERGIES NOUVELLES

发明人： Thibault Alphazan ,  Audrey Bonduelle ,  Christele Legens ,  Pascal Raybaud ,  Christophe Coperet

IPC分类号： B01J37/08 ,  B01J31/26 ,  B01J37/20 ,  B01J37/02 ,  B01J23/30 ,  B01J31/02 ,  B01J31/22 ,  C10G45/08 ,  C10G47/12 ,  B01J23/888 ,  C10G45/00 ,  B01J35/10 ,  B01J37/00

CPC分类号： B01J31/26 ,  B01J23/30 ,  B01J23/888 ,  B01J31/0211 ,  B01J31/0212 ,  B01J31/0228 ,  B01J31/2226 ,  B01J31/2234 ,  B01J35/10 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0213 ,  B01J37/20 ,  B01J2531/64 ,  B01J2531/66 ,  B01J2531/847 ,  C07C2529/072 ,  C07C2529/076 ,  C10G45/00 ,  C10G45/08 ,  C10G47/12

摘要： The invention concerns a process for the preparation of a catalyst based on tungsten intended for hydrotreatment or hydrocracking processes.The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor compound based on tungsten (W), in its monomeric or dimeric form, having at least one W═O or W—OR bond or at least one W═S or W—SR bond where [R═CxHy where x≧1 and (x−1)≦y≦(2x+1) or R═Si(OR′)3 or R═Si(R′)3 where R′═Cx′Hy′ where x′≧1 and (x′−1)≦y′≦(2x′+1)], optionally at least one Mo precursor and optionally at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst advantageously being sulphurized before being deployed in said process.

摘要翻译： 本发明涉及制备用于在加氢处理和加氢裂化过程中进行氢化反应的催化剂的方法。 所述催化剂由至少一种基于钨（W）的单体前体化合物制备，其单体或二聚体形式具有至少一个W = O或W-OR键或至少一个W = S或W-SR键，其中 其中x≥1和（x-1）≤y≤（2x + 1）或R = Si（OR'）3或R = Si（R'）3，其中R'= Cx'Hy'其中x '≧1和（x'-1）≤y'≤（2x'+ 1）]，任选地至少一种Mo前体和任选的至少一种来自VIII族的启动子元件。 所述前体沉积在氧化物载体上，其适用于其使用的方法，所述催化剂有利地在所述方法部署之前进行硫化。

公开(公告)号：US10737254B2

公开(公告)日：2020-08-11

申请号：US15749297

申请日：2016-07-26

申请人： IFP Energies Nouvelles

发明人： Audrey Bonduelle ,  Alexandra Chaumonnot ,  Damien Delcroix ,  Christophe Vallee ,  Souad Rafik-Clement ,  Severine Forget

IPC分类号： C07C6/04 ,  B01J31/22 ,  B01J31/16 ,  B01J35/10 ,  B01J37/02 ,  B01J23/28 ,  B01J27/19 ,  B01J23/882 ,  B01J37/00 ,  B01J37/08 ,  C07C11/02

摘要： The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and silicon, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and silicon and having at least one sequence of Si—O—Mo bonds.

公开(公告)号：US10322983B2

公开(公告)日：2019-06-18

申请号：US15749344

申请日：2016-07-26

申请人： IFP Energies nouvelles

发明人： Audrey Bonduelle ,  Alexandra Chaumonnot ,  Damien Delcroix ,  Christophe Vallee

IPC分类号： C07C6/04 ,  B01J23/28 ,  B01J27/19 ,  B01J37/02 ,  B01J21/02 ,  B01J21/06 ,  B01J21/10 ,  B01J23/12 ,  B01J23/22 ,  B01J23/30 ,  B01J23/882 ,  B01J35/10 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08

摘要： The invention relates to a process for the metathesis of olefins implemented with a catalyst comprising a mesoporous matrix and at least the elements molybdenum and aluminum, said elements being incorporated into said matrix by means of at least one precursor comprising molybdenum and aluminum.

公开(公告)号：US09839903B2

公开(公告)日：2017-12-12

申请号：US14262835

申请日：2014-04-28

申请人： IFP ENERGIES NOUVELLES

发明人： Thibault Alphazan ,  Audrey Bonduelle ,  Christele Legens ,  Pascal Raybaud ,  Christophe Coperet

IPC分类号： B01J23/00 ,  B01J23/883 ,  C07C5/11 ,  C10G47/02 ,  C07C4/06 ,  B01J37/20 ,  B01J37/02 ,  B01J23/28 ,  B01J31/02 ,  B01J31/22 ,  C10G45/08 ,  C10G47/12 ,  B01J23/881 ,  B01J23/882 ,  C10G45/00 ,  C10G45/10 ,  B01J35/10 ,  B01J37/00

CPC分类号： B01J23/883 ,  B01J23/28 ,  B01J23/881 ,  B01J23/882 ,  B01J31/0211 ,  B01J31/0212 ,  B01J31/0228 ,  B01J31/2226 ,  B01J31/2234 ,  B01J35/10 ,  B01J35/1019 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/0213 ,  B01J37/20 ,  B01J2531/64 ,  B01J2531/847 ,  C07C4/06 ,  C07C5/11 ,  C10G45/00 ,  C10G45/08 ,  C10G45/10 ,  C10G47/02 ,  C10G47/12

摘要： The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor based on molybdenum (Mo), in its monomeric or dimeric form, having at least one Mo═O or Mo—OR bond or at least one Mo═S or Mo—SR bond where [R=CxHy where x≧1 and (x−1)≦y≦(2x+1) or R=Si(OR′)3 or R=Si(R′)3 where R′=Cx′Hy′ where x′≧1 and (x′−1)≦y′≦(2x′+1)], and optionally from at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst being dried at a temperature of less than 200° C. then advantageously being sulphurized before being deployed in said process.

公开(公告)号：US20150231615A1

公开(公告)日：2015-08-20

申请号：US14367260

申请日：2012-11-23

申请人： IFP ENERGIES NOUVELLES

发明人： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC分类号： B01J29/80 ,  C10G65/12 ,  C10G47/20

CPC分类号： B01J29/80 ,  B01J29/076 ,  B01J29/14 ,  B01J29/146 ,  B01J29/166 ,  C10G47/20 ,  C10G65/12

摘要： The invention relates to a catalyst comprising at least one metal selected from the group formed by metals of group VIB and of group VIII of the periodic table, used alone or as a mixture, and a support comprising at least one zeolite NU-86, at least one zeolite Y and at least one porous mineral matrix containing at least aluminium and/or at least silicon. The invention also relates to a process for hydrocracking of hydrocarbon feeds employing said catalyst.

摘要翻译： 本发明涉及包含至少一种金属的催化剂，所述金属选自由VIB族金属和元素周期表中的VIII族金属单独使用或作为混合物形成的基团，以及包含至少一种沸石NU-86的载体， 至少一种沸石Y和至少含有至少铝和/或至少硅的多孔矿物基质。 本发明还涉及使用所述催化剂加氢裂解烃进料的方法。

公开(公告)号：US20140326641A1

公开(公告)日：2014-11-06

申请号：US14366292

申请日：2012-11-23

申请人： IFP ENERGIES NOUVELLES

发明人： Audrey Bonduelle ,  Emmanuelle Guillon ,  Magalie Roy-Auberger

IPC分类号： B01J29/78 ,  C10G47/18 ,  C10G47/20

CPC分类号： B01J37/0236 ,  B01J29/76 ,  B01J29/78 ,  B01J31/0201 ,  B01J35/002 ,  B01J37/0201 ,  B01J2229/20 ,  B01J2229/42 ,  C10G47/18 ,  C10G47/20 ,  C10G65/10

摘要： The invention relates to a method of preparing a catalyst comprising a) preparation of a support comprising 0.2 to 30 wt % of zeolite NU-86 and from 70 to 99.8 wt % of a porous mineral matrix, the percentages by weight being expressed relative to the total weight of said support, b) impregnation of the support prepared according to step a) with at least one solution containing at least one precursor of at least one metal selected from group VIII metals and group VIB metals, used alone or as a mixture, c) at least one ripening step, and d) at least one drying step carried out at a temperature below 150° C., without a subsequent calcining step. The present invention also relates to a process for hydrocracking hydrocarbon feeds using the catalyst prepared according to the method of preparation according to the invention.

摘要翻译： 本发明涉及一种制备催化剂的方法，其包括：a）制备包含0.2至30重量％的沸石NU-86和70至99.8重量％的多孔矿物基质的载体，所述重量百分比相对于 所述载体的总重量，b）根据步骤a）制备的载体浸渍至少一种含有至少一种选自Ⅷ族金属和ⅥB族金属的金属的前体的溶液，其单独使用或作为混合物使用， c）至少一个熟化步骤，和d）在低于150℃的温度下进行至少一个干燥步骤，而不用随后的煅烧步骤。 本发明还涉及使用根据本发明的制备方法制备的催化剂加氢裂化烃进料的方法。