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公开(公告)号:US20220168948A1
公开(公告)日:2022-06-02
申请号:US17277486
申请日:2019-09-18
发明人: Bianca WILHELMUS , Norbert NIESSNER
IPC分类号: B29C64/153 , B33Y70/00
摘要: The present invention relates to a process for producing a three-dimensional component by means of selective laser sintering (SLS), wherein a processing temperature Tx is established in a build chamber, and a powder layer consisting of a thermoplastic polymer powder is provided in the build chamber. The thermoplastic polymer powder comprises a blend of a semicrystalline polymer, an amorphous polymer and a polymeric compatibilizer. The polymer powder is then melted in a spatially resolved manner by means of a directed beam of electromagnetic radiation, wherein binding of the regions of the melted and resolidified polymer layer by layer in multiple steps affords a three-dimensional component. In the process of the invention, the temperature in the build chamber during the performance of the individual steps varies by not more than +/−10% from the processing temperature Tx set. In addition, the processing temperature Tx differs by not more than +/−20 K from the processing temperature Tx(A) of a polymer powder comprising the corresponding semicrystalline polymer as the sole polymeric component.
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公开(公告)号:US20220411351A1
公开(公告)日:2022-12-29
申请号:US17641842
申请日:2020-09-17
发明人: Norbert NIESSNER , Bianca WILHELMUS , Achim SCHMIDT-RODENKIRCHEN , Konstantin MIERDEL , Frank NEUNER
摘要: The invention relates to a method for producing styrene monomers by the depolymerisation of polystyrene in the presence of foreign polymers, such as polyolefins. Said method comprises the following steps: a) introducing a polymer composition (A) containing: I) 10 to 99.5% by weight, based on the polymer composition (A), of polystyrene (I); and II) 0.1 to 89.9% by weight of polyolefin (II); and/or III) 0.1 to 4.9% by weight of acrylonitrile-based polymer (III); and/or IV) 0.1 to 4.9% by weight of polyester (IV), into the reaction zone (R) of a pyrolysis reactor (P); b) thermal cracking the polystyrene contained in the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) at a temperature of between 400-1000° C., c) removing the product mixture (G) obtained from the reaction zone (R), d) cooling of the product mixture (G), and e) separating the styrene monomers from the further components.
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公开(公告)号:US20210277232A1
公开(公告)日:2021-09-09
申请号:US16330581
申请日:2017-09-07
IPC分类号: C08L77/02 , C08L55/02 , B33Y10/00 , B33Y70/00 , B33Y40/10 , B29C64/153 , B29C64/314
摘要: The present invention relates to a thermoplastic polymer powder and to the use thereof as material for selective laser sintering (SLS). The polymer powder contains a partially crystalline polymer, an amorphous polymer and a compatibilizing agent, and optionally additional additives and/or auxiliary substances, wherein the partially crystalline polymer, the amorphous polymer and the compatibilizing agent are in the form of a polymer blend. The invention also relates to a method for producing the thermoplastic polymer powder and to a method of selective laser sintering (SLS).
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公开(公告)号:US20210277202A1
公开(公告)日:2021-09-09
申请号:US16614162
申请日:2018-06-05
摘要: The invention relates to a method for economically using styrene-containing plastic waste as raw material for new high-quality plastic products as part of a raw material recycling process, optionally having the steps of pre-treating a styrene-containing starting material, decomposing the styrene-containing starting material in a suitable reactor, discharging and collecting the resulting gases and condensing the low-molecular products in a suitable separator, separating the collected low-molecular components of the previous step by means of a fractioning distillation process, and optionally additionally decomposing the styrene oligomers in a steam cracker.
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公开(公告)号:US20220324777A1
公开(公告)日:2022-10-13
申请号:US17641474
申请日:2020-09-17
发明人: Norbert NIESSNER , Bianca WILHELMUS , Achim SCHMIDT-RODENKIRCHEN , Konstantin MIERDEL , Frank NEUNER
摘要: The invention relates to a process for the preparation of styrene monomers by depolymerising polystyrene, to a device for carrying out the process and to the use of a fluidised bed reactor for the depolymerisation of polystyrene. Said process comprising the following steps: a) feeding a polymer composition (A) containing 60 to 99.9 wt. polystyrene, based on the total weight of the polymer composition (A), into the reaction zone (R) of a pyrolysis reactor (P); b) thermally cracking the polystyrene contained in the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) at a temperature of between 400° C. to 1000° C. to obtain a product mixture (G) containing styrene monomers and other components; c) removing the product mixture (G) obtained in step b) from the reaction zone (R) of the pyrolysis reactor (P); d) cooling the product mixture (G) removed in step c) to obtain a condensed product mixture (K) containing styrene monomers and further components; and e) separating the styrene monomers from the further components of the condensed product mixture (K) obtained in step d), wherein the average residence time (Z) of the polymer composition (A) in the reaction zone (R) of the pyrolysis reactor (P) is from 0.01 sec to 10 sec.
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公开(公告)号:US20220081372A1
公开(公告)日:2022-03-17
申请号:US17419063
申请日:2020-01-07
发明人: Norbert NIESSNER , Bianca WILHELMUS , Hannes KERSCHBAUMER , Michiel VERSWYVEL , Petra INGHELBRECHT , Thomas W. COCHRAN , KyungHo SHON , Mohammed ABBOUD , Ricardo CUETOS , Hans-Dieter SCHWABEN , Jens KATHMANN , Thad URQUHART , Timothy A. BROWN , Tim WONG , Walter DE VET , Hans-Werner SCHMIDT , Andreas SCHEDL , Tristan KOLB
摘要: The invention relates to an improved process for providing purified styrenic monomers, such as styrene, from styrene-containing polymer waste. Styrene-containing waste is depolymerized in a suitable reactor, and the depolymerization products are condensed and separated in a three-step distillation process.
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公开(公告)号:US20220033593A1
公开(公告)日:2022-02-03
申请号:US17277484
申请日:2019-09-18
发明人: Bianca WILHELMUS , Norbert NIESSNER
IPC分类号: C08J3/12 , C08L23/06 , C08L23/12 , C08L23/16 , C08L25/10 , C08L25/12 , C08L25/14 , C08L53/00 , C08L55/02 , C08K3/36 , C08J3/00 , B29C64/153
摘要: The invention relates to a thermoplastic polymer powder and to the use thereof as material for selective laser sintering (SLS). The polymer powder contains a semi-crystalline polyolefin, an amorphous styrene-polymer and a selected polymeric compatibilizer, in addition to optionally further additives and/or auxiliary agents. The semi-crystalline polymer, amorphous polymer and selected polymeric compatibilizer are present in the polymer powder in the form of a polymer blend. The invention also relates to a method for producing the thermoplastic polymer powder and to a method for selective laser sintering (SLS) using the polymer powder according to the invention.
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