公开(公告)号：US20160312022A1

公开(公告)日：2016-10-27

申请号：US15104797

申请日：2014-12-18

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Frank EISENTRAEGER ,  Stephanie BAUMANN ,  Itana RADOVANOVIC ,  Hans-Werner SCHMIDT ,  Josef MEINERS ,  Florian WIEBERGER

IPC: C08L25/12 ,  B33Y40/00 ,  B33Y50/02 ,  B33Y70/00 ,  B29C67/00 ,  B33Y10/00

Abstract: Thermoplastic moulding composition for 3D printing containing a polymer mixture A made of components a and b: a being from 30 to 95% by weight of at least one vinylaromatic copolymer a with average molar mass Mw from 150 000 to 360 000 g/mol, b being from 5 to 70% by weight of at least one impact modifier b, where the viscosity of the moulding composition (measured in accordance with ISO 11443) at shear rates of from 1 to 10 l/sec and at a temperature of 250° C. is not higher than 1×105 Pa*s and the Melt Volume Rate (MVR, measured in accordance with ISO 1133 for 220° C. and 10 kg load) is more than 6 ml/10 min.

Abstract translation: 含有由a和b组分组成的聚合物混合物A的3D印刷用热塑性成型组合物：a为30至95重量％的至少一种乙烯基芳族共聚物a，平均摩尔质量Mw为150,000至360,000g / mol，b 为至少一种抗冲改性剂b的5至70重量％，其中在1至10升/秒的剪切速率和250℃的温度下模塑组合物的粘度（根据ISO 11443测量） 不高于1×105Pa * s，熔体体积率（MVR，根据ISO 1133测定，220℃和10kg负荷）大于6ml / 10分钟。

公开(公告)号：US20170044355A1

公开(公告)日：2017-02-16

申请号：US15305838

申请日：2015-04-24

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Frank EISENTRAEGER ,  Norbert NIESSNER ,  Eugen WIEDEL

IPC: C08L9/06 ,  C23C18/34 ,  C23C18/16 ,  C23C18/24 ,  C08L25/12 ,  C08L69/00

CPC classification number: C08L9/06 ,  C08L25/12 ,  C08L69/00 ,  C08L2205/025 ,  C08L2205/03 ,  C08L2207/04 ,  C23C18/1641 ,  C23C18/1653 ,  C23C18/2086 ,  C23C18/24 ,  C23C18/34 ,  C08L55/02

Abstract: A thermoplastic molding composition can be used for metal plating, in particular for electroplating, comprising the components A) to C): A) 20 to 55 wt. % of at least one graft rubber copolymer (A), B) 20 to 55 wt. % of at least one rubber free SAN copolymer, and C) 25 to 34% by weight of at least one aromatic polycarbonate; the metal-plated polymer composition can be used for automotive applications.

Abstract translation: 热塑性模塑组合物可用于金属电镀，特别是用于电镀，包括组分A）至C）：A）20至55wt。 ％的至少一种接枝橡胶共聚物（A），B）20〜55wt。 ％的至少一种无橡胶SAN共聚物，和C）25至34重量％的至少一种芳族聚碳酸酯; 金属镀覆的聚合物组合物可用于汽车应用。

公开(公告)号：US20190135990A1

公开(公告)日：2019-05-09

申请号：US16307339

申请日：2017-06-06

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Gisbert MICHELS ,  Ulrich JANSEN ,  Frank EISENTRAEGER ,  Stefan KAMINSKY

IPC: C08J3/215 ,  C08K5/00 ,  C08K5/13 ,  C08K5/372 ,  C08L55/02 ,  C08L83/04 ,  C08F279/04

Abstract: The invention relates to a process for producing a stabilizer dispersion S, wherein the stabilizer dispersion is an aqueous composition comprising at least one phenolic stabilizer A, at least one thio co-stabilizer B, at least one surfactant C and at least one silicon oil component D. Further the present invention is directed to a process for producing a thermoplastic moulding composition, in particular an composition based on acrylonitrile butadiene styrene copolymers (ABS), using the stabilizer dispersion S.

公开(公告)号：US20160319122A1

公开(公告)日：2016-11-03

申请号：US15105853

申请日：2014-12-18

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Frank EISENTRAEGER

IPC: C08L53/02 ,  B33Y70/00 ,  B33Y10/00 ,  C08L25/06 ,  B29C67/00

CPC classification number: C08L53/02 ,  B29C64/00 ,  B29C64/106 ,  B29K2025/00 ,  B29K2025/04 ,  B29K2105/0005 ,  B33Y10/00 ,  B33Y70/00 ,  C08L25/04

Abstract: The invention relates to the use of molding materials for 3-D printing, containing components A, B1, B2, and C, wherein: A:5 to 100 wt % of at least one vinyl aromatic/diene block copolymer A, containing: a) 30 to 95 wt % of at least one vinyl aromatic and b) 5 to 70 wt % of at least one diene, B1:0 to 95 wt % of at least one polymer B1 selected from the group comprising standard polystyrene, high-impact polystyrene (HIPS), styrene/acrylonitrile copolymers, α-methylstyrene/acrylonitrile copolymers, styrene/maleic anhydride copolymers, styrene/phenylmaleimide copolymers, styrene/methylmethacrylate copolymers, styrene/acrylonitrile/maleic anhydride copolymers, styrene/acrylonitrile/phenylmaleimide copolymers, methylstyrene/acrylonitrile/methylmethacrylate copolymers, α-methylstyrene/acrylonitrile/t-butyl methacrylate copolymers, and styrene/acrylonitrile/t-butyl methacrylate copolymers, B2:0 to 60 wt % of one or more further polymers B2 selected from: polycarbonates, polyamides, poly(meth)acrylates, polyesters, semicrystalline polyolefins, and polyvinyl chloride, C:0 to 50 wt % of common additives and auxiliary agents, wherein the viscosity (measured as per ISO 11443) of the molding material at shear rates of 1 to 10 1/s and at temperatures of 250° C. is not greater than 1×105 Pa*s and the melt volume rate (MVR, measured as per ISO 1133 at 220° C. and 10 kg load) is more than 6 ml/10 min.

Abstract translation: 本发明涉及成型材料在含有A，B1，B2和C组分的3-D印刷中的用途，其中：A：5至100重量％的至少一种乙烯基芳族二烯嵌段共聚物A，其含有： ）30至95重量％的至少一种乙烯基芳族化合物和b）5-70重量％的至少一种二烯，B1：0至95重量％的至少一种选自包含标准聚苯乙烯，高冲击 聚苯乙烯（HIPS），苯乙烯/丙烯腈共聚物，α-甲基苯乙烯/丙烯腈共聚物，苯乙烯/马来酸酐共聚物，苯乙烯/苯基马来酰亚胺共聚物，苯乙烯/甲基丙烯酸甲酯共​​聚物，苯乙烯/丙烯腈/马来酸酐共聚物，苯乙烯/丙烯腈/苯基马来酰亚胺共聚物，甲基苯乙烯/ 丙烯腈/甲基丙烯酸甲酯共​​聚物，α-甲基苯乙烯/丙烯腈/甲基丙烯酸叔丁酯共聚物，和苯乙烯/丙烯腈/甲基丙烯酸叔丁酯共聚物，B2：0-60重量％的一种或多种另外的聚合物B2，其选自聚碳酸酯，聚酰胺，聚 （m 乙基）丙烯酸酯，聚酯，半结晶聚烯烃和聚氯乙烯，C：0至50重量％的常用添加剂和助剂，其中模塑材料的剪切速率为1至10升/秒的粘度（根据ISO 11443测量） 并且在250℃的温度下不大于1×105Pa·s，熔体体积率（MVR，根据ISO 1133在220℃和10kg负荷下测量）大于6ml / 10分钟 。

公开(公告)号：US20210355310A1

公开(公告)日：2021-11-18

申请号：US17278392

申请日：2019-09-23

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Gisbert MICHELS ,  Frank EISENTRAEGER ,  Shridhar MADHAV ,  Kirit GEVARIA ,  Pratik BHAVSAR ,  KwanHee LEE

IPC: C08L25/12

Abstract: A heat resistant ABS thermoplastic molding composition with reduced odor can be employed for automotive interior applications if it comprises a graft copolymer (A) based on a diene rubber latex substrate with a SAN graft sheath; a SAN matrix polymer (B) and specific amounts of additives such as fatty acid amides or fatty acid esters,metal oxides such as MgO, CaO or ZnO, antioxidants and a silicon oil having a kinematic viscosity in the range of from 25000 to 80000 centi Stokes.

公开(公告)号：US20210139698A1

公开(公告)日：2021-05-13

申请号：US17252148

申请日：2019-06-11

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Gisbert MICHELS ,  Frank EISENTRAEGER ,  HanBok SONG ,  Shridhar MADHAV ,  Kirit GEVARIA ,  Pankaj BHARADWAJ

IPC: C08L69/00

Abstract: High heat resistant impact modified polycarbonate blend for use in the industrial, household and automotive sector comprising (A) 10 to 40 wt.-% ABS graft copolymer; (B) 25 to 50 wt.-% aromatic polycarbonate; (C) 20 to 40 wt.-% omethylstyrene/acrylonitrile copolymer; (D) 10 to 25 wt.-% terpolymer of vinylaromatic monomer, a, 13 ethylenically unsaturated dicarboxylic cyclic anhydride, and Ci-C3-alkyl-(meth)acrylate; and (E) 0.3 to 5 wt.-% further additives and/or processing aids.

公开(公告)号：US20210087379A1

公开(公告)日：2021-03-25

申请号：US17115164

申请日：2020-12-08

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Stephanie BAUMANN ,  Frank EISENTRAEGER ,  Josef MEINERS ,  Norbert NIESSNER ,  Hans-Werner SCHMIDT

IPC: C08L25/12 ,  C08K5/098 ,  C08K5/20 ,  B33Y70/00 ,  C08L55/02 ,  B29C64/00

Abstract: A thermoplastic molding composition can be employed for 3D printing if it comprises: A: 92.9 to 98.59 wt % of impact-modified polymer A, consisting of: 40 to 90 wt % of vinylaromatic copolymer a, 10 to 60 wt % of ABS graft copolymer b; B1: 1.2 to 3.5 wt % of amide or amide derivative of saturated higher fatty acid having 14 to 22 carbon atoms; B2: 0.2 to 0.6 wt % of salt of saturated higher fatty acid having 14 to 22 carbon atoms; and C: 0.01 to 3 wt % of auxiliaries C such as stabilizers, oxidation retarders, agents against heat and UV light decomposition.

公开(公告)号：US20210277232A1

公开(公告)日：2021-09-09

申请号：US16330581

申请日：2017-09-07

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Bianca WILHELMUS ,  Norbert NIESSNER ,  Viktor WIEBE ,  Frank EISENTRAEGER

IPC: C08L77/02 ,  C08L55/02 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y40/10 ,  B29C64/153 ,  B29C64/314

Abstract: The present invention relates to a thermoplastic polymer powder and to the use thereof as material for selective laser sintering (SLS). The polymer powder contains a partially crystalline polymer, an amorphous polymer and a compatibilizing agent, and optionally additional additives and/or auxiliary substances, wherein the partially crystalline polymer, the amorphous polymer and the compatibilizing agent are in the form of a polymer blend. The invention also relates to a method for producing the thermoplastic polymer powder and to a method of selective laser sintering (SLS).

公开(公告)号：US20190092952A1

公开(公告)日：2019-03-28

申请号：US16084330

申请日：2017-03-16

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Stephanie BAUMANN ,  Frank EISENTRAEGER ,  Josef MEINERS ,  Norbert NIESSNER ,  Hans-Werner SCHMIDT

IPC: C09D11/106 ,  C09D11/102 ,  B33Y70/00

Abstract: The invention relates to the use of a thermoplastic moulding compound for 3D Printing, made of a mixture of the following components A-E: A: 35-60 wt. % impact resistant modified polymer A comprising: 30-95 wt. % SAN-copolymer and 5-70 wt. % ABS-graft copolymer; B: 33-58 wt. % aliphatic polyamide B; C: 1-10 wt. % SANMSA-terpolymer C as a compatibilizing agent; D: 0.01-5 wt. % processing agent D; and E: 0-30 wt. % other additives E.

公开(公告)号：US20190077948A1

公开(公告)日：2019-03-14

申请号：US16084354

申请日：2017-03-16

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Stephanie BAUMANN ,  Frank EISENTRAEGER ,  Josef MEINERS ,  Norbert NIESSNER ,  Hans-Werner SCHMIDT

IPC: C08L25/12 ,  C08L55/02 ,  C08K5/20 ,  C08K5/098

Abstract: A thermoplastic molding composition can be employed for 3D printing if it comprises: A: 92.9 to 98.59 wt % of impact-modified polymer A, consisting of: 40 to 90 wt % of vinylaromatic copolymer a, 10 to 60 wt % of ABS graft copolymer b; B1: 1.2 to 3.5 wt % of amide or amide derivative of saturated higher fatty acid having 14 to 22 carbon atoms; B2: 0.2 to 0.6 wt % of salt of saturated higher fatty acid having 14 to 22 carbon atoms; and C: 0.01 to 3 wt % of auxiliaries C such as stabilizers, oxidation retarders, agents against heat and UV light decomposition.