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    Aromatic sulfonic acid ester derivative, polyarylene, polyarylene having sulfonic acid group and process for producing the same, and polymer solid electrolyte and proton-conductive membrane
    1.
    发明授权
    Aromatic sulfonic acid ester derivative, polyarylene, polyarylene having sulfonic acid group and process for producing the same, and polymer solid electrolyte and proton-conductive membrane 有权
    芳族磺酸酯衍生物，聚亚芳基，具有磺酸基的聚亚芳基及其制备方法，以及聚合物固体电解质和质子传导膜

    公开(公告)号：US07163988B2

    公开(公告)日：2007-01-16

    申请号：US10642694

    申请日：2003-08-19

    申请人： Igor Rozhanskii ,  Masayuki Takahashi ,  Kohei Goto ,  Yousuke Konno ,  Toshihiro Ohtsuki ,  Yoshitaka Yamakawa ,  Toshiaki Kadota

    发明人： Igor Rozhanskii ,  Masayuki Takahashi ,  Kohei Goto ,  Yousuke Konno ,  Toshihiro Ohtsuki ,  Yoshitaka Yamakawa ,  Toshiaki Kadota

    IPC分类号： C08F283/08 ,  C08G61/10

    CPC分类号： C08G61/12 ,  C07C309/73 ,  C07C309/75

    摘要： Disclosed is an aromatic sulfonic acid ester derivative represented by the formula (1); in the formula, X is an atom or a group selected from a halogen atom excluding fluorine, —OSO3CH3 and —OSO3CF3, A is a divalent electron attractive group, B is a divalent electron donating group or a direct bonding, Ra is a hydrocarbon group of 1 to 20 carbon atoms, Ar is an aromatic group having a substituent of —SO3Rb (wherein Rb is a hydrocarbon group of 1 to 20 carbon atoms), m is an integer of 0 to 10, n is an integer of 0 to 10 and k is an integer of 1 to 4. Also disclosed is a process for producing a polyarylene having a sulfonic acid group, which process comprises the steps of coupling polymerization of an aromatic compound containing the derivative of the formula (1), to prepare a polyarylene and hydrolysis of the polyarylene, and which process has high safety and is easily capable of controlling the amount of sulfonoc acid group introduced into a polymer and the introducing position thereof.

    摘要翻译： 公开了由式（1）表示的芳族磺酸酯衍生物; 在该式中，X是选自除氟以外的卤素原子的原子或基团，-OSO 3 CH 3和-OSO 3 CF A是二价吸电子基团，B是二价给电子基团或直接键合，R a是1-20个碳原子的烃基，Ar 是具有-SO 3 R b的取代基的芳香族基团（其中R b为1〜20个碳原子的烃基）， m为0〜10的整数，n为0〜10的整数，k为1〜4的整数。还公开了具有磺酸基的聚亚芳基的制造方法，该方法包括使聚合 的含有式（1）的衍生物的芳族化合物，以制备聚亚芳基并且聚亚芳基的水解，并且该方法具有高安全性并且易于控制引入聚合物的磺酸基团的量和引入位置 那里 F。

    Aromatic compound and polyarylene copolymer having nitrogen-containing heterocycle including sulfonic acid group in side chain
    5.
    发明授权
    Aromatic compound and polyarylene copolymer having nitrogen-containing heterocycle including sulfonic acid group in side chain 有权
    具有侧链含有磺酸基的含氮杂环的芳香族化合物和聚亚芳基共聚物

    公开(公告)号：US08309678B2

    公开(公告)日：2012-11-13

    申请号：US12600742

    申请日：2008-05-16

    申请人： Toshiaki Kadota ,  Yoshitaka Yamakawa

    发明人： Toshiaki Kadota ,  Yoshitaka Yamakawa

    IPC分类号： C08G75/00

    CPC分类号： H01M8/1067 ,  C08G61/10 ,  C08G61/12 ,  C08G65/4006 ,  C08G65/4025 ,  C08G65/4037 ,  C08G65/4056 ,  C08G2261/126 ,  C08G2261/1452 ,  C08G2261/3442 ,  C08G2261/35 ,  C08G2261/516 ,  H01B1/122 ,  H01M8/1027 ,  H01M8/1032

    摘要： Provided is a solid polymer electrolyte having increased heat resistance and high proton conductivity and a proton conductive membrane composed of the electrolyte. Also provided is a copolymer having a sulfonic acid group. The copolymer includes a repeating unit represented by Formula (1): (in the formula, Y denotes at least one kind of structure selected from the group consisting of —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)l— (l is an integer of 1 to 10), and —C(CF3)2—; W denotes at least one kind of structure selected from the group consisting of a direct bond, —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)l— (l is an integer of 1 to 10), —C(CF3)2—, —O—, and —S—; Z denotes a direct bond or at least one kind of structure selected from the group consisting of —(CH2)l— (l is an integer of 1 to 10), —C(CH3)2—, —O—, —S—, —CO—, and —SO2—; R30 denotes a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —O(CH2)hSO3H, or —O(CF2)hSO3H (h is an integer of 1 to 12); p is an integer of 0 to 10; q is an integer of 0 to 10; r is an integer of 1 to 5; and k is an integer of 0 to 4).

    摘要翻译： 提供了具有增加的耐热性和高质子传导性的固体聚合物电解质和由电解质组成的质子传导膜。 还提供了具有磺酸基的共聚物。 共聚物包括由式（1）表示的重复单元：（式中，Y表示选自-CO - ， - SO 2 - ， - SO - ， - CONH - ， - COO - ， - （CF 2）1 - （1是1至10的整数）和-C（CF 3）2 - ; W表示选自直接键，-CO-， -SO 2 - ， - CO - ， - CO - ， - （CF 2）1 - （1是1至10的整数），-C（CF 3）2 - ， - O-和-S-; Z表示直接键或至少一种选自 - （CH 2）1 - （1为1至10的整数），-C（CH 3）2 - ， - O - ， - S - ，-CO-和-SO 2 - ; R 30表示具有-SO 3 H，-O（CH 2）h SO 3 H或-O（CF 2）h SO 3 H（h为1〜12的整数）表示的取代基的含氮芳香环， ; p为0〜10的整数，q为0〜10的整数，r为1〜5的整数，k为0〜4的整数。

    Sulfonated polymer having nitrile-containing hydrophobic block and solid polymer electrolyte
    6.
    发明申请
    Sulfonated polymer having nitrile-containing hydrophobic block and solid polymer electrolyte 有权
    具有含腈疏水嵌段和固体聚合物电解质的磺化聚合物

    公开(公告)号：US20050080220A1

    公开(公告)日：2005-04-14

    申请号：US10958622

    申请日：2004-10-06

    申请人： Yoshitaka Yamakawa ,  Makoto Higami ,  Toshiaki Kadota

    发明人： Yoshitaka Yamakawa ,  Makoto Higami ,  Toshiaki Kadota

    IPC分类号： C08G61/12 ,  C07C255/54 ,  C08G65/00 ,  C08G65/40 ,  C08G65/48 ,  C08J5/22 ,  H01B1/06 ,  H01M8/02 ,  H01M8/10 ,  C08G2/00

    CPC分类号： C07C255/54 ,  C08G61/12 ,  C08G65/40 ,  C08G65/4006 ,  C08G65/48 ,  C08J5/2256 ,  C08J2365/02 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M2300/0082

    摘要： Provided are a sulfonated polymer capable of high hot water resistance even if it has an increased amount of the sulfonic groups introduced therein, and a solid polymer electrolyte containing the sulfonated polymer that has high proton conductivity and excellent generating performance. The sulfonated polymer has repeating units represented by the formula (1′): wherein B's are each independently an oxygen or a sulfur atom, R1 to R3 may be the same or different and are selected from a hydrogen atom, a fluorine atom, a nitrile group and an alkyl group, n is an integer of 2 or greater, and Q is a structure represented by the formula (q): wherein A is independently a divalent atom or organic group or a direct bond, and R4 to R11 may be the same or different and are selected from a hydrogen atom, a fluorine atom, an alkyl group and an aromatic group.

    摘要翻译： 即使其中引入的磺酸基的量增加，也能够具有高耐热水性的磺化聚合物，以及含有高质子传导性和优异发生性能的磺化聚合物的固体高分子电解质。 磺化聚合物具有由式（1'）表示的重复单元：其中B各自独立地为氧或硫原子，R 1至R 3可以相同或不同，并且选自氢原子， 氟原子，腈基和烷基，n为2以上的整数，Q为式（q）所示的结构：其中A独立地为二价原子或有机基团或直接键合，以及 R 4〜R 11可以相同或不同，选自氢原子，氟原子，烷基和芳基。

    Sulfonated polymer having nitrile-containing hydrophobic block and solid polymer electrolyte
    7.
    发明授权
    Sulfonated polymer having nitrile-containing hydrophobic block and solid polymer electrolyte 有权
    具有含腈疏水嵌段和固体聚合物电解质的磺化聚合物

    公开(公告)号：US07115699B2

    公开(公告)日：2006-10-03

    申请号：US10958622

    申请日：2004-10-06

    申请人： Yoshitaka Yamakawa ,  Makoto Higami ,  Toshiaki Kadota

    发明人： Yoshitaka Yamakawa ,  Makoto Higami ,  Toshiaki Kadota

    IPC分类号： C08G75/00 ,  C08G65/38 ,  C08G67/00

    CPC分类号： C07C255/54 ,  C08G61/12 ,  C08G65/40 ,  C08G65/4006 ,  C08G65/48 ,  C08J5/2256 ,  C08J2365/02 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M2300/0082

    摘要： Provided are a sulfonated polymer capable of high hot water resistance even if it has an increased amount of the sulfonic groups introduced therein, and a solid polymer electrolyte containing the sulfonated polymer that has high proton conductivity and excellent generating performance.The sulfonated polymer has repeating units represented by the formula (1′): wherein B's are each independently an oxygen or a sulfur atom, R1 to R3 may be the same or different and are selected from a hydrogen atom, a fluorine atom, a nitrile group and an alkyl group, n is an integer of 2 or greater, and Q is a structure represented by the formula (q): wherein A is independently a divalent atom or organic group or a direct bond, and R4 to R11 may be the same or different and are selected from a hydrogen atom, a fluorine atom, an alkyl group and an aromatic group.

    摘要翻译： 即使其中引入的磺酸基的量增加，也能够具有高耐热水性的磺化聚合物，以及含有高质子传导性和优异发生性能的磺化聚合物的固体高分子电解质。 磺化聚合物具有由式（1'）表示的重复单元：其中B各自独立地为氧或硫原子，R 1至R 3可以相同 或不同，选自氢原子，氟原子，腈基和烷基，n为2以上的整数，Q为式（q）所示的结构：其中A独立地为二价 原子或有机基团或直接键合，R 4至R 11可以相同或不同，并且选自氢原子，氟原子，烷基 和芳香族基团。

    AROMATIC COPOLYMER HAVING PROTON CONDUCTIVE GROUP AND USES THEREOF
    8.
    发明申请
    AROMATIC COPOLYMER HAVING PROTON CONDUCTIVE GROUP AND USES THEREOF 审中-公开
    具有导电组的芳族共聚物及其用途

    公开(公告)号：US20140154610A1

    公开(公告)日：2014-06-05

    申请号：US14235656

    申请日：2012-07-27

    申请人： Takuya Murakami ,  Toshiaki Kadota ,  Yoshitaka Yamakawa

    发明人： Takuya Murakami ,  Toshiaki Kadota ,  Yoshitaka Yamakawa

    IPC分类号： H01M8/10

    CPC分类号： H01M8/1023 ,  C08G61/12 ,  C08G61/126 ,  C08G65/4006 ,  C08G2261/1428 ,  C08G2261/143 ,  C08G2261/1452 ,  C08G2261/312 ,  C08G2261/344 ,  C08G2261/412 ,  C08G2261/516 ,  C08J5/2256 ,  H01B1/122 ,  H01M8/1025 ,  H01M8/1027 ,  H01M2008/1095

    摘要： An aromatic copolymer comprises a hydrophilic segment (A) and a hydrophobic segment (B), wherein the hydrophilic segment (A) comprises a structural unit (1) having a proton conductive group, and the hydrophobic segment (B) comprises at least one structural unit selected from the group consisting of a structural unit (2) and a structural unit (3), wherein the structural unit (2) is a divalent structural unit having an aromatic ring and no proton conductive groups and having two bonding sites at the para-position of one ring included in the aromatic ring, and the structural unit (3) is a divalent structural unit having a benzene ring and is a structural unit different from the structural unit (2), the hydrophobic segment (B) in its entirety contained in the aromatic copolymer including both the structural unit (2) and the structural unit (3).

    摘要翻译： 芳族共聚物包括亲水链段（A）和疏水链段（B），其中亲水链段（A）包含具有质子传导基团的结构单元（1），疏水链段（B）包含至少一个结构 选自由结构单元（2）和结构单元（3）组成的组的单元，其中所述结构单元（2）是具有芳环且不具有质子传导性基团的二价结构单元，并且在所述结构单元 包含在芳环中的一个环的位置，结构单元（3）是具有苯环的二价结构单元，并且是与结构单元（2）不同的结构单元，疏水性区段（B）的整体 包含在包括结构单元（2）和结构单元（3）的芳族共聚物中。

    NOVEL AROMATIC COMPOUND AND POLYARYLENE COPOLYMER HAVING NITROGEN-CONTAINING HETEROCYCLE INCLUDING SULFONIC ACID GROUP IN SIDE CHAIN
    10.
    发明申请
    NOVEL AROMATIC COMPOUND AND POLYARYLENE COPOLYMER HAVING NITROGEN-CONTAINING HETEROCYCLE INCLUDING SULFONIC ACID GROUP IN SIDE CHAIN 有权
    新型芳族化合物和具有含氮单体的聚亚烷基共聚物，包括侧链中的磺酸基

    公开(公告)号：US20100152308A1

    公开(公告)日：2010-06-17

    申请号：US12600742

    申请日：2008-05-16

    申请人： Toshiaki Kadota ,  Yoshitaka Yamakawa

    发明人： Toshiaki Kadota ,  Yoshitaka Yamakawa

    IPC分类号： B01J41/12 ,  C07D211/72

    CPC分类号： H01M8/1067 ,  C08G61/10 ,  C08G61/12 ,  C08G65/4006 ,  C08G65/4025 ,  C08G65/4037 ,  C08G65/4056 ,  C08G2261/126 ,  C08G2261/1452 ,  C08G2261/3442 ,  C08G2261/35 ,  C08G2261/516 ,  H01B1/122 ,  H01M8/1027 ,  H01M8/1032

    摘要： Provided is a solid polymer electrolyte having increased heat resistance and high proton conductivity and a proton conductive membrane composed of the electrolyte. Also provided is a copolymer having a sulfonic acid group. The copolymer includes a repeating unit represented by Formula (1): (in the formula, Y denotes at least one kind of structure selected from the group consisting of —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)l— (l is an integer of 1 to 10), and —C(CF3)2—; W denotes at least one kind of structure selected from the group consisting of a direct bond, —CO—, —SO2—, —SO—, —CONH—, —COO—, —(CF2)l— (l is an integer of 1 to 10), —C(CF3)2—, —O—, and —S—; Z denotes a direct bond or at least one kind of structure selected from the group consisting of —(CH2)l—(l is an integer of 1 to 10), —C(CH3)2—, —O—, —S—, —CO—, and —SO2—; R30 denotes a nitrogen-containing aromatic ring having a substituent represented by —SO3H, —O(CH2)hSO3H, or —O(CF2)hSO3H (h is an integer of 1 to 12); p is an integer of 0 to 10; q is an integer of 0 to 10; r is an integer of 1 to 5; and k is an integer of 0 to 4).

    摘要翻译： 提供了具有增加的耐热性和高质子传导性的固体聚合物电解质和由电解质组成的质子传导膜。 还提供了具有磺酸基的共聚物。 共聚物包括由式（1）表示的重复单元：（式中，Y表示选自-CO - ， - SO 2 - ， - SO - ， - CONH - ， - COO - ， - （CF 2）1 - （1是1至10的整数）和-C（CF 3）2 - ; W表示选自直接键，-CO-， -SO 2 - ， - CO - ， - CO - ， - （CF 2）1 - （1是1至10的整数），-C（CF 3）2 - ， - O-和-S-; Z表示直接键或至少一种选自 - （CH 2）1 - （1为1至10的整数），-C（CH 3）2 - ， - O - ， - S - ，-CO-和-SO 2 - ; R 30表示具有-SO 3 H，-O（CH 2）h SO 3 H或-O（CF 2）h SO 3 H（h为1〜12的整数）表示的取代基的含氮芳香环， ; p为0〜10的整数，q为0〜10的整数，r为1〜5的整数，k为0〜4的整数。