摘要:
A coating for use on a superalloy substrate comprising a diffusion barrier as an intermediate layer overlying the substrate and underlying a protective coating having a high aluminum content. The diffusion barrier layer is characterized by having low solubility for aluminum from either the substrate or the protective coating. Further, the diffusion barrier layer has low interdiffusivity for elements from the substrate and the coating, a minimal impact on the mechanical properties of the article which is coated, a minimal thermal expansion mismatch with both the substrate and the high aluminum content protective coating, and can be applied readily using existing coating application techniques. The diffusion barrier is preferably a single phase alloy or intermetallic compound.
摘要:
A diffusion barrier coating includes, in an exemplary embodiment, a composition selected from the group consisting of a solid-solution alloy comprising rhenium and ruthenium wherein the ruthenium comprises about 50 atom % or less of the composition and where a total amount of rhenium and ruthenium is greater than 70 atom %; an intermetallic compound including at least one of Ru(TaAl) and Ru2TaAl, where Ru(TaAl) has a B2 structure and Ru2TaAl has a Heusler structure; and an oxide dispersed in a metallic matrix wherein greater than about 50 volume percent of the matrix comprises the oxide.
摘要:
One exemplary embodiment of a turbine component (which may be a blade) comprises a substrate comprising a silicide-based material, a plurality of through holes disposed in the substrate, the holes being configured to receive an airflow, a silicide coating disposed at the surfaces of the substrate and the through holes, and a thermal barrier coating disposed at the silicide coating. In another exemplary embodiment the silicide coating may be replaced by a Laves phase-containing layer. In still another exemplary embodiment the silicide coating may be replaced by a diffusion barrier layer disposed at a surface of the substrate and a platinum group metal layer disposed at the diffusion barrier layer. One exemplary embodiment of a blade may comprise an airfoil comprising a silicide-based material and through holes disposed therein, a cooling plenum disposed in the airfoil, and a base configured to receive the airfoil in a dovetail fit, the base comprising a superalloy.
摘要:
A turbine engine component comprising a substrate made of a nickel-base or cobalt-base superalloy and a protective coating overlying the substrate, the coating formed by electroplating at least two platinum group metals selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium. The protective coating is typically heat treated to increase homogeneity of the coating and adherence with the substrate. The component typically further comprises a ceramic thermal barrier coating overlying the protective coating. Also disclosed are methods for forming the protective coating on the turbine engine component by electroplating the platinum group metals.
摘要:
An article for use in a hot gas path of a gas turbine assembly, a metallic skin for such an article, and a method for making such an article are presented with, for example, the article comprising a spar, the spar providing mechanical support for the article and comprising a cooling fluid delivery system, a top end, and a bottom end; a standoff structure attached to the spar, the standoff structure comprising a plurality of spacing elements in a spaced-apart relation to each other, the spacing elements having first ends adjacent to the spar and second ends opposite to the first ends; a skin conformally surrounding the spar and the standoff structure, the skin comprising a top end and a bottom end, wherein the standoff structure separates the spar and the skin, wherein the plurality of spacing elements is disposed with an inner surface of the skin adjacent to the second ends of the spacing elements to form a plurality of plena between the spar and the skin, the plena in fluid communication with the cooling fluid delivery system, the skin comprising at least one metal selected from the group consisting of Rh, Pd, and Pt; and a base connecting the bottom end of the spar and the bottom end of the skin.
摘要:
An oxidation-resistant coating is described, formed of an alloy containing: about 40 to about 50 atom % aluminum and about 0.5 atom % to about 3 atom % tantalum; with a balance of nickel; cobalt, iron, or combinations thereof. The coating may also include chromium and a precious metal, as well as other components, such as zirconium or molybdenum. A method for applying the oxidation-resistant coating to a substrate is also described. The substrate can be formed of superalloy material, e.g., a turbine engine component. Related articles are also disclosed.
摘要:
A group of alloys suitable for use in a high-temperature, oxidative environment, a protective coating system comprising a diffusion barrier that comprises an alloy selected from the group, an article comprising the diffusion barrier layer, and a method for protecting an article from a high-temperature oxidative environment comprising disposing the diffusion barrier layer onto a substrate are presented.
摘要:
A turbine engine component comprising a substrate made of a nickel-base or cobalt-base superalloy and a protective coating overlying the substrate, the coating formed by electroplating at least two platinum group metals selected from the group consisting of platinum, palladium, rhodium, ruthenium and iridium. The protective coating is typically heat treated to increase homogeneity of the coating and adherence with the substrate. The component typically further comprises a ceramic thermal barrier coating overlying the protective coating. Also disclosed are methods for forming the protective coating on the turbine engine component by electroplating the platinum group metals.
摘要:
An environmentally resistant coating comprising silicon, titanium, chromium, and a balance of niobium and molybdenum for turbine components formed from molybdenum silicide-based composites. The turbine component may further include a thermal barrier coating disposed upon an outer surface of the environmentally resistant coating comprising zirconia, stabilized zirconia, zircon, mullite, and combinations thereof. The molybdenum silicide-based composite turbine component coated with the environmentally resistant coating and thermal barrier coating is resistant to oxidation at temperatures in the range from about 2000° F. to about 2600° F. and to pesting at temperatures in the range from about 1000° F. to about 1800° F.
摘要:
Disclosed herein is a hydrogen storage material comprising a metal hydride and an organic hydrogen carrier. Also disclosed herein is a hydrogen storage/fuel cell system which employs the hydrogen storage material.