公开(公告)号：US20060148640A1

公开(公告)日：2006-07-06

申请号：US10531420

申请日：2003-10-15

申请人： Jacques Roziere ,  Deborah Jones ,  Melanie Jacquin ,  Stefano Rossini ,  Roberto Catani ,  Angelo Vaccari ,  Maurizio Lenarda ,  Antonio Jimenez-Lopez ,  Jose-Manuel Trejo-Menayo ,  Enrique Rodriguez-Castellon ,  Pedro Mairelles-Torres

发明人： Jacques Roziere ,  Deborah Jones ,  Melanie Jacquin ,  Stefano Rossini ,  Roberto Catani ,  Angelo Vaccari ,  Maurizio Lenarda ,  Antonio Jimenez-Lopez ,  Jose-Manuel Trejo-Menayo ,  Enrique Rodriguez-Castellon ,  Pedro Mairelles-Torres

IPC分类号： B01J29/04

CPC分类号： B01J29/043 ,  B01J21/12 ,  B01J23/40 ,  B01J23/464 ,  B01J23/755 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/044 ,  B01J35/002 ,  C10G50/00

摘要： The present invention relates to the use of a silicon-based porous catalytic system for oligomerizing light olefins, the porous silicon-based catalytic system having an average pore diameter of between about 1 nm and about 5 nm and an acidity level of between about 150 μmol/g and about 650 μmol/g, and prepared from at least one hydrolysable silicon-based compound, or other source of silicon, and at least one non-ionic surface active agent. The invention also relates to a process for oligomerizing light olefins using the silicon-based porous catalytic system, and to certain silicon-based porous catalytic systems.

摘要翻译： 本发明涉及硅基多孔催化体系用于低聚烯烃的用途，多孔硅基催化体系的平均孔径在约1nm至约5nm之间，酸度水平介于约150μmol之间 并且由至少一种可水解的硅基化合物或其它硅源生成，以及至少一种非离子表面活性剂。 本发明还涉及使用硅基多孔催化体系和某些硅基多孔催化体系低聚烯烃的方法。

公开(公告)号：US20050156622A1

公开(公告)日：2005-07-21

申请号：US10512296

申请日：2003-04-21

申请人： Jacques Roziere ,  Deborah Jones ,  Melanie Jacquin ,  Antonio Jimenez-Lopez ,  Enrique Rodriguez-Castellon ,  Pedro Maireles-Torres ,  Jose-Manuel Trejo-Menayo ,  Angelo Vaccari ,  Maurizio Lenarda ,  Guido Busca

发明人： Jacques Roziere ,  Deborah Jones ,  Melanie Jacquin ,  Antonio Jimenez-Lopez ,  Enrique Rodriguez-Castellon ,  Pedro Maireles-Torres ,  Jose-Manuel Trejo-Menayo ,  Angelo Vaccari ,  Maurizio Lenarda ,  Guido Busca

IPC分类号： G01R31/28 ,  G01R31/319 ,  H03K19/00

CPC分类号： G01R31/31922

摘要： A semiconductor test device for acquiring a multiplexed clock signal from LSI output data and using the clock to test the LSI. The device includes a time interpolator 30 and registers 41a to 41n connected in series. The time interpolator has flip-flops 31a to 31n connected in parallel for inputting output data from an LSI 1 to be measured, a delay circuit 32 for successively inputting strobes delayed at a constant timing interval to the flip-flops 31 and outputting time-series level data, and an encoder 34 for inputting the time-series level data output from the flip-flops 31 and encoding it into position data indicating an edge timing. The registers 41a to 41n successively store position data from the encoder 34 and output them at a predetermined timing. The device further includes a digital filter for outputting the position data output from the registers 41 as a recovery clock.

摘要翻译： 一种用于从LSI输出数据获取多路复用时钟信号并使用时钟测试LSI的半导体测试装置。 该装置包括串联连接的时间插入器30和寄存器41a至41n。 时间插值器具有并联连接的触发器31a至31n，用于输入来自要测量的LSI1的输出数据;延迟电路32，用于将以恒定定时间隔延迟的选通脉冲输入到触发器31，并输出时间 - 系列电平数据，以及编码器34，用于输入从触发器31输出的时间序列电平数据，并将其编码为指示边沿定时的位置数据。 寄存器41a至41n依次存储来自编码器34的位置数据，并以预定的定时输出。 该装置还包括数字滤波器，用于将从寄存器41输出的位置数据作为恢复时钟输出。

公开(公告)号：US20050181930A1

公开(公告)日：2005-08-18

申请号：US10503381

申请日：2003-01-31

申请人： Jacques Roziere ,  Deborah Jones ,  Melanie Jacquin ,  Antonio Jimenez-Lopez ,  Enrique Rodriguez-Castellon ,  Pedro Maireles-Torres ,  Jose-Manuel Trejo-Menayo ,  Angelo Vaccari ,  Maurizio Lenarda ,  Guido Busca

发明人： Jacques Roziere ,  Deborah Jones ,  Melanie Jacquin ,  Antonio Jimenez-Lopez ,  Enrique Rodriguez-Castellon ,  Pedro Maireles-Torres ,  Jose-Manuel Trejo-Menayo ,  Angelo Vaccari ,  Maurizio Lenarda ,  Guido Busca

IPC分类号： B01J21/08 ,  B01J29/04 ,  B01J37/03 ,  C10G45/48 ,  C10G45/52

CPC分类号： B01J29/042 ,  B01J21/08 ,  B01J29/0316 ,  B01J29/043 ,  B01J37/033 ,  B01J37/036 ,  C10G2400/04

摘要： A process of preparation of silicon-based multifunctional catalytic systems synthesised together with one or more surface active agents is described. Also described is a multifunctional silicon-based porous catalytic system including at least one porous catalytic support structurally including silica and at least one other metal or non-metal oxide chosen from aluminium, zirconium, and boron. The catalytic support is synthesised together with one or more surface active agents, and at least one or more catalyst chosen from among metallic elements of groups 6-10 of the periodic table of the elements. The catalytic systems are useful in hydrogenation and/or decyclisation reactions of (poly)aromatic compounds, especially for improving the quality of diesel fuels and increasing their cetane number.

摘要翻译： 描述了与一种或多种表面活性剂一起制备的硅基多功能催化体系的制备方法。 还描述了一种多功能硅基多孔催化体系，其包括至少一种结构上包含二氧化硅和选自铝，锆和硼的至少一种其它金属或非金属氧化物的多孔催化剂载体。 催化载体与一种或多种表面活性剂和至少一种或多种选自元素周期表的6-10族金属元素的催化剂一起合成。 催化体系可用于（多）芳族化合物的氢化和/或二环化反应，特别是用于改善柴油燃料的质量和增加其十六烷值。

公开(公告)号：US20120149548A1

公开(公告)日：2012-06-14

申请号：US13324429

申请日：2011-12-13

申请人： Daniel Gary ,  Pascal Del-Gallo ,  Francesco Basile ,  Angelo Vaccari ,  Giuseppe Fornasari ,  Valentina Rosetti ,  Erika Scavetta ,  Domenica Tonelli

发明人： Daniel Gary ,  Pascal Del-Gallo ,  Francesco Basile ,  Angelo Vaccari ,  Giuseppe Fornasari ,  Valentina Rosetti ,  Erika Scavetta ,  Domenica Tonelli

IPC分类号： B01J37/34 ,  B01J23/83 ,  B01J23/89 ,  C01B3/40 ,  B01J21/02

CPC分类号： B01J23/002 ,  B01J23/007 ,  B01J23/464 ,  B01J23/755 ,  B01J23/83 ,  B01J23/892 ,  B01J23/894 ,  B01J37/08 ,  B01J37/349 ,  B01J2523/00 ,  C01B3/386 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/822 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/842 ,  B01J2523/847

摘要： Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An−z/n) kH2O.

摘要翻译： 用于制备基本上由金属载体组成的催化剂的方法，该金属载体涂覆有陶瓷活性相，主要是通式（I）的化合物：[RhxNiyMglAlm（OH）2] z +（An-z / n） kH2O。

公开(公告)号：US08105973B2

公开(公告)日：2012-01-31

申请号：US12949289

申请日：2010-11-18

申请人： Francesco Basile ,  Pascal Del Gallo ,  Giuseppe Fornasari ,  Daniel Gary ,  Valentina Rosetti ,  Angelo Vaccari

发明人： Francesco Basile ,  Pascal Del Gallo ,  Giuseppe Fornasari ,  Daniel Gary ,  Valentina Rosetti ,  Angelo Vaccari

IPC分类号： B01J21/06 ,  C01B3/26

CPC分类号： C01B3/40 ,  B01J23/002 ,  B01J23/005 ,  B01J23/892 ,  B01J37/08 ,  B01J2523/00 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01P2002/72 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/822 ,  B01J2523/847

摘要： Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf  (I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d≠0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase.Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.

摘要翻译： 在与惰性固相表面共价结合的活性固相之间的化学组合（C），其特征在于所述固体活性相基本上由至少一种氧化镁型相化合物的混合物和 至少一种其中Al和Rh和/或Ni阳离子被溶解并表征的硅酸镁型相化合物，其特征在于所述惰性固相是由通式（I）表示的化合物：AlaNibRhcMgdSieOf（I）其中a，b， c，d和e是大于或等于0的整数，f是大于0的整数，和a + b + c + d≠0，其中（3a + 2b + 3c + 2d + 4e） / 2 = f或由所述通式（I）表示的化合物的混合物，条件是存在于固体活性相中的Si，Al，Mg，Rh或Ni元素中的至少一种也存在 在固体惰性相中。 在涉及烃类原料转化的化学反应中使用催化剂。

公开(公告)号：US08092716B2

公开(公告)日：2012-01-10

申请号：US12160376

申请日：2007-01-10

申请人： Daniel Gary ,  Pascal Del-Gallo ,  Francesco Basile ,  Angelo Vaccari ,  Giuseppe Fornasari ,  Valentina Rosetti ,  Erika Scavetta ,  Domenica Tonelli

发明人： Daniel Gary ,  Pascal Del-Gallo ,  Francesco Basile ,  Angelo Vaccari ,  Giuseppe Fornasari ,  Valentina Rosetti ,  Erika Scavetta ,  Domenica Tonelli

IPC分类号： C05D5/02 ,  C01B3/26

CPC分类号： B01J23/002 ,  B01J23/007 ,  B01J23/464 ,  B01J23/755 ,  B01J23/83 ,  B01J23/892 ,  B01J23/894 ,  B01J37/08 ,  B01J37/349 ,  B01J2523/00 ,  C01B3/386 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/822 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/842 ,  B01J2523/847

摘要： Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An−z/n)kH2O,  (I) wherein An− is mainly a silicate or a polysilicate anion; 0≦x≦0.3; 0≦y≦0.9; 0≦l≦0.9; 0≦m≦0.5; 0≦k≦10; x+y>0; 0.5≦y+l≦0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA′1-z][B1-x-yNixRhy]O3-δ  (II) wherein A and A′ are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0≦x≦0.7, 0≦y≦0.5, 0≦x+y≦0.8, 0≦z≦1 and is the sub stoechiometric value of oxygen to obtain the electric neutrality of the Perovskite compound; said process essentially consisting in a step (a) of electro-deposition of said ceramic active phase on said metallic support. Use of said catalytic specie as a catalyst oxidation of gaseous hydrocarbons, to produce synthesis gas.

摘要翻译： 用于制备基本上由金属载体组成的催化剂的方法，该金属载体涂覆有陶瓷活性相，主要是通式（I）的化合物：[RhxNiyMglAlm（OH）2] z +（An-z / n） kH 2 O，（I）其中An-主要是硅酸盐或聚硅酸盐阴离子; 0＆nlE; x＆nlE; 0.3; 0＆nlE; y＆nlE; 0.9; 0＆nlE; l＆nlE; 0.9; 0＆nlE; m＆nlE; 0.5; 0＆nlE; k＆nlE; 10; x + y> 0; 0.5＆nlE; y + 1＆nlE; 0.9; x + y + l + m = 1; 并且z是阳离子元素或通式（II）的化合物的总电荷：其中A和A'不同的[AzA'1-z] [B1-x-yNixRhy] O3-δ（II） 选自镧系元素或锕系元素族，或选自门德列夫元素周期表IIa族; B选自门多列夫元素周期表第IIIb，IVb，Vb，VIb，VIIb，Ib和IIb族和VIIIb族的过渡金属组; 0＆nlE; x＆nlE; 0.7,0和nlE; y＆nlE; 0.5,0和nlE; x + y＆nlE; 0.8,0和nlE; z＆nlE; 1并且是氧的亚微观值，以获得钙钛矿化合物的电中性; 所述方法基本上包括将所述陶瓷活性相电沉积在所述金属载体上的步骤（a）。 使用所述催化剂作为气态烃的催化剂氧化，产生合成气。

公开(公告)号：US07329691B2

公开(公告)日：2008-02-12

申请号：US10712691

申请日：2003-11-13

申请人： Francesco Basile ,  Giuseppe Fornasari ,  Angelo Vaccari ,  Pascal Del Gallo ,  Daniel Gary

发明人： Francesco Basile ,  Giuseppe Fornasari ,  Angelo Vaccari ,  Pascal Del Gallo ,  Daniel Gary

IPC分类号： C07C27/06 ,  C07C27/00 ,  B01J23/00 ,  B01J23/40 ,  B01J23/42

CPC分类号： C01B3/40 ,  B01J23/002 ,  B01J23/63 ,  B01J23/83 ,  B01J23/894 ,  B01J23/8946 ,  B01J2523/00 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/044 ,  C01B2203/1052 ,  C01B2203/1064 ,  Y02P20/142 ,  Y02P20/52 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/822 ,  B01J2523/842 ,  B01J2523/847

摘要： A composition and method for a Catalytic Partial Oxidation (CPO) of methane to synthesis gas. The catalyst allows the process to proceed at low residence time providing a long time thermal stability. The perovskite structure [AzA′1-z][B1-x-yNix Rhy] O3-δ of the catalyst is obtained using mainly La, Sr, as A and A′ cation sites (A, A′: actinide and/or lanthanide, elements and/or elements from Group I and II) and mainly Fe, Ni, as B cation sites (B: transition metal element and/or element from Group III to V).

摘要翻译： 甲烷对合成气的催化部分氧化（CPO）的组成和方法。 催化剂允许该方法在低停留时间下进行，提供长时间的热稳定性。 钙钛矿结构[A 1 Z 1 -Z 1] - [B 1-xy N 2 N z N 2 使用主要为La，Sr作为A和A'阳离子位点（A，A'：锕系元素和/或镧系元素，元素和/或镧系元素）获得催化剂的O 3-δ /或来自组I和II的元素）和主要是Fe，Ni，作为B阳离子位点（B：过渡金属元素和/或从III至V族的元素）。

公开(公告)号：US5698713A

公开(公告)日：1997-12-16

申请号：US696871

申请日：1997-02-20

申请人： Rosa Lancia ,  Angelo Vaccari ,  Carlo Fumagalli ,  Erich Armbruster

发明人： Rosa Lancia ,  Angelo Vaccari ,  Carlo Fumagalli ,  Erich Armbruster

IPC分类号： C07D307/33 ,  B01J23/80 ,  C07B61/00 ,  C07D315/00 ,  C07D307/26

CPC分类号： C07D315/00

摘要： Disclosed is a process for the production of gamma-butyrolactone from maleic anhydride or succinic anhydride by hydrogenation in the presence of a catalyst composition comprising the mixed oxides of copper, zinc and zirconium.

摘要翻译： PCT No.PCT / EP95 / 00589 371日期1997年2月20日 102（e）日期1997年2月20日PCT提交1995年2月17日PCT公布。 公开号WO95 / 22539 日期1995年8月24日公开是在包含铜，锌和锆的混合氧化物的催化剂组合物的存在下，通过氢化从马来酸酐或琥珀酸酐制备γ-丁内酯的方法。

公开(公告)号：US20110118112A1

公开(公告)日：2011-05-19

申请号：US12949289

申请日：2010-11-18

申请人： Francesco Basile ,  Pascal Del Gallo ,  Giuseppe Fornasari ,  Daniel Gary ,  Valentina Rosetti ,  Angelo Vaccari

发明人： Francesco Basile ,  Pascal Del Gallo ,  Giuseppe Fornasari ,  Daniel Gary ,  Valentina Rosetti ,  Angelo Vaccari

IPC分类号： B01J21/10

CPC分类号： C01B3/40 ,  B01J23/002 ,  B01J23/005 ,  B01J23/892 ,  B01J37/08 ,  B01J2523/00 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0261 ,  C01B2203/1011 ,  C01B2203/1023 ,  C01B2203/1052 ,  C01B2203/1064 ,  C01P2002/72 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/822 ,  B01J2523/847

摘要： Chemical combination (C) between an active solid phase which is covalently bound to the surface of an inert solid phase, characterized in that said solid active phase essentially consists in a solid solution of a mixture of at least a magnesium oxide type phase compound and at least a magnesium silicate type phase compound in which Al, and Rh and/or Ni cations are soluted and characterized in that said inert solid phase is either a compound represented by the general formula (I): AlaNibRhcMgdSieOf  (I) wherein a, b, c, d, and e are integers which are greater than or equal to 0, f is an integer greater than 0, the sum a+b+c+d≠0, and wherein (3a+2b+3c+2d+4e)/2=f, or a mixture of compounds represented by the said general formula (I), provided that at least one of the Si, Al, Mg, Rh or Ni elements, which is present in the solid active phase, is also present in the solid inert phase. Use of a catalyst in chemical reactions involving the conversion of hydrocarbonaceous feedstocks.

摘要翻译： 在与惰性固相表面共价结合的活性固相之间的化学组合（C），其特征在于所述固体活性相基本上由至少一种氧化镁型相化合物的混合物和 至少一种其中Al和Rh和/或Ni阳离子被溶解并表征的硅酸镁型相化合物，其特征在于所述惰性固相是由通式（I）表示的化合物：AlaNibRhcMgdSieOf（I）其中a，b， c，d和e是大于或等于0的整数，f是大于0的整数，和a + b + c + d≠0，其中（3a + 2b + 3c + 2d + 4e） / 2 = f或由所述通式（I）表示的化合物的混合物，条件是存在于固体活性相中的Si，Al，Mg，Rh或Ni元素中的至少一种也存在 在固体惰性相中。 在涉及烃类原料转化的化学反应中使用催化剂。

公开(公告)号：US20110017953A1

公开(公告)日：2011-01-27

申请号：US12160376

申请日：2007-01-10

申请人： Daniel Gary ,  Pascal Del-Gallo ,  Francesco Basile ,  Angelo Vaccari ,  Giuseppe Fornasari ,  Valentina Rosetti ,  Erika Scavetta ,  Domenica Tonelli

发明人： Daniel Gary ,  Pascal Del-Gallo ,  Francesco Basile ,  Angelo Vaccari ,  Giuseppe Fornasari ,  Valentina Rosetti ,  Erika Scavetta ,  Domenica Tonelli

IPC分类号： B01J23/58 ,  B01J21/06 ,  B01J23/10 ,  C01B3/38

CPC分类号： B01J23/002 ,  B01J23/007 ,  B01J23/464 ,  B01J23/755 ,  B01J23/83 ,  B01J23/892 ,  B01J23/894 ,  B01J37/08 ,  B01J37/349 ,  B01J2523/00 ,  C01B3/386 ,  C01B3/40 ,  C01B2203/0261 ,  C01B2203/1058 ,  C01B2203/1064 ,  C01B2203/1082 ,  Y02P20/52 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/41 ,  B01J2523/822 ,  B01J2523/3706 ,  B01J2523/3712 ,  B01J2523/842 ,  B01J2523/847

摘要： Process for the preparation of a catalytic specie consisting essentially of a metallic support, which is coated with a ceramic active phase layer, mainly compound of the general formula (I): [RhxNiyMglAlm(OH)2]z+(An−z/n)kH2O,  (I) wherein An− is mainly a silicate or a polysilicate anion; 0≦x≦0.3; 0≦y≦0.9; 0≦l≦0.9; 0≦m≦0.5; 0≦k≦10; x+y>0; 0.5≦y+l≦0.9; x+y+l+m=1; and z is the total electrical charge of the cationic element or a compound of the general formula (II): [AzA′1-z][B1-x-yNixRhy]O3-δ  (II) wherein A and A′ are different and are selected from the Lanthanide or the Actinide families or from the group IIa of the Mendeleev's periodical table of elements; B is selected from the transition metal groups of columns IIIb, IVb, Vb, VIb, VIIb, Ib and IIb and group VIIIb of the Mendeleev's periodical table of elements; 0≦x≦0.7, 0≦y≦0.5, 0≦x+y≦0.8, 0≦z≦1 and is the sub stoechiometric value of oxygen to obtain the electric neutrality of the Perovskite compound; said process essentially consisting in a step (a) of electro-deposition of said ceramic active phase on said metallic support. Use of said catalytic specie as a catalyst oxidation of gaseous hydrocarbons, to produce synthesis gas.

摘要翻译： 用于制备基本上由金属载体组成的催化剂的方法，该金属载体涂覆有陶瓷活性相，主要是通式（I）的化合物：[RhxNiyMglAlm（OH）2] z +（An-z / n） kH 2 O，（I）其中An-主要是硅酸盐或聚硅酸盐阴离子; 0＆nlE; x＆nlE; 0.3; 0＆nlE; y＆nlE; 0.9; 0＆nlE; l＆nlE; 0.9; 0＆nlE; m＆nlE; 0.5; 0＆nlE; k＆nlE; 10; x + y> 0; 0.5＆nlE; y + 1＆nlE; 0.9; x + y + l + m = 1; 并且z是阳离子元素或通式（II）的化合物的总电荷：其中A和A'不同的[AzA'1-z] [B1-x-yNixRhy] O3-δ（II） 选自镧系元素或锕系元素族，或选自门德列夫元素周期表IIa族; B选自门多列夫元素周期表第IIIb，IVb，Vb，VIb，VIIb，Ib和IIb族和VIIIb族的过渡金属组; 0＆nlE; x＆nlE; 0.7,0和nlE; y＆nlE; 0.5,0和nlE; x + y＆nlE; 0.8,0和nlE; z＆nlE; 1并且是氧的亚微观值，以获得钙钛矿化合物的电中性; 所述方法基本上包括将所述陶瓷活性相电沉积在所述金属载体上的步骤（a）。 使用所述催化剂作为气态烃的催化剂氧化，产生合成气。