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1.发明授权Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process 有权控制在含氧化合物中产生的乙烯与丙烯的比例对烯烃转化过程公开(公告)号：US07199276B2
公开(公告)日：2007-04-03
申请号：US10717006
申请日：2003-11-19
申请人： Jaimes Sher , Cornelis F. Van Egmond , Luc R. M. Martens , Mechilium Johannes Janssen , James R. Lattner , Teng Xu
发明人： Jaimes Sher , Cornelis F. Van Egmond , Luc R. M. Martens , Mechilium Johannes Janssen , James R. Lattner , Teng Xu
CPC分类号： C07C29/1518 , C07C1/20 , C07C29/1512 , C07C2529/85 , Y02P30/42 , C07C11/02 , C07C31/04 , C07C31/08
摘要： The present invention provides various processes for producing methanol and ethanol, preferably in a mixed alcohol stream. In one embodiment, the invention includes directing syngas to a synthesis zone wherein the syngas contacts a methanol synthesis catalyst and an ethanol synthesis catalyst (either a homologation catalyst or a fuel alcohol synthesis catalyst) under conditions effective to form methanol and ethanol. The methanol and ethanol, in a desired ratio, are directed to an oxygenate to olefin reaction system for conversion thereof to ethylene and propylene in a desired ratio. The invention also relates to processes for varying the weight ratio of ethylene to propylene formed in an oxygenate to olefin reaction system.
摘要翻译： 本发明提供用于生产甲醇和乙醇的各种方法，优选在混合的醇流中。 在一个实施方案中，本发明包括将合成气引导至合成区，其中合成气在有效形成甲醇和乙醇的条件下与甲醇合成催化剂和乙醇合成催化剂（同系催化剂或燃料醇合成催化剂）接触。 以所需的比例将甲醇和乙醇引导至含氧化合物至烯烃反应体系，以将其转化为所需比例的乙烯和丙烯。 本发明还涉及改变在含氧化合物至烯烃反应体系中形成的乙烯与丙烯的重量比的方法。
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公开(公告)号：US07754933B2
公开(公告)日：2010-07-13
申请号：US11807450
申请日：2007-05-29
CPC分类号： B01J29/85 , B01J29/90 , B01J38/02 , C07C1/20 , C07C2529/85 , Y02P20/52 , Y02P20/584 , C07C11/02
摘要： This invention is directed to a method of rejuvenating a molecular sieve that has decreased catalytic activity as a result of contact with moisture, and a method of using the rejuvenated catalyst to make an olefin product from methanol feed. The molecular sieve can be rejuvenated by heating at a rate sufficient to increase the catalytic activity of the molecular sieve. The molecular sieve is considered to be rejuvenated when the molecular sieve has a CMCPS that is increased by at least 5% relative to that at a heat rate basis of 40° C./min over a temperature range of from 25° C. to 475° C.
摘要翻译： 本发明涉及一种由于与水分接触而使具有降低的催化活性的分子筛再生的方法，以及使用再生催化剂从甲醇进料制备烯烃产物的方法。 分子筛可以通过以足以增加分子筛的催化活性的速度加热来回复。 当分子筛具有相对于在25℃至475℃的温度范围内以40℃/分钟的热速率升高至少5％的CMCPS时，分子筛被认为是恢复活力的 C。
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公开(公告)号：US07223896B2
公开(公告)日：2007-05-29
申请号：US10835494
申请日：2004-04-29
申请人： Luc R. M. Martens , James R. Lattner , Rutton D. Patel , David C. Skouby , Stephen Neil Vaughn , Yun-feng Chang , Jesse F. Goellner , Mareel J. Janssen , Richard C. Senior
发明人： Luc R. M. Martens , James R. Lattner , Rutton D. Patel , David C. Skouby , Stephen Neil Vaughn , Yun-feng Chang , Jesse F. Goellner , Mareel J. Janssen , Richard C. Senior
CPC分类号： B01J8/1809 , B01J8/0025 , B01J2208/00672 , B01J2208/00752 , B01J2208/00769 , C07C1/20 , C10G3/42 , C10G3/45 , C10G3/47 , C10G3/49 , C10G2300/703 , C10G2400/20 , Y02P30/20 , C07C11/02
摘要： This invention provides processes for maintaining a desired particle size distribution in an oxygenate to olefin reaction system. In one embodiment, the invention comprises replacing lost catalyst fines with less active co-catalyst particles. By adding less active co-catalyst particles to the reaction system, desirable fluidization characteristics and hydrodynamics can be maintained without affecting the overall (or primary catalyst) performance and product selectivities. The invention is also directed to a population of catalyst particles having a desirable particle size distribution well-suited for realizing ideal fluidization and hydrodynamic characteristics.
摘要翻译： 本发明提供了在含氧化合物至烯烃反应体系中维持所需粒度分布的方法。 在一个实施方案中，本发明包括用较少活性的助催化剂颗粒代替失去的催化剂细粉。 通过将更少的活性助催化剂颗粒加入到反应体系中，可以保持所需的流化特性和流体动力学，而不影响总体（或初级催化剂）性能和产物选择性。 本发明还涉及具有适合于实现理想的流化和流体动力特性的理想粒度分布的催化剂颗粒群。
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公开(公告)号：US06797851B2
公开(公告)日：2004-09-28
申请号：US09943610
申请日：2001-08-30
IPC分类号： C07C1207
CPC分类号： C07C1/20 , C07C2529/80 , Y02P30/42 , C07C11/02
摘要： This invention is to a process of making olefin, particularly ethylene and propylene, from an oxygenate feed. The invention uses two or more zeolite catalysts. Examples of zeolite catalysts include a first catalyst containing of ZSM-5, and a second catalyst containing a 10-ring molecular sieve, including but not limited to, ZSM-22, ZSM-23, ZSM35, ZSM-48, and mixtures thereof. The ZSM-5 can be unmodified, phosphorous modified, steam modified having a micropore volume reduced to not less than 50% of that of the unsteamed ZSM-5, or various mixtures thereof.
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公开(公告)号：US07230151B2
公开(公告)日：2007-06-12
申请号：US10891975
申请日：2004-07-15
IPC分类号： C07C1/20
CPC分类号： C07C1/20 , C07C2529/80 , Y02P30/42 , C07C11/02
摘要： This invention is to a process of making olefin, particularly ethylene and propylene, from an oxygenate feed. The invention uses two or more zeolite catalysts. Examples of zeolite catalysts include a first catalyst containing of ZSM-5, and a second catalyst containing a 10-ring molecular sieve, including but not limited to, ZSM-22, ZSM-23, ZSM35, ZSM-48, and mixtures thereof. The ZSM-5 can be unmodified, phosphorous modified, steam modified having a micropore volume reduced to not less than 50% of that of the unsteamed ZSM-5, or various mixtures thereof.
摘要翻译： 本发明是由含氧化合物进料制备烯烃，特别是乙烯和丙烯的方法。 本发明使用两种或更多种沸石催化剂。 沸石催化剂的实例包括含有ZSM-5的第一催化剂和含有10环分子筛的第二催化剂，包括但不限于ZSM-22，ZSM-23，ZSM35，ZSM-48及其混合物。 ZSM-5可以是未改性的，磷改性的，蒸汽改性的，具有减小到不少于未蒸发的ZSM-5或其各种混合物的50％的微孔体积。
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6.发明授权Method for improving light olefin selectivity in an oxygenate conversion reaction 有权改善含氧化合物转化反应中轻烯烃选择性的方法公开(公告)号：US06482999B2
公开(公告)日：2002-11-19
申请号：US09251142
申请日：1999-02-17
申请人： Shun C. Fung , James R. Lattner , Stephen N. Vaughn , Richard B. Hall , Hsiang-Ning Sun , Ron G. Searle , Luc R. M. Martens
发明人： Shun C. Fung , James R. Lattner , Stephen N. Vaughn , Richard B. Hall , Hsiang-Ning Sun , Ron G. Searle , Luc R. M. Martens
IPC分类号： C07C1207
CPC分类号： B01J38/12 , B01J29/04 , B01J29/85 , B01J29/90 , C07C1/20 , C07C2529/85 , C10G3/49 , C10G3/50 , C10G3/57 , C10G3/62 , C10G2300/708 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y10S585/905 , Y10S585/906 , C07C11/02
摘要： A method for converting oxygenates to light olefins. The method comprises contacting, in a reactor, a feedstock comprising oxygenates with a molecular sieve catalyst under conditions effective to convert the feedstock to a product including light olefins and by-products, the contacting causing carbonaceous deposits to form on at least a portion of the molecular sieve catalyst producing deactivated catalyst; removing a portion of the deactivated catalyst from the reactor; regenerating the portion of the deactivated catalyst under conditions effective to remove at least a portion of the carbonaceous deposits from the deactivated catalyst to form an at least partially regenerated catalyst; exposing at least a portion of the at least partially regenerated catalyst to at least a portion of the by-products to selectivate the portion of the at least partially regenerated catalyst to form light olefins; and contacting the selectivated portion of the at least partially regenerated catalyst with the feedstock to form the product.
摘要翻译： 将含氧物转化为轻质烯烃的方法。 该方法包括在反应器中将包含含氧化合物的原料与分子筛催化剂在有效将原料转化为包含轻质烯烃和副产物的产物的条件下接触，使得碳质沉积物形成在至少一部分 分子筛催化剂产生失活催化剂; 从反应器中除去一部分失活的催化剂; 在有效地从失活的催化剂除去至少一部分碳质沉积物以形成至少部分再生的催化剂的条件下，使失活催化剂的部分再生; 将所述至少部分再生的催化剂的至少一部分暴露于所述副产物的至少一部分以选择所述至少部分再生催化剂的所述部分以形成轻质烯烃; 并使至少部分再生的催化剂的选定部分与原料接触以形成产物。
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公开(公告)号：US06965057B2
公开(公告)日：2005-11-15
申请号：US10807818
申请日：2004-03-24
CPC分类号： C07C1/20 , B01J38/30 , B01J38/32 , C10G3/49 , C10G3/62 , C10G2300/4093 , C10G2300/708 , C10G2300/802 , C10G2300/805 , C10G2400/20 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The invention relates to a process for converting an oxygenate feedstock into an olefin product stream comprising (a) contacting an oxygenate feedstock with a molecular sieve catalyst in a reactor under conditions effective to convert the feedstock into an olefin product stream and to form carbonaceous deposits on the catalyst; (b) contacting at least a portion of the catalyst having said carbonaceous deposits with an oxygen containing gas under conditions effective to obtain a regenerated catalyst having a reduced carbonaceous deposit level and having an increased molecular oxygen content; (c) removing at least 60% by volume of said molecular oxygen from the regenerated catalyst based upon the total volume of molecular oxygen; (d) returning said regenerated catalyst to said reactor; and (e) repeating steps (a)–(d).
摘要翻译： 本发明涉及一种将含氧化合物原料转化成烯烃产物流的方法，该方法包括（a）在有效将原料转化成烯烃产物流并形成碳质沉积物的条件下，使反应器中的含氧化合物原料与分子筛催化剂接触 催化剂; （b）在有效获得具有降低的碳沉积物水平并且具有增加的分子氧含量的再生催化剂的条件下使至少一部分具有所述碳质沉积物的催化剂与含氧气体接触; （c）基于分子氧的总体积从再生催化剂中除去至少60体积％的所述分子氧; （d）将所述再生催化剂返回到所述反应器; 和（e）重复步骤（a） - （d）。
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公开(公告)号：US06437208B1
公开(公告)日：2002-08-20
申请号：US09481364
申请日：2000-01-11
申请人： Keith H. Kuechler , Marcel J. G. Janssen , Stephen N. Vaughn , Shun C. Fung , Nicolas P. Coute , Jeffrey Scott Smith , James R. Lattner , Jeffrey L. White , Teng Xu , William L. Kuechler, Sr. , Machteld M. Mertens , Cornelius W. M. Van Oorschot
发明人： Keith H. Kuechler , Marcel J. G. Janssen , Stephen N. Vaughn , Shun C. Fung , Nicolas P. Coute , Jeffrey Scott Smith , James R. Lattner , Jeffrey L. White , Teng Xu , William L. Kuechler, Sr. , Machteld M. Mertens , Cornelius W. M. Van Oorschot
IPC分类号： C07C120
CPC分类号： C10G50/00 , B01J29/85 , B01J29/90 , B01J35/0006 , B01J2229/123 , C10G3/49 , C10G3/57 , C10G3/62 , C10G2300/1022 , C10G2300/1029 , C10G2300/4018 , C10G2300/708 , C10G2400/02 , C10G2400/20 , C10G2400/22 , Y02P30/42
摘要： Disclosed is a method for making olefin product from an oxygenate-containing feedstock. In the method, a silicoaluminophosphate molecular sieve catalyst is contacted with the oxygenate-containing feedstock in a reactor at an average catalyst feedstock exposure index of at least 1.0. The method produces lower coke yield and provides an olefin product which is low in C1-C4 paraffin content. The invention is particularly effective in producing an olefin product having a very low propane content.
摘要翻译： 公开了一种从含氧化合物的原料制备烯烃产物的方法。 在该方法中，将硅铝磷酸盐分子筛催化剂在反应器中与含氧化合物的原料接触，平均催化剂原料暴露指数为至少1.0。 该方法产生较低的焦炭产量，并提供C1-C4链烷烃含量低的烯烃产物。 本发明在生产丙烷含量非常低的烯烃产物方面特别有效。
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公开(公告)号：US09024078B2
公开(公告)日：2015-05-05
申请号：US13515104
申请日：2010-12-17
申请人： Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
发明人： Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
IPC分类号： C07C37/08 , C07C5/32 , C07C37/07 , C07C45/53 , C07C407/00
CPC分类号： C07C37/08 , B01J23/58 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0203 , C07C5/367 , C07C37/07 , C07C45/53 , C07C407/00 , C07C2521/08 , C07C2523/42 , C07C2523/58 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C15/04
摘要： A dehydrogenation process for the dehydrogenation of at least one dehydrogenatable hydrocarbon, the process comprising contacting a feed comprising the at least one dehydrogenatable hydrocarbon under dehydrogenation conditions with a catalyst composition comprising a support and at least one dehydrogenation component wherein said conditions include a temperature of from 400° C. to 750° C. and a pressure of at least 50 psig (345 kPag).
摘要翻译： 用于脱氢至少一种可脱氢烃的脱氢方法，该方法包括在脱氢条件下使包含至少一种可脱氢烃的进料与包含载体和至少一种脱氢组分的催化剂组合物接触，其中所述条件包括 400℃至750℃，压力至少为50psig（345kPag）。
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公开(公告)号：US20120302798A1
公开(公告)日：2012-11-29
申请号：US13515104
申请日：2010-12-17
申请人： Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
发明人： Jihad M. Dakka , Lorenzo C. Decaul , Sabato Miseo , James R. Lattner , Tan-Jen Chen , Terry E. Helton , Teng Xu
CPC分类号： C07C37/08 , B01J23/58 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0203 , C07C5/367 , C07C37/07 , C07C45/53 , C07C407/00 , C07C2521/08 , C07C2523/42 , C07C2523/58 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C15/04
摘要： A dehydrogenation process for the dehydrogenation of at least one dehydrogenatable hydrocarbon, the process comprising contacting a feed comprising the at least one dehydrogenatable hydrocarbon under dehydrogenation conditions with a catalyst composition comprising a support and at least one dehydrogenation component wherein said conditions include a temperature of from 400° C. to 750° C. and a pressure of at least 50 psig (345 kPag).
摘要翻译： 用于脱氢至少一种可脱氢烃的脱氢方法，该方法包括在脱氢条件下使包含至少一种可脱氢烃的进料与包含载体和至少一种脱氢组分的催化剂组合物接触，其中所述条件包括 400℃至750℃，压力至少为50psig（345kPag）。
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