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公开(公告)号：US4269783A
公开(公告)日：1981-05-26
申请号：US775129
申请日：1977-03-07
CPC分类号： C07C1/02 , C07C2521/12 , C07C2521/14 , C07C2523/745 , C07C2529/14 , C07C2529/24 , C07C2529/56 , C07C2529/76
摘要： A method is disclosed for the conversion of a syngas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead and being a predominantly olefinic product, wherein the olefins have substantially internal double bonds. The method for accomplishing this stated result involves an improvement in the method for the conversion of synthesis gas by contacting the same with a catalyst composite comprising a mixture of a Fischer-Tropsch catalyst and a volume excess of an acidic catalyst, e.g., silica-alumina or a crystalline aluminosilicate zeolite and wherein the activity of the acidic component is balanced with the activity of the Fischer-Tropsch component so as to maximize the yield of desired olefinic product.
摘要翻译： 公开了一种在90％塔顶馏分将合成气转化为沸点低于400°F的液体烃产物并且主要是烯烃产物的方法，其中烯烃具有基本上内部的双键。 实现所述结果的方法涉及通过使合成气与包含费 - 托催化剂和体积过量的酸性催化剂的混合物的催化剂复合物接触来改进合成气的方法，例如二氧化硅 - 氧化铝 或结晶硅铝酸盐沸石，并且其中酸性组分的活性与费 - 托组分的活性相平衡，以使所需烯属产物的产率最大化。
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2.发明授权Conversion of synthesis gas to hydrocarbon mixtures utilizing a dual catalyst bed 失效使用双催化剂床将合成气转化为烃混合物
公开(公告)号：US4304871A
公开(公告)日：1981-12-08
申请号：US825875
申请日：1977-08-19
IPC分类号： C07C1/04
CPC分类号： C07C1/044 , C07C1/0435 , C07C1/0485 , C07C2529/46
摘要： A gaseous mixture of carbon monoxide and hydrogen is passed in contact over a first catalyst bed comprising an iron or cobalt containing Fischer-Tropsch catalyst in combination with a crystalline aluminosilicate of the class of crystalline zeolite represented by ZSM-5 so as to obtain a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead and being a predominantly olefinic product. The total products from said contact including said liquid hydrocarbon product are then converted over a second catalyst bed containing HZSM-5 to obtain a highly aromatic product, i.e., greater than 20 weight percent.
摘要翻译： 将一氧化碳和氢气的气体混合物在包含含铁或钴的费 - 托催化剂的第一催化剂床上与由ZSM-5表示的结晶沸石类的结晶硅铝酸盐组合使其接触，以获得液体 烃产物在90％塔顶馏出物下沸点低于400°F，主要是烯烃产物。 来自包括所述液体烃产物的所述接触的总产物然后在含有HZSM-5的第二催化剂床上转化，以获得高度芳族的产物，即大于20重量％。
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公开(公告)号：US4150062A
公开(公告)日：1979-04-17
申请号：US889486
申请日：1978-03-23
CPC分类号： C07C2/00 , B01J29/40 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70 , C07C2529/40 , C07C2529/70 , Y10S208/02
摘要： An improved processing technique is provided for conversion of olefins of 2 to 4 carbon atoms to product comprising high octane gasoline components. Embodiments of the present improved processing technique include conversion of light olefins to high octane olefinic gasoline components, and conversion of light olefins to high octane aromatic gasoline components.The improved technique comprises contacting an appropriate light olefin feedstock with a catalyst comprising a crystalline aluminosilicate zeolite characterized by a silica/alumina mole ratio of at least 12 and a constraint index, hereinafter defined, within the approximate range of 1 to 12 in the presence of a relatively large amount of co-fed water. The amount of co-fed water is maintained at from about 0.5 to about 15 moles of water/mole of olefin feedstock.
摘要翻译： 提供了一种改进的加工技术，用于将2至4个碳原子的烯烃转化成包含高辛烷值汽油组分的产品。 本改进的处理技术的实施方案包括将轻质烯烃转化成高辛烷值的烯烃汽油组分，以及将轻质烯烃转化成高辛烷值的芳族汽油组分。
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公开(公告)号：US4149960A
公开(公告)日：1979-04-17
申请号：US889483
申请日：1978-03-23
IPC分类号： B01J29/00 , B01J29/40 , B01J29/65 , B01J29/70 , C10G11/05 , C10G29/16 , C10G45/64 , C10G73/02 , C10G13/04 , B01J29/28 , C10G11/04
CPC分类号： C10G29/16 , B01J29/40 , C10G11/05 , B01J2229/26 , B01J2229/42 , B01J29/65 , B01J29/70 , C10G2400/06
摘要： An improved processing technique is provided for gas oil pour point reduction and dewaxing. The improved technique comprises contacting an appropriate gas oil feedstock with a catalyst comprising a crystalline aluminosilicate zeolite characterized by a silica/alumina mole ratio of at least 12 and a constraint index, hereinafter defined, within the approximate range of 1 to 12 in the presence of a relatively large amount of co-fed water. The amount of co-fed water is maintained at from about 0.5 to about 15 moles of water/mole of gas oil feedstock.
摘要翻译： 提供了一种改进的加工技术，用于瓦斯油倾点降低和脱蜡。 改进的技术包括使合适的瓦斯油原料与包含结晶硅铝酸盐沸石的催化剂接触，其结晶硅铝酸盐沸石的特征在于二氧化硅/氧化铝摩尔比为至少12，约束指数（下文中定义）在大约1至12的范围内， 相对大量的共同供水。 共同供水的量保持在约0.5至约15摩尔的水/摩尔瓦斯油原料。
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公开(公告)号：US4239927A
公开(公告)日：1980-12-16
申请号：US27226
申请日：1979-04-05
申请人： James A. Brennan , Henry D. Norris
发明人： James A. Brennan , Henry D. Norris
IPC分类号： C07C15/107 , C08F6/10 , C08F8/00 , C10M105/06 , C10M107/10 , C10N70/00
CPC分类号： C10M107/10 , C07C15/107 , C08F6/10 , C08F8/00 , C08F8/04 , C10M105/06 , C08F2800/20 , C10M2203/06 , C10M2205/00
摘要： In producing synthetic hydrocarbon oils by polymerization of olefins using aluminum halide as the catalyst, organic halides are produced. These are corrosive to metal equipment and are poisonous to certain hydrogenation catalysts. This invention is concerned with reacting such organic halides with an aromatic hydrocarbon in a system also containing the polyolefins thus forming an alkylation product with both reactants prior to removal of the aluminum chloride catalyst.
摘要翻译： 在通过使用卤化铝作为催化剂的烯烃聚合制备合成烃油时，产生有机卤化物。 这些对金属设备具有腐蚀性，对某些氢化催化剂是有毒的。 本发明涉及在还含有聚烯烃的体系中使这种有机卤化物与芳族烃反应，从而在除去氯化铝催化剂之前与两种反应物形成烷基化产物。
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公开(公告)号：US4078990A
公开(公告)日：1978-03-14
申请号：US774304
申请日：1977-03-04
CPC分类号： C10L1/06 , C07C6/12 , C10G2400/30
摘要： Certain acidic heterogeneous catalysts produce large yields of benzene, toluene and xylene from alkyl aromatics of at least nine carbon atoms by a mechanism different from the classical disproportionation reaction characteristic of acid catalysts. Typically, aromatic mixtures so derived from such stocks have unusually low content of ethyl benzene, thus greatly simplifying separation of xylene isomers.
摘要翻译： 某些酸性非均相催化剂通过与酸催化剂的经典歧化反应特性不同的机理，从至少9个碳原子的烷基芳族化合物产生大量的苯，甲苯和二甲苯。 通常，从这种原料得到的芳族混合物具有非常低的乙苯含量，因此极大地简化了二甲苯异构体的分离。
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7.发明授权
公开(公告)号：US4605678A
公开(公告)日：1986-08-12
申请号：US720916
申请日：1985-04-08
CPC分类号： B03C1/0335 , B01J37/342 , B03C1/288 , C07C1/0445 , C07C1/0485 , C07C1/066 , B03C2201/18 , C07C2523/04 , C07C2523/72 , C07C2523/745 , Y02P20/584 , Y10S208/95
摘要： A process for removing catalyst fines from the wax product produced in a slurry Fischer-Tropsch reactor comprises removing the wax product from the reactor and separating the catalyst fines by passing the wax product through a high gradient magnetic field, whereby the catalyst fines are held by a magnetized filter element and the wax product passes through unhindered to form a purified wax product which is ready for upgrading. The separated catalyst fines are returned to the reactor by backwashing the filter element.
摘要翻译： 从浆料费 - 托反应器中产生的蜡产物中除去催化剂细粉的方法包括从反应器中除去蜡产物并通过使蜡产物通过高梯度磁场分离催化剂细粒，由此将催化剂细粒保持在 磁化过滤元件和蜡产品不受阻碍地通过以形成准备升级的纯化蜡产品。 分离的催化剂细粒通过反冲洗过滤元件返回反应器。
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公开(公告)号：US4480145A
公开(公告)日：1984-10-30
申请号：US419105
申请日：1982-09-16
IPC分类号： B01J29/00 , B01J29/40 , C07C1/00 , C07C1/20 , C07C4/06 , C07C11/04 , C07C67/00 , C10G3/00 , C07C2/68 , B01J29/28
CPC分类号： C10G3/49 , C07C1/20 , B01J2229/26 , B01J2229/36 , B01J29/40 , C07C2529/40 , C10G2400/02 , C10G2400/20 , Y02P20/52 , Y02P30/42
摘要： A methanol conversion process in which a methanol feed is catalytically converted to ethylene and gasoline over a crystalline aluminosilicate zeolite catalyst which has been presteamed in order to adjust the alpha activity of the catalyst to about 6-100. Catalyst stability and cycle time on stream are increased.
摘要翻译： 一种甲醇转化方法，其中甲醇进料被催化转化成乙烯和汽油超过结晶硅铝酸盐沸石催化剂，其已经被预先蒸发，以便将催化剂的α活性调节至约6-100。 催化剂稳定性和流动循环时间增加。
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公开(公告)号：US3997621A
公开(公告)日：1976-12-14
申请号：US559101
申请日：1975-03-17
申请人： James A. Brennan
发明人： James A. Brennan
CPC分类号： C07C2/20 , C07C2527/1213 , C07C2531/02 , Y10S585/952
摘要： Oligomerization of alpha olefins catalyzed by boron trifluoride is controlled to yield desired trimer as a dominant product by adding small amounts of ester together with water or alcohol promoter.
摘要翻译： 通过三氟化硼催化的α-烯烃的低聚被控制，通过将少量的酯与水或醇促进剂一起加入，产生所需的三聚体作为主要产物。
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公开(公告)号：US3945913A
公开(公告)日：1976-03-23
申请号：US500432
申请日：1974-08-26
IPC分类号： C07C4/18 , B01J29/00 , C07B61/00 , C07C1/00 , C07C5/27 , C07C15/02 , C07C67/00 , C10G59/02 , C10G35/06 , C07C3/58
CPC分类号： C10G59/02
摘要： Certain acidic heterogeneous catalysts produce large yields of benzene, toluene and xylene from alkyl aromatics of at least nine carbon atoms by a mechanism different from the classical disproportionation reaction characteristic of acid catalysts. These catalysts are characterized by a zeolite of the ZSM-5 type or zeolite ZSM-12 or zeolite ZSM-21. The reaction has the unique function of providing aliphatic by-products of higher molecular weight than is to be expected by splitting side chains from benzene rings. Typically, aromatic mixtures so derived from such charge stocks have unusually low content of ethyl benzene, thus greatly simplifying separation of xylene isomers.
摘要翻译： 某些酸性非均相催化剂通过与酸催化剂的经典歧化反应特性不同的机理，从至少9个碳原子的烷基芳族化合物产生大量的苯，甲苯和二甲苯。 这些催化剂的特征在于ZSM-5型沸石或沸石ZSM-12或沸石ZSM-21。 该反应具有提供比通过从苯环分离侧链预期的更高分子量的脂肪族副产物的独特功能。 通常，从这种电荷原料得到的芳族混合物具有非常低的乙苯含量，因此极大地简化了二甲苯异构体的分离。
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