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公开(公告)号：US20060122053A1
公开(公告)日：2006-06-08
申请号：US11258440
申请日：2005-10-25
申请人： Jean Beeckman , Glenn Sweeten , Daria Lissy , David Stern , Stephen McCarthy , Dominick Mazzone , Christine Elia
发明人： Jean Beeckman , Glenn Sweeten , Daria Lissy , David Stern , Stephen McCarthy , Dominick Mazzone , Christine Elia
IPC分类号： B01J29/06
CPC分类号： B01J29/40 , B01J2229/42
摘要： The present invention describes a method to increase the activity of a catalyst by first performing an ion exchange step with a potassium ion, followed by performing an ion-exchange step with an ammonium ion. Specifically, the present invention describes a method to increase the acidity of a zeolite by incorporating a potassium salt ion-exchange prior to an ammonium salt ion-exchange step. Even more specifically, the present invention is drawn to a method of increasing the activity of a zeolite by employing more than one potassium ion exchanges followed by at least one ammonium ion exchange. The present invention also describes a method to reduce the amount of sodium normally found in commercially produced zeolite by employing any of these methods. The present invention is also drawn to the catalysts produced by any of these methods.
摘要翻译： 本发明描述了通过首先用钾离子进行离子交换步骤，然后用铵离子进行离子交换步骤来提高催化剂活性的方法。 具体地，本发明描述了通过在铵盐离子交换步骤之前引入钾盐离子交换来提高沸石的酸度的方法。 更具体地说，本发明涉及通过使用多于一种的钾离子交换，然后进行至少一种铵离子交换来提高沸石的活性的方法。 本发明还描述了一种通过使用任何这些方法来减少通常在商业生产的沸石中发现的钠的量的方法。 本发明还涉及通过任何这些方法制备的催化剂。
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2.发明申请Selectivation of molecular sieve catalysts and use thereof in hydrocarbon conversion 有权分子筛催化剂的选择及其在烃转化中的应用公开(公告)号：US20050036295A1
公开(公告)日：2005-02-17
申请号：US10641604
申请日：2003-08-15
申请人： Jean Beeckman , William Borghard , Arthur Chester , Robert Crane , Owen Feeley , John Fried , Dominick Mazzone , Glenn Sweeten
发明人： Jean Beeckman , William Borghard , Arthur Chester , Robert Crane , Owen Feeley , John Fried , Dominick Mazzone , Glenn Sweeten
CPC分类号： B01J29/40 , B01J2229/12 , B01J2229/18 , B01J2229/40 , B01J2229/42 , C07C6/123 , C07C2521/08 , C07C2529/40 , Y02P20/52 , Y10S585/906 , C07C15/08
摘要： In a process for preparing a selectivated catalyst composition useful in the disproportionation of toluene, a catalyst comprising an acidic molecular sieve is contacted with a boron compound at a temperature in excess of 500° C.; and the resultant catalyst is then contacted with a medium containing hydrogen ions to at least partially restore the acid activity of the molecular sieve.
摘要翻译： 在制备可用于甲苯歧化的选择性催化剂组合物的方法中，包含酸性分子筛的催化剂在硼氢化合物与超过500℃的温度下接触; 然后使得到的催化剂与含有氢离子的介质接触，至少部分地恢复分子筛的酸活性。
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公开(公告)号：US20060052233A1
公开(公告)日：2006-03-09
申请号：US11189665
申请日：2005-07-26
CPC分类号： B01J37/0018 , B01J20/183 , B01J29/041 , B01J29/084 , B01J29/40 , B01J29/65 , B01J37/0009 , B01J2229/42 , C04B35/18 , C04B38/0022 , C04B2111/00793 , C08L83/04 , C10G45/04 , C10G49/02 , C04B38/0006 , C04B38/0054 , C08L2666/54 , C08L2666/58
摘要： The invention relates to the use of particulate silicone resins in the absence of added organic solvents with particulate inorganic materials to form structured bodies and in particular molecular sieve containing structured bodies. The silicone resin is used in the form of a particulate with an average particle size of less than 700 um. Upon calcining, the silicone resin is converted to silica which acts as a binder.
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公开(公告)号：US20060070916A1
公开(公告)日：2006-04-06
申请号：US11205641
申请日：2005-08-17
CPC分类号： B01J29/0325 , B01J29/0308 , B01J29/041 , B01J29/043 , B01J37/0009 , B01J2229/20 , B01J2229/42 , C10G45/46 , C10G45/52 , C10G45/54 , C10G2400/10
摘要： An improved aromatics saturation process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof, a mesoporous support, and a binder.
摘要翻译： 改进的芳族化合物饱和方法，其用于使用含有选自VIII族贵金属及其混合物，中孔载体和粘合剂的氢化 - 脱氢组分的催化剂的润滑油沸程进料流。
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公开(公告)号：US20060199986A1
公开(公告)日：2006-09-07
申请号：US11205606
申请日：2005-08-17
IPC分类号： C07C5/10
CPC分类号： B01J29/043 , B01J29/0308 , B01J29/0325 , B01J29/041 , B01J2229/20 , B01J2229/42 , C07C5/10 , C07C2521/04 , C10G45/62 , C10G45/64 , C10G65/08 , C10G2400/10
摘要： An improved hydrotreating process for use with lube oil boiling range feedstreams utilizing a catalyst comprising a hydrogenation-dehydrogenation component selected from the Group VIII noble metals and mixtures thereof, a mesoporous support, and a binder.
摘要翻译： 改进的加氢处理方法，其利用含有选自第VIII族贵金属及其混合物的氢化 - 脱氢组分的催化剂，中孔载体和粘合剂，与润滑油沸腾的原料流一起使用。
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6.发明申请公开(公告)号：US20060073961A1
公开(公告)日：2006-04-06
申请号：US11205640
申请日：2005-08-17
申请人： Stephen McCarthy , Wenyih Lai , Jean Beeckman , Sylvain Hantzer
发明人： Stephen McCarthy , Wenyih Lai , Jean Beeckman , Sylvain Hantzer
IPC分类号： B01J21/08
CPC分类号： B01J29/0325 , B01J29/043 , B01J35/002 , B01J2229/20 , B01J2229/42 , C10G49/06 , C10G49/08
摘要： An improved noble metal-containing catalyst comprising at least one Group VIII noble metal selected from Pt, Pd, and mixtures thereof on a mesoporous support having an average pore diameter of about 15 to less than about 40 Å for use in the hydroprocessing of hydrocarbonaceous feeds.
摘要翻译： 一种改进的含贵金属的催化剂，其包含至少一种选自Pt，Pd的VIII族贵金属及其混合物，其在平均孔径为约15至小于约40埃的介孔载体上用于烃类进料的加氢处理 。
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公开(公告)号：US20060073965A1
公开(公告)日：2006-04-06
申请号：US11228366
申请日：2005-09-16
IPC分类号： B01J31/00
CPC分类号： B01J29/0325 , B01J23/40 , B01J29/043 , B01J29/064 , B01J35/0013 , B01J35/002 , B01J35/0066 , B01J37/06 , B01J37/14 , B01J37/18 , B01J37/20
摘要： A method of ex-situ activation and dry passivation of supported noble metal catalysts including the steps of reducing in the presence of hydrogen and dry passivation by cooling in an inert atmosphere and exposing to air or by filling the pores of the catalyst with a low sulfur oil before exposing to air.
摘要翻译： 一种负载型贵金属催化剂的原位活化和干法钝化的方法，包括以下步骤：在惰性气氛中冷却并通过在惰性气氛中冷却并且暴露于空气或通过用低硫填充催化剂的孔来减少氢气和干燥钝化 油在暴露于空气之前。
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8.发明申请Process to hydrogenate aromatics present in lube oil boiling range feedstreams 有权氢化存在于润滑油沸腾范围的原料流中的芳烃的方法公开(公告)号：US20060070917A1
公开(公告)日：2006-04-06
申请号：US11205642
申请日：2005-08-17
申请人： Stephen McCarthy , Wenyih Lai , Jean Beeckman , Sylvain Hantzer
发明人： Stephen McCarthy , Wenyih Lai , Jean Beeckman , Sylvain Hantzer
CPC分类号： B01J29/043 , B01J29/0325 , B01J2229/42 , C10G45/52 , C10G2400/10
摘要： An improved hydrogenation process for lube oil boiling range feedstreams utilizing a catalyst comprising at least one Group VIII noble metal selected from Pt, Pd, and mixtures thereof having an average pore diameter of about 15 to less than about 40 Å.
摘要翻译： 利用包含平均孔径为约15至小于约的至少一种选自Pt，Pd及其混合物的第Ⅷ族贵金属的催化剂，用于润滑油沸程的进料流的改进的氢化方法。
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公开(公告)号：US20060229198A1
公开(公告)日：2006-10-12
申请号：US11388807
申请日：2006-03-24
申请人： Stephen McCarthy , Jean Beeckman
发明人： Stephen McCarthy , Jean Beeckman
IPC分类号： B01J23/40
CPC分类号： B01J29/041 , B01J23/40 , B01J29/068 , B01J37/0205 , B01J2229/20 , C10G45/52
摘要： The present invention is a method to form a noble metal catalyst including two noble metals alloy on a catalyst support. The steps include impregnating a first noble metal onto said catalyst support, and thereafter impregnating a second noble metal onto said catalyst support. In a preferred embodiment, the first noble metal is palladium and the second noble metal is platinum.
摘要翻译： 本发明是一种在催化剂载体上形成包含贵金属合金的贵金属催化剂的方法。 步骤包括将第一贵金属浸渍到所述催化剂载体上，然后将第二贵金属浸渍到所述催化剂载体上。 在优选的实施方案中，第一贵金属是钯，第二贵金属是铂。
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公开(公告)号：US20060052235A1
公开(公告)日：2006-03-09
申请号：US11189664
申请日：2005-07-26
申请人： Chuansheng Bai , Gary McVicker , Stuart Shih , Michael Kerby , Edward Lemon , Jean Beeckman
发明人： Chuansheng Bai , Gary McVicker , Stuart Shih , Michael Kerby , Edward Lemon , Jean Beeckman
IPC分类号： B01J29/06
CPC分类号： C10G45/08 , B01J29/0333 , B01J29/0341 , B01J29/044 , B01J29/045 , B01J2229/42 , C10G45/12
摘要： This invention relates to a catalyst and process for selectively hydrodesulfurizing naphtha feedstreams using a catalyst comprising at least one hydrodesulfurizing metal supported on a low acidity, ordered mesoporous support material.
摘要翻译： 本发明涉及使用包含至少一种负载在低酸性有序介孔载体材料上的加氢脱硫金属的催化剂来选择性加氢脱硫石脑油原料流的催化剂和方法。
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