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公开(公告)号：US5164409A
公开(公告)日：1992-11-17
申请号：US661399
申请日：1991-02-26
IPC分类号： A01N53/00 , A01N53/04 , C07D207/32 , C07D207/333
CPC分类号： C07D207/333 , A01N53/00
摘要： All possible stereoisomers and mixtures of a compound of the formula ##STR1## wherein X and Y are different and are selected from the group consisting of hydrogen, halogen, --CN, alkyl and haloalkyl of 1 to 8 carbon atoms and phenyl optionally substituted by at least one member of the group consisting of halogen and alkyl and alkoxy of 1 to 8 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, methyl, --CN and ethynyl, ##STR2## A and B are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms and the --CF.sub.3 is in the 2-, 4- or 5-position of the pyrrole ring having pesticidal activity.
摘要翻译： 式（I）化合物的所有可能的立体异构体和混合物，其中X和Y不同，并且选自氢，卤素，-CN，具有1至8个碳原子的烷基和卤代烷基，以及任选的苯基 被至少一个由卤素和1至8个碳原子的烷基和烷氧基组成的组取代，R 1选自氢，甲基，-CN和乙炔基，A和B分别选自 由氢，卤素，碳原子数1〜8的烷基和碳原子数为6〜14的芳基构成的基团，在具有杀虫活性的吡咯环的2-，4-或5-位。
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公开(公告)号：US5030655A
公开(公告)日：1991-07-09
申请号：US412081
申请日：1989-09-25
IPC分类号： C07D209/49 , A01N53/00 , A01N53/02 , A01N53/10 , C07C62/08 , C07C309/70 , C07D213/62 , C07D213/68 , C07D233/72 , C07D307/45
摘要： A compound selected from the group consisting of all possible isomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms and cycloalkyl and cycloalkylalkyl of 3 to 8 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, cycloalkyl of 3 to 8 carbon atoms and acyl of 1 to 9 carbon atoms, X.sub.1 and X.sub.2 are individually selected from the group consisting of fluorine, chlorine, bromine, iodine, --CF.sub.3, --CN, --COOR and ##STR2## R is alkyl of 1 to 8 carbon atoms, Hal is chlorine, bromine or fluorine and R.sub.3 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid synthesis having excellent pesticidal properties.
摘要翻译： 选自下列化合物的化合物的化合物的化合物的所有可能的异构体形式及其混合物，其中R 1选自氢，1至8个碳原子的烷基，2至2的烯基和炔基 8个碳原子和3至8个碳原子的环烷基和环烷基烷基，R2选自氢，1至8个碳原子的烷基，2至8个碳原子的烯基和炔基，3至8个碳原子的环烷基和 1至9个碳原子的酰基，X 1和X 2分别选自氟，氯，溴，碘，-CF 3，-CN，-COOR，R 1是具有1至8个碳原子的烷基，Hal 是氯，溴或氟，并且R 3选自氢，1至8个碳原子的烷基和用于除虫菊酯合成中具有优异杀虫性质的醇的残基。
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公开(公告)号：US4925862A
公开(公告)日：1990-05-15
申请号：US221948
申请日：1988-07-20
IPC分类号： A01N53/04 , C07D263/32 , C07D263/34 , C07D263/38 , C07D263/44 , C07D263/46 , C07D277/10 , C07D277/20 , C07D277/34 , C07D277/36 , C07D413/12 , C07D417/12
CPC分类号： C07D413/12 , C07D263/32 , C07D263/38 , C07D263/46 , C07D277/10 , C07D277/34 , C07D277/36 , C07D417/12
摘要： All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein X is --O-- or --S--, Y is --C.dbd.O, ##STR2## or --CH.sub.2 --, R.sub.1 is selected from the group consisting of hydrogen, halogen, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms, the latter two being optionally substituted with one or more halogen and aryl of 6 to 14 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, --CF.sub.3, --NO.sub.2, --CN, halogen, alkoxy of 1 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, an ester, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms the latter two being optionally substituted with one or more halogen, R.sub.3 is selected from the group consisting of hydrogen, alkyl of 1 to 3 carbon atoms, --CN and --C.tbd.CH and A is the residue of an ACOOH pyrethrinoid acid having pesticidal properties.
摘要翻译： 其中X为-O-或-S-，Y为-C = O， - 或 - 2-的式I化合物的所有立体异构形式及其混合物选自： 氢，卤素，1〜8个碳原子的任选不饱和的烷基和3〜8个碳原子的任选的不饱和环烷基，后两个任选被一个或多个6-14个碳原子的卤素和芳基取代，R2选自 由氢，-CF 3，-NO 2，-CN，卤素，1至8个碳原子的烷氧基，6至14个碳原子的芳基，酯，任选不饱和的1至8个碳原子的烷基和任选的不饱和的环烷基3至 8个碳原子，后两个任选被一个或多个卤素取代，R 3选自氢，1至3个碳原子的烷基，-CN和-C 3 C CH，A是ACOOH拟除虫菊酯酸的残基 具有杀虫性。
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公开(公告)号：US5008281A
公开(公告)日：1991-04-16
申请号：US432529
申请日：1989-11-07
IPC分类号： A01N53/04 , C07D263/32 , C07D263/34 , C07D263/38 , C07D263/44 , C07D263/46 , C07D277/10 , C07D277/20 , C07D277/34 , C07D277/36 , C07D413/12 , C07D417/12
CPC分类号： C07D413/12 , C07D263/32 , C07D263/38 , C07D263/46 , C07D277/10 , C07D277/34 , C07D277/36 , C07D417/12
摘要： All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein X is --O-- or --S--, Y is --C.dbd.O, ##STR2## or --CH.sub.2 --, R.sub.1 is selected from the group consisting of hydrogen, halogen, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms, the latter two being optionally substituted with one or more halogen and aryl of 6 to 14 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, --CF.sub.3, --NO.sub.2, --CN, halogen, alkoxy of 1 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, an ester, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms, the latter two being optionally substituted with one or more halogen, R.sub.3 is selected from the group consisting of hydrogen, alkyl of 1 to 3 carbon atoms, --CN and --C.tbd.CH and A is the residue of an ACOOH pyrethrinoid acid having pesticidal properties.
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公开(公告)号：US4939172A
公开(公告)日：1990-07-03
申请号：US153157
申请日：1988-02-08
IPC分类号： C07C69/743 , A01N53/00 , A01N53/06 , A01N55/00 , A01N55/10 , A61K31/215 , C07C33/46 , C07C43/23 , C07C67/00 , C07C67/08 , C07C69/73 , C07C69/747 , C07C69/757 , C07C213/08 , C07C219/32 , C07C253/00 , C07C253/30 , C07C255/38 , C07C255/39 , C07C255/41 , C07C255/53 , C07C255/55 , C07C319/20 , C07C323/16 , C07C323/18 , C07C323/19 , C07C323/60 , C07C323/62 , C07D309/12 , C07F7/08 , C07F7/18
CPC分类号： C07C255/00 , A01N53/00 , C07C43/23 , C07D309/12 , C07F7/1852
摘要： Novel cyclopropane carboxylic acid esters of all possible stereoisomeric forms and mixtures thereof of the formula ##STR1## wherein X is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, R is selected from the group consisting of optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted, optionally unsaturated cycloalkyl of 3 to 8 carbon atoms optionally substituted, optionally substituted aryl of 6 to 14 carbon atoms and optionally substituted heterocycle, Z is selected from the group consisting of hydrogen, --CH.sub.3, --CN and --C.tbd.CH and Y is selected from the group consisting of hydrogen, --OH, optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted, --CN, --(CH.sub.2).sub.m --OAlk, --(CH.sub.2).sub.m --S--Alk, ##STR2## m is 0,1,2,3 or 4, Alk is alkyl of 1 to 12 carbon atoms, --Si(Alk').sub.3, Alk' is optionally unsaturated alkyl of 1 to 8 carbon atoms optionally substituted, --O--Ar and --(CH.sub.2).sub.m --Ar and Ar is aryl of 6 to 14 carbon atoms having excellent pesticidal activities and novel intermediates.
摘要翻译： 所有可能的立体异构体形式的新型环丙烷羧酸酯及其混合物，其中X选自氢，氟，氯和溴，R选自任选不饱和的1位烷基 至8个碳原子任选取代，任选取代的3至8个碳原子的任意不饱和环烷基，任选取代的6至14个碳原子的任选取代的芳基和任选取代的杂环，Z选自氢，-CH 3，-CN和 - C 3 CH 3和Y选自氢，-OH，任选取代的具有1至8个碳原子的任选不饱和烷基，-CN， - （CH 2）m -OAlk， - （CH 2）m S-Alk， > m为0,1,2,3或4，Alk为1〜12个碳原子的烷基，-Si（Alk'）3，Alk'为任选取代的1〜8个碳原子的任意不饱和烷基，-O-Ar 和 - （CH 2）m -Ar，Ar是具有优异p的6至14个碳原子的芳基 杀虫活动和新颖的中间体。
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公开(公告)号：US4849443A
公开(公告)日：1989-07-18
申请号：US96849
申请日：1987-09-14
IPC分类号： A01N53/00 , A01N53/04 , A61K31/40 , A61K31/403 , A61K31/404 , A61P33/10 , C07D209/12 , C07D209/18 , C07D405/12 , C07D409/12
CPC分类号： A01N53/00 , C07D209/12 , C07D209/18
摘要： A compound of the formula ##STR1## wherein A is the residue of a ACOOH pyrethrinoid acid, Z is selected from the group consisting of hydrogen, --CN, --C.tbd.CH, --CH.sub.3 and alkyl of 1 to 3 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, cycloalkyl, cycloalkenyl and cycloalkynyl of 3 to 8 carbon atoms, aryl of 6 to 14 carbon atoms and aralkyl of 7 to 18 carbon atoms and R.sub.2 is selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, cycloalkyl, cycloalkenyl and cycloalkynyl of 3 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CN, --CF.sub.3, --NO.sub.2 and --COOAlK and AlK is alkyl of 1 to 18 carbon atoms having pesticidal activities.
摘要翻译： 式Ⅰ化合物，其中A是ACOOH拟除虫菊酯酸的残基，Z选自氢，-CN，-C3BCH，-CH3和1-3个碳原子的烷基，R1 选自氢，1至8个碳原子的烷基，2至8个碳原子的烯基和炔基，3至8个碳原子的环烷基，环烯基和环炔基，6至14个碳原子的芳基和7个芳基的芳烷基 至18个碳原子，R 2选自氢，卤素，1至8个碳原子的烷基，2至8个碳原子的烯基和炔基，3至8个碳原子的环烷基，环烯基和环炔基，6 至14个碳原子，7至18个碳原子的芳烷基，-CN，-CF 3，-NO 2和-COOAlK，AlK是具有杀虫活性的具有1至18个碳原子的烷基。
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公开(公告)号：US5401771A
公开(公告)日：1995-03-28
申请号：US82761
申请日：1993-06-25
CPC分类号： A01N53/00
摘要： An insecticidal composition comprising an insecticidally effective amount of (S) .alpha.-cyano-3-phenoxy-benzyl(1R, trans) 2,2-dimethyl-3-[(.DELTA.Z) 2-fluoro-3-oxo-3-methoxy-propenyl]-cyclopropane carboxylate and an inert carrier having excellent insecticidal activity and low mammal toxicity.
摘要翻译： 一种杀虫组合物，其包含杀虫有效量的（S）α-氰基-3-苯氧基 - 苄基（1R，反式）2,2-二甲基-3 - [（DELTA Z）2-氟-3-氧代-3-甲氧基 - 丙烯基] - 环丙烷羧酸酯和具有优异杀虫活性和低哺乳动物毒性的惰性载体。
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公开(公告)号：US5405865A
公开(公告)日：1995-04-11
申请号：US012723
申请日：1993-02-03
IPC分类号： A01N43/08 , A01N43/10 , A01N53/00 , A01N53/04 , C07D307/42 , C07D307/45 , C07D307/68 , C07D307/71 , C07D333/16 , C07D333/28
CPC分类号： C07D307/42 , A01N43/08 , A01N53/00 , C07D307/68 , C07D307/71 , C07D333/16
摘要： A compound in all possible stereoisomeric forms and mixtures thereof of the formula ##STR1## wherein the substituents are defined as in the specification having pesticidal properties.
摘要翻译： 所有可能的立体异构形式的化合物及其具有式I的混合物，其中取代基如说明书中具有杀虫性质所定义。
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公开(公告)号：US5262438A
公开(公告)日：1993-11-16
申请号：US906406
申请日：1992-07-01
IPC分类号： C07D309/12 , A01N53/00 , A01N53/06 , C07C213/06 , C07C219/32 , C07C255/43 , C07D317/54 , C07C69/74
CPC分类号： A01N53/00 , C07C219/32 , C07C255/43 , C07C2101/02
摘要： All possible stereoisomers and mixtures thereof of a compound of the formula ##STR1## wherein X is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, R is selected from the group consisting of optionally substituted alkyl, alkenyl, alkynyl and cycloalkyl of up to 8 carbon atoms, optionally substituted aryl and aralkyl of up to 14 carbon atoms and optionally substituted heterocyclic and Z is selected from the group consisting of hydrogen, methyl, --CN and --C.tbd.CH having pesticidal, particularly insecticidal properties.
摘要翻译： 式I化合物的所有可能的立体异构体及其混合物，其中X选自氢，氟，氯和溴，R选自任选取代的烷基，烯基，炔基和环烷基 至多8个碳原子，任选取代的芳基和至多14个碳原子的芳烷基和任选取代的杂环基，Z选自具有杀虫，特别是杀虫性质的氢，甲基，-CN和-C 3BOND CH。
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10.发明授权Pyrethrinoid esters of 1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl-methanol and pesticidal compositions thereof 失效1,3,4,5,6,7-六氢-1,3-二氧代-2H-异吲哚-2-基 - 甲醇的除虫菊酯及其杀虫组合物
公开(公告)号：US5310751A
公开(公告)日：1994-05-10
申请号：US906405
申请日：1992-07-01
IPC分类号： C07D209/49 , A01N53/00 , A01N53/04 , C07D209/48 , C07D405/08 , C07D405/14 , A61K31/40
CPC分类号： C07D209/49 , A01N53/00
摘要： All possible stereoisomer forms and mixtures thereof of a compound of the formula ##STR1## wherein X is halogen, Y is --0-- or --S-- and R is selected from the group consisting of optionally substituted alkyl, alkenyl and alkynyl of up to 8 carbon atoms, cycloalkyl of 3 to 8 carbon atoms, optionally substituted aryl and aralkyl of up to 14 carbon atoms and optionally substituted heterocyclic having pesticidal properties.
摘要翻译： 式Ⅰ化合物的所有可能的立体异构体形式及其混合物，其中X是卤素，Y是-O-或-S-，R选自任选取代的烷基，烯基和炔基，直到 8个碳原子的碳原子数为3〜8的环烷基，可以具有取代基的芳基和至多14个碳原子的芳烷基，以及具有农药性质的任意取代的杂环。
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