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    Pyrroles possessing insecticidal activity
    1.
    发明授权
    Pyrroles possessing insecticidal activity 失效
    PYRROLES POSSESSING INSECTICIDAL活动

    公开(公告)号：US5164409A

    公开(公告)日：1992-11-17

    申请号：US661399

    申请日：1991-02-26

    Applicant: Marc Benoit ,  Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    Inventor： Marc Benoit ,  Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC: A01N53/00 ,  A01N53/04 ,  C07D207/32 ,  C07D207/333

    CPC classification number: C07D207/333 ,  A01N53/00

    Abstract: All possible stereoisomers and mixtures of a compound of the formula ##STR1## wherein X and Y are different and are selected from the group consisting of hydrogen, halogen, --CN, alkyl and haloalkyl of 1 to 8 carbon atoms and phenyl optionally substituted by at least one member of the group consisting of halogen and alkyl and alkoxy of 1 to 8 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, methyl, --CN and ethynyl, ##STR2## A and B are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms and aryl of 6 to 14 carbon atoms and the --CF.sub.3 is in the 2-, 4- or 5-position of the pyrrole ring having pesticidal activity.

    Abstract translation: 式（I）化合物的所有可能的立体异构体和混合物，其中X和Y不同，并且选自氢，卤素，-CN，具有1至8个碳原子的烷基和卤代烷基，以及任选的苯基 被至少一个由卤素和1至8个碳原子的烷基和烷氧基组成的组取代，R 1选自氢，甲基，-CN和乙炔基，A和B分别选自 由氢，卤素，碳原子数1〜8的烷基和碳原子数为6〜14的芳基构成的基团，在具有杀虫活性的吡咯环的2-，4-或5-位。

    Novel pyrethrinoids
    2.
    发明授权
    Novel pyrethrinoids 失效
    新型拟除虫菊酯类

    公开(公告)号：US4925862A

    公开(公告)日：1990-05-15

    申请号：US221948

    申请日：1988-07-20

    Applicant: Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    Inventor： Jacques Demassey ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC: A01N53/04 ,  C07D263/32 ,  C07D263/34 ,  C07D263/38 ,  C07D263/44 ,  C07D263/46 ,  C07D277/10 ,  C07D277/20 ,  C07D277/34 ,  C07D277/36 ,  C07D413/12 ,  C07D417/12

    CPC classification number: C07D413/12 ,  C07D263/32 ,  C07D263/38 ,  C07D263/46 ,  C07D277/10 ,  C07D277/34 ,  C07D277/36 ,  C07D417/12

    Abstract: All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein X is --O-- or --S--, Y is --C.dbd.O, ##STR2## or --CH.sub.2 --, R.sub.1 is selected from the group consisting of hydrogen, halogen, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms, the latter two being optionally substituted with one or more halogen and aryl of 6 to 14 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, --CF.sub.3, --NO.sub.2, --CN, halogen, alkoxy of 1 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, an ester, optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl of 3 to 8 carbon atoms the latter two being optionally substituted with one or more halogen, R.sub.3 is selected from the group consisting of hydrogen, alkyl of 1 to 3 carbon atoms, --CN and --C.tbd.CH and A is the residue of an ACOOH pyrethrinoid acid having pesticidal properties.

    Abstract translation: 其中X为-O-或-S-，Y为-C = O， - 或 - 2-的式I化合物的所有立体异构形式及其混合物选自： 氢，卤素，1〜8个碳原子的任选不饱和的烷基和3〜8个碳原子的任选的不饱和环烷基，后两个任选被一个或多个6-14个碳原子的卤素和芳基取代，R2选自 由氢，-CF 3，-NO 2，-CN，卤素，1至8个碳原子的烷氧基，6至14个碳原子的芳基，酯，任选不饱和的1至8个碳原子的烷基和任选的不饱和的环烷基3至 8个碳原子，后两个任选被一个或多个卤素取代，R 3选自氢，1至3个碳原子的烷基，-CN和-C 3 C CH，A是ACOOH拟除虫菊酯酸的残基 具有杀虫性。

    Novel cyclopropane carboxylates
    3.
    发明授权
    Novel cyclopropane carboxylates 失效
    新型环丙烷羧酸酯

    公开(公告)号：US5030655A

    公开(公告)日：1991-07-09

    申请号：US412081

    申请日：1989-09-25

    Applicant: Jean Tessier ,  Jacques Demassey ,  Jean-Pierre Demoute

    Inventor： Jean Tessier ,  Jacques Demassey ,  Jean-Pierre Demoute

    IPC: C07D209/49 ,  A01N53/00 ,  A01N53/02 ,  A01N53/10 ,  C07C62/08 ,  C07C309/70 ,  C07D213/62 ,  C07D213/68 ,  C07D233/72 ,  C07D307/45

    CPC classification number: C07C62/08 ,  A01N53/00

    Abstract: A compound selected from the group consisting of all possible isomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms and cycloalkyl and cycloalkylalkyl of 3 to 8 carbon atoms, R.sub.2 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, cycloalkyl of 3 to 8 carbon atoms and acyl of 1 to 9 carbon atoms, X.sub.1 and X.sub.2 are individually selected from the group consisting of fluorine, chlorine, bromine, iodine, --CF.sub.3, --CN, --COOR and ##STR2## R is alkyl of 1 to 8 carbon atoms, Hal is chlorine, bromine or fluorine and R.sub.3 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid synthesis having excellent pesticidal properties.

    Abstract translation: 选自下列化合物的化合物的化合物的化合物的所有可能的异构体形式及其混合物，其中R 1选自氢，1至8个碳原子的烷基，2至2的烯基和炔基 8个碳原子和3至8个碳原子的环烷基和环烷基烷基，R2选自氢，1至8个碳原子的烷基，2至8个碳原子的烯基和炔基，3至8个碳原子的环烷基和 1至9个碳原子的酰基，X 1和X 2分别选自氟，氯，溴，碘，-CF 3，-CN，-COOR，R 1是具有1至8个碳原子的烷基，Hal 是氯，溴或氟，并且R 3选自氢，1至8个碳原子的烷基和用于除虫菊酯合成中具有优异杀虫性质的醇的残基。

    Indoles and pesticidal use thereof
    6.
    发明授权
    Indoles and pesticidal use thereof 失效
    吲哚和杀虫剂的使用

    公开(公告)号：US4849443A

    公开(公告)日：1989-07-18

    申请号：US96849

    申请日：1987-09-14

    Applicant: Jean Tessier ,  Jacques Demassey ,  Jean-Pierre Demoute

    Inventor： Jean Tessier ,  Jacques Demassey ,  Jean-Pierre Demoute

    IPC: A01N53/00 ,  A01N53/04 ,  A61K31/40 ,  A61K31/403 ,  A61K31/404 ,  A61P33/10 ,  C07D209/12 ,  C07D209/18 ,  C07D405/12 ,  C07D409/12

    CPC classification number: A01N53/00 ,  C07D209/12 ,  C07D209/18

    Abstract: A compound of the formula ##STR1## wherein A is the residue of a ACOOH pyrethrinoid acid, Z is selected from the group consisting of hydrogen, --CN, --C.tbd.CH, --CH.sub.3 and alkyl of 1 to 3 carbon atoms, R.sub.1 is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, cycloalkyl, cycloalkenyl and cycloalkynyl of 3 to 8 carbon atoms, aryl of 6 to 14 carbon atoms and aralkyl of 7 to 18 carbon atoms and R.sub.2 is selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms, cycloalkyl, cycloalkenyl and cycloalkynyl of 3 to 8 carbon atoms, aryl of 6 to 14 carbon atoms, aralkyl of 7 to 18 carbon atoms, --CN, --CF.sub.3, --NO.sub.2 and --COOAlK and AlK is alkyl of 1 to 18 carbon atoms having pesticidal activities.

    Abstract translation: 式Ⅰ化合物，其中A是ACOOH拟除虫菊酯酸的残基，Z选自氢，-CN，-C3BCH，-CH3和1-3个碳原子的烷基，R1 选自氢，1至8个碳原子的烷基，2至8个碳原子的烯基和炔基，3至8个碳原子的环烷基，环烯基和环炔基，6至14个碳原子的芳基和7个芳基的芳烷基 至18个碳原子，R 2选自氢，卤素，1至8个碳原子的烷基，2至8个碳原子的烯基和炔基，3至8个碳原子的环烷基，环烯基和环炔基，6 至14个碳原子，7至18个碳原子的芳烷基，-CN，-CF 3，-NO 2和-COOAlK，AlK是具有杀虫活性的具有1至18个碳原子的烷基。

    Vinylsulfone nor-pyrethric compounds
    7.
    发明授权
    Vinylsulfone nor-pyrethric compounds 失效
    乙烯基砜除虫菊酯化合物

    公开(公告)号：US5329017A

    公开(公告)日：1994-07-12

    申请号：US51177

    申请日：1993-04-22

    Applicant: Didier Babin ,  Jean-Pierre Demoute ,  Jean Tessier

    Inventor： Didier Babin ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC: C07C69/743 ,  C07D327/04

    CPC classification number: C07C69/743

    Abstract: Novel all possible stereoisomers and mixtures thereof of vinylsulfone nor-pyrethric compounds of the formula ##STR1## wherein R.sub.a is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms unsubstituted or substituted with at least one functional group, n is 0, 1 or 2, R.sub.b is selected from the group consisting of alkyl of 1 to 18 carbon atoms, alkenyl and alkynyl of 2 to 18 carbon atoms, cycloalkyl of 3 to 18 carbon atoms, cycloalkylalkyl of 4 to 18 carbon atoms and aryl of 6 to 14 carbon atoms, all unsubstituted or unsubstituted with at least one functional group or R.sub.a and R.sub.b together with the C-S-C to which they are attached form ##STR2##

    Abstract translation: 其中R a选自1至18个碳原子的烷基，2至18个碳原子的烯基和炔基，3个环烷基的全部可能的立体异构体及其混合物， 至18个碳原子，4至18个碳原子的环烷基烷基和未被取代或被至少一个官能团取代的6至14个碳原子的芳基，n为0,1或2，Rb选自1至 2至18个碳原子的烯基和炔基，3至18个碳原子的环烷基，4至18个碳原子的环烷基烷基和6至14个碳原子的芳基，全部未取代或未取代，至少有一个官能团或Ra 和Rb与它们所连接的CSC一起形成

    3-(2-cyano-2-halo-ethenyl)-2,2-dimethyl-cyclopropanecarboxylates
    8.
    发明授权
    3-(2-cyano-2-halo-ethenyl)-2,2-dimethyl-cyclopropanecarboxylates 失效
    3-（2-氰基-2-甲基-2-戊烯）-2,2-二甲基 - 环丙烷氧基甲酸酯

    公开(公告)号：US5135951A

    公开(公告)日：1992-08-04

    申请号：US661383

    申请日：1991-02-26

    Applicant: Didier Babin ,  Marc Benoit ,  Jean-Pierre Demoute ,  Jean Tessier

    Inventor： Didier Babin ,  Marc Benoit ,  Jean-Pierre Demoute ,  Jean Tessier

    IPC: C07F7/10 ,  A01N53/00 ,  A01N53/06 ,  A01N53/08 ,  A01N55/10 ,  C07C253/30 ,  C07C255/31 ,  C07C255/39 ,  C07C255/55 ,  C07C319/20 ,  C07C323/16 ,  C07F7/12

    CPC classification number: A01N53/00 ,  C07C255/31

    Abstract: All stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein the cyclopropane copula has (1R, cis) or (1R, trans) structure, the geometry of the double bond carried by the 3-carbon atom is (E) or (Z), X is halogen, Z is selected from the group consisting of hydrogen, methyl, --CN and --C.tbd.CH, n is an integer from 1 to 5, m represents the number 5-n, Y is selected from the group consisting of hydrogen, halogen, --CH.sub.2 --CN, --OH, optionally unsaturated alkyl of 1 to 8 carbon atoms unsubstituted or substituted with at least one halogen, --CN, --COOAlk, --COAlk, --(CH.sub.2).sub.m' OAlk, --(CH.sub.2).sub.m' --S--Alk, --(CH.sub.2).sub.m' --N(Alk).sub.2, --Si(Alk).sub.3, --OAr and (CH.sub.2).sub.m' --Ar, m' is 0, 1,2,3 or 4, Alk is optionally unsaturated alkyl of 1 to 8 carbon atom unsubstituted or substituted with at least one halogen and Ar is aryl of 6 to 14 carbon atoms and the Ys identical or different may be on any position of the phenyl having pesticidal properties.

    Abstract translation: 式（I）化合物的所有立体异构体形式及其混合物，其中环丙烷共聚物具有（1R，顺式）或（1R，反式）结构，由3-碳原子携带的双键的几何形状为（E ）或（Z）中，X为卤素，Z选自氢，甲基，-CN和-C 3BOND CH，n为1〜5的整数，m为5〜n的数，Y为 由氢，卤素，-CH 2 -CN，-OH，未取代或被至少一个卤素，-CN，-COOAlk，-COAlk， - （CH 2）m'取代或被取代的碳原子数1〜 OAlk， - （CH 2）m'-S-Alk， - （CH 2）m'-N（Alk）2，-Si（Alk）3，-OAr和（CH 2）m'-Ar，m' ，2,3或4，Alk任选是未被取代或被至少一个卤素取代的1至8个碳原子的不饱和烷基，Ar是6至14个碳原子的芳基，并且Y相同或不同可以在苯基的任何位置 具有杀虫性。

    Process for the preparation of a bicyclic lactone through a sulfonated derivative
    10.
    发明授权
    Process for the preparation of a bicyclic lactone through a sulfonated derivative 失效
    通过磺化衍生物制备双环内酯的方法

    公开(公告)号：US4554361A

    公开(公告)日：1985-11-19

    申请号：US517794

    申请日：1983-07-27

    Applicant: Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

    Inventor： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

    IPC: C07B61/00 ,  C07D307/33 ,  C07D307/60 ,  C07D307/93 ,  C07D307/77

    CPC classification number: C07D307/33 ,  C07D307/60 ,  C07D307/93

    Abstract: A novel process for the preparation of sulfonic acid esters containing a lactonic ring comprising compounds in the trans form in the 4- and 5-positions having (4SR,5RS), (4S,5R) or (4R,5S) configuration of the formula ##STR1## wherein Z is selected from the group consisting of alkyl of 1 to 4 carbon atoms and cycloalkyl and monocyclic aryl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen and nitro and R is organic residue of an optionally chiral alcohol of the formula ROH and a process using the compounds of formula I to prepare compounds of (1RS, 4RS, 5SR), (1S, 4S, 5R) or (1R, 4R, 5S) configuration of the formula ##STR2## wherein X is selected from the group consisting of hydrogen and R useful for the preparation of insecticidally active esters.

    Abstract translation: 一种制备含有内酯环的磺酸酯的新方法，其包含在4-和5-位的反式形式的具有式（4SR，5RS），（4S，5R）或（4R，5S）构型的式 其中Z选自1至4个碳原子的烷基，环烷基和任选被至少一个由1至4个碳原子的烷基取代的单环芳基，1至4的烷氧基， 碳原子，卤素和硝基，R是式ROH的任选手性醇的有机残基，以及使用式I化合物制备（1RS，4RS，5SR），（1S，4S，5R）或（ 1R，4R，5S）构型，其中X选自用于制备杀虫活性酯的氢和R。

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