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11 条记录 (耗时 0.021 秒)

    Coating composition comprising hydroxylamine esters
    1.
    发明授权
    Coating composition comprising hydroxylamine esters 有权
    包含羟胺酯的涂料组合物

    公开(公告)号：US07820248B2

    公开(公告)日：2010-10-26

    申请号：US10545755

    申请日：2004-03-03

    申请人： Jean-Pierre Wolf ,  Ljubomir Misev ,  Peter Nesvadba ,  Sevgi Zeren

    发明人： Jean-Pierre Wolf ,  Ljubomir Misev ,  Peter Nesvadba ,  Sevgi Zeren

    IPC分类号： B05D3/00 ,  B29C71/02

    CPC分类号： C09D4/00 ,  C08K5/3435

    摘要： The invention relates to a dual thermal and ultraviolet radiation curable coating composition, comprising a) at least an ethylenically unsaturated compound; b) a hydroxylamine ester effective to enable IR-curing or NIR-curing of the ethylenically unsaturated compound; c) a photoinitiator effective to enable UV-curing of the ethylenically unsaturated compound; wherein the thermal initiator is a hydroxylamine ester which has a structural element of formula (1) or formula (1) or a polymeric hydroxylamine ester which has a repetitive structural unit of formula (11) or (I[′) of formula (11) Furthermore, the invention relates to a process for curing a thermal curable coating composition composing hydroxylamine esters as thermal initiators using NIR-curing.

    摘要翻译： 本发明涉及双重热和紫外线辐射固化涂料组合物，其包含a）至少一种烯属不饱和化合物; b）有效地使烯属不饱和化合物进行IR固化或NIR固化的羟胺; c）有效使烯属不饱和化合物进行UV固化的光引发剂; 其中所述热引发剂是具有式（1）或式（1）的结构元件的羟胺酯或具有式（11）或式（11）的（I ['）的重复结构单元的聚羟胺， 此外，本发明涉及使用NIR固化固化构成羟胺酯作为热引发剂的热固化性涂料组合物的方法。

    Coating composition comprising hydroxylamine esters
    2.
    发明申请
    Coating composition comprising hydroxylamine esters 有权
    包含羟胺酯的涂料组合物

    公开(公告)号：US20060172080A1

    公开(公告)日：2006-08-03

    申请号：US10545755

    申请日：2004-03-03

    申请人： Jean-Pierre Wolf ,  Ljubomir Misev ,  Peter Nesvadba ,  Sevgi Zeren

    发明人： Jean-Pierre Wolf ,  Ljubomir Misev ,  Peter Nesvadba ,  Sevgi Zeren

    IPC分类号： B05D3/00 ,  B29C71/02

    CPC分类号： C09D4/00 ,  C08K5/3435

    摘要： The invention relates to a dual thermal and ultraviolet radiation curable coating composition, comprising a) at least an ethylenically unsaturated compound; b) a hydroxylamine ester effective to enable IR-curing or NIR-curing of the ethylenically unsaturated compound; c) a photoinitiator effective to enable UV-curing of the ethylenically unsaturated compound; wherein the thermal initiator is a hydroxylamine ester which has a structural element of formula (1) or formula (1) or a polymeric hydroxylamine ester which has a repetitive structural unit of formula (11) or (I[′) of formula (11) Furthermore, the invention relates to a process for curing a thermal curable coating composition compOsing hydroxylamine esters as thermal initiators using NIR-curing.

    摘要翻译： 本发明涉及双重热和紫外线辐射固化涂料组合物，其包含a）至少一种烯属不饱和化合物; b）有效地使烯属不饱和化合物进行IR固化或NIR固化的羟胺; c）有效使烯属不饱和化合物进行UV固化的光引发剂; 其中所述热引发剂是具有式（1）或式（1）的结构元件的羟胺酯或具有式（11）或式（11）的（I ['）的重复结构单元的聚合羟胺酯， 此外，本发明涉及一种使用NIR固化将羟胺酯作为热引发剂的热固化性涂料组合物的固化方法。

    Daylight curing compositions containing bisacylphosphine oxide photoinitiators
    4.
    发明授权
    Daylight curing compositions containing bisacylphosphine oxide photoinitiators 失效
    含有双酰基氧化膦光引发剂的日光固化组合物

    公开(公告)号：US5534559A

    公开(公告)日：1996-07-09

    申请号：US451115

    申请日：1995-05-25

    申请人： David G. Leppard ,  Manfred Kohler ,  Ljubomir Misev

    发明人： David G. Leppard ,  Manfred Kohler ,  Ljubomir Misev

    IPC分类号： C07F9/53 ,  C08F2/50 ,  C08F4/00 ,  C08F283/01 ,  C08K3/22 ,  C08L67/06

    CPC分类号： C08F2/50 ,  C07F9/5337 ,  C08F283/01

    摘要： Ethylenically unsaturated polymerisable compounds can be cured with daylight or with light sources equivalent to daylight by using as hardener a photoinitiator of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.12 alkyl, cyclopentyl, cyclohexyl, unsubstituted phenyl, naphthyl or biphenyl,R.sub.2 and R.sub.3 are each independently of the other C.sub.1 -C.sub.12 alkyl,R.sub.4 is hydrogen or C.sub.1 -C.sub.12 alkyl, andR.sub.5 is hydrogen or methyl.

    摘要翻译： 烯键式不饱和可聚合化合物可以用日光或通过使用与光线相当的光源来固化，通过使用式I的光引发剂（I）的硬化剂，其中R 1是C 1 -C 12烷基，环戊基，环己基，未取代的苯基，萘基或联苯基，R2 和R 3各自独立地为C 1 -C 12烷基，R 4为氢或C 1 -C 12烷基，R 5为氢或甲基。

    Alkylbisacylphosphine oxides
    5.
    发明授权
    Alkylbisacylphosphine oxides 失效
    烷基双酰基氧化膦

    公开(公告)号：US5399770A

    公开(公告)日：1995-03-21

    申请号：US947653

    申请日：1992-09-17

    申请人： David G. Leppard ,  Manfred Kohler ,  Ljubomir Misev

    发明人： David G. Leppard ,  Manfred Kohler ,  Ljubomir Misev

    IPC分类号： C07F9/53 ,  C08F2/50 ,  C08K5/53 ,  C09D4/00 ,  C09J4/00 ,  C09J4/02 ,  G03F7/028 ,  G03F7/029

    CPC分类号： G03F7/029 ,  C07F9/5337 ,  Y10S430/126

    摘要： Compounds of the formula I ##STR1## in which R.sub.1 is C.sub.1 -C.sub.18 alkyl, cyclopentyl or cyclohexyl, and R.sub.2 and R.sub.3, independently of one another, are phenyl which is unsubstituted or monosubstituted to tetrasubstituted by halogen, C.sub.1 -C.sub.4 alkyl and/or C.sub.1 -C.sub.4 alkoxy, with the proviso that R.sub.1 is not decyl if R.sub.2 and R.sub.3 are chlorine-substituted phenyl, are suitable for the photopolymerization of compounds containing ethylenically unsaturated double bonds.

    摘要翻译： 其中R 1为C 1 -C 18烷基，环戊基或环己基，R 2和R 3彼此独立地为通式I（I）的化合物为未被取代或被卤素单取代至四取代的苯基，C 1 -C 4烷基和/ 或C 1 -C 4烷氧基，条件是如果R 2和R 3是氯取代的苯基，则R 1不是癸基，适用于含有烯属不饱和双键的化合物的光聚合。

    Method for producing adhesive surface coatings
    6.
    发明授权
    Method for producing adhesive surface coatings 有权
    生产粘合剂表面涂层的方法

    公开(公告)号：US06548121B1

    公开(公告)日：2003-04-15

    申请号：US09830485

    申请日：2002-01-09

    申请人： Michael Bauer ,  Manfred Köhler ,  Martin Kunz ,  Ljubomir Misev

    发明人： Michael Bauer ,  Manfred Köhler ,  Martin Kunz ,  Ljubomir Misev

    IPC分类号： B05D138

    CPC分类号： B05D3/062 ,  B05D3/10 ,  B05D3/142 ,  C23C14/024

    摘要： The invention relates to a process for the production of strongly adherent coatings on an inorganic or organic substrate that comprises, in a first step a) subjecting the inorganic or organic substrate to the action of a low-temperature plasma discharge, a corona discharge, high-energy UV radiation or electron radiation, then discontinuing the radiation or discharge; in a further step b) under vacuum or at normal pressure, applying one or more photoinitiators containing at least one ethylenically unsaturated group to the inorganic or organic substrate, and allowing reaction with the free-radical sites formed there; and c1) coating the substrate so precoated with photoinitiator with a composition comprising at least one ethylenically unsaturated monomer or oligomer, and curing the coating by means of UV/VIS radiation or c2) depositing a metal, semi-metal oxide or metal oxide from the gaseous phase, in the presence of UV light, on the substrate so precoated with photoinitiator. The invention relates also to the use of photoinitiators having at least one ethylenically unsaturated group in the production of such layers and to the strongly adherent coatings themselves.

    摘要翻译： 本发明涉及一种用于在无机或有机基底上生产强粘附涂层的方法，该方法包括在第一步骤中，使无机或有机基底经受低温等离子体放电，电晕放电， 紫外辐射或电子辐射，然后停止辐射或放电; 在进一步的步骤b）中，在真空或常压下，将一种或多种含有至少一个烯键式不饱和基团的光引发剂施加到无机或有机底物上，并允许与在其上形成的自由基部位反应; 和c1）使用包含至少一种烯键式不饱和单体或低聚物的组合物用光引发剂预涂底物，并通过UV / VIS辐射固化该涂层; c）从气相沉积金属，半金属氧化物或金属氧化物 在UV光的存在下，在光引发剂上预涂的基材上。 本发明还涉及在制备这些层中使用具有至少一个烯属不饱和基团的光引发剂和本身具有强粘附性的涂层。

    Curing process for cationically photocurable formulations
    10.
    发明授权
    Curing process for cationically photocurable formulations 失效
    阳离子光固化制剂的固化过程

    公开(公告)号：US06235807B1

    公开(公告)日：2001-05-22

    申请号：US09202355

    申请日：1998-12-14

    申请人： Ljubomir Misev

    发明人： Ljubomir Misev

    IPC分类号： C08F248

    CPC分类号： G03F7/38 ,  C08G59/24 ,  C08G59/68 ,  C09D4/00 ,  C09D163/00 ,  G03F7/038 ,  C08F216/00

    摘要： A curing process for cationically polymerisable monomers, which comprises applying a composition comprising: (a) at least one cationically polymerisable monomer, (b) as photoinitiator at least one iodonium salt containing an SbF6, PF6 or BF4 anion, (c) one pigment, and (d) at least one sensitiser, to a substrate, irradiating it with light having a wavelength of 200-600 nm and then heat-postcuring it, is distinguished by little yellowing of the cured formulation.

    摘要翻译： 一种阳离子可聚合单体的固化方法，其包括应用包含以下组分的组合物：（a）至少一种阳离子可聚合单体，（b）作为光引发剂的至少一种含有SbF 6，PF 6或BF 4阴离子的碘鎓盐，（c）一种颜料， 和（d）至少一种敏化剂，至少一种敏化剂，通过用波长200-600nm的光照射到基底上，然后对其进行加热后固化，其特征在于固化的配方的黄变少。