公开(公告)号：US07662434B2

公开(公告)日：2010-02-16

申请号：US11497308

申请日：2006-08-02

申请人： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： B05D7/00

CPC分类号： C08J3/215 ,  C08F12/30 ,  C08F112/08 ,  C08F112/14 ,  C08F220/06 ,  C08F220/14 ,  C08J2325/00 ,  C08F212/08

摘要： A process for preparing a metal styrene polymer composite having nano metallic particles deposited thereon is disclosed, which includes a) undergoing free radical polymerization of styrene and an optional co-monomer in the presence of a persulfate initiator and a chain transfer agent; and b) contacting the resulting styrene oligomer or copolymer of styrene and the co-monomer from step a) with an aqueous solution containing a noble metal ion dissolved therein, so that the noble metal ion is reduced to element form particles and deposit on the styrene oligomer or copolymer of styrene and the co-monomer by sulfates on the oligomer or copolymer in the absence of a reducing agent.

摘要翻译： 公开了一种制备其上沉积有纳米金属颗粒的金属苯乙烯聚合物复合物的方法，其包括：a）在过硫酸盐引发剂和链转移剂的存在下进行苯乙烯和任选的共聚单体的自由基聚合; 和b）使得到的苯乙烯低聚物或苯乙烯共聚物与来自步骤a）的共聚单体与其中溶解有贵金属离子的水溶液接触，使得贵金属离子被还原为元素形式的颗粒并沉积在苯乙烯 在不存在还原剂的情况下，低聚物或共聚物上的苯乙烯和共聚单体的低聚物或共聚物由硫酸盐组成。

公开(公告)号：US20100015338A1

公开(公告)日：2010-01-21

申请号：US11497308

申请日：2006-08-02

申请人： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： B05D3/10

CPC分类号： C08J3/215 ,  C08F12/30 ,  C08F112/08 ,  C08F112/14 ,  C08F220/06 ,  C08F220/14 ,  C08J2325/00 ,  C08F212/08

摘要： A process for preparing a metal styrene polymer composite having nano metallic particles deposited thereon is disclosed, which includes a) undergoing free radical polymerization of styrene and an optional co-monomer in the presence of a persulfate initiator and a chain transfer agent; and b) contacting the resulting styrene oligomer or copolymer of styrene and the co-monomer from step a) with an aqueous solution containing a noble metal ion dissolved therein, so that the noble metal ion is reduced to element form particles and deposit on the styrene oligomer or copolymer of styrene and the co-monomer by sulfates on the oligomer or copolymer in the absence of a reducing agent.

摘要翻译： 公开了一种制备其上沉积有纳米金属颗粒的金属苯乙烯聚合物复合物的方法，其包括：a）在过硫酸盐引发剂和链转移剂的存在下进行苯乙烯和任选的共聚单体的自由基聚合; 和b）使得到的苯乙烯低聚物或苯乙烯共聚物与来自步骤a）的共聚单体与其中溶解有贵金属离子的水溶液接触，使得贵金属离子被还原为元素形式的颗粒并沉积在苯乙烯 在不存在还原剂的情况下，低聚物或共聚物上的苯乙烯和共聚单体的低聚物或共聚物由硫酸盐组成。

公开(公告)号：US20090041941A1

公开(公告)日：2009-02-12

申请号：US11979760

申请日：2007-11-08

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： B05D1/36

CPC分类号： H05K1/095 ,  H05K3/182 ,  H05K3/246 ,  H05K2201/0347 ,  H05K2203/0709 ,  H05K2203/072 ,  H05K2203/121

摘要： A method for forming a metal pattern on a substrate via printing and electroless plating is disclosed, which includes printing a pattern on the substrate with an ink composition, drying the printed pattern, and contacting the dried pattern with an electroless plating solution. The ink composition either contains components (i), (ii) and (iii), components (i) and (iv), or components (i) and (v), which are dissolved or dispersed in a solvent, wherein (i) is a binder; (ii) is a sulfate terminated polymer of an ethylenically unsaturated monomer; (iii) is a catalytic metal precursor; (iv) is a polymer of an ethylenically unsaturated monomer deposited with particles of catalytic metal; and (v) is a copolymer of an ethylenically unsaturated monomer and a hydrophilic monomer deposited with particles of catalytic metal. The binder (i) is a water swellable resin. The catalytic metal may be Au, Ag, Pd, Pt or Ru.

摘要翻译： 公开了一种通过印刷和化学镀在基板上形成金属图案的方法，其包括用油墨组合物在基板上印刷图案，干燥印刷图案，并将干燥图案与化学镀溶液接触。 油墨组合物中含有溶解或分散在溶剂中的组分（i），（ii）和（iii），组分（i）和（iv）或组分（i）和（v）），其中（i） 是一种粘合剂; （ii）是烯键式不饱和单体的硫酸封端聚合物; （iii）是催化金属前体; （iv）是沉积有催化金属颗粒的烯属不饱和单体的聚合物; 和（v）是烯属不饱和单体和沉积有催化金属颗粒的亲水单体的共聚物。 粘合剂（i）是水溶胀性树脂。 催化金属可以是Au，Ag，Pd，Pt或Ru。

公开(公告)号：US08318254B2

公开(公告)日：2012-11-27

申请号：US12289542

申请日：2008-10-30

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： B05D1/36 ,  B05D5/00

CPC分类号： H05K3/182 ,  C23C18/1608 ,  C23C18/168 ,  C23C18/1893 ,  C23C18/2086 ,  C23C18/32 ,  C23C18/38 ,  H05K3/422 ,  H05K2203/0709

摘要： A copolymer deposited with particles of catalytic metal is disclosed in the present invention, which is formed from an ethylenically unsaturated monomer and a hydrophilic monomer, and the catalytic metal is Au, Ag, Pd, Pt or Ru. The copolymer is hydrophilic when the temperature is lower than a specific temperature, and will become hydrophobic when the temperature is greater than the specific temperature. The present invention also discloses a method for forming a metal layer on a substrate via electroless plating, which includes contacting the substrate with an ink composition, drying the ink composition on the substrate, and contacting the dried ink composition with an electroless plating solution, wherein the ink composition contains the copolymer of the present invention in an aqueous phase. The present invention further discloses a method for forming metal conductors in through holes of a substrate.

摘要翻译： 在本发明中公开了由烯属不饱和单体和亲水性单体形成的催化金属颗粒的共聚物，催化金属是Au，Ag，Pd，Pt或Ru。 当温度低于特定温度时，共聚物是亲水性的，当温度大于特定温度时，共聚物变得疏水。 本发明还公开了一种通过化学镀在基板上形成金属层的方法，该方法包括使基材与油墨组合物接触，干燥基材上的油墨组合物，以及使干燥的油墨组合物与化学镀溶液接触，其中 油墨组合物含有本发明的水相共聚物。 本发明还公开了一种用于在基板的通孔中形成金属导体的方法。

公开(公告)号：US08323739B2

公开(公告)日：2012-12-04

申请号：US11979760

申请日：2007-11-08

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： C23C18/18 ,  C23C18/30 ,  C23C18/34 ,  C23C18/40 ,  B05D5/00

CPC分类号： H05K1/095 ,  H05K3/182 ,  H05K3/246 ,  H05K2201/0347 ,  H05K2203/0709 ,  H05K2203/072 ,  H05K2203/121

摘要： A method for forming a metal pattern on a substrate via printing and electroless plating is disclosed, which includes printing a pattern on the substrate with an ink composition, drying the printed pattern, and contacting the dried pattern with an electroless plating solution. The ink composition either contains components (i), (ii) and (iii), components (i) and (iv), or components (i) and (v), which are dissolved or dispersed in a solvent, wherein (i) is a binder; (ii) is a sulfate terminated polymer of an ethylenically unsaturated monomer; (iii) is a catalytic metal precursor; (iv) is a polymer of an ethylenically unsaturated monomer deposited with particles of catalytic metal; and (v) is a copolymer of an ethylenically unsaturated monomer and a hydrophilic monomer deposited with particles of catalytic metal. The binder (i) is a water swellable resin. The catalytic metal may be Au, Ag, Pd, Pt or Ru.

摘要翻译： 公开了一种通过印刷和化学镀在基板上形成金属图案的方法，其包括用油墨组合物在基板上印刷图案，干燥印刷图案，并将干燥图案与化学镀溶液接触。 油墨组合物中含有溶解或分散在溶剂中的组分（i），（ii）和（iii），组分（i）和（iv）或组分（i）和（v）），其中（i） 是一种粘合剂; （ii）是烯键式不饱和单体的硫酸封端聚合物; （iii）是催化金属前体; （iv）是沉积有催化金属颗粒的烯属不饱和单体的聚合物; 和（v）是烯属不饱和单体和沉积有催化金属颗粒的亲水单体的共聚物。 粘合剂（i）是水溶胀性树脂。 催化金属可以是Au，Ag，Pd，Pt或Ru。

公开(公告)号：US20060228550A1

公开(公告)日：2006-10-12

申请号：US11186872

申请日：2005-07-22

申请人： Jinn-Luh Ou ,  Ming-Der Ger ,  Yuh Sung ,  Hui Chen ,  Wang-Do May ,  Chun-Chieh Tseng ,  Hung-Wen Ling

发明人： Jinn-Luh Ou ,  Ming-Der Ger ,  Yuh Sung ,  Hui Chen ,  Wang-Do May ,  Chun-Chieh Tseng ,  Hung-Wen Ling

IPC分类号： B32B5/16

CPC分类号： C08F8/42 ,  Y10T428/2982 ,  C08F12/08

摘要： A method for synthesizing monodipersive polymeric microspheres is disclosed. The method can control the diameter distribution of the microspheres and make it homogeneous. The manufactured polymeric microspheres also have plural functional groups on the surface for depositing metal particles thereon through redox. Moreover, the metal particles can be distributed on the surface of the polymeric microspheres homogeneously.

摘要翻译： 公开了一种合成单二聚物微球的方法。 该方法可以控制微球的直径分布并使其均匀。 所制造的聚合物微球体在表面上还具有多个官能团，用于通过氧化还原将金属颗粒沉积在其上。 此外，金属颗粒可以均匀地分布在聚合物微球的表面上。

公开(公告)号：US20080081193A1

公开(公告)日：2008-04-03

申请号：US11889375

申请日：2007-08-13

申请人： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

发明人： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

IPC分类号： C08F292/00 ,  B01J13/02

CPC分类号： C08F292/00 ,  B01J13/14 ,  C08F257/02 ,  C08F285/00 ,  C08L51/003 ,  C08L51/10 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/2998 ,  C08L2666/02

摘要： The present invention discloses a two-stage process for preparing functionalized magnetizable microspheres. The first stage includes forming an inner shell of styrene polymer or styrene copolymer around magnetizable nano particles having a monolayer of a non-water-soluble dispersing agent coated thereon. The second stage includes forming an outer shell of styrene polymer or styrene copolymer with sulfate (SO4−) bounded thereto around the inner shell by free radical polymerization. Preferably, nano particles of a noble metal are deposited on the surface of the outer shell. The magnetizable microspheres prepared by the process of the present invention have a size of 100-1000 nm, and the thickness ratio of the inner shell to the outer shell ranges from 10:1 to 1:10.

摘要翻译： 本发明公开了一种用于制备官能化可磁化微球的两阶段方法。 第一阶段包括在其上涂覆有非水溶性分散剂的单层的可磁化纳米颗粒周围形成苯乙烯聚合物或苯乙烯共聚物的内壳。 第二阶段包括通过自由基聚合在内壳周围形成与硫酸盐（SO 4 SO 3 - ）结合的苯乙烯聚合物或苯乙烯共聚物的外壳。 优选地，贵金属的纳米颗粒沉积在外壳的表面上。 通过本发明的方法制备的可磁化微球的尺寸为100-1000nm，内壳与外壳的厚度比为10:1至1:10。

公开(公告)号：US07553542B2

公开(公告)日：2009-06-30

申请号：US11889375

申请日：2007-08-13

申请人： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

发明人： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

IPC分类号： B32B5/66

CPC分类号： C08F292/00 ,  B01J13/14 ,  C08F257/02 ,  C08F285/00 ,  C08L51/003 ,  C08L51/10 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/2998 ,  C08L2666/02

摘要： The present invention discloses a two-stage process for preparing functionalized magnetizable microspheres. The first stage includes forming an inner shell of styrene polymer or styrene copolymer around magnetizable nano particles having a monolayer of a non-water-soluble dispersing agent coated thereon. The second stage includes forming an outer shell of styrene polymer or styrene copolymer with sulfate (SO4−) bounded thereto around the inner shell by free radical polymerization. Preferably, nano particles of a noble metal are deposited on the surface of the outer shell. The magnetizable microspheres prepared by the process of the present invention have a size of 100-1000 nm, and the thickness ratio of the inner shell to the outer shell ranges from 10:1 to 1:10.

摘要翻译： 本发明公开了一种用于制备官能化可磁化微球的两阶段方法。 第一阶段包括在其上涂覆有非水溶性分散剂的单层的可磁化纳米颗粒周围形成苯乙烯聚合物或苯乙烯共聚物的内壳。 第二阶段包括通过自由基聚合在内壳上形成与硫酸盐（SO 4 - ）结合的苯乙烯聚合物或苯乙烯共聚物的外壳。 优选地，贵金属的纳米颗粒沉积在外壳的表面上。 通过本发明的方法制备的可磁化微球的尺寸为100-1000nm，内壳与外壳的厚度比为10:1至1:10。

公开(公告)号：US20100075026A1

公开(公告)日：2010-03-25

申请号：US12289542

申请日：2008-10-30

申请人： Yuh Sung ,  Ming-Der Ger ,  Chang-Pin Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

发明人： Yuh Sung ,  Ming-Der Ger ,  Chang-Pin Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC分类号： C08K3/08 ,  B05D3/10 ,  H01C17/00

CPC分类号： H05K3/182 ,  C23C18/1608 ,  C23C18/168 ,  C23C18/1893 ,  C23C18/2086 ,  C23C18/32 ,  C23C18/38 ,  H05K3/422 ,  H05K2203/0709

摘要： A copolymer deposited with particles of catalytic metal is disclosed in the present invention, which is formed from an ethylenically unsaturated monomer and a hydrophilic monomer, and the catalytic metal is Au, Ag, Pd, Pt or Ru. The copolymer is hydrophilic when the temperature is lower than a specific temperature, and will become hydrophobic when the temperature is greater than the specific temperature. The present invention also discloses a method for forming a metal layer on a substrate via electroless plating, which includes contacting the substrate with an ink composition, drying the ink composition on the substrate, and contacting the dried ink composition with an electroless plating solution, wherein the ink composition contains the copolymer of the present invention in an aqueous phase. The present invention further discloses a method for forming metal conductors in through holes of a substrate.

摘要翻译： 在本发明中公开了由烯属不饱和单体和亲水性单体形成的催化金属颗粒的共聚物，催化金属是Au，Ag，Pd，Pt或Ru。 当温度低于特定温度时，共聚物是亲水性的，当温度大于特定温度时，共聚物变得疏水。 本发明还公开了一种通过化学镀在基板上形成金属层的方法，该方法包括使基材与油墨组合物接触，干燥基材上的油墨组合物，以及使干燥的油墨组合物与化学镀溶液接触，其中 油墨组合物含有本发明的水相共聚物。 本发明还公开了一种用于在基板的通孔中形成金属导体的方法。

公开(公告)号：US20060228489A1

公开(公告)日：2006-10-12

申请号：US11246174

申请日：2005-10-11

申请人： Yuh Sung ,  Ming-Der Ger ,  Yu-Hsien Chou ,  Jinn-Luh Ou

发明人： Yuh Sung ,  Ming-Der Ger ,  Yu-Hsien Chou ,  Jinn-Luh Ou

IPC分类号： B05D1/18 ,  B05D3/02

CPC分类号： C23C18/1676 ,  C23C18/1607 ,  C23C18/1651 ,  C23C18/1879 ,  C23C18/31 ,  C23C18/34 ,  C23C18/405 ,  C23C18/44 ,  H01L21/288 ,  H01L21/76877

摘要： The present invention discloses a method for forming a metallic microstructure on a patterned surface of a substrate by a nonisothermal deposition (NTID) in an electroless plating solution. The substrate is immersed in the solution being heated by a heating device mounted on a bottom of an electroless plating reactor while the heated solution being cooled by a cooling device provided in the reactor, and thus a seed layer is formed the patterned surface of the substrate. The substrate is then immersed in an electroless plating solution with a back surface of the substrate lying on the bottom of the reactor, so that the exposed seed layer is thickened to form the metallic microstructure.

摘要翻译： 本发明公开了一种在化学镀溶液中通过非等温沉积（NTID）在衬底的图案化表面上形成金属微结构的方法。 将衬底浸入被安装在化学镀电镀反应器底部的加热装置加热的溶液中，同时通过设置在反应器中的冷却装置冷却加热的溶液，从而种子层形成衬底的图案化表面 。 然后将衬底浸入无碱电解溶液中，其中衬底的背面位于反应器的底部，使得暴露的种子层变厚以形成金属微结构。