公开(公告)号：US20130122191A1

公开(公告)日：2013-05-16

申请号：US13293237

申请日：2011-11-10

Applicant: Li-Chun Wang ,  Yuh Sung ,  Shiaw-Ruey Lin ,  Cheng-Long Ho ,  Chang-Ping Chang ,  Chen-Yu Lin

Inventor： Li-Chun Wang ,  Yuh Sung ,  Shiaw-Ruey Lin ,  Cheng-Long Ho ,  Chang-Ping Chang ,  Chen-Yu Lin

IPC: B05D5/12 ,  B82Y15/00 ,  B82Y40/00

CPC classification number: G01N27/126 ,  B82Y15/00 ,  B82Y30/00

Abstract: A method for making a conductive polymer composite for detecting a gas includes forming a porous conductive layer of a conductive powder on a substrate, applying a polymer solution containing a solvent and a gas responsive polymer material dissolved in the solvent to the porous conductive layer such that a portion of the polymer solution penetrates into the porous conductive layer and the remainder of the polymer solution forms a thin film covering a top of the porous conductive layer, the gas responsive polymer material being capable of adsorbing and desorbing the gas, and removing the solvent from the polymer solution so as to form a polymer matrix covering the porous conductive layer.

Abstract translation: 制造用于检测气体的导电聚合物复合材料的方法包括在基板上形成导电粉末的多孔导电层，将溶解在溶剂中的溶剂和气体响应性聚合物材料的聚合物溶液施加到多孔导电层，使得 聚合物溶液的一部分渗透到多孔导电层中，其余的聚合物溶液形成覆盖多孔导电层顶部的薄膜，气体响应性聚合物材料能够吸附和解吸气体，并除去溶剂 从聚合物溶液中形成覆盖多孔导电层的聚合物基体。

公开(公告)号：US07662434B2

公开(公告)日：2010-02-16

申请号：US11497308

申请日：2006-08-02

Applicant: Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

Inventor： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC: B05D7/00

CPC classification number: C08J3/215 ,  C08F12/30 ,  C08F112/08 ,  C08F112/14 ,  C08F220/06 ,  C08F220/14 ,  C08J2325/00 ,  C08F212/08

Abstract: A process for preparing a metal styrene polymer composite having nano metallic particles deposited thereon is disclosed, which includes a) undergoing free radical polymerization of styrene and an optional co-monomer in the presence of a persulfate initiator and a chain transfer agent; and b) contacting the resulting styrene oligomer or copolymer of styrene and the co-monomer from step a) with an aqueous solution containing a noble metal ion dissolved therein, so that the noble metal ion is reduced to element form particles and deposit on the styrene oligomer or copolymer of styrene and the co-monomer by sulfates on the oligomer or copolymer in the absence of a reducing agent.

Abstract translation: 公开了一种制备其上沉积有纳米金属颗粒的金属苯乙烯聚合物复合物的方法，其包括：a）在过硫酸盐引发剂和链转移剂的存在下进行苯乙烯和任选的共聚单体的自由基聚合; 和b）使得到的苯乙烯低聚物或苯乙烯共聚物与来自步骤a）的共聚单体与其中溶解有贵金属离子的水溶液接触，使得贵金属离子被还原为元素形式的颗粒并沉积在苯乙烯 在不存在还原剂的情况下，低聚物或共聚物上的苯乙烯和共聚单体的低聚物或共聚物由硫酸盐组成。

公开(公告)号：US08323739B2

公开(公告)日：2012-12-04

申请号：US11979760

申请日：2007-11-08

Applicant: Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

Inventor： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC: C23C18/18 ,  C23C18/30 ,  C23C18/34 ,  C23C18/40 ,  B05D5/00

CPC classification number: H05K1/095 ,  H05K3/182 ,  H05K3/246 ,  H05K2201/0347 ,  H05K2203/0709 ,  H05K2203/072 ,  H05K2203/121

Abstract: A method for forming a metal pattern on a substrate via printing and electroless plating is disclosed, which includes printing a pattern on the substrate with an ink composition, drying the printed pattern, and contacting the dried pattern with an electroless plating solution. The ink composition either contains components (i), (ii) and (iii), components (i) and (iv), or components (i) and (v), which are dissolved or dispersed in a solvent, wherein (i) is a binder; (ii) is a sulfate terminated polymer of an ethylenically unsaturated monomer; (iii) is a catalytic metal precursor; (iv) is a polymer of an ethylenically unsaturated monomer deposited with particles of catalytic metal; and (v) is a copolymer of an ethylenically unsaturated monomer and a hydrophilic monomer deposited with particles of catalytic metal. The binder (i) is a water swellable resin. The catalytic metal may be Au, Ag, Pd, Pt or Ru.

Abstract translation: 公开了一种通过印刷和化学镀在基板上形成金属图案的方法，其包括用油墨组合物在基板上印刷图案，干燥印刷图案，并将干燥图案与化学镀溶液接触。 油墨组合物中含有溶解或分散在溶剂中的组分（i），（ii）和（iii），组分（i）和（iv）或组分（i）和（v）），其中（i） 是一种粘合剂; （ii）是烯键式不饱和单体的硫酸封端聚合物; （iii）是催化金属前体; （iv）是沉积有催化金属颗粒的烯属不饱和单体的聚合物; 和（v）是烯属不饱和单体和沉积有催化金属颗粒的亲水单体的共聚物。 粘合剂（i）是水溶胀性树脂。 催化金属可以是Au，Ag，Pd，Pt或Ru。

公开(公告)号：US20100015338A1

公开(公告)日：2010-01-21

申请号：US11497308

申请日：2006-08-02

Applicant: Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

Inventor： Jinn-Luh Ou ,  Chang-Ping Chang ,  Yuh Sung ,  Ming-Der Ger ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC: B05D3/10

CPC classification number: C08J3/215 ,  C08F12/30 ,  C08F112/08 ,  C08F112/14 ,  C08F220/06 ,  C08F220/14 ,  C08J2325/00 ,  C08F212/08

Abstract: A process for preparing a metal styrene polymer composite having nano metallic particles deposited thereon is disclosed, which includes a) undergoing free radical polymerization of styrene and an optional co-monomer in the presence of a persulfate initiator and a chain transfer agent; and b) contacting the resulting styrene oligomer or copolymer of styrene and the co-monomer from step a) with an aqueous solution containing a noble metal ion dissolved therein, so that the noble metal ion is reduced to element form particles and deposit on the styrene oligomer or copolymer of styrene and the co-monomer by sulfates on the oligomer or copolymer in the absence of a reducing agent.

Abstract translation: 公开了一种制备其上沉积有纳米金属颗粒的金属苯乙烯聚合物复合物的方法，其包括：a）在过硫酸盐引发剂和链转移剂的存在下进行苯乙烯和任选的共聚单体的自由基聚合; 和b）使得到的苯乙烯低聚物或苯乙烯共聚物与来自步骤a）的共聚单体与其中溶解有贵金属离子的水溶液接触，使得贵金属离子被还原为元素形式的颗粒并沉积在苯乙烯 在不存在还原剂的情况下，低聚物或共聚物上的苯乙烯和共聚单体的低聚物或共聚物由硫酸盐组成。

公开(公告)号：US07553542B2

公开(公告)日：2009-06-30

申请号：US11889375

申请日：2007-08-13

Applicant: Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

Inventor： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

IPC: B32B5/66

CPC classification number: C08F292/00 ,  B01J13/14 ,  C08F257/02 ,  C08F285/00 ,  C08L51/003 ,  C08L51/10 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/2998 ,  C08L2666/02

Abstract: The present invention discloses a two-stage process for preparing functionalized magnetizable microspheres. The first stage includes forming an inner shell of styrene polymer or styrene copolymer around magnetizable nano particles having a monolayer of a non-water-soluble dispersing agent coated thereon. The second stage includes forming an outer shell of styrene polymer or styrene copolymer with sulfate (SO4−) bounded thereto around the inner shell by free radical polymerization. Preferably, nano particles of a noble metal are deposited on the surface of the outer shell. The magnetizable microspheres prepared by the process of the present invention have a size of 100-1000 nm, and the thickness ratio of the inner shell to the outer shell ranges from 10:1 to 1:10.

Abstract translation: 本发明公开了一种用于制备官能化可磁化微球的两阶段方法。 第一阶段包括在其上涂覆有非水溶性分散剂的单层的可磁化纳米颗粒周围形成苯乙烯聚合物或苯乙烯共聚物的内壳。 第二阶段包括通过自由基聚合在内壳上形成与硫酸盐（SO 4 - ）结合的苯乙烯聚合物或苯乙烯共聚物的外壳。 优选地，贵金属的纳米颗粒沉积在外壳的表面上。 通过本发明的方法制备的可磁化微球的尺寸为100-1000nm，内壳与外壳的厚度比为10:1至1:10。

公开(公告)号：US08551571B2

公开(公告)日：2013-10-08

申请号：US13293237

申请日：2011-11-10

Applicant: Li-Chun Wang ,  Yuh Sung ,  Shiaw-Ruey Lin ,  Cheng-Long Ho ,  Chang-Ping Chang ,  Chen-Yu Lin

Inventor： Li-Chun Wang ,  Yuh Sung ,  Shiaw-Ruey Lin ,  Cheng-Long Ho ,  Chang-Ping Chang ,  Chen-Yu Lin

IPC: B05D5/12 ,  B05D1/38

CPC classification number: G01N27/126 ,  B82Y15/00 ,  B82Y30/00

Abstract: A method for making a conductive polymer composite for detecting a gas includes forming a porous conductive layer of a conductive powder on a substrate, applying a polymer solution containing a solvent and a gas responsive polymer material dissolved in the solvent to the porous conductive layer such that a portion of the polymer solution penetrates into the porous conductive layer and the remainder of the polymer solution forms a thin film covering a top of the porous conductive layer, the gas responsive polymer material being capable of adsorbing and desorbing the gas, and removing the solvent from the polymer solution so as to form a polymer matrix covering the porous conductive layer.

Abstract translation: 制造用于检测气体的导电聚合物复合材料的方法包括在基板上形成导电粉末的多孔导电层，将溶解在溶剂中的溶剂和气体响应性聚合物材料的聚合物溶液施加到多孔导电层，使得 聚合物溶液的一部分渗透到多孔导电层中，其余的聚合物溶液形成覆盖多孔导电层顶部的薄膜，气体响应性聚合物材料能够吸附和解吸气体，并除去溶剂 从聚合物溶液中形成覆盖多孔导电层的聚合物基体。

公开(公告)号：US08318254B2

公开(公告)日：2012-11-27

申请号：US12289542

申请日：2008-10-30

Applicant: Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

Inventor： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC: B05D1/36 ,  B05D5/00

CPC classification number: H05K3/182 ,  C23C18/1608 ,  C23C18/168 ,  C23C18/1893 ,  C23C18/2086 ,  C23C18/32 ,  C23C18/38 ,  H05K3/422 ,  H05K2203/0709

Abstract: A copolymer deposited with particles of catalytic metal is disclosed in the present invention, which is formed from an ethylenically unsaturated monomer and a hydrophilic monomer, and the catalytic metal is Au, Ag, Pd, Pt or Ru. The copolymer is hydrophilic when the temperature is lower than a specific temperature, and will become hydrophobic when the temperature is greater than the specific temperature. The present invention also discloses a method for forming a metal layer on a substrate via electroless plating, which includes contacting the substrate with an ink composition, drying the ink composition on the substrate, and contacting the dried ink composition with an electroless plating solution, wherein the ink composition contains the copolymer of the present invention in an aqueous phase. The present invention further discloses a method for forming metal conductors in through holes of a substrate.

Abstract translation: 在本发明中公开了由烯属不饱和单体和亲水性单体形成的催化金属颗粒的共聚物，催化金属是Au，Ag，Pd，Pt或Ru。 当温度低于特定温度时，共聚物是亲水性的，当温度大于特定温度时，共聚物变得疏水。 本发明还公开了一种通过化学镀在基板上形成金属层的方法，该方法包括使基材与油墨组合物接触，干燥基材上的油墨组合物，以及使干燥的油墨组合物与化学镀溶液接触，其中 油墨组合物含有本发明的水相共聚物。 本发明还公开了一种用于在基板的通孔中形成金属导体的方法。

公开(公告)号：US20080081193A1

公开(公告)日：2008-04-03

申请号：US11889375

申请日：2007-08-13

Applicant: Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

Inventor： Jinn-Luh Ou ,  Yuh Sung ,  Chang-Ping Chang ,  Ming-Der Ger ,  Szu-Ching Hsiao ,  Yan-Cheng Chen

IPC: C08F292/00 ,  B01J13/02

CPC classification number: C08F292/00 ,  B01J13/14 ,  C08F257/02 ,  C08F285/00 ,  C08L51/003 ,  C08L51/10 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/2998 ,  C08L2666/02

Abstract: The present invention discloses a two-stage process for preparing functionalized magnetizable microspheres. The first stage includes forming an inner shell of styrene polymer or styrene copolymer around magnetizable nano particles having a monolayer of a non-water-soluble dispersing agent coated thereon. The second stage includes forming an outer shell of styrene polymer or styrene copolymer with sulfate (SO4−) bounded thereto around the inner shell by free radical polymerization. Preferably, nano particles of a noble metal are deposited on the surface of the outer shell. The magnetizable microspheres prepared by the process of the present invention have a size of 100-1000 nm, and the thickness ratio of the inner shell to the outer shell ranges from 10:1 to 1:10.

Abstract translation: 本发明公开了一种用于制备官能化可磁化微球的两阶段方法。 第一阶段包括在其上涂覆有非水溶性分散剂的单层的可磁化纳米颗粒周围形成苯乙烯聚合物或苯乙烯共聚物的内壳。 第二阶段包括通过自由基聚合在内壳周围形成与硫酸盐（SO 4 SO 3 - ）结合的苯乙烯聚合物或苯乙烯共聚物的外壳。 优选地，贵金属的纳米颗粒沉积在外壳的表面上。 通过本发明的方法制备的可磁化微球的尺寸为100-1000nm，内壳与外壳的厚度比为10:1至1:10。

公开(公告)号：US20090041941A1

公开(公告)日：2009-02-12

申请号：US11979760

申请日：2007-11-08

Applicant: Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

Inventor： Yuh Sung ,  Ming-Der Ger ,  Chang-Ping Chang ,  Chun-Chieh Tseng ,  Wen-Ding Chen

IPC: B05D1/36

CPC classification number: H05K1/095 ,  H05K3/182 ,  H05K3/246 ,  H05K2201/0347 ,  H05K2203/0709 ,  H05K2203/072 ,  H05K2203/121

Abstract: A method for forming a metal pattern on a substrate via printing and electroless plating is disclosed, which includes printing a pattern on the substrate with an ink composition, drying the printed pattern, and contacting the dried pattern with an electroless plating solution. The ink composition either contains components (i), (ii) and (iii), components (i) and (iv), or components (i) and (v), which are dissolved or dispersed in a solvent, wherein (i) is a binder; (ii) is a sulfate terminated polymer of an ethylenically unsaturated monomer; (iii) is a catalytic metal precursor; (iv) is a polymer of an ethylenically unsaturated monomer deposited with particles of catalytic metal; and (v) is a copolymer of an ethylenically unsaturated monomer and a hydrophilic monomer deposited with particles of catalytic metal. The binder (i) is a water swellable resin. The catalytic metal may be Au, Ag, Pd, Pt or Ru.

Abstract translation: 公开了一种通过印刷和化学镀在基板上形成金属图案的方法，其包括用油墨组合物在基板上印刷图案，干燥印刷图案，并将干燥图案与化学镀溶液接触。 油墨组合物中含有溶解或分散在溶剂中的组分（i），（ii）和（iii），组分（i）和（iv）或组分（i）和（v）），其中（i） 是一种粘合剂; （ii）是烯键式不饱和单体的硫酸封端聚合物; （iii）是催化金属前体; （iv）是沉积有催化金属颗粒的烯属不饱和单体的聚合物; 和（v）是烯属不饱和单体和沉积有催化金属颗粒的亲水单体的共聚物。 粘合剂（i）是水溶胀性树脂。 催化金属可以是Au，Ag，Pd，Pt或Ru。