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    Soluble organopolysiloxane free-radical macroinitators for graft copolymerization
    1.
    发明授权
    Soluble organopolysiloxane free-radical macroinitators for graft copolymerization 失效
    用于接枝共聚的可溶性有机聚硅氧烷自由基大分子

    公开(公告)号：US5605983A

    公开(公告)日：1997-02-25

    申请号：US360102

    申请日：1994-12-20

    申请人： Jochen Dauth ,  Catherine Oleggini ,  Bernward Deubzer

    发明人： Jochen Dauth ,  Catherine Oleggini ,  Bernward Deubzer

    IPC分类号： C08F4/00 ,  C08F283/12 ,  C08G77/48 ,  C08G77/392 ,  C08G77/388

    CPC分类号： C08G77/48 ,  C08F283/12

    摘要： The invention relates to partially crosslinked organopolysiloxanes which contain a radical forming group, a base-catalyzed process for their preparation, graft copolymers produced from these organopolysiloxanes and a process for the preparation of the graft copolymers. The present invention avoids problems related to known methods wherein a considerable portion of the organopolymer chains do not graft to the organopolysiloxane graft back-bone but remain as an unattached homopolymers.

    摘要翻译： 本发明涉及含有自由基形成基团的部分交联的有机聚硅氧烷，其制备的碱催化方法，由这些有机聚硅氧烷制备的接枝共聚物和制备接枝共聚物的方法。 本发明避免了与已知方法相关的问题，其中相当大一部分的有机聚合物链不接枝到有机聚硅氧烷移植物背骨上，而是保留为未附着的均聚物。

    Permanent organosilicon compounds, their preparation and use
    2.
    发明授权
    Permanent organosilicon compounds, their preparation and use 失效
    永久性有机硅化合物，其制备和用途

    公开(公告)号：US5998562A

    公开(公告)日：1999-12-07

    申请号：US888934

    申请日：1997-07-07

    申请人： Guenter Mahr ,  Jochen Dauth ,  Bernward Deubzer ,  Monika Ott ,  Petra Gratzl ,  Hans Lautenschlager

    发明人： Guenter Mahr ,  Jochen Dauth ,  Bernward Deubzer ,  Monika Ott ,  Petra Gratzl ,  Hans Lautenschlager

    IPC分类号： C14C11/00 ,  C07F7/10 ,  C07F7/18 ,  C08G77/10 ,  C08G77/26 ,  C08G77/388 ,  C08G77/54 ,  D06M15/643 ,  C08G77/08

    CPC分类号： C08G77/388 ,  C08G77/54 ,  Y10S8/01

    摘要： The present invention relates to triazine-containing organosilicon compounds having units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),whereR is identical or different and denotes a hydrogen atom or a monovalent substituted or unsubstituted hydrocarbon radical, having 1 to 26 carbon atoms, preferably 1 to 18 per radical,X is identical or different and is a halogen atom, a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical, having 1 to 18 carbon atoms, preferably 1 to 8 per radical and which may be substituted by an ether oxygen atom,a is 0 or 1, preferably 0.01-0.5b is 0, 1, 2 or 3, preferably 0.5-3.0c is 0, 1, 2 or 3, preferably 0.0-2.0 and the sum a+b+c.ltoreq.4, preferably 0.1-3.5, andA is a radical of the formula ##STR1## where R.sup.2 is an unbranched or branched, optionally substituted alkylene radical, having 1 to 18, preferably 1 to 12, carbon atoms,Y is identical or different and denotes a hydrogen atom or an unbranched or branched alkyl radical, having 1 to 12, preferably 1 to 8, carbon atoms or denotes a radical of the formula --OR.sup.1, where R.sup.1 has the meaning given above, andZ is identical or different and denotes X, --NR.sub.2, --(O)CR or --SR, where X and R have the meanings given above with the proviso that at least one radical A containing at least one halogen atom, preferably a chlorine atom, is present per polymer molecule.

    摘要翻译： 本发明涉及具有式AaRbXcSiO（4-abc）/ 2（I）单元的含三嗪的有机硅化合物，其中R相同或不同，表示氢原子或一价取代或未取代的烃基，其具有1至 26个碳原子，优选1至18个基团，X相同或不同，为卤素原子，氯原子或式-OR1基团，其中R1表示具有1至18个碳原子的烷基，优选1 至8个，并且可被醚氧原子取代，a为0或1，优选为0.01-0.5b为0,1,2或3，优选0.5-3.0c为0,1,2或3，优选为 总和a + b + c 4，优选0.1-3.5，A是下式的基团，其中R 2是无支链或支链的任选取代的亚烷基，其具有1至18，优选1至 12，碳原子，Y相同或不同，表示氢原子或无支链或支链烷基，具有1至12个， 优选为1〜8个碳原子，或表示式-OR1的基团，其中R1具有上述含义，Z相同或不同，表示X，-NR2， - （O）CR或-SR，其中X和 R具有上述含义，条件是每个聚合物分子存在至少一个含有至少一个卤素原子，优选氯原子的基团A.

    Process for preparing organosilicon compounds containing (meth)acryloxy groups
    4.
    发明授权
    Process for preparing organosilicon compounds containing (meth)acryloxy groups 失效
    制备含有（甲基）丙烯酰氧基的有机硅化合物的方法

    公开(公告)号：US5869726A

    公开(公告)日：1999-02-09

    申请号：US931723

    申请日：1997-09-16

    申请人： Jochen Dauth ,  Bernward Deubzer ,  Petra Gratzl ,  Josef Wolferseder

    发明人： Jochen Dauth ,  Bernward Deubzer ,  Petra Gratzl ,  Josef Wolferseder

    IPC分类号： C08G77/12 ,  C08G77/20 ,  C08G77/38 ,  C09D183/06 ,  C09D183/07 ,  C07F7/08

    CPC分类号： C09D183/06 ,  C08G77/38

    摘要： A novel process for preparing organosilicon compounds containing (meth)acxyloxy groups is described, in which alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) of the formula ##STR1## where R.sup.2 is a hydrogen atom or a methyl radical,R.sup.3 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical andR.sub.4 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical, andz is an integer from 1 to 12,are reacted with organosilicon compounds (2) comprising units of the formula ##STR2## where R is an identical or different monovalent, optionally halogenated hydrocarbon radical having from 1 to 18 carbon atoms per radical, ande is 0 or 1, on average from 0.01 to 1.0,f is 0, 1, 2 or 3, on average from 0.0 to 3.0, andhaving at least one Si-bonded hydrogen atom per molecule in the presence of catalysts (3) which promote the addition Si-bonded hydrogen onto aliphatic multiple bonds and also in the presence of polymerization inhibitors (4), where alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) are used in amounts of from 1.01 to 1.5 mole per gram atom of Si-bonded hydrogen in organosilicon compound (2).

    摘要翻译： 描述了制备含有（甲基）丙氧基的有机硅化合物的新方法，其中式（II）的烷氧基​​化烷基-2-炔基1,4-二（甲基）丙烯酸酯（1）其中R2是氢 原子或甲基，R3是每个基团具有1至6个碳原子的直链或支链亚烷基，R4是每个基团具有1至6个碳原子的直链或支链亚烷基，z是1至 12与包含式（III）的单元的有机硅化合物（2）反应，其中R是相对或不同的每个基团具有1至18个碳原子的单价，任选卤代烃基，e是0或1 平均为0.01〜1.0，f为0,1,2或3，平均为0.0〜3.0，在催化剂（3）的存在下，每分子具有至少一个Si键合的氢原子，促进Si的添加 键合的氢键到脂族多重键上，并且在聚合抑制剂的存在下（4）， 其中烷氧基化的烷基-2-炔1,4-二（甲基）丙烯酸酯（1）的用量为有机硅化合物（2）中每克原子的Si键合氢的1.01至1.5摩尔。

    Radiation-curing or heat-curing organosiloxane compositions containing (methyl) styrene groups
    6.
    发明授权
    Radiation-curing or heat-curing organosiloxane compositions containing (methyl) styrene groups 失效
    含有（甲基）苯乙烯基团的辐射固化或热固化有机硅氧烷组合物

    公开(公告)号：US6068929A

    公开(公告)日：2000-05-30

    申请号：US72211

    申请日：1998-05-04

    申请人： Jochen Dauth ,  Josef Wolferseder ,  Bernward Deubzer

    发明人： Jochen Dauth ,  Josef Wolferseder ,  Bernward Deubzer

    IPC分类号： C08F299/08 ,  C08F290/14 ,  C08G77/38 ,  C08G77/46 ,  C08G77/50 ,  C08L83/07 ,  C09D155/00 ,  C09D183/07 ,  C09D183/12 ,  C09D183/14 ,  C08F283/12 ,  B32B27/00

    CPC分类号： C09D183/12 ,  C08G77/46 ,  C08G77/50 ,  C09D183/14

    摘要： Novel organosiloxane compositions which contain (methyl)styrene groups and can be prepared on the basis ofA) oligomeric or polymeric organosilicon compounds comprising at least one unit of the formulaGR.sub.c SiO.sub.(4-c-1)/2 (I)or at least one unit of the formula (I) and at least one unit of the formulaO.sub.(4-c-1)/2) R.sub.c Si--G.sup.1 --R.sub.c SiO.sub.(4-c-1)/2(II)B) monomeric alkenyloxy compounds, maleates, fumarates, maleimides, (meth)acrylates, (methyl)styrenes, acrylamides, itaconic esters and/or oligomeric or polymeric organosilicon compounds containing on average more than one alkenyloxy, maleate, fumarate, maleimide or (meth)acrylate group, where R are identical or different hydrocarbon radicals which may be halogenated or unhalogenated or a radical of the formula--R.sup.1 --[OCH.sub.2 CH.sub.2 ].sub.o --[OCH(CH.sub.3)CH.sub.2 ].sub.p --[O(CH.sub.2).sub.4 ].sub.q --OR.sup.2,whereR.sup.1 is a linear or branched alkylene radical,R.sup.2 is a hydrogen atom, an alkyl radical or a radical of the formula --CO--R.sup.3, where R.sup.3 is an alkyl radical,G is a radical of the formula (IV) --R.sup.4 -(phenyl) which is substituted by [--Y.sub.(5-d) ] and (--R.sup.5.sub.d), with the proviso that at least one radical R.sup.5 is present andG.sup.1 is a radical of the formula (V) --(phenyl)-(R.sup.4).sub.d -- which is substituted by [--Y.sub.4-d ], whereR.sup.4 is a linear or branched, substituted or unsubstituted alkylene radical,R.sup.5 is a vinyl radical or isopropenyl radical,Y can be identical or different and each Y is a hydrogen atom or is as defined for R, or is a radical of the formula --OR.sup.6, whereR.sup.6 is a C.sub.1-8 alkyl radical optionally interrupted by an ether oxygen atom, andc is 0, 1 or 2, on average from 0.0 to 2.0,d is 1, 2 or 3,o is 0 or an integer from 1 to 100,p is 0 or an integer from 1 to 100, andq is 0 or an integer from 1 to 100, with the proviso that the sum o+p+q is >0.

    摘要翻译： 含有（甲基）苯乙烯基团的新型有机硅氧烷组合物并且可以基于A）包含至少一种式GRcO（4-c-1）/ 2（I）单元的低聚或聚合有机硅化合物或至少一个单元 （4-c-1）/ 2）RcSi-G1-RcSiO（4-c-1）/ 2（II）B）单体链烯氧基化合物，马来酸酯，富马酸酯的至少一个单元 ，马来酰亚胺，（甲基）丙烯酸酯，（甲基）苯乙烯，丙烯酰胺，衣康酸酯和/或低聚或聚合的有机硅化合物，其平均含有多于一个烯氧基，马来酸酯，富马酸酯，马来酰亚胺或（甲基）丙烯酸酯基团，其中R相同或 可以被卤化或未卤化的不同烃基或式-R1- [OCH2CH2] o- [OCH（CH3）CH2]对 - [O（CH2）4] q-OR2的基团，其中R1是直链或支链 亚烷基，R2是氢原子，烷基或式-CO-R3的基团，其中R3是烷基，G是式（IV）-R4-（苯基） h被[-Y（5-d）]和（-R5d）取代，条件是存在至少一个基团R 5，并且G 1是式（Ⅴ） - （苯基） - （R 4）d - 被[-Y4-d]取代，其中R4是直链或支链的取代或未取代的亚烷基，R5是乙烯基或异丙烯基，Y可以相同或不同，并且每个Y是氢原子或是 如R所定义，或者是式-OR 6的基团，其中R 6是任选被醚氧原子中断的C 1-8烷基，c是0,1或2，平均为0.0至2.0，d为 1,2或3，o为0或1〜100的整数，p为0或1〜100的整数，q为0或1〜100的整数，条件是+ o + p + q是> 0。

    Hydrophilic permanent organosilicon compounds
    7.
    发明授权
    Hydrophilic permanent organosilicon compounds 失效
    亲水性永久性有机硅化合物

    公开(公告)号：US6043362A

    公开(公告)日：2000-03-28

    申请号：US888557

    申请日：1997-07-07

    申请人： Jochen Dauth ,  Guenter Mahr ,  Bernward Deubzer ,  Petra Gratzl ,  Hans-Juergen Lautenschlager

    发明人： Jochen Dauth ,  Guenter Mahr ,  Bernward Deubzer ,  Petra Gratzl ,  Hans-Juergen Lautenschlager

    IPC分类号： C07F7/10 ,  C07F7/18 ,  C08G77/10 ,  C08G77/26 ,  C08G77/388 ,  C08G77/46 ,  D06M13/02 ,  D06M13/148 ,  D06M13/322 ,  D06M13/35 ,  D06M13/355 ,  D06M13/358 ,  D06M13/364 ,  D06M13/50 ,  D06M13/51 ,  D06M13/513 ,  C07D47/00

    CPC分类号： C08G77/388 ,  C08G77/26 ,  C08G77/46

    摘要： The invention relates to oxyalkylene-group-containing organosilicon compounds having units of the formula ##STR1## where R is identical or different, and denotes a monovalent halogenated or nonhalogenated hydrocarbon radical, X is identical or different and is a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical which can be substituted by an ether oxygen atom,a is 0 or 1,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the total a+b+c.ltoreq.4 andA is a radical of the formula ##STR2## where R.sup.2 signifies an unbranched or branched substituted or unsubstituted divalent hydrocarbon radical, which may or may not contain ether, amine, sulfide, ester, amide, carbonate, urea and urethane groups, B is identical or different, and denotes X, --NR.sub.2.sup.1, --O--C(.dbd.O)--R.sup.1, --SR.sup.1 or a radical of the formula--NR.sup.3 R.sup.2 [O--CH(CH.sub.3)--CH.sub.2 ].sub.d [OCH.sub.2 CH.sub.2 ].sub.e [O(CH.sub.2).sub.4 ].sub.f OR.sup.4 (III),where X, R.sup.1 and R.sup.2 have the meanings given for these above, R.sup.3 is identical or different and is a hydrogen atom or has the meaning of R, R.sup.4 has the meaning of R.sup.3 or signifies a radical of the formula--C(.dbd.O)--R, --R.sup.2 NR.sub.2.sup.3, --NR.sup.3 R.sup.2 --, --R.sup.2 NR.sub.2.sup.3 H.sup.+ X.sup.-,d, e and f are an integer from 0 to 200, with the proviso that the sum d+e+f.gtoreq.1 and B contains at least one radical of the formula (III) per polymer molecule.

    摘要翻译： 本发明涉及具有下式的单元的含氧化烯基的有机硅化合物，其中R相同或不同，表示一价卤代或非卤代烃基，X相同或不同，为氯原子或式 - OR1，其中R1表示可被醚氧原子取代的烷基，a为0或1，b为0,1,2或3，c为0,1,2或3，总计a + b + C 4和A是下式的基团，其中R 2表示无支链或支链的取代或未取代的二价烃基，其可以含有或不含有醚，胺，硫醚，酯，酰胺，碳酸酯，脲和氨基甲酸酯基团， B表示相同或不同的表示X，-NR 21，-OC（= O）-R 1，-SR 1或-NR 3 R 2基团的基团[O-CH（CH 3）-CH 2] d [OCH 2 CH 2] CH 2）4] fOR 4（III），其中X，R 1和R 2具有上述含义，R 3相同或不同，为氢原子或具有R的含义，R 4具有平均 或表示式-C（= O）-R，-R2NR23，-NR3R2-，-R2NR23H + X，D，e和f的基团为0至200的整数，条件是 总和d + e + f> / = 1，B包含每个聚合物分子中至少一个式（III）的基团。

    Polysiloxanes containing heterocyclic functions, their preparation and use
    8.
    发明授权
    Polysiloxanes containing heterocyclic functions, their preparation and use 失效
    含有杂环官能团的聚硅氧烷，其制备和用途

    公开(公告)号：US5969077A

    公开(公告)日：1999-10-19

    申请号：US163526

    申请日：1998-09-30

    申请人： Robert Schrock ,  Jochen Dauth ,  Bernward Deubzer

    发明人： Robert Schrock ,  Jochen Dauth ,  Bernward Deubzer

    IPC分类号： C08G77/388 ,  C08G77/54 ,  D06M15/643 ,  C08G77/12

    CPC分类号： C08G77/54 ,  C08G77/388 ,  D06M15/6436

    摘要： Organosiloxane compounds bearing nitrogen-containing heterocycles, in which the heterocycles are bonded to a silicon atom via divalent radicals containing a unit of the general formula (I) ##STR1## in which E is one of the radicals --O--, --S--, --NR.sup.1 -- or --N.dbd., where R and R.sup.1 are each a C.sub.1 - to C.sub.20 -hydrocarbon radical which is optionally substituted by halogen, amine, ammonium or mercapto groups and may optionally be interrupted by groups chosen from --C(O)--, --C(O)--O--, --C(O)--NR.sup.3 --, --NR.sup.3 --, --O--, --S--, and--N.dbd. is a constituent of a heterocycle,can be used for the treatment of textile fibers, textile sheet materials and leather and as stabilizers in synthetic polymers.

    摘要翻译： 带有含氮杂环的有机硅氧烷化合物，其中杂环通过含有通式（I）的单元的二价基团键合到硅原子上，其中E是基团-O - ， - S-，-NR1- 或-N =，其中R和R 1各自为任选被卤素，胺，铵或巯基取代的C 1 -C 20烃基，并且可以任选地被选自-C（O） - ， - C （O）-O - ， - C（O）-NR 3 - ， - NR 3 - ， - O - ， - S-和-N =是杂环的成分，可用于纺织纤维，织物 片材和皮革以及合成聚合物中的稳定剂。

    Organosilicon compounds containing amino groups, their preparation and their use
    9.
    发明授权
    Organosilicon compounds containing amino groups, their preparation and their use 失效
    含有氨基的有机硅化合物，其制备及其用途

    公开(公告)号：US5840951A

    公开(公告)日：1998-11-24

    申请号：US888405

    申请日：1997-07-07

    申请人： Thomas Hierstetter ,  Jochen Dauth ,  Joerg Pfister ,  Bernward Deubzer

    发明人： Thomas Hierstetter ,  Jochen Dauth ,  Joerg Pfister ,  Bernward Deubzer

    IPC分类号： C08G77/388 ,  C08G77/54 ,  C07F7/10

    CPC分类号： C08G77/54

    摘要： Organosilicon compounds containing amino groups, their preparation and their use Organosilicon compounds containing amino groups and comprising a) siloxane units of the formula R.sub.a Si(OR.sup.1).sub.b O.sub.(4-a-b)/2 (I) and b) at least one unit per molecule selected from the group consisting of units of the formulae AR.sub.C SiO.sub.(4-c-1)/2 (II), O.sub.(4-c-1)/2 R.sub.C Si--A.sup.1 --R.sub.C SiO.sub.(4-c-1)/2 (III) or ##STR1## where R is an identical or different hydrocarbon radical which has from 1 to 18 carbon atoms, optionally substituted by halogen atoms, alkoxy groups or hydroxy groups where the hydrocarbon radical is optionally interrupted by oxygen atoms, R.sup.1 is an identical or different alkyl radical which is optionally interrupted by oxygen atoms, a is 0, 1, 2 or 3 and b is 0, 1, 2 or 3, with the proviso that the sum a+b is not greater than 3, and c is 0, 1 or 2, A is a radical of the formula --R.sup.2 R.sup.3.sub.z N(--CR.sup.4.sub.2 --R.sup.5).sub.(2-z) (V), A.sup.1 is a radical of the formula ##STR2## and A.sup.2 is a radical of the formula ##STR3## where z is 0 or 1, R.sup.2 is an identical or different alkylene radical having from 2 to 8 carbon atoms, or a radical of the formula ##STR4## R.sup.3 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.4 is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, R.sup.5 is a radical of the formulae --CR.sup.6 .dbd.CR.sup.6.sub.2, --C.tbd.CR.sup.6, where R.sup.6 is identical or different and is a hydrogen atom or an alkyl radical having from 1 to 8 carbon atoms, with the proviso that the organosilicon compound containing amino groups has at least one siloxane unit of formula (II) per molecule and at least one unit selected from the group consisting of units of formulae (III) and (IV) per molecule.

    摘要翻译： 含有氨基的有机硅化合物及其制备及其用途含有氨基的有机硅化合物，包含a）式RaSi（OR1）bO（4-ab）/ 2（I））的硅氧烷单元，b）每分子选择至少一个单元 由式ARCSiO（4-c-1）/ 2（II），O（4-c-1）/ 2RCSi-A1-RCSiO（4-c-1）/ 2（III）或 （IV）其中R是具有1至18个碳原子的相同或不同的烃基，任选地被卤素原子，烷氧基或羟基取代，其中烃基任选被氧原子中断，R 1是相同的 或任选被氧原子间隔的不同烷基，a是0,1,2或3，b是0,1,2或3，条件是和a + b不大于3，c是 0,1或2，A是式-R 2 R 3 z N（-CR 42 -R 5）（2-z）（V）的基团，A 1是下式的基团（VI），并且A 2是 式（VII）其中z为0或1， R2是具有2至8个碳原子的相同或不同的亚烷基，或者式III的基团是氢原子或具有1至8个碳原子的烷基，R4是氢原子或烷基 具有1至8个碳原子的基团，R 5是下式的基团-CR 6 = CR 62，-C 3 CON CR 6，其中R 6相同或不同，并且是氢原子或具有1至8个碳原子的烷基， 含有氨基的有机硅化合物每分子具有至少一个式（II）的硅氧烷单元和至少一个选自每个分子式（III）和（IV）的单元的单元的单元。