摘要:
The present invention relates to thermoplastic moulding compositions comprising unbranched, thermoplastic polyamide, a phosphinic or diphosphinic salt, a nitrogen-containing flame retardant combination and also at least one oxygen-containing, nitrogen-containing or sulphur-containing metal compound and also to the production and the use of the inventive moulding compositions for production of fibres, of foils and of mouldings of any type.
摘要:
This invention relates to substance mixtures for thermoplastic molding compositions, comprising A) polyamide and/or copolyamide, B) copolymers of at least one olefin and of at least one acrylate of an aliphatic alcohol, C) additives with chain-extending effect and D) impact modifiers and optionally also E) other additives and/or F) fillers and reinforcing materials. The invention further relates to processes for producing molding compositions of the invention and molded products or semifinished products which are produced from the substance mixtures of the invention, preferably by means of extrusion or blow molding of the molding compositions to be produced from the substance mixtures.
摘要:
The present invention relates to thermoplastic moulding compositions comprising unbranched, thermoplastic polyamide, a phosphinic or diphosphinic salt, a nitrogen-containing flame retardant combination and also at least one oxygen-containing, nitrogen-containing or sulphur-containing metal compound and also to the production and the use of the inventive moulding compositions for production of fibres, of foils and of mouldings of any type.
摘要:
Saturated, liquid, low molecular weight and low-viscosity isobutylene polymers terminally functionalized by special groups, which correspond to the following formula ##STR1## are produced by solution ozonolysis of high molecular weight isobutylene/diene copolymers containing diene monomers, stabilization of the products obtained after the ozone treatment by addition of peroxide decomposers and subsequent reduction with hydrogen in the presence of hydrogenation catalysts under pressures of 10 to 300 bar and at temperatures of 20.degree. to 300.degree. C., optionally in the presence of sulfur or amines or ammonia.
摘要:
Aromatic dicarboxylic acids of the formula ##STR1## in which R.sup.1, R.sup.2, m, n, and X have the meaning mentioned in the description,can be prepared from the bisphenols, on which they are based, of the formula ##STR2## if the bisphenols are first reacted to give the bissulphonates, the sulphonate groups are removed catalytically with H.sub.2 and the hydrocarbons obtained in this way are doubly acylated in a known manner and the acyl groups are oxidized to the carboxyl groups.Many of the aromatic dicarboxylic acids which can be prepared in this way are new.
摘要:
A process for producing a graft copolymer is disclosed. The graft copolymer, based on a rubber which contains phenolic OH groups and grafted with polycarbonate chains is produced under the conditions of the two-phase interfacial polycondensation. Also disclosed are gasoline resistant thermoplastic polycarbonate compositions containing the graft.
摘要:
A thermoplastic molding composition containing 1 to 99 parts by weight of aromatic polycarbonate or polyester carbonate and 1 to 99 parts by weight of at least one graft polymer prepared by solution polymerization is disclosed. The graft polymer is characterized in having rubber content of 20 to 50 wt. % and in that the average particle size of its rubber phase is 80 to 600 nm. The composition, which optionally contains additives, flameproofing agents and reinforcing agents, is characterized by its improved mechanical properties.
摘要:
The present invention provides flame-resistant polycarbonate moulding compositions with a concentration of alkali metal or alkaline earth metal salts and of silicon compounds and their preparation.
摘要:
Polyester and polyester carbonates corresponding to the following formula ##STR1## in which R.sup.1 to R.sup.4, o to r, n, a and b and also X.sup.1 and Y.sup.1 are as defined in the specification,may be obtained by interfacial condensation from bisphenols corresponding to the following formula. ##STR2## aromatic dicarboxylic acid chlorides corresponding to the following formula ##STR3## and phosgene. The new polyesters and polyester carbonates combine outstanding heat resistance and light stability. They may be used both as thermoplastic materials as such or as constituents of polymer blends or even as UV (light) stabilizers or as UV (light)-stabilizing coatings. Accordingly, they have degrees of polycondensation n in the range from 2 to 100.
摘要:
A process for concentrating polymers by evaporation is disclosed. The process entails (i) obtaining a mixture containing a polymer and volatile component, the volatile components being present in the mixture at an amount less than 20 wt. % relative to the weight of the mixture, and (ii) introducing the mixture in a downward direction under pressure through a plurality of nozzles arranged vertically and next to one another into a degassing container to form an extrudate. The volatile component contains at least one of residual monomers, oligomers and solvents, and the throughput of the mixture per nozzle is 0.3 to 2 kg/h. The vapor pressure of the volatile component of the extrudate is more than 2.5 bar, and the absolute pressure in the degassing container is 50 to 5000 Pa. The polymer prepared by the process is characterized in that it contains volatile components in an amount of less than 300 ppm.