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    Polycarbonate-ABS moulding materials
    1.
    发明授权
    Polycarbonate-ABS moulding materials 有权
    聚碳酸酯ABS成型材料

    公开(公告)号：US06417256B1

    公开(公告)日：2002-07-09

    申请号：US09509161

    申请日：2000-03-22

    申请人： Thomas Eckel ,  Dieter Wittmann ,  Ralph Ostarek ,  Richard Weider ,  Gisbert Michels

    发明人： Thomas Eckel ,  Dieter Wittmann ,  Ralph Ostarek ,  Richard Weider ,  Gisbert Michels

    IPC分类号： C08L6900

    CPC分类号： C08L51/04 ,  C08K5/523 ,  C08L69/00 ,  C08L69/005 ,  C08L2666/14 ,  C08L51/00

    摘要： A thermoplastic molding composition containing 1 to 99 parts by weight of aromatic polycarbonate or polyester carbonate and 1 to 99 parts by weight of at least one graft polymer prepared by solution polymerization is disclosed. The graft polymer is characterized in having rubber content of 20 to 50 wt. % and in that the average particle size of its rubber phase is 80 to 600 nm. The composition, which optionally contains additives, flameproofing agents and reinforcing agents, is characterized by its improved mechanical properties.

    摘要翻译： 公开了一种含有1-99重量份芳族聚碳酸酯或聚酯碳酸酯和1-99重量份至少一种通过溶液聚合制备的接枝聚合物的热塑性模塑组合物。 接枝聚合物的特征在于橡胶含量为20〜50wt。 ％，其橡胶相的平均粒径为80〜600nm。 任选地含有添加剂，防火剂和增强剂的组合物的特征在于其改进的机械性能。

    Process for producing ABS moulding compositions having a high rubber content
    3.
    发明授权
    Process for producing ABS moulding compositions having a high rubber content 失效
    具有高橡胶含量的ABS模塑组合物的制造方法

    公开(公告)号：US06482897B1

    公开(公告)日：2002-11-19

    申请号：US08907202

    申请日：1997-08-06

    申请人： Richard Weider ,  Gisbert Michels ,  Frank Wingler

    发明人： Richard Weider ,  Gisbert Michels ,  Frank Wingler

    IPC分类号： C08F27904

    CPC分类号： C08F279/04

    摘要： A process for producing impact-resistant moulding compositions, which is characterised in that a monomer mixture comprising 90 to 20 parts by weight of an aromatic monoalkenyl compound, 10 to 50 parts by weight of an ethylenically unsaturated nitrile, 0 to 30 parts by weight of other copolymerisable compounds is polymerised by a radical mechanism in the presence of 15 to 50 parts by weight, per 100 parts by weight of monomers, of a soluble, gel-free butadiene polymer, and in the presence of 50 to 200 parts by weight, per 100 parts by weight of monomers, of a solvent, wherein the solvent is selected from the group comprising an aliphatic (C1-C8) or cycloaliphatic alcohol, ketone, ether, ester, nitrile (A) or mixtures thereof or a mixture of (A) with an aliphatic (C4-C10), cycloaliphatic or aromatic hydrocarbon (B) in an A:B weight ratio of 100:0 to 30:70, and the polymerisation is conducted as far as a polymer content of the total mixture of 30 to 70% by weight, with thorough mixing and optionally with the subsequent addition of a regulator and initiator, so that the isolated thermoplastic moulding composition contains 20 to 40% by weight of butadiene polymer.

    摘要翻译： 一种耐冲击成型组合物的制造方法，其特征在于，含有90〜20重量份芳香族单链烯基化合物，10〜50重量份烯属不饱和腈，0〜30重量份其它 可共聚合的化合物通过自由基机理在每100重量份单体，每100重量份单体，可溶性，无凝胶的丁二烯聚合物存在下共聚合15至50重量份，并且在50至200重量份的存在下，每100份 单体重量的溶剂，其中溶剂选自脂族（C1-C8）或脂环族醇，酮，醚，酯，腈（A）或其混合物或（A）与 脂族（C 4 -C 10），脂环族或芳族烃（B），其A:B重量比为100:0至30:70，并进行聚合，只要总混合物的聚合物含量为30-70％ 重量，充分混合和选择 随后加入调节剂和引发剂，使得分离的热塑性模塑组合物含有20至40重量％的丁二烯聚合物。

    Saturated, liquid isobutylene polymers terminally functionalized by special groups
    6.
    发明授权
    Saturated, liquid isobutylene polymers terminally functionalized by special groups 失效
    饱和的液体异丁烯聚合物由特殊的基团末端官能化

    公开(公告)号：US5274182A

    公开(公告)日：1993-12-28

    申请号：US904646

    申请日：1992-06-26

    申请人： Richard Weider ,  Thomas Scholl

    发明人： Richard Weider ,  Thomas Scholl

    IPC分类号： C08F8/00 ,  C08F8/04 ,  C08F8/06 ,  C08F8/30 ,  C08F8/32 ,  C08F210/00 ,  C08F210/12 ,  C08J3/24 ,  C08L23/00 ,  C08L23/22 ,  C08L23/26 ,  C07C263/10 ,  C07C211/09 ,  C07C265/04 ,  C07C321/14

    CPC分类号： C08F8/04 ,  C08F8/06

    摘要： Saturated, liquid, low molecular weight and low-viscosity isobutylene polymers terminally functionalized by special groups, which correspond to the following formula ##STR1## are produced by solution ozonolysis of high molecular weight isobutylene/diene copolymers containing diene monomers, stabilization of the products obtained after the ozone treatment by addition of peroxide decomposers and subsequent reduction with hydrogen in the presence of hydrogenation catalysts under pressures of 10 to 300 bar and at temperatures of 20.degree. to 300.degree. C., optionally in the presence of sulfur or amines or ammonia.

    摘要翻译： 通过特殊基团末端官能化的饱和，液体，低分子量和低粘度异丁烯聚合物，其对应于下式通过溶液臭氧分解产生，所述高分子量异丁烯/二烯共聚物含有二烯单体，所得产物的稳定化 在通过加入过氧化物分解剂进行臭氧处理之后，随后在氢化催化剂存在下，在10-300巴的压力和20-300℃的温度下，任选在硫或胺或氨的存在下用氢还原。

    Process for the preparation of aromatic dicarboxylic acids and aromatic hydrocarbons
    7.
    发明授权
    Process for the preparation of aromatic dicarboxylic acids and aromatic hydrocarbons 失效
    制备芳族二羧酸和芳香烃的方法

    公开(公告)号：US5183926A

    公开(公告)日：1993-02-02

    申请号：US759794

    申请日：1991-09-13

    申请人： Richard Weider ,  Thomas Scholl

    发明人： Richard Weider ,  Thomas Scholl

    IPC分类号： C07C13/28 ,  C07C51/255 ,  C07C69/76 ,  C07C309/65

    CPC分类号： C07C309/65 ,  C07C13/28 ,  C07C51/255 ,  C07C69/76 ,  C07C2101/14

    摘要： Aromatic dicarboxylic acids of the formula ##STR1## in which R.sup.1, R.sup.2, m, n, and X have the meaning mentioned in the description,can be prepared from the bisphenols, on which they are based, of the formula ##STR2## if the bisphenols are first reacted to give the bissulphonates, the sulphonate groups are removed catalytically with H.sub.2 and the hydrocarbons obtained in this way are doubly acylated in a known manner and the acyl groups are oxidized to the carboxyl groups.Many of the aromatic dicarboxylic acids which can be prepared in this way are new.

    摘要翻译： 其中R 1，R 2，m，n和X具有说明书中提到的含义的式（I）的芳族二羧酸可由其所基于的双酚制备，具有下式：IMAGE 如果双酚首先反应得到双磺酸盐，用H2催化除去磺酸盐基团，以这种方式得到的烃以已知的方式进行双重酰化，酰基被氧化成羧基。 可以以这种方式制备的许多芳族二羧酸是新的。

    Polyester and polyester carbonate from terephthalic or isophthalic acid, phosgene and phenols with heat resistance and light stability
    10.
    发明授权
    Polyester and polyester carbonate from terephthalic or isophthalic acid, phosgene and phenols with heat resistance and light stability 失效
    来自具有耐热性和光稳定性的正癸酸或异辛酸，磷酸酯和酚醛的聚酯和聚碳酸酯

    公开(公告)号：US5110895A

    公开(公告)日：1992-05-05

    申请号：US566172

    申请日：1990-08-13

    申请人： Richard Weider ,  Dieter Arlt ,  Christian Leuschke ,  Thomas Scholl

    发明人： Richard Weider ,  Dieter Arlt ,  Christian Leuschke ,  Thomas Scholl

    IPC分类号： C08G63/672 ,  C08G63/185 ,  C08G63/19 ,  C08G63/193 ,  C08G63/64 ,  C08G63/682 ,  C08G63/688

    CPC分类号： C08G63/185 ,  C08G63/193 ,  C08G63/64

    摘要： Polyester and polyester carbonates corresponding to the following formula ##STR1## in which R.sup.1 to R.sup.4, o to r, n, a and b and also X.sup.1 and Y.sup.1 are as defined in the specification,may be obtained by interfacial condensation from bisphenols corresponding to the following formula. ##STR2## aromatic dicarboxylic acid chlorides corresponding to the following formula ##STR3## and phosgene. The new polyesters and polyester carbonates combine outstanding heat resistance and light stability. They may be used both as thermoplastic materials as such or as constituents of polymer blends or even as UV (light) stabilizers or as UV (light)-stabilizing coatings. Accordingly, they have degrees of polycondensation n in the range from 2 to 100.

    摘要翻译： 对应于以下公式的聚酯和聚酯碳酸酯：其中R1至R4，o至r，n，a和b以及X1和Y1如说明书中所定义，可以通过界面 来自对应于下式的双酚的缩合。 对应于下式的“IMAGE”和光气的芳族二羧酸氯化物。 新的聚酯和聚酯碳酸酯具有出色的耐热性和光稳定性。 它们既可以作为热塑性材料，也可以用作聚合物共混物的成分，甚至可以用作UV（光）稳定剂或UV（光）稳定涂料。 因此，它们的缩聚度n在2〜100的范围内。